Safety Data Sheet

Octamar (TM) LI-5 Plus

1. Product and company identification
Product name : Octamar (TM) LI-5 Plus
Material uses : Petrochemical industry: Petrochemicals. Fuel additive.
Internal code : 14011
System code : 14011
Supplier : Innospec Canada Limited
1500, 850- 2nd Street S.W.
Calgary, Alberta
T2P 0R8
Information contact : 1-800-441-9547
e-mail address of person : sdsinfo@innospecinc.com
responsible for this SDS
NON-emergency enquiries : corporatecommunications@innospecinc.com
Emergency telephone number
In USA, Canada and North America, 24 hour / 7 day emergency information for our product is provided by the
CHEMTREC® Emergency Call Center based in the USA

Country information : Emergency telephone number

USA, Canada, Puerto Rico, Virgin Islands : +1 800 424 9300
In case of difficulties, or for ships at sea : +1 703 527 3887

In Europe, Middle East, Africa, Asia Pacific and South America 24 hour / 7 day
emergency response for our products is provided by the NCEC CARECHEM 24
global network
The main regional centres are listed here in Section 1.
Other local contact numbers for specific language support in Asia Pacific are listed in Section 16
Country information : Emergency telephone number Location
South America ( all countries ) : +1 215 207 0061 Philadelphia USA
Brazil : +55 11 3197 5891 Brazil
Mexico : +52 555 004 8763 Mexico
Europe ( all countries ) Middle East, Africa ( French, Portuguese, English ) : +44 (0) 1235 239 670 London, UK
Middle East, Africa ( Arabic, French, English ) : +44 (0) 1235 239 671 Lebanon
Asia Pacific ( all countries except China ) : +65 3158 1074 Singapore
China : +86 10 5100 3039 Beijing China

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Octamar (TM) LI-5 Plus

Section 2. Hazards identification

Classification of the : FLAMMABLE LIQUIDS - Category 4
substance or mixture EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
GHS label elements
Hazard pictograms :

Signal word : Warning

Hazard statements : H227 - Combustible liquid.
H319 - Causes serious eye irritation.
H317 - May cause an allergic skin reaction.
H351 - Suspected of causing cancer.
H336 - May cause drowsiness or dizziness.
Precautionary statements
Prevention : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P280 - Wear protective gloves: > 8 hours (breakthrough time): Viton®; 1 - 4 hours
(breakthrough time): nitrile rubber. Wear eye or face protection: Recommended: splash
goggles. Wear protective clothing.
P210 - Keep away from flames and hot surfaces. - No smoking.
P271 - Use only outdoors or in a well-ventilated area.
P261 - Avoid breathing vapor.
P264 - Wash hands thoroughly after handling.
P272 (OSHA) - Contaminated work clothing must not be allowed out of the workplace.
Response : P308 + P313 - IF exposed or concerned: Get medical attention.
P304 + P340 + P312 - IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell.
P302 + P352 + P363 - IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse.
P333 + P313 - If skin irritation or rash occurs: Get medical attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical attention.
Storage : P405 - Store locked up.
P403 - Store in a well-ventilated place.
P235 - Keep cool.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise : None known.
classified
Target organs : Contains material which causes damage to the following organs: blood, lungs, upper
respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.
Contains material which may cause damage to the following organs: kidneys, liver.

See toxicological information (Section 11)

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Octamar (TM) LI-5 Plus

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Ingredient name % CAS number
Solvent naphtha (petroleum), heavy arom. 30 - 60 64742-94-5
Solvent naphtha (petroleum), heavy arom. 9.99 - 14.99 64742-94-5
1,2,4-trimethylbenzene 0.99 - 4.99 95-63-6
naphthalene 0.99 - 4.99 91-20-3
Reaction mass of 2,6-di-tert-butylphenol and 2,4,6-tri-tert-butylphenol. 0.99 - 4.99 128-39-2, 732-26-3
cumene 0.09 - 0.99 98-82-8
Polyalkylenepolyamine Proprietary -
Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Ingestion : Remove dentures if any. Wash out mouth with water. Stop if the exposed person feels
sick as vomiting may be dangerous. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Do not induce vomiting unless directed to do so by
medical personnel. If vomiting occurs, the head should be kept low so that vomit does
not enter the lungs. Get medical attention. If necessary, call a poison center or
physician. Never give anything by mouth to an unconscious person. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
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Section 4. First aid measures

Skin contact : May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media
Specific hazards arising : Combustible liquid. In a fire or if heated, a pressure increase will occur and the
from the chemical container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Flash point : Closed cup: 66°C (150.8°F) [DIN EN ISO 2719]

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Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Empty containers retain
product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

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Octamar (TM) LI-5 Plus

Section 7. Handling and storage

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in a dry, cool and well-ventilated area, away from incompatible materials (see
incompatibilities Section 10). Store locked up. Eliminate all ignition sources. Separate from oxidizing
materials. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Organic acid. ACGIH TLV (United States).
STEL: 10 mg/m³, (Mist) Form: Respirable
TWA: 5 mg/m³, (Mist) Form: Respirable
1,2,4-trimethylbenzene CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 123 mg/m³, 0 times per shift, 8 hours.
8 hrs OEL: 25 ppm, 0 times per shift, 8 hours.
CA British Columbia Provincial (Canada, 6/2017).
TWA: 25 ppm, 0 times per shift, 8 hours.
CA Québec Provincial (Canada, 1/2014).
TWAEV: 25 ppm, 0 times per shift, 8 hours.
TWAEV: 123 mg/m³, 0 times per shift, 8 hours.
CA Ontario Provincial (Canada, 7/2015).
TWA: 25 ppm 8 hours.
CA Saskatchewan Provincial (Canada, 7/2013).
STEL: 30 ppm 15 minutes.
TWA: 25 ppm 8 hours.
naphthalene CA Alberta Provincial (Canada, 4/2009). Absorbed through skin.
15 min OEL: 15 ppm, 0 times per shift, 15 minutes.
8 hrs OEL: 10 ppm, 0 times per shift, 8 hours.
8 hrs OEL: 52 mg/m³, 0 times per shift, 8 hours.
15 min OEL: 79 mg/m³, 0 times per shift, 15 minutes.
CA British Columbia Provincial (Canada, 6/2017). Absorbed
through skin.
TWA: 10 ppm, 0 times per shift, 8 hours.
STEL: 15 ppm, 0 times per shift, 15 minutes.
CA Ontario Provincial (Canada, 7/2015). Absorbed through skin.

TWA: 10 ppm, 0 times per shift, 8 hours.

STEL: 15 ppm, 0 times per shift, 15 minutes.
CA Québec Provincial (Canada, 1/2014).
TWAEV: 10 ppm, 0 times per shift, 8 hours.
TWAEV: 52 mg/m³, 0 times per shift, 8 hours.
STEV: 15 ppm, 0 times per shift, 15 minutes.
STEV: 79 mg/m³, 0 times per shift, 15 minutes.
CA Saskatchewan Provincial (Canada, 7/2013). Absorbed
through skin.
STEL: 15 ppm 15 minutes.
TWA: 10 ppm 8 hours.
mesitylene CA Alberta Provincial (Canada, 4/2009).

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Octamar (TM) LI-5 Plus

Section 8. Exposure controls/personal protection

8 hrs OEL: 123 mg/m³, 0 times per shift, 8 hours.
8 hrs OEL: 25 ppm, 0 times per shift, 8 hours.
CA British Columbia Provincial (Canada, 6/2017).
TWA: 25 ppm, 0 times per shift, 8 hours.
CA Québec Provincial (Canada, 1/2014).
TWAEV: 25 ppm, 0 times per shift, 8 hours.
TWAEV: 123 mg/m³, 0 times per shift, 8 hours.
CA Ontario Provincial (Canada, 7/2015).
TWA: 25 ppm 8 hours.
CA Saskatchewan Provincial (Canada, 7/2013).
STEL: 30 ppm 15 minutes.
TWA: 25 ppm 8 hours.
cumene CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 50 ppm, 0 times per shift, 8 hours.
8 hrs OEL: 246 mg/m³, 0 times per shift, 8 hours.
CA British Columbia Provincial (Canada, 4/2014).
TWA: 25 ppm, 0 times per shift, 8 hours.
STEL: 75 ppm, 0 times per shift, 15 minutes.
CA Ontario Provincial (Canada, 1/2013). Absorbed through skin.

TWA: 50 ppm, 0 times per shift, 8 hours.

CA Quebec Provincial (Canada, 1/2014).
TWAEV: 50 ppm, 0 times per shift, 8 hours.
TWAEV: 246 mg/m³, 0 times per shift, 8 hours.
xylene CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 100 ppm, 0 times per shift, 8 hours.
15 min OEL: 651 mg/m³, 0 times per shift, 15 minutes.
15 min OEL: 150 ppm, 0 times per shift, 15 minutes.
8 hrs OEL: 434 mg/m³, 0 times per shift, 8 hours.
CA British Columbia Provincial (Canada, 6/2017).
TWA: 100 ppm, 0 times per shift, 8 hours.
STEL: 150 ppm, 0 times per shift, 15 minutes.
CA Québec Provincial (Canada, 1/2014).
TWAEV: 100 ppm, 0 times per shift, 8 hours.
TWAEV: 434 mg/m³, 0 times per shift, 8 hours.
STEV: 150 ppm, 0 times per shift, 15 minutes.
STEV: 651 mg/m³, 0 times per shift, 15 minutes.
CA Ontario Provincial (Canada, 7/2015).
STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.
CA Saskatchewan Provincial (Canada, 7/2013).
STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.

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Octamar (TM) LI-5 Plus

Section 8. Exposure controls/personal protection

Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Recommended: splash goggles
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated. > 8 hours (breakthrough
time): Viton®
1 - 4 hours (breakthrough time): nitrile rubber
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use. Recommended: organic vapor filter (Type A)
Personal protective :
equipment (Pictograms)

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Amber.
Odor : Aromatic.
Odor threshold : Not available.
pH : Not available.

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Octamar (TM) LI-5 Plus

Section 9. Physical and chemical properties

Melting point : Not available.
Boiling point : Lowest known value: 168.01°C (334.4°F) (1,2,4-trimethylbenzene). Weighted average:
204.4°C (399.9°F)
Flash point : Closed cup: 66°C (150.8°F) [DIN EN ISO 2719]
Evaporation rate : Highest known value: 0.05 (Solvent naphtha (petroleum), heavy arom.) Weighted
average: 0.05compared with butyl acetate
Flammability (solid, gas) : Not available.
Lower and upper explosive : Greatest known range: Lower: 0.6% Upper: 7% (Solvent naphtha (petroleum), heavy
(flammable) limits arom.)
Vapor pressure : Highest known value: 0.1 kPa (0.8 mm Hg) (at 20°C) (Solvent naphtha (petroleum),
heavy arom.). Weighted average: 0.06 kPa (0.45 mm Hg) (at 20°C)
Vapor density : Highest known value: 4.6 to 5.5 (Air = 1) (Solvent naphtha (petroleum), heavy arom.).
Weighted average: 5.01 (Air = 1)
Density : 0.925 g/cm³ [15°C (59°F)]
Specific gravity : Not available.
Solubility : Easily soluble in the following materials: diethyl ether, acetone.
Insoluble in the following materials: cold water, hot water.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Lowest known value: 362°C (683.6°F) (Aliphatic carboxylic acid.).
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C (104°F)): 0.77 cm2/s (77 cSt) [ISO 3104 / DIN 51562]
Aerosol product
Pour point : <-40°C

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Incompatible materials : Reactive or incompatible with the following materials:
oxidizing materials
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity

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Section 11. Toxicological information

Product/ingredient name Test Species Result Dose
Solvent naphtha (petroleum), - Rat LC50 Inhalation >590 mg/m³
heavy arom. Vapor
- Rabbit LD50 Dermal >2 mL/kg
- Rabbit LD50 Dermal 2000 mg/kg
- Rat LDLo Oral 5 mL/kg
Solvent naphtha (petroleum), - Rat LC50 Inhalation >590 mg/m³
heavy arom. Vapor
- Rabbit LD50 Dermal >2 mL/kg
- Rabbit LD50 Dermal 2000 mg/kg
- Rat LDLo Oral 5 mL/kg
naphthalene - Rat LC50 Inhalation >340 mg/m³
Vapor
- Rabbit LD50 Dermal >2000 mg/kg
- Rat LD50 Dermal >2500 mg/kg
- Rat LD50 Oral 490 mg/kg
Reaction mass of 2,6-di-tert- OECD 402 Acute Dermal Toxicity Rat - Male, LD50 Dermal >2000 mg/kg
butylphenol and 2,4,6-tri-tert- Female
butylphenol.
OECD 401 Acute Oral Toxicity Rat - Male, LD50 Oral 2976 mg/kg
Female
cumene - Rat LC50 Inhalation 39000 mg/m³
Vapor
- Rat LD50 Oral 1400 mg/kg
Polyalkylenepolyamine - Rat LD50 Dermal 1260 mg/kg
- Rat LD50 Oral 2100 to 3990 mg/
kg
Potential chronic health effects
Product/ingredient name Test Species Result Dose
Polyalkylenepolyamine - Rat Sub-chronic 43 mg/kg
LOAEL Oral
- Rabbit Sub-chronic 50 mg/kg
LOAEL Dermal
Irritation/Corrosion
Product/ingredient name Test Species Result
Solvent naphtha (petroleum), - Rabbit Skin - Mild irritant -
heavy arom.
- Mammal - Eyes - Mild irritant -
species
unspecified
Solvent naphtha (petroleum), - Rabbit Skin - Mild irritant -
heavy arom.
- Mammal - Eyes - Mild irritant -
species
unspecified
Reaction mass of 2,6-di-tert- OECD 404 Acute Dermal Rabbit Skin - Edema 0
butylphenol and 2,4,6-tri-tert- Irritation/Corrosion
butylphenol.
OECD 405 Acute Eye Irritation/ Rabbit Eyes - Cornea opacity 3
Corrosion
OECD 405 Acute Eye Irritation/ Rabbit Eyes - Redness of the 3

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Section 11. Toxicological information

Corrosion conjunctivae
cumene - Rabbit Eyes - Mild irritant -
- Rabbit Eyes - Mild irritant -
- Rabbit Skin - Mild irritant -
- Rabbit Skin - Moderate irritant -
Polyalkylenepolyamine - Rabbit Eyes - Moderate irritant -
- Rabbit Skin - Severe irritant -
Sensitization
Product/ingredient name Test Species Result
Reaction mass of 2,6-di-tert- - Guinea pig Not sensitizing -
butylphenol and 2,4,6-tri-tert-
butylphenol.
Polyalkylenepolyamine - Guinea pig Sensitizing -
Mutagenicity
Product/ingredient name Test Experiment Result
Polyalkylenepolyamine - Experiment: In vivo Negative
Subject: Mammalian-Animal
Carcinogenicity
Classification
Product/ingredient name OSHA IARC NTP
naphthalene - 2B Reasonably anticipated to be a human carcinogen.
cumene - 2B Reasonably anticipated to be a human carcinogen.
Reproductive toxicity
Product/ingredient name Test Species Result Dose
Polyalkylenepolyamine - Mammal - - Oral: 970 NOAEL
species
unspecified
- Mammal - - Dermal: 161
species NOAEL
unspecified
Teratogenicity
Not available.

Specific target organ toxicity (single exposure)

Name Category Route of Target organs
exposure
Octamar (TM) LI-5 Plus Category 3 Not applicable. Narcotic effects
Solvent naphtha (petroleum), heavy arom. Category 3 Not applicable. Narcotic effects
Solvent naphtha (petroleum), heavy arom. Category 3 Not applicable. Narcotic effects
1,2,4-trimethylbenzene Category 3 Not applicable. Respiratory tract
irritation
cumene Category 3 Not applicable. Narcotic effects
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
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Section 11. Toxicological information

Name Result
Solvent naphtha (petroleum), heavy arom. ASPIRATION HAZARD - Category 1
Solvent naphtha (petroleum), heavy arom. ASPIRATION HAZARD - Category 1
cumene ASPIRATION HAZARD - Category 1

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Solvent naphtha (petroleum), Acute EC50 1 to 3 mg/l Algae 72 hours
heavy arom.
Acute EC50 3 to 10 mg/l Daphnia 48 hours
Acute LC50 2 to 5 mg/l Fish 96 hours
Solvent naphtha (petroleum), Acute EC50 1 to 3 mg/l Algae 72 hours
heavy arom.
Acute EC50 3 to 10 mg/l Daphnia 48 hours
Acute LC50 2 to 5 mg/l Fish 96 hours
1,2,4-trimethylbenzene Acute LC50 7.72 mg/l Fish 96 hours
naphthalene Acute EC50 1.96 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 2350 µg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 1.6 mg/l Fish 96 hours
Reaction mass of 2,6-di-tert- Acute EC50 4.9 mg/l Key data sources Algae - S. capricornutum 72 hours
butylphenol and 2,4,6-tri-tert-
butylphenol.
Acute EC50 0.4 mg/l Key data sources Daphnia 48 hours
Acute LC50 0.3 mg/l Key data sources Fish - Oncorhynchus mykiss 96 hours
cumene Acute EC50 2600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 10.6 mg/l Daphnia 48 hours
Acute LC50 2.7 mg/l Fish 96 hours
Polyalkylenepolyamine Acute EC50 6.8 mg/l Algae 72 hours
Acute EC50 24.1 mg/l Daphnia 48 hours
Acute LC50 420 mg/l Fish 96 hours
Acute NOEC 0.5 mg/l Algae -
Persistence and degradability
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Solvent naphtha (petroleum), - - Inherent
heavy arom.
Solvent naphtha (petroleum), - - Inherent
heavy arom.
Reaction mass of 2,6-di-tert- Fresh water 73.5 days, 20°C <1 day(s) Not readily
butylphenol and 2,4,6-tri-tert-
butylphenol.
Polyalkylenepolyamine - - Not readily
Bioaccumulative potential

Date of issue/Date of revision : 2018-06-11 12/16

Octamar (TM) LI-5 Plus

Section 12. Ecological information

Product/ingredient name LogPow BCF Potential
Solvent naphtha (petroleum), 2.8 to 6.5 <100 low
heavy arom.
Solvent naphtha (petroleum), - <100 low
heavy arom.
1,2,4-trimethylbenzene 4.09 275 low
naphthalene 3.3 >100 low
Reaction mass of 2,6-di-tert- 4.9 - high
butylphenol and 2,4,6-tri-tert-
butylphenol.
cumene 3.66 94.69 low
Polyalkylenepolyamine -3.16 - low

Section 13. Disposal considerations

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal
contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all
authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when
recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product
residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do
not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.

Section 14. Transport information

DOT Classification TDG Classification IATA

UN number NA1993 UN3082 UN3082

UN proper Combustible liquid, n.o.s. ENVIRONMENTALLY Environmentally hazardous

shipping name (Solvent naphtha (petroleum), HAZARDOUS SUBSTANCE, substance, liquid, n.o.s.
heavy arom., naphthalene). LIQUID, N.O.S. (Solvent (Solvent naphtha (petroleum),
Marine pollutant (Solvent naphtha (petroleum), heavy heavy arom., naphthalene)
naphtha (petroleum), heavy arom., naphthalene). Marine
arom., naphthalene) RQ pollutant (Solvent naphtha
(naphthalene) (petroleum), heavy arom.,
Solvent naphtha (petroleum),
heavy arom.)
Transport Combustible liquid. 9 9
hazard class(es)

Packing group III III III

Environmental Yes. Yes. Yes.

hazards

Date of issue/Date of revision : 2018-06-11 13/16

Octamar (TM) LI-5 Plus

Section 14. Transport information

Additional Non-bulk packages (less than Product classified as per the This product is not regulated
information or equal to 119 gal) of following sections of the as a dangerous good when
combustible liquids, that are Transportation of Dangerous transported in sizes of ≤5 L or
marine pollutants, are not Goods Regulations: 2.43-2.45 ≤5 kg, provided the packagings
regulated as hazardous (Class 9), 2.7 (Marine pollutant meet the general provisions of
materials in package sizes less mark). 5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.
than the product reportable 8.
quantity, unless transported by Non-bulk packages of this Passenger and Cargo Aircraft
vessel. product are not regulated as Quantity limitation: 450 L
dangerous goods when Packaging instructions: 964
This product is not regulated transported by road or rail. Cargo Aircraft Only Quantity
as a marine pollutant when limitation: 450 L
transported on inland Explosive Limit and Limited Packaging instructions: 964
waterways in sizes of ≤5 L or Quantity Index Limited Quantities -
≤5 kg or by road, rail, or inland 5 Passenger Aircraft Quantity
air in non-bulk sizes, provided limitation: 30 kg
the packagings meet the Special provisions Packaging instructions: Y964
general provisions of §§ 173.24 16, 99
and 173.24a. Special provisions
A97, A158, A197
Reportable quantity
6454 lbs / 2930.1 kg [836.82
gal / 3167.7 L]
Package sizes shipped in
quantities less than the product
reportable quantity are not
subject to the RQ (reportable
quantity) transportation
requirements.

Limited quantity
Yes.

Packaging instruction
Passenger aircraft
Quantity limitation: 60 L

Cargo aircraft
Quantity limitation: 220 L

Special provisions
IB3, T4, TP1

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Date of issue/Date of revision : 2018-06-11 14/16

Octamar (TM) LI-5 Plus

Section 15. Regulatory information

Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.

Canadian lists
Canada inventory : All components are listed or exempted.
Canadian NPRI : The following components are listed: Heavy aromatic solvent naphtha; Heavy aromatic
solvent naphtha; Heavy aromatic solvent naphtha
CEPA Toxic substances : The following components are listed: Naphthalene

International lists
National inventory
Australia inventory (AICS) : All components are listed or exempted.
Canada inventory : All components are listed or exempted.
China inventory (IECSC) : All components are listed or exempted.
Europe inventory : All components are listed or exempted.
Japan inventory (ENCS) : Japan inventory (ENCS): All components are listed or
exempted.
Japan inventory (ISHL): Not determined.
New Zealand Inventory of Chemicals (NZIoC) : All components are listed or exempted.
Philippines inventory (PICCS) : All components are listed or exempted.
Korea inventory (KECI) : All components are listed or exempted.
Taiwan inventory (TCSI) : All components are listed or exempted.
United States inventory (TSCA 8b) : All components are listed or exempted.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health * 2
Flammability 2
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks
Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used
with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be
purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

National Fire Protection Association (U.S.A.)

2 Flammability
Health 2 0 Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire
Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association,
on the referenced subject which is represented only by the standard in its entirety.

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Octamar (TM) LI-5 Plus

Section 16. Other information

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by
properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with
recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or
not, anyone using the 704 systems to classify chemicals does so at their own risk.

Classification according to Directive 67/548/EEC [DSD] or Classification according to Directive 1999/45/EC [DPD]
Risk phrases : R40- Limited evidence of a carcinogenic effect.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapors may cause drowsiness and dizziness.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety phrases : S36/37- Wear suitable protective clothing and gloves.
S61- Avoid release to the environment. Refer to special instructions/safety data
sheet.
History
Date of printing : 2018-06-11
Date of issue/Date of : 2018-06-11
revision
Date of previous issue : No previous validation
Version : 1
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the
Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

Date of issue/Date of revision : 2018-06-11 16/16