Electronic Devices
BITS Pilani                            Dr. Navneet Gupta
Pilani Campus   Department of Electrical and Electronics Engineering
                                BITS Pilani
                                Pilani Campus
Course No. EEE F214/INSTR F214/ECE F214
               Module-10
       Special Purpose Diodes
Disclaimer
 The content used in this presentation is collected from
 various standard textbooks. The copyright is held with
 respective publishers/authors. The content is used for
 academic    purpose    only   and   to    disseminate       the
 knowledge in the field of electronic devices.
                                          Navneet Gupta
                                                   BITS Pilani, Pilani Campus
Optoelectronic Devices                                                   Lecture 36
 Basic particle of light i.e Photon-plays a major role.            Photons Energy:
 Optical sources, detectors & data transmission                    E ph (eV ) 
                                                                                    1.24
                                                                                    (  m)
                         Optoelectronic Devices
     1. Photodiodes/Photodetectors              3. Light Emitting Diodes
     2. Solar Cells                             4. Laser Diodes
      optical              electrical          electrical          optical
       E ph  Eg    not absorbed (semiconductor is transparent).
       E ph  Eg    are absorbed (semiconductor is opaque).
                                                                                              4
                               Prof. Navneet Gupta                   BITS Pilani, Pilani Campus
Photon Absorption
Photons may travel a considerable distance in the semiconductor before being
absorbed. The light intensity decreases exponentially with the distance of travel x
                                          I ( x)  I 0e x
                                           absorption coefficient
                                          1
                                               penetration depth
                                         
                                           I ( x)
                                    gop            optical generation rate
                                            h
 If α is very large then most of the absorption will be close to the surface.
 if α is very small, then most of the light will pass though without absorption.
                                Prof. Navneet Gupta                     BITS Pilani, Pilani Campus
Photodiodes                                               E ph  Eg
                                               Iop
In n-region:    pop  gop p
                                Prof. Navneet Gupta   BITS Pilani, Pilani Campus
 Optically generated current: I op  qAgop ( Lp  Ln  W )
                                          Dp            D      
 Thermally generated current: I th  qA         pn         np 
                                                           n
                                         L              L      
                                          p              n     
                                                   qV       
Total reverse current with illumination: I  I th 
                                                   e kT
                                                          1   I op
                                                             
                                                            
When device is short circuited (V=0)
When device is open circuited (I=0) and V=Voc
For symmetrical junction:
                                                Discuss the effect of
pn = np and τp = τn                              Doping
                                                 Temperature
pn/τn = gth                                      Band Gap
If we neglect the generation within W and gop >> gth; then ??
                                                                        7
          Power is delivered from the         Power is delivered to the
          external circuit                    external circuit
 A photodiode may be used to detect optical signals as we observe the change
in current with change in light intensity when a reverse bias voltage is applied.
 Why are PDs used in reversed biased?
 Performance Parameters: Quantum efficiency and Responsivity
                                                                              8
                             Prof. Navneet Gupta
Solar cell: (unbiased PDs)
Structure
 A solar cell’s structure is identical to a PN junction diode but
  with finger-shaped or transparent electrodes so that light can
  strike the semiconductor.
                          Prof. Navneet Gupta             BITS Pilani, Pilani Campus
   …Solar cell
                                                                  Solar power in India is a fast
                                                                  developing industry. The
                                                   In 2021        country's solar installed
                                                                  capacity was 61.625 GWAC as
                                                                  of 31 October 2022. Solar
                                                                  power generation in India
                                                                  ranks fourth globally in 2021
High quality mono-crystalline solar panels     Solar panel array as the roof on a house
                                   Prof. Navneet Gupta                      BITS Pilani, Pilani Campus
  Solar Cell:
  Principle of Operation
                                                                   The amount of absorption reduces
                                                                   with depth and hence the depletion
                                                                   region must be close to the surface
                                                                   to maximize absorption. This is
                                                                   achieved by having a thin n region.
Adapted from Principles of Electronic Materials - S.O. Kasap
                                             Prof. Navneet Gupta                       BITS Pilani, Pilani Campus
Solar cell
Equivalent circuit
                                Iop
                                            Ith    q
 The total diode (solar cell) current is the sum of the current generated by the
 voltage and that generated by light.
             qV    
   I  I th  e  1  I op
                kT
                    
  Output Power = P = IV
                                                                      BITS Pilani, Pilani Campus
 Solar Cell:
 IV Characteristics
Solar cell operates in the fourth quadrant of the IV plot. Since I and V have opposite signs,
solar cell generates power.
                                                                              I mVm
     Pm  I mVm
                                 P   I V
                                m  m m                          FF 
                                 Pin  Pin                                     I scVoc
                                                                                 BITS Pilani, Pilani Campus
Light Emitting Diodes                                          Lecture 37
 LED is essentially a pn junction diode typically made from a direct bandgap
  semiconductor.
 The electrons and holes recombine by emitting photons (light) with hv ≈ Eg.
 By adjusting the composition of the semiconductor, Eg can be altered to
  make blue, green, yellow, red, infrared, and UV LEDs possible. They are
  made of compound semiconductors involving In, Ga, Al, As, P, and N.
                              Prof. Navneet Gupta                 BITS Pilani, Pilani Campus
Light Emitting Diodes
Light emitting diodes (LEDs)
 LEDs are made of compound semiconductors such as InP and GaN.
 Light is emitted when electron and hole undergo radiative recombination.
             Ec
           Radiative                     Non-radiative
           recombination                recombination
                                        through traps
             Ev
                           Prof. Navneet Gupta              BITS Pilani, Pilani Campus
Light Emitting Diodes
Performance Parameters
• Frequency (colour) of the photons:                     Eg (eV ) 
                                                                       1.24
                                                                       ( m)
• External quantum efficiency:                        no. of photons escaped
                                           ext. 
                                                    no. of injected charge carriers
• Internal efficiency:                    no. of photons radiated
                              int 
                                       no. of injected charge carriers
                                               no. of photons escaped
• Extraction efficiency: extraction 
                                       no. of photons radiated
• ηext = ηint x ηextraction
                                                                                              16
                         Prof. Navneet Gupta                            BITS Pilani, Pilani Campus
Loss Mechanisms
  Absorption within the LED material
  Fresnel loss: Reflection loss when light passes from
   semiconductor to air due to difference in R.I.
  Critical angle loss: TIR at angles > critical angle (θc)
 Hence , typically LEDs are made with a dome-type encapsulation,
 which acts as lens so that more of the photons can be extracted.
                        Prof. Navneet Gupta             BITS Pilani, Pilani Campus
                          LED Materials
                                                    Compound semiconductors
                                          Lattice
       Eg(eV)
       E (eV )   Wavelength
                   (μm)
                               Color     constant
                                           (Å)
                                                    binary semiconductors:
InAs    0.36       3.44                   6.05        - Ex: GaAs, efficient emitter
InN     0.65       1.91       infrared    3.45
                                                    ternary semiconductor :
InP     1.36       0.92                   5.87       - Ex: GaAs1-xPx , tunable Eg (to vary
                                                    the color)
GaAs    1.42       0.87         Red
                                red       5.66
                               yellow
                              Yellow
GaP     2.26       0.55         blue
                              Green       5.46      quaternary semiconductors:
                               violet
                               Blue                 - Ex: AlInGaP , tunable Eg and lattice
AlP     3.39       0.51                   5.45      constant (for growing high quality
GaN     2.45       0.37                   3.19      epitaxial films on inexpensive
                                                    substrates)
AlN     6.20       0.20         UV        3.11
Light-emitting diode materials
                                    1.24       1.24
       LED wavelengt h (  m)               
                                photon energy Eg (eV )
                                Prof. Navneet Gupta
LED Material
Eg  AB1 x Cx   Eg ( AB)   Eg ( AC )  Eg ( AB)  x
Eg (GaAs1-xPx)
Direct Band gap:
GaAs = 1.43 eV
GaP = 2.75 eV
Indirect band gap:
GaAs = 1.86 eV
GaP = 2.26 eV
                                       Prof. Navneet Gupta   BITS Pilani, Pilani Campus
New Technology
OLED
 OLED’ stands for Organic Light-Emitting Diode - a technology that
  uses LEDs in which the light is produced by organic molecules.
                                                      Flexible OLED
                                                            BITS Pilani, Pilani Campus
Advance ED Course
 EEE F419: Flexible and Stretchable Electronics
Course Description:
    Introduction to flexible and stretchable electronics (FSE), material systems
    and scaling issues; materials and substrates for flexible and printed
    electronics, Material Considerations and various properties, techniques
    for fabrication and characterization of FSE devices, mechanics of thin-films
    and flexible devices, various flexible and stretchable devices: solar cells,
    displays, thin-film transistors, sensors, artificial skin and actuators;
    human-machine interfaces, wearable electronics for emerging
    applications.
                                                                          BITS Pilani, Pilani Campus