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            Helel Dalel
            University of Sousse
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         U.R.E.E, Institut Supérieur des Sciences Appliquées et de Technologie de Sousse, 4003 Ibn Khaldoun, Sousse
                                                          Tunisia .
                         Email: *dalel.helel@enim.rnu.tn      **noureddine.Boukadida@issatso.rnu.tn
ABSTRACT
        The aim of this work is to study the mechanism of heat and mass transfer during drying process of an unsaturated porous
        medium having clay brick characteristics witch is placed in horizontal channel. The porous medium is submitted to a forced
        convection laminar flow. We particularly bring out the space time variability effect of heat and mass transfer coefficients on
        space-time evolution of temperature, water saturation and gas-pressure in the porous medium, in the solid-fluid interface and
        in the channel during the drying process.
                                                                     25
effect of liquid films when viscous effects are important in            convective drying of unsaturated porous media. They mainly
the film but not in the liquid saturated pores. It is shown that        showed the effect of that limit conditions on mechanism of
the overall drying time is greatly affected by the pore shape           convective drying of porous media.
and contact angle when film flows are important, the                        It should be kept in mind that during drying process heat
quantitative prediction of drying rate becomes very difficult           and mass transfer coefficients depend on water saturation of
because it depends on tiny details of the pore space geometry           the porous media interface. In order to bring out this effect
and is affected by possible changes in the local humidity               Boukadida et al. using the same equations system as
conditions. This contributes to explain why the accurate                described in [27] and by assuming that the lower surface of
prediction of drying rate still remains essentially an open             the channel is wet, made a preliminary study in which they
question, at least when the effect of films cannot be                   considered that saturated water vapour pressure at interface is
neglected.                                                              function of the wet bulb temperature and of the water
    In the porous media convective drying domain,                       saturation. So they determined evolution of average
Boukadida et al. [24] studied numerically two-dimensional               coefficients of heat and mass transfer with water saturation
heat and mass transfer during convective drying of porous               for different ambient temperatures. They obtained
media. The established code based on the Whitaker’s theory              correlations which are in the following form: ht=Σ4i=1AtiSi and
took into account the effect of gas pressure and permitted to           hm=Σ4i=1AmiSi where Ati and Ami are positive constants which
determine the space-time evolution of the medium's state                depend on limit conditions at the channel entrance.
variables (temperature, gas pressure, and water saturation).                Later, inspired by Whitaker theory and by using
The choice of average heat and mass transfer coefficients               BICGSTB (Bi-Conjugate Gradient Stabilised) method [29-
was based on analogy between heat and mass transfer. In                 30], Mobarki et al. [31-33] developed a mathematical model
[25], they extended their work by investigating a numerical             governing heat and mass transfer during convective and
study to determine effects of the surrounding air's                     convective-radiative drying of unsaturated porous media.
(temperature, water-vapour concentration, etc.) on drying               The main purpose of this model was to resolve many
kinetic and on the space-time evolution of the medium's state           numerical problems encountered at the moment of the
variables.                                                              appearance of the drying front when the drying operation is
    Using by default the analogy between heat and mass                  conducted at high temperature and high vapour-water
transfer presents insufficiency because it can not really and           concentration. By using correlations of local or average heat
precisely describe the real transport phenomena during drying           and mass transfer coefficients that were brought out by
process in space and time.                                              Boukadida et al. in case where the heat radiation transfer is
    Basing on this, in the same way, Boukadida et al. have              taken into account or by assuming that the lower interface is
established a second code permitting to study two                       wet [27], they presented [31-33] effects of ambient
dimensional coupled heat and mass transfer in laminar forced            temperature, ambient vapour-water concentration, interfacial
convection flow inside a horizontal channel [26]. They                  saturation and effects of variability of fluid thermo-physical
brought out the domain of the validity of analogy between               properties on drying process. They depicted that the
heat and mass transfer and they showed that the analogy is              interfacial liquid saturation can have a slight effect on the
valid only for low ambient temperature and low water-vapour             evolution of medium’s temperature and gas pressure while
concentration. Many other results were obtained as the effect           the global drying time is nearly not affected. This slight
of radiation on the different state variables (temperature,             effect mainly appears in hygroscopic domain especially for
water-vapour concentration, etc) and on local heat and mass             high ambient temperature. They also studied the effect of
transfer coefficients and their variations with ambient state           surrounding temperature lower or higher than the inversion
variables. These local coefficients are calculated by                   temperature and the effect of the variables fluid thermo-
considering that lower surface of the channel is assumed to             physical properties on the space time evolution of medium’s
be at the wet bulb temperature which depends mainly on the              temperature and gas pressure for different ambient
ambient temperature, ambient gas pressure and water-vapour              temperature, gas pressure and vapour-water concentration.
concentration. The lower surface was not considered as a                Principal results showed that the effect of fluid thermo-
surface of a porous media in which the drying mechanism is              physical properties dependence on temperature and on the
considered. Then the considered saturated water vapour                  gas pressure affects drying process and modifies in certain
pressure at interface is that of a plane surface.                       cases the temperature and gas pressure profiles.
    In their other paper [27], they studied the effect of the               However an insufficiency is noted in the fact that the
radiation heat transfer on inversion temperature in the case of         used correlations are independent of time. In reality local
water evaporation into two-dimensional laminar flow inside              coefficients of heat and mass transfer principally depend on
the channel. Their results showed that gas pressure and                 space time evolution of interfacial temperature which is
velocity affect inversion temperature and the inclusion of              linked to the thermal, dynamic and mass evolution variables
radiation effect decreases the inversion temperature.                   in the boundary layers and on initial thermal and liquid
                                                                        volume fraction in the porous media for every step in the
    Believing that the use of average heat and mass transfer            time. They also depend on physical properties of the porous
coefficient can not allow a precise idea of the real mechanism          media and on thermo-physical properties of the drier fluid.
of space time drying process, then by fitting space-evolutions              The present study which extends the previous works
of local coefficients of heat and mass transfer that were               consists in studying numerically the effect of thermal, mass
determined in reference [26], Boukadida et al. obtained                 and dynamic boundaries layers on mechanism of heat and
correlations in the form: htx=atxb and hmx=amxb where x is
                                  t               m
                                                                        mass transfer during drying process of flat plat having a clay
the axial coordinate and at, bt, am and bm are positive                 brick characteristics (table 1) via the space-time variability
constants. These correlations were injected as thermal and              effect of heat and mass transfer coefficients. For each time
mass limit conditions [28] in the first code which permits to           step the different state variables inside and outside the porous
simulate mechanism of heat and mass transfer during                     medium are determined and local coefficients of heat and
                                                                   26
mass transfer are deduced. We principally describe the space                   • Heat equation
time evolution of the temperature, the water saturation and                          ∂T    ∂T  ∂  ∂T                           ∂T ∂C v
the pressure fields in particular in the porous medium. The                ρg c pg  u  +v     =  λ g  + ρg D v c pv − c pa              (                 )                (3)
space time evolution of local coefficients of heat and mass                          ∂x    ∂y  ∂y  ∂y                          ∂y ∂y
transfer and of the interfacial temperature and water                      where c pg = (1 − C v )c pa + C v c pv
saturation will also be presented and analysed.                                •    Species equation
                                                                                   ∂C v       ∂C   ∂           ∂C v 
2. BASIC FORMULATIONS                                                       ρg u        + ρg v v =     ρg D v                                                                   (4)
                                                                                    ∂x         ∂y  ∂y           ∂y 
2.1 Position of the problem
                                                                           2.2.2 In the porous media
    The system considered in this work is composed of                             Mass conservation equations
unsaturated porous plate composed of an inert and rigid solid
                                                                                Liquid phase
phase, a liquid phase (pure water) and a gas phase which
contains both air and water vapour. The two vertical faces of              Assuming that liquid density is constant, the mass
the porous plate as well as the low face are assimilated to                conservation equation of the liquid phase is:
adiabatic and impervious faces. The high face of the plate                            ∂εl             mɺ
                                                                                          + ∇ Vl = − v                   (5)
represents the permeable interface of the horizontal plane                            ∂t              ρl
channel when is exposed of a hot air out-flow with fixed
characteristics (velocity, temperature and humidity). The                  where m ɺ v is the mass rate of evaporation and                                                  ε l is the
geometrical configuration used for the slab is shown in                    volume fraction of the liquid phase.
figure1.                                                                        Gas phase
              y
             To
              BB
                                                                           For this phase, the average density ρ g                                          is not constant, the
Air flow C vo  BB                        Channel       E                   mass conservation equation is given by:
             P go
                                                                                   ∂ ρg
              BB
             Uo                           L
                                                                                         + ∇ ρg Vg  = m
                   BB   BB
                                                                                                  g
                                                                                                             ɺv                                                                    (6)
                                                                                     ∂t                 
                                       Porous Medium   ℓ                                   Vapour phase
                                                            x
                                                                                            ∂ ρv
                                                                                                ∂t
                                                                                                                   (
                                                                                                              + ∇ ρv
                                                                                                                        g
                                                                                                                                  )
                                                                                                                             Vv = m
                                                                                                                                  ɺv                                               (7)
                                                                      27
       Energy conservation equation                                              (ρ   l
                                                                                           l
                                                                                               Vl + ρ v
                                                                                                             g
                                                                                                                  Vv) =h (ρ  y       mx   v
                                                                                                                                               g
                                                                                                                                                    − ρv 0   )       (13)
∂
∂t
    (             )
                        l             g         
     ρc p T + ∇  ρ l c pl Vl + ∑ ρ k c pk Vk  T  =                          λ eff
                                                                                           ∂T
                                                                                                    + ∆H vap      (ρ V ) =h
                                                                                                                         l
                                                                                                                                               (T      − T       )   (14)
                              k =a,v                                                     ∂y
                                                                                                                     l           l   y    tx       o
∆H vap is the latent heat of vaporization at temperature T(K):                    heat and mass transfer, determined by resolution of boundary
                       (         )
                                                                                  layer equations.
∆H vap = ∆H ovap − c pv − c pl T where ∆H ovap is the latent                      The pressure of gas on surfaces of exchange is equal to the air
heat of vaporization at temperature T = 0 K.                                                            g
                                                                                  pressure: Pg              = Pg 0
 ρc p is the constant pressure heat capacity of the porous
                                                                                  - The equilibrium vapour pressure is a function of the
media given by : ρc p = ρs c ps + ρl cpl + ρ v c pv + ρa c pa                     temperature and the liquid saturation:
                                                                                                    2σM v 
where ρs c ps , ρl c pl , ρv c pv and ρa c pa are respectively                        Pv = Pvs exp −                                       (15)
the mass heat capacity at constant pressure of the solid,                                           rRρT 
liquid, vapour and air.                                                           Where Pvs is the saturating vapour pressure at interface, given
                                                                                  by:
                                                                                   Pvs = 10 5 exp(65.832 − 8.2 ln(Tint ) + 5.71710 −3 Tint −
2.3 Initial and boundary conditions                                                                                                          7235.46
                                                                                                                                               Tint
2.3.1 Initial conditions                                                           r is the ray of curvature that depends on the saturation and
                                                                                   σ is the superficial tension.
Initially (t=0), the temperature, the gas pressure and the liquid
saturation are uniform inside the porous medium.                                  3. NUMERICAL RESOLUTION
2.3.2 Boundary conditions
                                                                                      For the fluid in the channel the system of equation is
• For the fluid in the channel                                                    solved numerically by the method of a finite differences
- At the entry of the channel, the temperature, the pressure                      scheme. The numerical resolution with this method consists
and the water-vapour concentration of the free ambient flow                       in transforming the system of equations in an algebraic
are constant and uniform.                                                         equation system. The resolution takes place plan by plan in
- Assuming that the gas-water interface is semi-permeable,                        the sense of the out flow. The mesh [26] considered in the
the velocity gas phase at the interface is written as:                            channel is regular and rectangular one with 180 nodes in the
               D v ∂C v                                                           x-direction and 180 nodes in the y-direction. The unknown
 v g int = −                                             (11)                     variables (temperature, vapour-water concentration, velocity
             1 − C v ∂y
                                                                                  and gas pressure) at column k+1 are calculated using the
- The longitudinal component of the velocity at the interface                     know variables of column k. For the porous medium the
is equal zero:                                                                    equations system is numerically solved by a finite volume
For 0<x<L and y = ℓ :                       u=0                                   method based on the control domain notion as described by
- At the upper surface of the channel, the velocity of the gas                    Patankar [35]. In our case, we considered a regular mesh
mixture must respect the condition of adhesion:                                   with 180 nodes in the x-direction and 24 nodes in the y-
For 0< x <L and y = E + ℓ :           u=0; v=0                                    direction. For more details concerning the numeric model,
- The local interfacial evaporating mass flux which is                            the method of resolution and the thermo-physical properties
evaluated by the following equation:                                              of the fluid, the reader can refer to [25,35].
                               ρ D ∂C v 
                     ɺ vx = −  g v
For 0 ≤ Cv(x,0) < 1: m                                               (12)        4. RESULTS AND DISCUSSIONS
                              1 − C v ∂y  y      = 0
T (x,E+ℓ) = T0.
• For the porous medium                                                              Figure 2 shows evolution of temperature, water-vapour
- On the adiabatic and impervious sides, the mass and heat                        concentration, gas density, longitudinal         and vertical
                                                                                  velocities in the transverse direction of the channel. These
fluxes are equal zero:
                                                                                  evolutions are drawn in a representative case characterized
For x= 0, x=L and 0 ≤ y ≤ ℓ :                                                     by To= 70°C, Cvo=10-3, U0=0.2m.s-1, Pgo=1atm, Sini = 40%
                 ∂ T                                                              and Tini= 15°C.
         λ eff         = 0; Vv       = 0; Vg       = 0; Vl       =0                  At a given time (figure 2-a), the temperature that is
                 ∂x              x             x             x
                                                                                  minimal at the interface fluid-porous medium, increases
For y=0 and 0 ≤ x ≤ L :                                                           according to the height of the channel and tends to reach the
                 ∂ T                                                              ambient temperature (70°C). This increase of the interfacial
         λ eff         = 0; Vv       = 0; Vg       = 0; Vl       =0               temperature tends to decrease the boundary layer inside the
                  ∂y             y             y             y
                                                                                  channel; it depends on parameters as the drying phase of
- On the permeable side (y=ℓ), heat and mass fluxes can be                        porous medium, the initial saturation, the initial temperature
written as follows:                                                               of the porous medium and the regime of flow, etc. The
                                                                                  evolution of Tint in x=L/2 at different times (45°C for t=84h
                                                                                  and 61°C for t=168h) explains that the interface in this point
                                                                             28
   is dry. The vapour concentration (Figure 2-b) is maximum at                                                                                                                Tint(°C)                                                          Sint(%)
   the interface and decreasing according to the height of the                                                                                                                                                             t=168h                                                                 t=168h
                                                                                                                                                                                                                           t=84h                                                                  t=84h
   channel until the ambient vapour-water concentration (10-3).                                                                                                                      80
                                                                                                                                                                                                                           t=10mn                                                                 t=10mn
                                                                                                                                                                                                                                                    40
   The interface concentration decreases according to the time
                                                                                                                                                                                     60
   and this decrease is bound strongly to the interfacial
   saturation of water. The decrease of gas density according to
                                                                                                                                                                                                                                                    20
   the time (Figure 2-c) is owed to the increase of the interfacial                                                                                                                  40
                                                                                                                                                                                                                                                     0
                                                                                                                                                                                                                                         X(m)                                                                    X(m)
         T(°C)                                                                                                Cv                                                                          0.0     0.2       0.4     0.6    0.8     1.0                    0.0     0.2          0.4         0.6    0.8      1.0
           30
                                                                                                             0.004
                                                                                                                                                                               4.3 Space time evolution of local heat and mass transfer
           20
                                                                                                             0.002
                                                                                                                                                                               coefficients
           10
               0                                                                                                0
                   0.0         0.2         0.4         0.6          0.8         1.0    Y/E                           0.0   0.2     0.4        0.6    0.8     1.0   Y/E             Figures 4-a and 4-b illustrate the effect of drying time on
                                                 (a)                                                                                         (b)                               the longitudinal evolution of local heat (htx) and mass (hmx)
                                      ρg(Kg.m-3)                                                                                                                               transfer coefficients. These values are very important in the
                                                 1.3                                                                                                                           vicinity of the left surface exchange. Coefficients decrease
                                                                                                                t=168h
                                                                                                                                                                               and tend to be constant far from the side entrance. Their
                                                                                                                t=84h
                                                 1.2                                                            t=10mn
                                                                                                                                                                               variation according the time is bound strongly to the out flow
                                                                                                                                                                               regime, the ambient conditions, and the drying phase (first
                                                 1.1
                                                                                                                                                                               phase characterized by the increase or decrease of the
                                                                                                                                                                               medium temperature, isenthalpic phase, falling rate period).
                                                 1.0
                                                                                                                                                                                                      -2   -1                                                             -1
                                                                                                                                                                                           htx (w.m .K )                                                        hmx (m.s )
                                                        0.0               0.2          0.4        0.6           0.8        1.0    Y/E                                           24
                                                                                               (c)                                                                                                                                                1.0E-2
                                                                                                                                                                                20
U(m/s)                                                                                        V(m/s)                                                                                                                      t=168h                                                                        t=168h
                                                                                                                                                                                                                                                  8.0E-3
                                                                      t=168h                                                                         t=168h                     16                                        t=10mn                                                                        t=10mn
                                                                      t=84h                                                                          t=84h
  0.3                                                                 t=10mn                                                                         t=10mn                                                                                       6.0E-3
                                                                                                                                                                                12
                                                                                             1.0E-3
                                                                                                                                                                                                                                                  4.0E-3
                                                                                                                                                                                 8
  0.2                                                                                        5.0E-4
                                                                                                                                                                                 4                                                                2.0E-3
                                                                                             0.0E+0
  0.1
                                                                                                                                                                                                                                                  0.0E+0
                                                                                                                                                                                                                                         X(m)
                                                                                                                                                                                     0.0        0.2        0.4     0.6    0.8      1.0                      0.0     0.2         0.4         0.6    0.8     1.0 X(m)
                                                                                             -5.0E-4
                                                                                                                                                                                                                   (a)                                                                 (b)
  0.0
                                                                                      Y/E
                                                                                             -1.0E-3
                                                                                                                                                             Y/E
                                                                                                                                                                                Figure 4: Evolution of local heat and mass transfer
         0.0             0.2         0.4         0.6          0.8           1.0                        0.0           0.2   0.4         0.6     0.8     1.0
                                           (d)                                                                                   (e)                                            coefficients (htx(a), hmx(b)) with X at different times.
                                                                                                                                                                         29
evaporation front sensitively depends of the space time                 -The interfacial temperature and vapour-water concentration
evolution of transfer coefficients.                                     depend on the phase of drying.
    In case 2 where coefficients of heat and mass transfer are          -The variability of heat and mass transfer coefficients with
assumed to be constant, whatever the drying phase, at a given           time and with x-direction sensitively affects space time
time, for a given y-value, the space time evolution of state            temperature, pressure and water saturation profiles of the
variables are uniform along x-direction. The evaporation                porous medium during the drying process.
front has a straight line form.
4.4.1 Space time evolution of the temperature inside the
porous medium
    In figures 5-a and 5-b, we have presented the space time                             t=5mn
evolution of medium temperature for different times during
drying kinetic. In case 1, figure 5-a obviously shows that the
temperature of porous medium increases sensitively with time
according to x-and y-direction. This increase is more
important at the left top corner, this is due to the high values
of local coefficients of heat and mass transfer in this zone, it                         t=70h
is that part of porous medium which enters first in
hygroscopic domain. In case 2, all nodes of a same line in x-
direction and at given period have same value of variables
state (temperature, gas pressure and water saturation). In case
1, the evolution nature of porous medium state variables
sensitively depends on the space-time variability of htx and
hmx.                                                                                     t=168h
5. CONCLUSION
                                                                   30
                                                                        t=5mn
                               t=5mn
t=70h
t=70h
t=168h
t=168h
 Figure 6-a: Space time evolution of water saturation        Figure 6-b: Space time evolution of water saturation
 in the porous medium. (Case 1)                              in the porous medium. (Case 2)
t=5mn
t=70h
t=168h
Figure 7-a: Space time evolution of gas pressure in          Figure 7-b: Space time evolution of gas pressure in
the porous medium. (Case 1)                                  the porous medium. (Case 2)
                                                        31
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34. A. E. Scheidegger, the physics of flow through porous                    ε          porosity
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    1974.                                                                    µ          dynamic viscosity , Kg.m-1.s-1
35. S.V. Patankar, Numerical heat and fluid flow,                            ρ          density, Kg.m-3
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36. Dahlen R. J., 1962, A relation between heat and mass                     σ          superficial tension, N.m-1
    transfer coefficients verified for adiabatic evaporation                 Lower indices
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37. Katto Y., Koizumi and Yamaguchi T, Turbulent heat                        a          dry air
    transfer of a gas flow on an evaporation liquid surface,                 eff        effective
    Bull, J.S.M.E., 18, pp. 866-873,1975.                                    g          gas (air-water vapor mixture)
38. Lewis J. S., Heat transfer predictions from mass transfer                ini        initial
    measurements around a single cylinder in cross flow,                     int        interface
    Int. Journal of Heat and Mass Transfer., Vol. 14, pp.                    irr        irreducible
    325-329, 1971.                                                           l          liquid
                                                                             o          ambient
7. NOMENCLATURE                                                              resp.      respectively
                                                                             s          solid
Cv            vapour-water concentration                                     v          water vapour
cp            specific heat of fluid at constant pressure, J.kg-1.K-1        vs         saturated vapour
Dv            vapor diffusion coefficient into air, m2.s-1                   x          local
E             height of the channel
g             gravitational constant, m.s-2                                  Symbols
hmx           local mass transfer coefficient , m.s-1
hm            average mass transfer coefficient , m.s-1                                 average value
htx           local heat transfer coefficient, W.m-2.K-1
ht            average heat transfer coefficient, W.m-2.K-1
K             intrinsic permeability, m2
L             Channel length, m
M             molecular weight, Kg
P             pressure, Pa                                                   Porosity                        ε=0.26
Pc            capillary pressure, Pa                                         Density                         ρs=2600 Kg.m-3
R             universal gas constant, J.mole-1.K-1
r             curve ray                                                      Specific heat                   Cps=879 J.Kg-1.K-1
S             liquid saturation
                                                                             Thermal conductivity            λs=1.44 W.m-1.K-1
T             temperature, K
t             time, s                                                        Intrinsic permeability          K=2.510-4m2
u             longitudinal velocity, m.s-1
v             transverse velocity, m.s-1
m
ɺv            masse flow rate, Kg.m-2.s-1                                    Table 1: Physical characteristics of porous medium.
X              longitudinal direction, m
y              transverse direction, m
33