Safety Data Sheet according to Regulation (EC) No 1907/2006

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SDS No. : 557934
POLYCURE AC V001.0
Revision: 07.06.2017
printing date: 24.12.2017
Replaces version from: -

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
POLYCURE AC
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use:
Acrylic emulsion

1.3. Details of the supplier of the safety data sheet

Henkel Polybit Industries Ltd.
PO BOX 293
Umm Al Quwain

Utd.Arab.Emir.

Phone: +971 (6) 7670777

Fax-no.: +971 (6) 7670197

psra.imea@henkel.com

1.4. Emergency telephone number

HAAD Poison and Drug Information Center UAE, TOLL FREE TEL. NUMBER 800-424

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (CLP):
The substance or mixture is not hazardous according to Regulation (EC) No 1272/2008 (CLP).

2.2. Label elements

Label elements (CLP):

The substance or mixture is not hazardous according to Regulation (EC) No 1272/2008 (CLP).

Supplemental information Contains 1,2-Benzisothiazol-3(2H)-one. May produce an allergic reaction.

Precautionary statement: P262 Do not get in eyes, on skin, or on clothing.

Prevention

2.3. Other hazards

None if used properly.
Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria.
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SECTION 3: Composition/information on ingredients

3.2. Mixtures

General chemical description:

Emulsifier solution, water-based
Base substances of preparation:
CP Styrene
Aqueous solution

Declaration of the ingredients according to CLP (EC) No 1272/2008:

Hazardous components EC Number content Classification

CAS-No.
1,2-Benzisothiazol-3(2H)-one 220-120-9 50- < 500 PPM Aquatic Acute 1
2634-33-5 H400
Aquatic Chronic 2
H411
Acute Tox. 4; Oral
H302
Skin Irrit. 2
H315
Skin Sens. 1
H317
Eye Dam. 1
H318

For full text of the H - statements and other abbreviations see section 16 "Other information".
Substances without classification may have community workplace exposure limits available.

Declaration of ingredients according to DPD (EC) No 1999/45:

Hazardous components EC Number content Classification

CAS-No.
1,2-Benzisothiazol-3(2H)-one 220-120-9 50 - < 500 PPM Xi - Irritant; R38, R41
2634-33-5 R43
N - Dangerous for the environment; R50
Xn - Harmful; R22

For full text of the R-Phrases indicated by codes see section 16 'Other Information'.
Substances without classification may have community workplace exposure limits available.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information:
In case of adverse health effects seek medical advice.

Inhalation:
Move to fresh air, consult doctor if complaint persists.

Skin contact:
Rinse with running water and soap. Skin care. Remove contaminated clothes immediately.

Eye contact:
Rinse immediately with plenty of running water, seek medical advice if necessary.

Ingestion:
Rinse mouth and throat. Drink 1-2 glasses of water. Seek medical advice.

4.2. Most important symptoms and effects, both acute and delayed
No data available.

4.3. Indication of any immediate medical attention and special treatment needed
See section: Description of first aid measures
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SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media:
carbon dioxide, foam, powder, water spray jet, fine water spray

Extinguishing media which must not be used for safety reasons:

High pressure waterjet

5.2. Special hazards arising from the substance or mixture

In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released.
5.3. Advice for firefighters
Wear protective equipment.
Wear self-contained breathing apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Wear protective equipment.
Danger of slipping on spilled product.
Ensure adequate ventilation.
Avoid contact with skin and eyes.

6.2. Environmental precautions

Do not empty into drains / surface water / ground water.

6.3. Methods and material for containment and cleaning up

Remove with liquid-absorbing material (sand, peat, sawdust).
Dispose of contaminated material as waste according to Section 13.

6.4. Reference to other sections

See advice in section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Ensure that workrooms are adequately ventilated.
Avoid skin and eye contact.

Hygiene measures:
Wash hands before work breaks and after finishing work.
Do not eat, drink or smoke while working.

7.2. Conditions for safe storage, including any incompatibilities

< +30°C
Do not store together with food or other consumables (coffee, tea, tobacco, etc.).

7.3. Specific end use(s)

Acrylic emulsion

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational Exposure Limits

Valid for
Ver.Arab.Emir.

None
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Occupational Exposure Limits

Valid for
Bharain

None

Occupational Exposure Limits

Valid for
Egypt

None

Occupational Exposure Limits

Valid for
Jordan

None

Occupational Exposure Limits

Valid for
Kuwait

None

Occupational Exposure Limits

Valid for
Israel

None

Occupational Exposure Limits

Valid for
Kenya

None

Biological Exposure Indices:

None

8.2. Exposure controls:

Respiratory protection:
Ensure adequate ventilation.

Hand protection:
Recommended are gloves made from Nitril rubber ( Material thickness >0,1 mm, Perforation time < 30s).Gloves should be
replaced after each short time contact or contamination. Available at laboratory specialized trade or at pharmacies / chemist's
shops.

Eye protection:
Goggles which can be tightly sealed.
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SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance liquid
liquid
white, up to,
brownish
Odor Acrylic
Odour threshold No data available / Not applicable

pH 7,0 - 8,5
(20 °C (68 °F))
Initial boiling point Not available.
Flash point Not available.
Decomposition temperature No data available / Not applicable
Vapour pressure No data available / Not applicable
Density 1,00 g/cm3
(20 °C (68 °F))
Bulk density No data available / Not applicable
Viscosity No data available / Not applicable
Viscosity (kinematic) No data available / Not applicable
Explosive properties No data available / Not applicable
Solubility (qualitative) No data available / Not applicable
Solidification temperature No data available / Not applicable
Melting point No data available / Not applicable
Flammability No data available / Not applicable
Auto-ignition temperature No data available / Not applicable
Explosive limits No data available / Not applicable
Partition coefficient: n-octanol/water No data available / Not applicable
Evaporation rate No data available / Not applicable
Vapor density No data available / Not applicable
Oxidising properties No data available / Not applicable

9.2. Other information

Flow cup viscosity 10 - 15 s

(40 °C (104 °F); )

SECTION 10: Stability and reactivity

10.1. Reactivity
None if used for intended purpose.

10.2. Chemical stability

Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

See section reactivity

10.4. Conditions to avoid

None if used for intended purpose.

10.5. Incompatible materials

None if used properly.

10.6. Hazardous decomposition products

None known.
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SECTION 11: Toxicological information

11.1. Information on toxicological effects

General toxicological information:

The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria
for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available
health/ecological information for the substances listed under Section 3 is provided in the following.

Sensitizing:
An allergic reaction cannot be excluded after repeated skin contact.

Acute oral toxicity:

Hazardous components Value Value Route of Exposure Species Method

CAS-No. type application time
1,2-Benzisothiazol-3(2H)- LD50 1.193 mg/kg oral rat not specified
one
2634-33-5

Acute dermal toxicity:

Hazardous components Value Value Route of Exposure Species Method

CAS-No. type application time
1,2-Benzisothiazol-3(2H)- LD50 > 5.000 mg/kg dermal rat EPA OPP 81-2 (Acute Dermal
one Toxicity)
2634-33-5

Skin corrosion/irritation:

Hazardous components Result Exposure Species Method

CAS-No. time
1,2-Benzisothiazol-3(2H)- moderately irritating 4h rabbit EPA OPP 81-5 (Acute Dermal
one Irritation)
2634-33-5

Serious eye damage/irritation:

Hazardous components Result Exposure Species Method

CAS-No. time
1,2-Benzisothiazol-3(2H)- highly irritating 48 h rabbit EPA OPP 81-4 (Acute Eye
one Irritation)
2634-33-5

Respiratory or skin sensitization:

Hazardous components Result Test type Species Method

CAS-No.
1,2-Benzisothiazol-3(2H)- sensitising Guinea pig guinea pig Magnusson and Kligman
one maximisat Method
2634-33-5 ion test
1,2-Benzisothiazol-3(2H)- sensitising Mouse mouse OECD Guideline 429 (Skin
one local Sensitisation: Local Lymph
2634-33-5 lymphnod Node Assay)
e assay
(LLNA)
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Germ cell mutagenicity:

Hazardous components Result Type of study / Metabolic Species Method

CAS-No. Route of activation /
administration Exposure time
1,2-Benzisothiazol-3(2H)- negative bacterial reverse with and without OECD Guideline 471
one mutation assay (e.g (Bacterial Reverse Mutation
2634-33-5 Ames test) Assay)
negative mammalian cell with and without OECD Guideline 476 (In vitro
gene mutation assay Mammalian Cell Gene
Mutation Test)
1,2-Benzisothiazol-3(2H)- negative oral: gavage mouse OECD Guideline 474
one (Mammalian Erythrocyte
2634-33-5 Micronucleus Test)
negative oral: unspecified rat OECD Guideline 486
(Unscheduled DNA Synthesis
(UDS) Test with Mammalian
Liver Cells in vivo)

Repeated dose toxicity

Hazardous components Result Route of Exposure time / Species Method

CAS-No. application Frequency of
treatment
1,2-Benzisothiazol-3(2H)- NOAEL=10 mg/kg oral: gavage 90 daysdaily rat OECD Guideline 408
one (Repeated Dose 90-Day Oral
2634-33-5 Toxicity in Rodents)

SECTION 12: Ecological information

General ecological information:
The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria
for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available
health/ecological information for the substances listed under Section 3 is provided in the following.
Do not empty into drains, soil or bodies of water.

12.1. Toxicity

Hazardous components Value Value Acute Exposure Species Method

CAS-No. type Toxicity time
Study
1,2-Benzisothiazol-3(2H)-one LC50 1,4 mg/l Fish 96 h Salmo gairdneri (new name: OECD Guideline
2634-33-5 Oncorhynchus mykiss) 203 (Fish, Acute
Toxicity Test)
NOEC 0,21 mg/l Fish 30 d Oncorhynchus mykiss OECD Guideline
215 (Fish, Juvenile
Growth Test)
1,2-Benzisothiazol-3(2H)-one EC50 1,05 mg/l Daphnia 48 h Daphnia magna OECD Guideline
2634-33-5 202 (Daphnia sp.
Acute
Immobilisation
Test)
1,2-Benzisothiazol-3(2H)-one EC50 0,11 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline
2634-33-5 201 (Alga, Growth
Inhibition Test)
NOEC 0,027 mg/l Algae 72 h Skeletonema costatum OECD Guideline
201 (Alga, Growth
Inhibition Test)
1,2-Benzisothiazol-3(2H)-one EC 50 23 mg/l Bacteria 3h activated sludge of a OECD Guideline
2634-33-5 predominantly domestic sewage 209 (Activated
Sludge, Respiration
Inhibition Test)
1,2-Benzisothiazol-3(2H)-one NOEC 1,2 mg/l chronic 21 d Daphnia magna OECD 211
2634-33-5 Daphnia (Daphnia magna,
Reproduction Test)

12.2. Persistence and degradability

Hazardous components Result Route of Degradability Method

CAS-No. application
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1,2-Benzisothiazol-3(2H)-one readily biodegradable aerobic > 60 % OECD 301 A - F

2634-33-5

12.3. Bioaccumulative potential / 12.4. Mobility in soil

Hazardous components LogPow Bioconcentration Exposure Species Temperature Method

CAS-No. factor (BCF) time
1,2-Benzisothiazol-3(2H)-one 6,62 not specified OECD Guideline 305
2634-33-5 (Bioconcentration: Flow-
through Fish Test)
1,2-Benzisothiazol-3(2H)-one 1,3 EU Method A.8 (Partition
2634-33-5 Coefficient)

12.5. Results of PBT and vPvB assessment

Hazardous components PBT/vPvB

CAS-No.
1,2-Benzisothiazol-3(2H)-one Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very
2634-33-5 Bioaccumulative (vPvB) criteria.

12.6. Other adverse effects

No data available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product disposal:
Dispose of waste and residues in accordance with local authority requirements.

Disposal of uncleaned packages:

Use packages for recycling only when totally empty.

Waste code
080410

SECTION 14: Transport information

14.1. UN number

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.2. UN proper shipping name

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.3. Transport hazard class(es)

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.4. Packing group

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.5. Environmental hazards

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.6. Special precautions for user

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not applicable
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SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

VOC content 0%
(VOCV 814.018 VOC regulation
CH)

15.2. Chemical safety assessment

A chemical safety assessment has not been carried out.

SECTION 16: Other information

The labelling of the product is indicated in Section 2. The full text
of all abbreviations indicated by codes in this safety data sheet are as follows:
R22 Harmful if swallowed.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R50 Very toxic to aquatic organisms.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.

Further information:
This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety requirements and is not intended to guarantee any
particular properties.
The product is intended for industrial use.

Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document.
Corresponding text is displayed in a different color on shadowed fields.