onsite quelopped and for bylbid
a) tei Thuse huptapih orbit de 05 <3 0-873
a oalapping fore Coorclinaly bend 4 ha
p. occu
ST no, hybulddianen gor | Witeut "
2 for -—< “4
y Tebrabedral
= “— _ — Sqyote i
= ‘aman | i Agana igen onn
a weak Wong
= Ce eho "peat no paiwig nogaon
2 pets |
& Sarit tapes) @ Soe te Follow. gues bascd on ver
oP — lLompleres involwes Sy Caan? ma Bet
i inner osbi tals +y10)=
= he affiliate x THOS
Te tm onbivas tamper (A* ni i
2, ° (4 *%5p3, dep) na strong Ugansh S&P,
exes LuVvotnt a ate = 7
i a 1, sia OO buke d- orbital idan a OT)
Pour “Erbitold vowielll " Parag} ty ce
- & > spam aie aig — relrabudee
v4 feline) CI Col! Sue
oO Bd %
tte co
© scanned wthonenSanera.
Fey Ode
di) Creceny 7”
fe = sdtus*
Fe =ad®
mith O OD
3d as up
atte ee
Jedidee
30k
aei.6) & fe,
> a2sp? Cinner Orbiectl lomplex
— Octakrchat Chee
> pao Momoyretre
ii), Cwiady 3”
Hr a-2
wee -24y
neat?
Ni + aol? Us*
Ni sad?
rele
Bd Ps
ow
Uganal 3 a ad >
pee
a ae
(Tepalaedwel)
> Malate) (Ponamagnstic
Te
WO Clr chy I
Wrqened
ke te
hs & weak Vgtue hance fo paliuiig
ue BAN tw sd? F
wll)
me SY
7 7. (Tara badral
— sp?
Kay” | paseonaspetd ©
(wy Eni Cow
Colello!
“ep 2d ‘
NW on aa
—dsp* — Squom plomor
di tamagmttre (50
Wy or uy)
Sd see eds e
pe = bdd ys? y
Pe =baé
dsp> Liane wbieel Compe)
A Wow plemen
— Mamogune
Wid Cee cu) 7*
u-b=-3
Az67
m6
Fe = 3d! usr
Ferl= 303
th wnak Ugewek Mo pauig
Azo
—> Spd (oukn orbital wupen
= inl ° D
> paaongoqatte © pus Isis
=e.
wily Emig a
—nsptd* (ours opitel “
nety
ite y3 Ge as
Wit = gat Puny 8tcus
RWS G =
tie GA Wes
ow Tue bes
GaneBae
= =
=
= ieee. Cinats Obits eonyoux)
BO (slong
ae) Cee cen jyy*
=
==
se 7b = actus!
me PE = aa? parry occum
= (ieee)
) fat & yO
= oN NN
=P — dep® Cond plauan)
SF = damage feo
=
=e Exception
Bi Cay?” goes
= ‘ ented
= Ca > 3d" 4s
Dw aw?
5 os — sto tigand nA = pabing octus,
of) i
-_D> a Wlolv |
Fa -
a4 hy Ra Me ")
Ld —
2 > Syyare plone
ee Ponommayrtic Me Speen = SE
2.
Salli) Com) J
2 w= th
em re ah 4s’
DB oe ad?
i NH, gy a Shon Ugandl = page
-» GhhT-) GI Gh
- BA}! fs I tp
— dh*sp3 ., (inner orbital complex?
pt deat
— ped 3(342) 20s.
iin) Cer (n0),97*
Met?
cre 3474s! |
crit « 3AF
yp — weak ligand 4 no pairing
suk.
Spratt (ube Orbital cong)
uivy Ccotnng2,I**
Com ad F4s*
(o** + 3b?
pairing octive
NH, shong Ugenst
em 9
4s
ERED] op ‘oD
— d*sp3
oh
pt T5 (Patemapetic
(v> mnoy
Mn = 298 ust
mitts 3a!
— $p? or dés
st fetraledral
-
SI.
o
Limitations_of V8T
> Jalled '~ cuplain nuAs %
amet . s
a Bo Mot predicr Gyauti tative eikneanin
q siti ¥ Compiler.
ws Th involues mamy anumpbe-
2) pw not predit euat qeorety
wr oovelimation Mot ¢2
— pode anol Spectral properse J
onypler OU nok erap (alrrd
© Scanned with OnE ScanoeeCET (Crystal Field Theory)
— propesed by Hans Bee amd
Hasbrouck "Ven leek,
> Ther a no sharing , trdnsforg e;
no overttypping | orbitals vin bjw
metal ant “ugamd.
SF ually “gan ond mete ane
womideud “2 point — daargen ome
lta on bly them pwr
ALN RUT C le
OY, tganct * necttrat trum parbellg
suely charged pare y Ugawol &
auNaced dows mptol
abense gq Ugamd, apt Che dorbinds
J metal ane degencrared (how
Seome emdyy) lout at a Ugaonel
Spproaches Con, spitting a ol Debited
tarts ple, Ais os cold Cer
Shapes g -orbi ta
duy dye den,
In bfvo the axis
olny dey =
a
om
Fietd Splitting In Octabe-
lex
-orah
Gn Oitanedroh vornpler, wt ty & Ugandl
appear on Same canis as Fh
gerd appreochan the Ont8 ihe tavegy
g all dm crbieats inuucaser eppastlly Tae
frruly spuitiy sakes pine, Nau
col
jomercte
opi tals
B02 CSE Bm On Lampe
P > paying emery
Dubos
the Fourth etechron
x ee
> 9F bo - OLDE |
at cn) bg eg [pes teeKl 9 Foeaa deus) [ots tome 9 Hea
Arcus) | agi eg” |-oux ese aE iC aend a Uns) Sptea egy PS eaa: |
dS (Hs) | igh eg 0-43 Ho€x2 3[0) At (Lsy Todxy #09 -24+2F
aus) | tag ef [wwe re zea] de cus ee |
dé Cus) tag? eg [exw hoges IURTH) ALFCLS)| eu. nee |
a = eel Se A |
af ces! bgh ef nouns co =[-24 +30] ans) ded ob 3 to4K3 ea |
a tus] af of OTOH aig SEITE Yared
a Us) | tag’ 9 FrORQETAM a
dé | bag’ gt [-ouxe ro-exe as
% 6,3 oie =| x | OENMOURS B= By 2
a 2_| bagieg? [cure sees ca _—a he
a” by @ nouns $06x4 = [04 TT) a” XY 404K FA=L4 pat |
oor ese |
Loeystot Field splitting tn Tetrabedrl
Conapsten. s
4, Tetroedial compte , lig anol 14
approaching tre CA from Yo He
guy $0, me wmnetgy q these
orbitas unk inoueses where lobe
be bla Ae ames
Who? Ne = mo. yf electrons tin € Orbital
Me
Ho. ge- dn te orbited
he b
pabeig wry
Woe spin — Sony Uigamel —» prising
Nigh spin > weak Hig arol =e -
ely
Lyyare Planar comple ane formes by
rome! two ganas orn zany
on Octabuctual “onnplta. |
Now Onrrgey an orbitat: alory
zon dials anol tnenyy 9
orautat along A amor, priacneasea,
“, fl,
Wy
we,
Squase
J
s dyn
~
Oclahasiral Uenplin
Smo,
eri
order G eay
https://t.me/Medicoinfinity
+7 dun? der rdyerdcn f
© scanned wthonen Sane
hubsVo fadors affediirg CASE 2
L Mature of cma
A value P fom
metab
3d —> yt us [ees @)
oi Cr ody 7 Cre cen”
Fet a
$ Geometiy oF habe
| bsp ptoh 2? ATA
Dep 2130] fata Hae
D = che
a
' on = Octabudtal
Th = Tebrabasleal
5. Cese x Bare stung ¢ ligand
4 hh, 2a
A leaion. o ger
tation 4 vompien can be enplatnede
by f= of bids Hen for d-d transiian
or’ a compler! tp enlastois
unpaid © ey mut
Ths unparid €- Mbrorbed Wits
dae amen OH Fhawss vote
volun Ht
can tes
> drwy aol Twamsltion @- seemmype Keon
lower’ gt orbitad to Wgtsr © of orbital
Gn ahswn 4g Uigamd » no splitting ¥
A- orbitad | becker place, he deel tyamare
Oct, amd te Coloue ts Obsoued
, mo
Tha, > CT tor Us
bate Miotet-
usdy —B2— > wsay. 540
whicte Blue
ters Stet tel
tin ol- crbteat
—> dor d-ol tamiten,
be atleast cue €°
Segegpli¢n = K,On0q KMney
) i
co's s2 Mut? Sal”
tags He
+ mekeul t Ugownst
— ligtna +0 mead
ange Comore | tangs won
mene, ieee
> Take place when
mekod i tin Wigher
Ob. he mesa howe
orbieat ama
lig ana havnt Sort
ety 2°
re- move from
gana. do rested
Faker get redeed
ee nan merch get
> Kemnay, ky or,02 09)
Chapt) (orange)
vo < EY [i
+ Dbrowest vole
fig wml rove raph,
m erbitel ana
mural none pied
d- orbital,
a, ew , Gy, 20%,
Buen,
velemied
if
visible
vagion
)
(© seamed th oF Sane—> when one Ugonor sepltes one
eiganct
In case g ot amd al? ced bramsino
do not occen but lonyplex May be
Colowad tu te charge wenger
»
uctronic Coniston, CSP BESS
&
Crew) “4
A+oen
nate
Fe adbuss
Fett saat
CN Stvong Ugand, ‘ow SP,
ee
[10) tag “4
(oT)
3. Mage othe Natun
un patickol
oh
if
wo nb + Riamnagestre
Conay
PRUUEGLUGLUUU GLUE ENN Sd see e es
yen Wolorr qf vompiex Conger
cont tut > Paramagne|
'gQ “a
A dhe tellewing m dec. order
a { wWamelon gts tuferbed. A
@ Ceo, T? () Cooto)I?
Cuan, yt te Citron 2" “| ©) Croton]? (a) Ceo lo),
te nagar bat
n 43
Twice te (higem, co, ©) Cound
Wiee” dank blue | 1 7% >Phzrem ON
< (ay 7 (dy 22) 2@) 206)
Di linitetions_ of _ CFT
— Hwa — Uganda molecules aA
Ve ee rot
‘appropriate because vn Oase
netrad Uigands thks no amd MG,
Fo shoul be 4 stronger Ugewel
as ot a -moce Polar, but at Meee
— a dow not stake anything abouA
7 bondtigg om. Geomupter
+ & condos metah Brom as Vey
changed paride ur to on
Same cues 0 which Ke
O. state gq metal ty 2040
Bonding IN METAL CARBON,
Ce A Organam tellie “nyo
lompocurels Wouting Cleon mere
bonel catthon “ metalicid borat
A: Idenrity the Orgamometaeei a7
D Ring x
DCU), 2H 1
4) si Coty ——
) mien),
5) Kali —
6) 606%), X Boron 9 my
9) BO, AA Bove”
8) COMsAyPb —
9) Lich,
i Ceasi eatin
_T4pes
ee meee,
[Syomebeutcat
aU organic womp
Ablacad “arith Muley
or
Yes
[Zens prametelcaly
re ee
4 Jann = Teller Yfeue
Te Oledses due Ww Uneg nel Aishi buHen of
ena bag ancl ty Orbital
Sock Bund
SM bien Fs Weprmatid! 1p ie Wo seven
i danqoue™ sq“ ei bwin 2 fia
mae by orbitas
(ode “ei egy
Qe —
md"
am ai ==
2 «
a #
ators)
ais
a ws)
re
Psy
Pas
datacteed! «tis
‘© samedithonen sare
enn w> En(eh),J 3 Biese’s Gott 7
go Tl, we
k (eba, (n° 44D
of | nN
or bonded 2 boned RN ZL Sou: sy, Sperone]
) Sigma bonded Ds] Bamagnt «
Mantle ~
d mee Mm!
5 bonded Org anemttalll: FE and x Bonds
» Examples of — Sigma bonds Orgautyn | cm te ta
, a , cmn ligand nord’
Kg x Chuignasl Reagent) | gen donb ag Vee
Chi: Se rates Sap eee
a | The m-o & bonds a formed by he
fk forme Free (eal
leak poisoning
Zeigler Masta. Cabalyst .
LR, At. icky) Bo atky alumina’ im
Titanium bebraclileride
3
4. Wilkingon » Catalyst Cop, spnod
This tui phanyt pros;
s. Reubi - Gilman's Reagent
corny eure sypltenis
2) A= bended complexes *-
1 Pelsocens
[he (4? (oss, J]
&?
fe ttps://t.me/Medicoinfinity
2. Dibenzen Clucomi win
[te tat (Gh)]
&
iphire KRhooli wm cds
elutkrons
| Vlaneuion vF tone Pur B
caton
vile
on be Mize
hls Orblent ap He) etm.
= tn at, & pe Smet %
of a par
6 lt eth orbits
ree vacant
xt Orbital | Catiben
tne donation
Cleutrons Om
4 .
aiibon dey
mono nds,
> Te metal Ug
a syangic oe
Hee ‘bond pelle
mete.
and bonding Onentes
cauieh Slreng than
co ome maa
eo tan Arttbondi'f
orb) tals, Borel Oreler
a 0.
BO x Bond strength %J—
Bonet sgt
om «KS
B04 co
Keve ost
ie KL os.
he
— 9 no.
molecular
dieveases
Aighes Ma dlonatton 4
Os 6-0 bond Sbengen i oto. jn?
) Cv] ° .
() Cric@r,3*
©) Concur)
(a) [ma (eos?
© scanned wtnonenScanserD> camp > high the omen Ceacorney
!
wine Ost,
Bo fie
g
Beshery
@ (rans
Stability of Complen
4 Stability < Formation lonstaut or
Stability constout
ye
‘ Ter
Stepwise Oval
Stecbiti hy Salpollty
constact lonateul
mee ln) me Ne
PTL yak qe ly
Mote CML)
Ke om 6 |
GuFeed
—m,
—6
WLUW UE U EDD d seo a oS
Matt
k= Lines)
cm J09
Muy te —S My
Tm? —()
cmy3Cu9
LEGG
ay
Ki 7K 7 Ky? Ky
disouakKin tonsa /
Basra, ree (Stability corgh
2. htability « te OS of CMA
ed
Sigeo# muttat jon
% Strength 4) ligand
3
dutote Uganas forms more Stable
lompuen,
] - Ceol) I? — Coolen),J”?
MN,
on Pay on iy
en
Sm BE LEI
neo uigands J
tnerepy '
Stabiity *
4 Maveeylle 2
JE gant 2 cycle Wom
het
‘ak Ferma Stalste omplon.
ortamce abd Licaliore.
Coontination Compounds.
wn and estimation gf metal
fearive and j ka
analy can be done Farrar
colour! reattons uu 0 Mo. F Ugors
ecitlly chelating tigamds, %p- 4 euch
Hobie uate ein, 2MG, xanibcse,
e- ‘naphthol, espron |
2 Hordes of voaker & Hoke by — |
Singpp Hbratton Watlen 9, E0TA. Trg
Ca2* ancl Mgr jens Foon Stable cong
aon. corn, “The seceunre esHoraiten § Hose
be cone Bie Ye biffiune a te
1, Detectror
ions
om cam
Btobility lonsterd g ealoum and 0G
Couplers.
3) Exaltion processes of metals Ui Sius
and quid, make use g comply frnass
Gore, for ‘example ,watbing with vyontes
wit tee predemer amd water t
forms the ‘vooeaswesien Caring Cul cn),J
Og neous soutien. tell cam “We Separates
Ue matedtic. form Vacs Soluihian bey bee
aolclivien 4 zine
W) Similarly 5 pudetfi cats ew
acuicmecl Mitouglr formianinn Atel Subsea uses
devemposition 4 tht tooreltvaiien — coupeursl
Fox exanpe, Impun ny kel, es convener! 10
fee, which 4 ducomperseel Yyfetol pu
metals wnt be
BD) Coordin ato vompounrds wu jinponte
ped) ore i ee
for pholosynttetit,, cuerephytlr, &i a Oo
lomp. y My, Hasmegtoon , te red pgm
blood cakes ach md Shain cane’
Coord ican on vor pouee! ag iva
Wer tal = pems'eieus Abwanes
gb
Vitewvien B,,
Gy enoloctasneie »
Loc clita OY)
© scanned wthonen Sanev
caxbonie
eyes Line, Conboy peplidase A amd
anny rare Ceateelysh $ dlelgica!
Systems)
6)
cwoordunction to
cakelyss Fr many Inetusbiel procenes
fvemply Incluse
CrhP),an aI, 4
#)
2)
Wed for Har My Uuagiuation g atkones.
Akticle can be elechopinret ite
Silvey amd golel , math more §i00Hty
onal
womplens, — Cig Con,” wo! ChucenyT™
tran fom
In’ black anol “white - phoregraply.| 2. Linkage leommension ]
Pomvdim apis lus 10 aeabidint RT
tre qeloged — ffilin Fixeal by
Wetsteing — auth
ab solier Mr Umoltronposek
frm a compux jon, [Ay (50) Pe
There 2 ges ingore vo toe wae q
dutate bi methenuten
eset
hom. fan exomuple fs Hak Brennen 3. Solwate./ conta
problems Causeat ly, tu presonue 4 mht
Gh ponte proportions tn lor Fomine
Sptems. Ths, enews 4 topper duel
tron ae rumored by Me Chetlading
Lignacs 0- penile Ark deskenotacn
Big the formotion
ergo viets,, 08
f (ead petiowg Some Coordtiiiaien comp
4 platinum
4
Ga -platin
I50meRISM
[somes - Compounds | compleses
ems
Same
Formula) but Ai Mar
of ah
proces
+ at asda ds
»
diy Out
sprain
[Teommsin]
mypounas ane ied as
MMoclius tompler,
tottkinien Catetlyst, 4
from Solow 4 Hs
Souter claypte metal de,
solution — valitch
Ayfir be
g Pordusrectin
used cin fee brent
Seti Goliiocy Moe
“fumow. te au-
canck PAGE temp
eee
mole war poue Coban cot
csegenntch
‘ma one callad reernny ned
mid teenie
[Eveaiotsorner]
a causa daze 10 Spalkt
urnnpeenint 6 oat
in (90
}: tonisation (sermeceen
ye Cectngy,Ce.).3 on Gotan (ope2J
Tis bsennerccim ebsis bey ely ertude fore
produced by ome fn ogvetms pir Cc]
]- Ceo Cay 4, 18», <> [eetn4 day c
L bmietiee J
Coe Cog), Soy UI Br <> [pe Cy) BF- E’
Thos
vate Ligamel.
nedonge o-donoe
This. som besm oveeres oleae to Ayfoince
in no, Myo molecule [Solvent mrorectes
insicle amet Btkesike Me Co-ordination
spre
histo Speiat type/y lenlsation
Isom estltnn,
%- Ceotnn),I4, Conds TE",
Ceotwy)y LIu 20
4 [otnoI 4, , Cow tno), 4 IU, no,
Coby )y te JADA
+ onfdetion ne Aad Coordination 16
noe changes but no. BO amecleir
a Ug ands yoy f
4. (o- ordination Isomeutim
Thus Uvomouge abuses due re ciffernu
th Ug ants vn vomplae fu
‘ouper tanger lomptet
ee, ei tes Q Respect
EL to-ordinatien tolymuuiiation tomer
buss Ulu | cOmyplen jon gor pelyin erie
2 [ee Cony cy, J — Cre Con), ITPE Gy)
Pehl /
er
Fas|ivom i J
come,
© scanned wtnonen SenerEVES
6) (co-ordination Position som exis © asymenciii eat bidentate Upamas
= Qeytinate
Kk sums cut fe exchange is (yy) z
RW posinen tigands tn beige
* pesin ae. Te bs g U4 ae .
fe complese ong
wa
ny,
aN 2
(4), — Ne b, [>] ew : |
‘on Bes, oA ues Jadentity tompoumels shoves GE2?
=a t
= than diy spar sonngtn (a) Mag
= Stuctotam ea rear Mee 9 [reand
= oe
= (Geomencical] ) Mab |
= bipiypniied aah ne G3 |
Gizee pound nob chats DS ya Cre nny, &
2 on Re BOA |
must has more Seay . ° °
than one A plone’ tuhich |
fore fatal ay gene
Cpa Nad Shows us 4 |
Note: Tetrahediat vomplex not Doin Gx ex in er |
Orly ons rye 4 bord angle as 7 mJ
Price ie. 109.8",
> Gr / ck anc Trae oneeism | td) Mabed ies ceit? brea
shows Gl. > CPE Ne Be FD |
UWordinaton no 72 > ro GF
Coordiivatior ne. 73 7 No.4)
Coovelwin action wo. 4 © M (aay, ji
Co wo.gr Shu 5 4 Ceclend, J
<
i aTebrabed as Squsser Aver a
ne One Genie gr | 4) mCaa) be
essex estuibi _
Catt aegis or iknstemody — rok [de One J ty- Lilon) ch 69 |
Gi — phen Goce Same Ugands au biductite Upam aee aluoayy plac
@nr on Go te lat, ela At 96° te cath oie,
haw 9 uWlin Hoo Same Ugevay
ais preter on 1 % cath e Maa) b,
ole nowt ey
mo
(aa) — symmetnical bidentate ligands ws,
FOR AS 5 Sy (1) mase
: they i
he 7 <
Na qi; [Mm el Com
(ox) °
é aoe frp tro ~ C Obktnedttal comple
a :
oe SLA] Bas
& MA eye 8 4
2 i 3 % 35 25)
- It tS Jue er sf | ge
© scanned wtnonen Saney
Bus Fem fre tonpounds Show OE)?
@) Ma,
Wo. GE ne OF
(b) Ma,s
ho ur Or
) Mab +
ape coe Comp, ad
v ;
ao | iz 4nd
a mM.
sh | z a™ o
bans e
(4 fab,
265
ne 0
fe Stina
| chin? “7 to
Lb
Fadal
1
ye ar
z
faac
Cempen to. of GE | Hog et |
#
Maye, ~ 2 2
“2, May BC 2
2, Magzbs
4, Maghc
sn a,bed
Mab, o
a mahed
SMG be Che Yee a
1Mabodet Te
Maa), be |
Lo Mfaad be
™ (ad),
pie Oe saiyeeneroceitony