Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No.

2015/830

SAFETY DATA SHEET

Tankguard Storage Comp B

SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.1 Product identifier
Product name : Tankguard Storage Comp B
Product code : 739
Product description : Hardener.
Product type : Liquid.
Other means of : Not available.
identification
UFI : UF12-A0NC-A00T-P3T6
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use in coatings - Industrial use
Use in coatings - Professional use
See Annex to the Safety data sheet for additional information in the Exposure Scenario(s).
1.3 Details of the supplier of the safety data sheet
Jotun Paints (Europe) Ltd. Jotun A/S
Stather Road P.O.Box 2021
Flixborough, Scunthorpe 3202 Sandefjord
North Lincolnshire Norway
DN15 8RR
England Tel: + 47 33 45 70 00
Fax: +47 33 45 72 42
Tel: +44 17 24 40 00 00
Fax: +44 17 24 40 01 00 SDSJotun@jotun.no

1.4 Emergency telephone number

Contact NHS Direct; phone 0845 4647 or 111. Open 24/7.
1 739
^(ValidationDate) 1
Industrial applications, Professional applications, Used by spraying.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Acute Tox. 4, H302
Skin Corr. 1B, H314
Eye Dam. 1, H318
Skin Sens. 1, H317
STOT RE 2, H373 (kidneys)
Aquatic Chronic 2, H411
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Danger.

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 1/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 2: Hazards identification

Hazard statements : H302 - Harmful if swallowed.
H314 - Causes severe skin burns and eye damage.
H317 - May cause an allergic skin reaction.
H373 - May cause damage to organs through prolonged or repeated exposure.
(kidneys)
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements
General : Not applicable.
Prevention : P280 - Wear protective gloves, protective clothing and eye or face protection.
P273 - Avoid release to the environment.
P260 - Do not breathe vapour or spray.
P270 - Do not eat, drink or smoke when using this product.
Response : P391 - Collect spillage.
P304 + P310 - IF INHALED: Immediately call a POISON CENTER or doctor.
P301 + P310, P330, P331 - IF SWALLOWED: Immediately call a POISON
CENTER or doctor. Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353, P310 - IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. Immediately call a POISON CENTER
or doctor.
P363 - Wash contaminated clothing before reuse.
P302 + P352 - IF ON SKIN: Wash with plenty of water.
P333 + P313 - If skin irritation or rash occurs: Get medical advice or attention.
P305 + P351 + P338, P310 - IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor.
Storage : Not applicable.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national and international regulations.
Hazardous ingredients : formaldehyde, polymer with benzenamine, hydrogenated
m-xylene-alpha,alpha'-diamine
cyclohexanamine, 4,4'-methylenebis-
Supplemental label : Not applicable.
elements
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger : Not applicable.

2.3 Other hazards

Product meets the criteria : This mixture does not contain any substances that are assessed to be a PBT or a
for PBT or vPvB according vPvB.
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : None known.
not result in classification

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 2/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 3: Composition/information on ingredients

3.2 Mixtures : Mixture
Product/ingredient name Identifiers Weight % Regulation (EC) No. Type
1272/2008 [CLP]
formaldehyde, polymer with REACH #: ≥25 - ≤50 Acute Tox. 3, H301 [1]
benzenamine, hydrogenated 01-2119541673-38 Skin Corr. 1C, H314
EC: 603-894-6 Eye Dam. 1, H318
CAS: 135108-88-2 Skin Sens. 1, H317
STOT RE 2, H373 (kidneys)
(oral)
Aquatic Chronic 3, H412
benzyl alcohol REACH #: ≥25 - ≤48 Acute Tox. 4, H302 [1]
01-2119492630-38 Acute Tox. 4, H332
EC: 202-859-9 Eye Irrit. 2, H319
CAS: 100-51-6
Formaldehyde, oligomeric reaction REACH #: Polymer ≤10 Aquatic Acute 1, H400 (M=1) [1]
products with phenol and m- EC: 500-137-0 Aquatic Chronic 1, H410
phenylenebis(methylamine) CAS: 57214-10-5 (M=1)
m-xylene-alpha,alpha'-diamine REACH #: ≤6.8 Acute Tox. 4, H302 [1]
01-2119480150-50 Acute Tox. 4, H332
EC: 216-032-5 Skin Corr. 1B, H314
CAS: 1477-55-0 Eye Dam. 1, H318
Skin Sens. 1B, H317
Aquatic Chronic 3, H412
EUH071
cyclohexanamine, 4,4'- REACH #: ≤5 Acute Tox. 4, H302 [1]
methylenebis- 01-2119541673-38 Skin Corr. 1B, H314
EC: 217-168-8 Eye Dam. 1, H318
CAS: 1761-71-3 Skin Sens. 1B, H317
STOT RE 2, H373 (liver)
salicylic acid REACH #: <3 Acute Tox. 4, H302 [1]
01-2119486984-17 Eye Dam. 1, H318
EC: 200-712-3 Repr. 2, H361d
CAS: 69-72-7
See Section 16 for the full
text of the H statements
declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of
equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
[6] Additional disclosure due to company policy
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery
position and seek medical advice.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running
water for at least 15 minutes, keeping eyelids open. Seek immediate medical
attention.

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 3/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 4: First aid measures

Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do NOT induce vomiting.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
There are no data available on the mixture itself. The mixture has been assessed following the conventional method
of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2
and 3 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the
skin. Repeated or prolonged contact with the mixture may cause removal of natural fat from the skin, resulting in non-
allergic contact dermatitis and absorption through the skin. Ingestion may cause nausea, diarrhea and vomiting.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.

See toxicological information (Section 11)

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Recommended: alcohol-resistant foam, CO₂, powders, water spray.
media
Unsuitable extinguishing : Do not use water jet.
media

5.2 Special hazards arising from the substance or mixture

Hazards from the : Fire will produce dense black smoke. Exposure to decomposition products may
substance or mixture cause a health hazard.

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 4/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 5: Firefighting measures

Hazardous combustion : Decomposition products may include the following materials: carbon monoxide,
products carbon dioxide, smoke, oxides of nitrogen.

5.3 Advice for firefighters

Special protective actions : Cool closed containers exposed to fire with water. Do not release runoff from fire to
for fire-fighters drains or watercourses.
Special protective : Appropriate breathing apparatus may be required.
equipment for fire-fighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.
personnel Refer to protective measures listed in sections 7 and 8.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2 Environmental : Do not allow to enter drains or watercourses. If the product contaminates lakes,
precautions rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.

6.3 Methods and material : Contain and collect spillage with non-combustible, absorbent material e.g. sand,
for containment and earth, vermiculite or diatomaceous earth and place in container for disposal
cleaning up according to local regulations (see Section 13). Preferably clean with a detergent.
Avoid using solvents.

6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Prevent the creation of flammable or explosive concentrations of vapours in air and avoid vapour concentrations
higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition have
been excluded. Electrical equipment should be protected to the appropriate standard.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another.
Operators should wear antistatic footwear and clothing and floors should be of the conducting type.
Keep away from heat, sparks and flame. No sparking tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arising from the application
of this mixture. Avoid inhalation of dust from sanding.
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed.
Put on appropriate personal protective equipment (see Section 8).
Never use pressure to empty. Container is not a pressure vessel.
Always keep in containers made from the same material as the original one.
Comply with the health and safety at work laws.
Do not allow to enter drains or watercourses.
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air.

When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to
control particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed
respirator during the spraying process and until such time as the particulates and solvent vapour concentration has

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 5/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 7: Handling and storage

fallen below the exposure limits.
7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Keep away from: oxidising agents, strong alkalis, strong acids.
Additional information on storage conditions
Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight.
Keep away from sources of ignition. No smoking. Prevent unauthorised access. Containers that have been opened
must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)

Recommendations : Not available.
Industrial sector specific : Not available.
solutions

SECTION 8: Exposure controls/personal protection

The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the
Exposure Scenario(s).
8.1 Control parameters
Occupational exposure limits
No exposure limit value known.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to monitoring standards, such as
the following: European Standard EN 689 (Workplace atmospheres - Guidance for
the assessment of exposure by inhalation to chemical agents for comparison with
limit values and measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for the assessment
of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures
for the measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous substances will also be
required.
DNELs/DMELs
Product/ingredient name Exposure Value Population Effects
formaldehyde, polymer with benzenamine, Long term 0.2 mg/m³ Workers Systemic
hydrogenated Inhalation
Long term Dermal 2 mg/kg Workers Systemic
bw/day
Short term 2 mg/m³ Workers Systemic
Inhalation
Short term Dermal 6 mg/kg Workers Systemic
bw/day
benzyl alcohol Long term Oral 4 mg/kg General Systemic
bw/day population
Long term Dermal 4 mg/kg General Systemic
bw/day population
Long term 5.4 mg/m³ General Systemic
Inhalation population
Long term Dermal 8 mg/kg Workers Systemic
bw/day
Short term Oral 20 mg/kg General Systemic
bw/day population
Short term Dermal 20 mg/kg General Systemic
bw/day population
Long term 22 mg/m³ Workers Systemic
Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 6/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 8: Exposure controls/personal protection

Inhalation
Short term 27 mg/m³ General Systemic
Inhalation population
Short term Dermal 40 mg/kg Workers Systemic
bw/day
Short term 110 mg/m³ Workers Systemic
Inhalation
m-xylene-alpha,alpha'-diamine Long term 0.2 mg/m³ Workers Local
Inhalation
Long term Dermal 0.33 mg/ Workers Systemic
kg bw/day
Long term 1.2 mg/m³ Workers Systemic
Inhalation
cyclohexanamine, 4,4'-methylenebis- Short term Dermal 0.63 mg/ Workers Systemic
kg bw/day
Short term 1.5 mg/m³ Workers Systemic
Inhalation
Long term Dermal 0.21 mg/ Workers Systemic
kg bw/day
Long term 0.5 mg/m³ Workers Systemic
Inhalation
Long term Dermal 0.125 mg/ Workers Systemic
kg bw/day
Long term Oral 0.125 mg/ General Systemic
kg bw/day population
[Consumers]
Long term Oral 0.06 mg/ General Systemic
kg bw/day population
Long term Dermal 0.06 mg/ General Systemic
kg bw/day population
Long term Dermal 0.1 mg/kg Workers Systemic
bw/day
Long term 0.21 mg/m³ General Systemic
Inhalation population
Long term 1 mg/m³ Workers Systemic
Inhalation
salicylic acid Long term Oral 1 mg/kg General Systemic
bw/day population
Long term Dermal 1 mg/kg General Systemic
bw/day population
Long term Dermal 2.3 mg/kg Workers Systemic
bw/day
Short term Oral 4 mg/kg General Systemic
bw/day population
Long term 4 mg/m³ General Systemic
Inhalation population
Long term 5 mg/m³ Workers Local
Inhalation
Long term 5 mg/m³ Workers Systemic
Inhalation
PNECs
Product/ingredient name Compartment Detail Value Method Detail
benzyl alcohol Fresh water 1 mg/l -
Marine 0.1 mg/l -
Sewage Treatment 39 mg/l -
Plant
Fresh water sediment 5.27 mg/kg dwt -
Marine water sediment 0.527 mg/kg dwt -
Soil 0.456 mg/kg dwt -
cyclohexanamine, 4,4'-methylenebis- Fresh water 0.008 mg/l -
Marine 0.0008 mg/l -
Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 7/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 8: Exposure controls/personal protection

Sewage Treatment 80 mg/l -
Plant
Fresh water sediment 0.39 mg/kg dwt -
Marine water sediment 0.039 mg/kg dwt -
Soil 0.072 mg/kg dwt -

8.2 Exposure controls

Appropriate engineering : Provide adequate ventilation. Where reasonably practicable, this should be
controls achieved by the use of local exhaust ventilation and good general extraction. If
these are not sufficient to maintain concentrations of particulates and solvent
vapours below the OEL, suitable respiratory protection must be worn.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying to EN 166 should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: chemical splash goggles and/
or face shield. If inhalation hazards exist, a full-face respirator may be required
instead.
Skin protection
Gloves : There is no one glove material or combination of materials that will give unlimited
resistance to any individual or combination of chemicals.
The breakthrough time must be greater than the end use time of the product.
The instructions and information provided by the glove manufacturer on use,
storage, maintenance and replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.
Always ensure that gloves are free from defects and that they are stored and used
correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical
damage and poor maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.
Wear suitable gloves tested to EN374.
Recommended, gloves(breakthrough time) > 8 hours: Viton®, 4H, neoprene
May be used, gloves(breakthrough time) 4 - 8 hours: butyl rubber, nitrile rubber, PVC

For right choice of glove materials, with focus on chemical resistance and time of
penetration, seek advice by the supplier of chemical resistant gloves.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.
Body protection : Personnel should wear antistatic clothing made of natural fibres or of high-
temperature-resistant synthetic fibres.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : If workers are exposed to concentrations above the exposure limit, they must use a
respirator according to EN 140. Use respiratory mask with charcoal and dust filter
when spraying this product, according to EN 14387 (as filter combination A2-P2). In
confined spaces, use compressed-air or fresh-air respiratory equipment. When use
of roller or brush, consider use of charcoalfilter.

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 8/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 8: Exposure controls/personal protection

Environmental exposure : Do not allow to enter drains or watercourses.
controls

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state : Liquid.
Colour : Colourless.
Odour : Characteristic.
Odour threshold : Not applicable.
pH : Not applicable.
Melting point/freezing point : Not applicable.
Initial boiling point and : Lowest known value: 205.3°C (401.5°F) (benzyl alcohol). Weighted average:
boiling range 230.7°C (447.3°F)
Flash point : Closed cup: 100°C
Evaporation rate : 0.007 (benzyl alcohol) compared with butyl acetate
Flammability (solid, gas) : Not applicable.
Upper/lower flammability or : 1.3 - 13%
explosive limits
Vapour pressure : Highest known value: 0.007 kPa (0.05 mm Hg) (at 20°C) (benzyl alcohol).
Weighted average: 0.003 kPa (0.02 mm Hg) (at 20°C)
Vapour density : Highest known value: 3.7 (Air = 1) (benzyl alcohol).
Density : 1.07 g/cm³
Solubility(ies) : Insoluble in the following materials: cold water and hot water.
Partition coefficient: n-octanol/ : Not available.
water
Auto-ignition temperature : Lowest known value: 300°C (572°F) (cyclohexanamine, 4,4'-methylenebis-).
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C): >20.5 mm2/s (>20.5 cSt)
Explosive properties : Not available.
Oxidising properties : Not available.

9.2 Other information

No additional information.

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : Stable under recommended storage and handling conditions (see Section 7).
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition
products.
10.5 Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.
10.6 Hazardous : Decomposition products may include the following materials: carbon monoxide,
decomposition products carbon dioxide, smoke, oxides of nitrogen.

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 9/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 11: Toxicological information

11.1 Information on toxicological effects
There are no data available on the mixture itself. The mixture has been assessed following the conventional method of
the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2 and 3
for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the
skin. Repeated or prolonged contact with the mixture may cause removal of natural fat from the skin, resulting in non-
allergic contact dermatitis and absorption through the skin. Ingestion may cause nausea, diarrhea and vomiting.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
formaldehyde, polymer with LD50 Oral Rat 300 mg/kg -
benzenamine, hydrogenated
benzyl alcohol LD50 Oral Rat 1230 mg/kg -
m-xylene-alpha,alpha'- LD50 Oral Rat 980 mg/kg -
diamine
Acute toxicity estimates
Route ATE value
Oral 544.51 mg/kg
Inhalation (vapours) 24.64 mg/l
Irritation/Corrosion
Product/ingredient name Exposure Species Score Exposure Observation
benzyl alcohol Eyes - Mild irritant Mammal - - - -
species
unspecified
m-xylene-alpha,alpha'- Eyes - Severe irritant Rabbit - 24 hours 50 -
diamine µg
Skin - Severe irritant Rabbit - 24 hours 750 -
µg
cyclohexanamine, 4,4'- Eyes - Severe irritant Rabbit - 24 hours 10 -
methylenebis- microliters
salicylic acid Skin - Mild irritant Mammal - - - -
species
unspecified
Eyes - Mild irritant Mammal - - - -
species
unspecified
Sensitisation
Product/ingredient name Route of Species Result
exposure
m-xylene-alpha,alpha'- skin Mammal - species Sensitising
diamine unspecified
cyclohexanamine, 4,4'- skin Mammal - species Sensitising
methylenebis- unspecified
Mutagenicity
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Reproductive toxicity

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 10/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 11: Toxicological information

Product/ingredient name Maternal Fertility Developmental Species Dose Exposure
toxicity toxicity
salicylic acid - - Positive Rat Oral: 150 -
mg/kg
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Specific target organ toxicity (single exposure)
Based on available data, the classification criteria are not met.
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of Target organs
exposure
formaldehyde, polymer with benzenamine, hydrogenated Category 2 oral kidneys
cyclohexanamine, 4,4'-methylenebis- Category 2 - liver
Aspiration hazard
Based on available data, the classification criteria are not met.
Other information : None identified.

SECTION 12: Ecological information

12.1 Toxicity
There are no data available on the mixture itself.
Do not allow to enter drains or watercourses.

The mixture has been assessed following the summation method of the CLP Regulation (EC) No 1272/2008 and is
classified for eco-toxicological properties accordingly. See Sections 2 and 3 for details.
Product/ingredient name Result Species Exposure
Formaldehyde, oligomeric Acute LC50 25.9 mg/l Fish 96 hours
reaction products with
phenol and m-phenylenebis
(methylamine)
m-xylene-alpha,alpha'- Acute EC50 12 mg/l Algae 72 hours
diamine
cyclohexanamine, 4,4'- Acute EC50 6.84 mg/l Daphnia 48 hours
methylenebis-
Acute IC50 140 mg/l Algae 72 hours
Acute LC50 46 mg/l Fish 96 hours
salicylic acid Acute LC50 32 μg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Chronic NOEC 1 mg/l Fresh water Daphnia - Daphnia longispina - 21 days
Neonate
This material is toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability

Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
benzyl alcohol - - Readily
cyclohexanamine, 4,4'- - - Not readily
methylenebis-

12.3 Bioaccumulative potential

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 11/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 12: Ecological information

Product/ingredient name LogPow BCF Potential
formaldehyde, polymer with - 209 to 219 low
benzenamine, hydrogenated
benzyl alcohol 0.87 <100 low
m-xylene-alpha,alpha'- 0.18 2.69 low
diamine
cyclohexanamine, 4,4'- 2.03 - low
methylenebis-
salicylic acid 2.21 to 2.26 - low

12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction.
Hazardous waste : Yes.
Disposal considerations : Do not allow to enter drains or watercourses.
Dispose of according to all federal, state and local applicable regulations.
If this product is mixed with other wastes, the original waste product code may no
longer apply and the appropriate code should be assigned.
For further information, contact your local waste authority.
European waste catalogue (EWC)
The European Waste Catalogue classification of this product, when disposed of as waste, is:
Waste code Waste designation
08 01 11* Waste paint and varnish containing organic solvents or other dangerous substances

Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Disposal considerations : Using information provided in this safety data sheet, advice should be obtained from
the relevant waste authority on the classification of empty containers.
Empty containers must be scrapped or reconditioned.
Dispose of containers contaminated by the product in accordance with local or
national legal provisions.

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 12/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 13: Disposal considerations

Result European waste catalogue (EWC)
CEPE Guidelines 15 01 10* packaging containing residues of or contaminated by
hazardous substances
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information

ADR/RID ADN IMDG IATA
14.1 UN number UN2735 UN2735 UN2735 UN2735

14.2 UN proper Polyamines, liquid, Polyamines, liquid, Polyamines, liquid, Polyamines, liquid,
shipping name corrosive, n.o.s. (m- corrosive, n.o.s. (m- corrosive, n.o.s. (m- corrosive, n.o.s. (m-
xylene-alpha,alpha'- xylene-alpha,alpha'- xylene-alpha,alpha'- xylene-alpha,alpha'-
diamine) diamine) diamine). Marine diamine)
pollutant
(Formaldehyde,
oligomeric reaction
products with phenol
and m-phenylenebis
(methylamine))
14.3 Transport 8 8 8 8
hazard class(es)

14.4 Packing II II II II
group
14.5 Yes. Yes. Yes. Yes. The
Environmental environmentally
hazards hazardous substance
mark is not required.
Additional information
ADR/RID : The environmentally hazardous substance mark is not required when transported in
sizes of ≤5 L or ≤5 kg.
Hazard identification number 80
Tunnel code (E)
ADN : The environmentally hazardous substance mark is not required when transported in
sizes of ≤5 L or ≤5 kg.
IMDG : The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Emergency schedules F-A, S-B
Segregation Group: 18 - Alkalis
IATA : The environmentally hazardous substance mark may appear if required by other
transportation regulations.

14.6 Special precautions for : Transport within user’s premises: always transport in closed containers that are
user upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

14.7 Transport in bulk : Not applicable.

according to IMO
instruments

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 13/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Other EU regulations
VOC : Not available.
VOC for Ready-for-Use : Not available.
Mixture
Europe inventory : At least one component is not listed.
Ozone depleting substances (1005/2009/EU)
Not listed.
Prior Informed Consent (PIC) (649/2012/EU)
Not listed.
Seveso Directive
This product may add to the calculation for determining whether a site is within the scope of the Seveso Directive on
major accident hazards.
National regulations
Industrial use : The information contained in this safety data sheet does not constitute the user’s
own assessment of workplace risks, as required by other health and safety
legislation. The provisions of the national health and safety at work regulations apply
to the use of this product at work.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

15.2 Chemical safety : Not applicable.

assessment

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 14/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 16: Other information

Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Acute Tox. 4, H302 Calculation method
Skin Corr. 1B, H314 Calculation method
Eye Dam. 1, H318 Calculation method
Skin Sens. 1, H317 Calculation method
STOT RE 2, H373 (kidneys) Calculation method
Aquatic Chronic 2, H411 Calculation method
Full text of abbreviated H statements
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated
exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH071 Corrosive to the respiratory tract.
Full text of classifications [CLP/GHS]
Acute Tox. 3 ACUTE TOXICITY - Category 3
Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Acute 1 SHORT-TERM (ACUTE) AQUATIC HAZARD - Category 1
Aquatic Chronic 1 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 1
Aquatic Chronic 2 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 2
Aquatic Chronic 3 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 3
Eye Dam. 1 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1
Eye Irrit. 2 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2
Repr. 2 REPRODUCTIVE TOXICITY - Category 2
Skin Corr. 1B SKIN CORROSION/IRRITATION - Category 1B
Skin Corr. 1C SKIN CORROSION/IRRITATION - Category 1C
Skin Sens. 1 SKIN SENSITISATION - Category 1
Skin Sens. 1B SKIN SENSITISATION - Category 1B
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY - REPEATED
EXPOSURE - Category 2
Date of printing : 29.03.2022
Date of issue/ Date of : 29.03.2022
revision
Date of previous issue : 16.04.2020
Version : 2
Notice to reader
Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 15/18
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Tankguard Storage Comp B

SECTION 16: Other information

The information in this document is given to the best of Jotun's knowledge, based on laboratory testing and
practical experience. Jotun's products are considered as semi-finished goods and as such, products are
often used under conditions beyond Jotun's control. Jotun cannot guarantee anything but the quality of the
product itself. Minor product variations may be implemented in order to comply with local requirements.
Jotun reserves the right to change the given data without further notice.

Users should always consult Jotun for specific guidance on the general suitability of this product for their
needs and specific application practices.

If there is any inconsistency between different language issues of this document, the English (United
Kingdom) version will prevail.

Date of issue/Date of revision : 29.03.2022 Date of previous issue : 16.04.2020 Version :2 16/18
 Annex

Tankguard Storage Comp B

Exposure Scenario: Use in coatings - Industrial use
Sector of Use : Industrial use
Process Category : PROC05 PROC07 PROC08a PROC10
Environmental release category(ies) : ERC4

Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by
brush, spray by hand or similar methods) and equipment cleaning.

Operational conditions and risk management measures

Control of worker exposure
Frequency and duration of use : Covers daily exposures up to 8 hours
General - Operational conditions : Assumes use at not more than 20°C above ambient temperature. Assumes a good basic standard of
occupational hygiene is implemented
General - Risk management measures : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.
Wear suitable coveralls to prevent exposure to the skin. Use suitable eye protection. See Section 8
for information on appropriate personal protective equipment.

Type of activity or process Risk management measures

Preparation of material for application : Provide extract ventilation to points where emissions occur.
Roller, spreader, flow application : Provide extract ventilation to points where emissions occur.
Spraying - Manual : Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation
at openings. Wear a respirator conforming to EN140 with type A/P2 filter or better.

Control of environmental exposure

Organisational measures to prevent/limit : Prevent environmental discharge consistent with regulatory requirements.
release from site
Conditions and measures related to : External treatment and disposal of waste should comply with applicable local and/or national
external treatment of waste for disposal regulations. See Section 13 for additional waste treatment information.
Conditions and measures related to : External recovery and recycling of waste should comply with applicable local and/or national
external recovery of waste regulations.

Additional information
The exposure scenario for the mixture is based on the following substances:
REACH #: 01-2119492630-38
REACH #: 01-2119456619-26 (from Comp A)

Page: 17/18
 Annex

Tankguard Storage Comp B

Exposure Scenario: Use in coatings - Professional use
Sector of Use : Professional use
Process Category : PROC05 PROC08a PROC10 PROC11
Environmental release category(ies) : ERC8a ERC8d

Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by
brush, spray by hand or similar methods) and equipment cleaning.

Operational conditions and risk management measures

Control of worker exposure
Frequency and duration of use : Covers daily exposures up to 8 hours
General - Operational conditions : Assumes use at not more than 20°C above ambient temperature. Assumes a good basic standard of
occupational hygiene is implemented
General - Risk management measures : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training.
Wear suitable coveralls to prevent exposure to the skin. Use suitable eye protection. See Section 8
for information on appropriate personal protective equipment.

Type of activity or process Risk management measures

Preparation of material for application - : Provide extract ventilation to points where emissions occur. Avoid carrying out activities involving
Indoor exposure for more than 1 hour per day.
or
Provide extract ventilation to points where emissions occur. Wear a respirator conforming to EN140
with type A/P2 filter or better.
Preparation of material for application - : Ensure operation is undertaken outdoors. Avoid carrying out activities involving exposure for more
Outdoor than 1 hour per day.
or
Ensure operation is undertaken outdoors. Wear a respirator conforming to EN140 with type A/P2
filter or better.
Equipment cleaning and maintenance : Drain down system prior to equipment break-in or maintenance. Avoid carrying out activities involving
exposure for more than 4 hours per day.
Roller, spreader, flow application - Indoor : Provide extract ventilation to points where emissions occur. Wear a respirator conforming to EN140
with type A/P2 filter or better.
Roller, spreader, flow application - Outdoor : Ensure operation is undertaken outdoors. Wear a full-face respirator conforming to EN136 with Type
A/P2 filter or better.
Spraying - Manual - Indoor : Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation
at openings. Wear a full-face respirator conforming to EN136 with Type A/P2 filter or better.
Spraying - Manual - Outdoor : Ensure operation is undertaken outdoors. Wear a full-face respirator conforming to EN136 with Type
A/P2 filter or better.

Control of environmental exposure

Organisational measures to prevent/limit : Prevent environmental discharge consistent with regulatory requirements.
release from site
Conditions and measures related to : External treatment and disposal of waste should comply with applicable local and/or national
external treatment of waste for disposal regulations. See Section 13 for additional waste treatment information.
Conditions and measures related to : External recovery and recycling of waste should comply with applicable local and/or national
external recovery of waste regulations.

Additional information
The exposure scenario for the mixture is based on the following substances:
REACH #: 01-2119492630-38
REACH #: 01-2119456619-26 (from Comp A)

Page: 18/18