Index
Index
GHS02 GHS07
55.2.1
Page 2/13
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.11.2022 Version number 111.01 Revision: 17.11.2022
(Contd. of page 1)
- 2.3 Other hazards
- Results of PBT and vPvB assessment
- PBT: Not applicable.
- vPvB: Not applicable.
- Determination of endocrine-disrupting properties
78-93-3 2-Butanone List II
55.2.1
Page 3/13
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.11.2022 Version number 111.01 Revision: 17.11.2022
(Contd. of page 2)
- 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
55.2.1
Page 4/13
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.11.2022 Version number 111.01 Revision: 17.11.2022
(Contd. of page 3)
- 7.2 Conditions for safe storage, including any incompatibilities
- Storage
Protect against direct sunlight, other sources of heat and ignition.
Store in cool, dry conditions in well sealed containers.
- Requirements to be met by storerooms and containers:
Observe official regulations on storage and handling of water harzardous substances
- Information about storage in one common storage facility:
Pay attention to regulations / technical guidelines on mixed storage of flammable liquids.
- Further information about storage conditions:
Pay attention to regulations/technical rules for the storage of combustible liquids.
Store in cool, dry conditions in well sealed containers.
- Storage class 3 (VCI - Konzept, 2007)
- 7.3 Specific end use(s) No further relevant information available.
55.2.1
Page 5/13
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.11.2022 Version number 111.01 Revision: 17.11.2022
(Contd. of page 4)
Inhalative DNEL (worker) 600 mg/m³ (Long-term, systemic effects)
DNEL (population) 106 mg/m³ (Long-term, systemic effects)
- PNECs
64-17-5 ethanol
PNEC water 2.75 mg/l (intermittent releases)
0.96 mg/l (freshwater)
0.79 mg/l (marine water)
PNEC sediment 3.6 mg/kg dw (freshwater)
2.9 mg/kg dw (marine water)
PNEC soil 0.63 mg/kg dw (soil)
PNEC STP 580 mg/l (sewage plant)
67-64-1 acetone
PNEC water 10.6 mg/l (freshwater)
1.06 mg/l (marine water)
PNEC 21 mg/l (intermittent releases)
100 mg/l (sewage plant)
PNEC sediment 30.4 mg/kg dw (freshwater)
3.04 mg/kg dw (marine water)
PNEC soil 29.5 mg/kg dw (soil)
67-63-0 propan-2-ol
PNEC water 140.9 mg/l (freshwater)
140.9 mg/l (marine water)
PNEC 2,251 mg/l (sewage plant)
PNEC sediment 552 mg/kg dw (freshwater)
552 mg/kg dw (marine water)
PNEC 140.9 (intermittent releases)
PNEC soil 28 mg/kg (soil)
78-93-3 2-Butanone
PNEC water 55.8 mg/l (freshwater)
55.8 mg/l (marine water)
PNEC sediment 284.74 mg/kg dw (freshwater)
284.7 mg/kg dw (marine water)
PNEC soil 22.5 mg/kg dw (soil)
PNEC STP 709 mg/l (sewage plant)
- Additional information: The lists that were valid during the compilation were used as basis.
- 8.2 Exposure controls
- Appropriate engineering controls
Room ventilation i.e. vacuum suction. Measures to be taken against electro-static sparks.
- Individual protection measures, such as personal protective equipment
- General protective and hygienic measures
Keep away from food, beverages and fodder.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Gases, fumes and aerosols should not be inhaled.
(Contd. on page 6)
EUE
55.2.1
Page 6/13
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.11.2022 Version number 111.01 Revision: 17.11.2022
(Contd. of page 5)
- Breathing equipment: Use breathing protection in case of insufficient ventilation.
- Recommended filter device for short term use: Combination filter A-P2
- Hand protection Protective gloves.
- Material of gloves
Butyl rubber, BR
Fluorocarbon rubber (Viton)
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
- Penetration time of glove material
Material of gloves is recommended for a short-term single use to protect from splashes. For permanent
usage contact manufacturer of gloves.
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
- Eye/face protection Eye glasses with side protection (EN 166)
- Body protection:
Standard proctective clothing. Chemical resistant safety-shoes or boots. If skin contact is possible, wear
inpenetrable protective clothing against this solvent.
55.2.1
Page 7/13
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.11.2022 Version number 111.01 Revision: 17.11.2022
(Contd. of page 6)
55.2.1
Page 8/13
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.11.2022 Version number 111.01 Revision: 17.11.2022
(Contd. of page 7)
Dermal LD50 >2,000 mg/kg (rabbit) (OECD 402)
Inhalative LC 50 / 4 h >50 mg/l (rat) (OECD 403)
>20 mg/l (mouse)
67-64-1 acetone
Oral LD50 5,800 mg/kg (rat)
Dermal LD50 7,426-15,800 mg/kg (rbt)
Inhalative LC 50 / 4 h 76 mg/l (rat)
67-63-0 propan-2-ol
Oral LD50 5,840 mg/kg (rat) (OECD 401)
4,570 mg/kg (rat)
Dermal LD50 >2,000 mg/kg (rabbit)
13,400 mg/kg (rab)
Inhalative LC 50 / 4 h 30 mg/l (rat)
78-93-3 2-Butanone
Oral LD50 3,300 mg/kg (rat)
Dermal LD50 5,000 mg/kg (rbt)
Inhalative LC 50 / 4 h 34.5 mg/l (rat)
40 mg/l (mus)
- Skin corrosion/irritation Less irritating. Remove lipid skin-film.
- Serious eye damage/irritation
Causes serious eye irritation.
- Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
- Germ cell mutagenicity Based on available data, the classification criteria are not met.
- Carcinogenicity Based on available data, the classification criteria are not met.
- Reproductive toxicity Based on available data, the classification criteria are not met.
- STOT-single exposure Based on available data, the classification criteria are not met.
- STOT-repeated exposure Based on available data, the classification criteria are not met.
- Aspiration hazard Based on available data, the classification criteria are not met.
- STOT-repeated exposure:
64-17-5 ethanol
Oral NOAEL 1,760 mg/kg (rat) (OECD 408, 90 d, target organ: liver)
67-64-1 acetone
Oral NOAEL 900 mg/kg (rat) (KG/day 90 days)
67-63-0 propan-2-ol
Oral NOAEL 900 mg/kg (rat) ((90d) OECD 408)
- 11.2 Information on other hazards
- Endocrine disrupting properties
78-93-3 2-Butanone List II
EUE
(Contd. on page 9)
55.2.1
Page 9/13
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.11.2022 Version number 111.01 Revision: 17.11.2022
(Contd. of page 8)
55.2.1
Page 10/13
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.11.2022 Version number 111.01 Revision: 17.11.2022
(Contd. of page 9)
55.2.1
Page 11/13
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.11.2022 Version number 111.01 Revision: 17.11.2022
- Stowage Category B
- 14.7 Maritime transport in bulk according to IMO
instruments Not applicable.
- Transport/Additional information:
- ADR/RID
- Limited quantities (LQ) 1L
- Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
- IMDG
- Limited quantities (LQ) 1L
- Excepted quantities (EQ) Código E4
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
- UN "Model Regulation": UN 1993 FLAMMABLE LIQUID, N.O.S. (ETHANOL
(ETHYL ALCOHOL), ACETONE), 3, II
GHS02 GHS07
55.2.1
Page 12/13
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.11.2022 Version number 111.01 Revision: 17.11.2022
55.2.1
Page 13/13
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.11.2022 Version number 111.01 Revision: 17.11.2022
55.2.1