SAFT Safety Energy Storage
SAFT Safety Energy Storage
energy storage
Why safe operation of Li-ion
energy storage requires a
holistic system approach.
Saft White Paper
3 Design phase - p7
3.1 Electrical risks
7
3.3 Thermal risks
Case studies - p21
4
7.1 Dunkerque – France’s largest battery
Thermal runaway energy storage project
- p9
7.2 RINGO – relieving transmission grid
4.1 Thermal runaway prevention
congestion
measures
8
4.2 Fire containment measures
– the fire suppression system (FSS) About the authors
- p24
Reliability analysis
Cathode & anode
Electrochemical
manufacturing
management
In line layered
Electronics &
Mechanical
Safety tests
technology
capabilities
validations
software
Thermal
controls
Process
Process
design
Clean
stack
User Requirements
The starting point for in designing for safety design, system design, certification,
is a detailed analysis of potential risks manufacturing and quality control,
and their consequences. This risk analysis installation and day-to-day operation.
follows international standards, covering
Saft’s safety solution is designed to enable in-
risks of any possible nature that can be
depth defense against risk, from preventing
identified for the entire ESS. In particular, we
critical events during operation to ensuring
look in detail at interdependencies, where
safe decommissioning, as shown in Figure 3.
the coincident occurrence of two or more
We look at the possible consequences
factors can give rise to a safety incident.
of a risk, and then define mitigation
ESS safety must, however, go beyond safe measures at the system and environmental
product designs for a truly holistic approach. level. The process starts with the
As shown in Figure 2, we adopt an end-to- detection and possible prevention of a
end overview from design, development and critical event.
installation to operation. This includes cell
Severity:
Negligible Slight Moderate High Very High
Material cost • $1k • 1k to $20k • 20k to 200k$ • 200k to 2m$ • > 2m$
Personal injury • None • Minor cuts • Injury w/ short • Serious injury w/ • 1+ fatalities
time off long time off
Very unlikely
< 0.010%
Unlikely
Likelihood:
0.01% to 0.10%
Posssible
0.10% to 1.0%
Likely
1.0% to 10%
Very likely
>10%
Having identified the root cause, we addressed the issue by improving the winding
process and implementing additional manufacturing controls. Furthermore, this
risk is now systematically addressed in all risk analysis exercises. This example
shows that manufacturing control is just as important as chemistry or design
features.
4. Thermal runaway
Thermal runaway (TR) is the single most An ISC is the most critical root cause of
critical event that can result either from one a TR because it can be neither predicted
or more of the risks outlined in section 3, nor prevented by the BMS, and because it
such as over-temperature, over-voltage or results in an immediate rise in cell
an internal short circuit (ISC). temperature to the point where it is able to
trigger a thermal runaway.
While many in the industry define thermal runaway as the point where the
cathode (positive electrode) experiences catastrophic breakdown and spiraling
temperature rise, it is important to recognize that this is the culmination of a
chain of reactions of increasing severity. The initiating point is the breakdown
of the passivating layer, or solid-electrolyte interphase, at the surface of the
anode (negative electrode), which occurs above about 120°C. This breakdown
allows an uncontrolled reaction between the electrolyte and the lithium ions in
the anode, generating gas and more heat. As the temperature increases, higher
energy reactions are triggered, involving the separator and electrolyte, and
producing more gas and heat.
The evolved gas raises the cell internal pressure to the point where the cell
vents, releasing a large volume of hot gas. If the event is limited to a single
cell, the heat released during venting is often sufficient to avoid catastrophic
reactions at the cathode. However, if heat from the initiating cell propagates
to adjacent cells and causes them to undergo the same sequence of
reactions, the accumulated heat makes full-blown thermal runaway at the
cathode inevitable. Different cathode materials show different thresholds,
and the amount of heat generated is different:
- Highest heat generation is for batteries with cathodes that have a high nickel
(Ni) content, such as NMC and NCA materials.
It is vital to ensure that such protection Although the primary FSS will usually stop
functions are highly reliable and/or the original fire, the initial heat transfer
redundant. Therefore, BMS safety functions to adjacent cells or modules may have
are qualified to SIL 13 and critical sensors triggered further thermal runaways through
and switches are equipped with regular, overheating. These will take between 60 to
automatic function testing. 90 minutes to escalate. In this “worst case”
scenario, only intensive cooling with water
3 - SIL: Safety Integrity Level according to IEC 61508 can definitely stop the event.
The Saft solution is designed to spray water ceiling-mounted sprinklers. The system is
onto each individual module inside the entirely activated from outside, without the
container. This guarantees much higher need to open container doors.
module cooling effectiveness compared to
• When one of the sensors detects a fire event (gas, heat or smoke), it trips
a “warning” signal. This first signal will stop the cabinet’s fans and the air
conditioning. The system will stay in alert mode until a second detection is
performed by another sensor.
This sequence is triggered by the FSS control panel. It is linked to the battery
control system in order to command the battery shutdown. This includes
opening of contactors in the battery management module (BMM) and
managing all local (visual, audible) and remote alarm functions. Its design must,
therefore, ensure high reliability and routine inspection is part of the regular
maintenance operation.
1 4 1 2 3
• Carbon monoxide (CO) – which is • Blast panels on the container roof that
flammable and toxic burst in the case of an internal explosion.
This releases the pressure, protecting the
• Hydrogen (H ) - which is flammable if the
2
local environment and people from container
concentration exceeds about 4% by volume
deflagration.
(40,000 ppm)
The interior temperature is indicated
To reduce risk, and especially to
outside the container, and gas concen-
protect fire fighters who may need
tration can also be measured, so that
to approach the ESS in case of an
firefighters can assess the criticality of the
accident, it is essential to both ensure
situation without opening or entering the
dilution of gases and avoid any dangerous
container. They can determine if thermal
overpressure inside the container. Saft
runaway is happening and if the atmosphere
containers (see Figure 7) are therefore
is explosive. Depending on their observations
equipped with:
and using decision tree instructions
• An overpressure vent that operates at provided by Saft, first responders will then
around 100 Pa, enabling the controlled decide upon the most appropriate actions
release of gases and, therefore, preventing to take.
Figure 6 provides an overview of the ESS safety protection system that covers fire
containment and gas and pressure management measures.
2 – Blast panels
Thanks to safety testing at the container level, we recognized the need to implement a
water-spray system for our new generation of high energy ESS containers. In
contrast to Saft’s first three generations, which were built with smaller Li-ion
modules in a less energy-dense arrangement, we found that a primary FSS
was not sufficient to prevent heat propagation. Despite extinguishing
fires, larger modules and a very high packing density inside the container led
to levels of heat transfer not seen in previous generations and which could
not be investigated in module component testing. Saft was, therefore, one
of the first manufacturers to systematically adopt a water spray system
for cooling in its safety design.
Laboratories)
The most significant tests applicable to
In order to be “UL listed”, the ESS battery
ESS are:
must be certified against UL 1973.
• UL 1642 Lithium Batteries 4
The prerequisite for this is to obtain UL 1642
• UL 1973 Standard for Batteries for Use or UL 1973 for the Li-ion cells inside the
in Stationary, Vehicle Auxiliary Power and container.
Light Electric Rail (LER) Applications
In order to be “UL listed”, the ESS battery
• UL 9540 Energy Storage Systems and must be certified against UL 1973.
Equipment
• UL 9540A Test Method for Evaluating 4 - Since the addition of cell-level requirements to the latest version
Thermal Runaway Fire Propagation in of UL 1973, the latter is increasingly used in practice instead of UL
1642, which was one of the first standards specifying safety tests
Battery Energy Storage Systems at cell level.
The initial step for this is to certify the Li-ion context (indoor, outdoor, floor mounted,
cells inside the container against UL 1642 wall mounted…).
or UL 1973.
Saft has conducted UL9540A testing at cell,
This is followed by a process to achieve UL module and DC string level. Due to thermal
listing for the full ESS battery system, with a insulators integrated to Saft’s 18 kWh LFP
typical duration of 6 months. battery module, no propagation occurred
during the test. The test report according to
The four main steps to complete with UL are:
9.8 of UL 9540A 4th edition concludes the
• 1 - Preliminary Investigation module passes all 4 criteria, i.e.
• Post-event instructions
We provide training courses and collect
feedback, keeping always in mind our main
overarching objective is to protect people,
the environment and the energy storage site
itself.
6. Outlook
Recent incidents with Li-ion ESS have • Standards do not always reflect the reality
alerted regulators and operators, illustrating of abuse scenarios. For example:
that safety is not yet mature in the energy
- The nail test. It is spectacular. But does
storage market. This is despite the huge
it really mean the cell is safe?
number of safety rules and standards
that exist already. The main challenges - Methods of triggering a thermal runaway.
in achieving a coherent, industry-wide Some methods are harsher than others,
approach to safety are: and do not accurately represent the reality
of an ISC.
• Diverse approaches to safety across
different areas - electrical safety, • Standards do not cover all areas of
electrochemical cells in general, Li-ion risk, in particular gas management
batteries in particular, electromagnetic and the prevention of deflagration are
compatibility (EMC) and other factors. At the not, or only poorly, dealt with in most
same time there are different system levels standards. However, these aspects have
– cells, DC battery systems, full AC ESS. been recently addressed by NFPA 855
Some rely on design rules, others on test
methods or safety performance values. • Tests are expensive. Carrying out an abusive
test of a full ESS involves considerable costs
• Standards are not necessarily applied in materials, test equipment and effort.
by all manufacturers.
The 61 MW AC peak power and 61 MWh so as to assess and minimize any potential
facility at Dunkerque is the largest battery- risk for their sites.
based energy storage facility in France. It
connects to the network operated by RTE,
7.2 RINGO - relieving
France’s transmission system operator (TSO),
transmission grid
at a 90 kV grid connection point. Its primary
congestion now
use is to provide Frequency Containment
Reserves (FCR) services to RTE, but it is
and stacking services
designed to provide additional services for the future
as the market evolves, such as automatic RTE has adopted a 30 MWh Saft Li-
frequency restoration reserve (aFRR) or peak ion ESS for its ground-breaking RINGO
shaving to relieve grid congestion. project. The trial project is using
energy storage to boost the grid’s flexibility
Saft’s ESS solution comprises 27 Intensium
to prepare for the growing deployment of
Max High Energy containers, each providing
renewable energy in France’s electricity mix.
2.5 MWh of energy storage built with NMC cell
technology. The safety case was of utmost Rather than upgrading the grid, RTE is using
importance to TotalEnergies, as this ESS -like the RINGO project to explore the concept of
several others to come- is installed at an oil a ‘virtual transmission line;’ an innovative
and gas facility (in order to share existing approach using digitally controlled energy
grid connections). Therefore, TotalEnergies storage to absorb and release energy
and their insurance companies performed simultaneously at different sites located up
an in-depth audit of Saft’s safety concept and downstream of grid bottlenecks.