Paper - 1
Paper - 1
SYMPOSIUM
Paper No. 1
IFA
PARIS - FRANCE
ABSTRACT
In 1828, Frederick Waller for the first time synthesized an organic substance, urea,
fiom purely inorganic salts. From that date till now urea has become the most used
nitrogen fertilizer in the world.
For the &re there are still a lot of opportunities to invest in urea market, even if
the efficiency of urea during soil application should increase.
3rd SNAMPROGElTI WORLDWIDE                        PAPER 1
UREA USERS SYMPOSIUM                              Page 1
Sorrento-Italy,June 18-22, 1996
Contents
1. Introduction
4. Trade Ammonia
         6.   Conclusions
3rd SNAMPROGETZI. WORLDWIDE                                                          PAPER 1
UREA USERS SYMPOSIUM                                                                 Page 2
Sorrento-Italy,June 18-22, 1996
INTRODUCTION
         In 1828, Frederick Waller synthesized for the first time an organic substance, urea,
         from purely inorganic salts. This started the whole science of organic chemistry.
         Most of the urea produced is used as fertilizer. In the USA, for example, about 92%
         is used as a fertilizer, particularly on corn, wheat, cotton and rice.
         The success of urea as a fertilizer is primarily explained by its high nitrogen content.
         With 46% N, urea is the straight nitrogen fertilizer with the highest nutrient
         concentration, thus providing substantial economies per unit of N in the costs of
         storage, handling, transport and application.
         A major problem with urea is its incompatibility with certain other fertilizers, such as
         ammonium nitrate and other nitrates, and limited compatibility with the
         superphosphates.
         Both urea and ammonium nitrate are hygroscopic unless treated, but the
         hygroscopicity of a mixture of the two components is much greater than that of the
         individual components. The critical relative humidity of urea at 30°C is 73%, that of
         ammonium nitrate 59%, that of a mixture of the two, 18%. This may in fact be
         helpfbl in the production of urea-ammonium nitrate solution but causes difficulties in
         blends. The high hygroscopicity of most urea-based NPK products can pose a
         problem in hot, humid areas.
                 Urea has increased its share of ammonia demand fiom 34% to 41% during the
                 period 1988 to 1994. Other fertilizer products, including direct application ammonia
                 account for approximately 45% of total ammonia demand, with the balance of 14%
                 used in non-fertilizer applications.
                 In 1922, Germany was the iirst country to produce urea commercially, followed by
                 the USA in 1932 and England in 1935. The US industry developed fiom one
                 producer in the early 1930s, when 800 t of urea was produced by Dupont, to 3 1 in
                 1981, falling to 17 by 1991, due largely to mergers.
                 Up to the 1960s, the development of the nitrogen industry took place in the
                 developed countries of West Europe, North America and Japan. However, after the
                 mid-1970s, the construction of new plants shifted to the gas-rich countries of the
                 Caribbean and Middle East and also to some large consuming countries such as
                 China, India, Indonesia and Pakistan. At the same time, many plant closures
                 occurred in West Europe and Japan.
                 During the period 1973 to 1995, urea increased its share of the world nitrogen
                 fertilizer market fiom 20% to nearly 50%. Urea is by far the dominant nitrogen
                 fertilizer used in developing countries and is increasing its share in these markets.
                 During the period 1988 to 1994, urea increased its share of nitrogen fertilizer
                 demand fiom 58% to 62% in Asia and fiom 50 to 58% in Latin America. In Europe
                 and the FSU the use of ammonium nitrate is more widespread, for agronomic
                 reasons
Gas
                 Gas costs represent up to 75% of ammonia production costs. The cost of gas, which
                 is linked to the price of crude oil, has a direct bearing on the price of ammonia.
                 Approximately 7% of total annual industrial natural gas use in the USA goes to
                 nitrogenous fertilizer production, with about one fourth of this amount, or 2%, to
                 urea production. In West Europe, the fertilizer industry accounts for approximately
                 4% of gas usage. Natural gas accounts for more than 80% of all input costs to urea
                 production.
                 The countries of the FSU have the biggest share of world natural gas reserves,
                 followed by the Middle East. While the price of gas in Russii has increased
                 dramatically, when converted to US dollars it remains very competitive. About one
      'Note: A disadvantage of urea compared,for example, with ammonium nitrate, is that the amide nitrogen must
     first be transjormed to ammonium as a result of soil microbial action, which is dependent upon temperature.
     Also, ammonium N, althoughfilly available, has a somewhat slower eflect, because it isfirst acisorbed on soil
     particles and then only gradually released and nitrified. This is a disadvantage when quick action is required,
     for example, for application in spring at rather low temperatures.
3rd SNAMPROGE'ITI WORLDWIDE                                                           PAPER 1
UREA USERS SYMPOSIUM                                                                  Page 4
Sorrento-Italy,June 18-22, 1996
            third of the world's supplies are in the Arabian Gulf,where gas costs are
            exceptionally low, but where capital, labour and water costs are high. Trinidad has
            low cost gas and substantial reserves. The cost of gas for fertilizer production is
            relatively low in Indonesia and Malaysia.
            In the 1980s, many experts predicted that US prices of natural gas would increase
            very sigruflcantly, forcing many ammonia plants to close. However, recent
            technological breakthroughs have also helped to reduce the cost of production of
            natural gas :
            - computer assisted three dimensional seismic exploration helps to reduce the
                 time and cost of exploration and field delineation;
            - horizontal drilling over an horizontal distance of up to 8-10 krn from the well-
                 head helps to reduce field development costs;
            - the development of deeper offshore fields gives access to additional oil and gas
                 resources. Shell has now undertaken the development of the Mensa gas field in
                 the gulf of Mexico, under 1600 m of water.
            In West Europe, the new technologies have made it possible to increase oil
            production very sigruflcantly. They also help developing gas production in the North
            Sea, but gas use is expected to grow very significantly in Central and West Europe.
            Many developing countries do their best to attract international oil and gas
            companies for exploration and field development. The production of natural gas may
            increase, but in most cases, gas demand, for power generation particularly, will grow
            faster. The possibilities of building additional gas-based ammonia plants are
            relatively limited. Competition for available gas supplies is posing problems for the
            fertilizer production industry in India and Pakistan.
            International urea trade increased steadily up to 1988, reaching a peak of almost 9.5
            Mt' N. It fell back in 1990 and 1991, due to lower West European demand, the
            disintegration of COMECON, US anti-dumping measures, increased production and
            leveling off of demand in China as well as high stocks in India. During this period,
            supply declined as Romanian exports collapsed, Iraq and Kuwait production was
            removed from the world market. However, trade recovered in 1993 to return to its
            1988 level, and there were substantial increases in 1994 and 1995.
          Urea export supplies fiom Central Europe and the FSU continue to dominate the
          market, accounting for nearly 40% of world trade. In 1995, the FSU represented
          29% of world exports, Central Europe 11%, the Middle East 21%, Indonesia1
          Malaysia/Bangladesh accounted for 11% and MexicolTrinidad/Venezuela for 8%.
          There has been a large increase in the price levels for both ammonia and urea since
          1994. There was a recovery in demand and, contrary to earlier practice, the FSU has
          acted as the main price setter. At the same time, the cost of supply has increased,
          particularly in the Ukraine which relies heavily upon imported natural gas feedstocks
          fiom Russia to produce both ammonia and urea for export.
         The economics of urea production in 1995 were so favourable that plants operated
         at the maximum of their capability virtually all over the world, with the exception of
         the former Soviet Union where long distances to the ports and poor logistics remain
         serious constraints.
         Central Europe
         In spite of the high cost of natural gas, the production and exports of urea increased
         in 1995 by about 0.3 Mt N to reach 1.3 Mt. The main increases were in Romania
         and Poland.
         FSU
         FSU urea production and exports increased respectively by 11% and 19% in 1995.
         The annualized rate of the Russian urea exports for the first quarter 1996 was 2 %
         higher than that of 1995. Despite earlier forecasts that the cost of gas would make
         its industry uncompetitive, Ukraine continues to be a significant contributor to world
         trade. In fact, urea exports fiom Ukraine increased by 3% in 1995, accounting for
         10% of world urea trade.
          Middle East
          Contrary to the FSU, priority has been given to urea exports rather than ammonia.
          The major increase in urea export supplies in recent years has come fiom the
3rd SNAMPROGE'ITI WORLDWIDE                                                        PAPER 1
UREA USERS SYMPOSIUM                                                               Page 6
Sorrento-Italy,June 18-22, 1996
         Arabian Gulf and this is expected to continue to be the case in future. There are a
         number of export projects either under construction or scheduled to enter
         production before the end of the century within the Arabian Gulfarea.
         The urea exports of the region increased in 1995 by 7 % to reach 1.9 Mt N. The
         main increases were in Abu Dhabi and Kuwait. The commissioning of a urea plant in
         Bahrain in 1997198 will fbrther increase urea exports at the expense of ammonia
         shipments.
         Asia
         In 1995, China and India accounted for 28% and 13% respectively of world imports.
         For many years Asia has dominated world urea import demand, although there have
         been shifts in the volumes imported into individual countries. In 1988, China
         dominated the market, accounting for over 40% of total world import demand.
         Chinese imports of urea fell dramatically in 1993, following some major agricultural
         and economic reforms, recovering in 1994 and 1995. The fill in China's imports was
         compensated by increases by India and other countries in the Far East, which helped
         to maintain Asia's dominance of the world import market for urea.
         As regards China, it is estimated that the total urea imports of China reached 3.1 Mt
         N in 1995, compared to 1.6 Mt N in 1994, 62 % of the tonnage being supplied by
         the FSU. China, having increased imports during the first quarter of 1996 by lo%, is
         generally expected to import at least as much as it did last year, close to 7 Mt
         product.
         As regards India, it is estimated that the total urea imports of India reached 1.5 Mt
         N in 1995, compared to 1.2 Mt in 1994. Indian urea imports in 1996 will be sharply
         reduced from the very high level of 1995, due to high stocks and good domestic
         production levels.
         The urea exports of Indonesia and Malaysia increased by 19% in 1995 to reach 1.1
         Mt N. This is somewhat less than anticipated as 2 new plants were commissioned in
         Indonesia in 1994195 and 2 others were debottlenecked. A further increase is
         anticipated in 1996 and also in 1997198 when a new urea plant will be commissioned
         at Bontang. However, domestic urea consumption is also growing fast.
         Nitrogen solutions are aqueous mixtures, usually of urea and ammonium nitrate, the
         nitrogen content of which usually ranges from 28 to 32%. UAN solutions are easy
         to handle, can be more uniformly applied to the soil than solid fertilizers, can be
         metered into irrigation water, are less costly than ammonia to transport and store,
         and direct production from urea and ammonium nitrate reactor solutions eliminates
         prilling or granulation costs. However, lower nitrogen content increases shipping
         costs per unit of nitrogen and different equipment is required for application than
         that used to apply dry fertilizers.
3rd SNAMPROGETTI WORLDWIDE                                                        PAPER 1
UREA USERS SYMPOSIUM                                                              Page 7
Sorrento-Italy,June 18-22, 1996
         In 1995, UAN exports from the USA to Europe virtually ceased as the product was
         in high demand in the US and the European prices were not attractive. However
         they were replaced by UAN shipments from the FSU, where there are several
         projects for the production of this product. The port logistics have also improved.
         Ventspils uses tanks formerly used to receive superphosphoric acid. These tanks are
         therefore equipped with heating devices which make it possible to store UAN 32 in
         winter.
         Improved financial results in 1994 and 1995, and the experience of a very tight
         ammonia supply in early 1995, have led many producers of ammonia and
         nitrogenous fertilizers to consider projects for the debottlenecking of existing
         capacities or the building of new ammonia and urea plants.
         The FSU urea exports are expected to increase slightly in 1996 due to the
         commissioning in 1995 of a new urea plant at Cherepovets (Russia). The building of
         a new urea plant at Dneprozerzhinsk (Ukraine) has been announced but will
         probably not be implemented before the end of the review period, though part of the
         equipment was already delivered before the collapse of the USSR.
3rd SNAMPROGETI'I WORLDWIDE                                                                                                                                                   PAPER 1
UREA USERS SYMPOSIUM                                                                                                                                                          Page 8
Sorrento-Italy, June 18-22, 1996
         Further modernization of all the FSU capacity is needed but a limited number of
         plants urgently need to be revamped in order to cut energy consumption and
         improve reliabiity. These plants belong to rather conservative companies which have
         done little so far to improve them. It may be too late now to modernize the plants. It
         will be very difEcult for these companies to find the necessary financial resources
         and some of the plants could close. However, much will depend on the future
         government of Russia and on the support it may give to State enterprises and to
         employment.
          Elsewhere in the world, many projects for the construction of new capacities have
          been announced or are under implementation.                                                                                                                                              --
          Some of the projects are firm or already under implementation. Others could still be
          delayed or abandoned.
3rd SNAMPROGETII WORLDWIDE                                                          PAPER 1
UREA USERS SYMPOSIUM                                                                Page 9
Sorrento-Italy,June 18-22, 1996
         USA
         There is an unanticipated expansion of production capacity in the USA reflecting a
         change in the expectations concerning gas availability and cost. Our 1996 survey
         shows that the North American ammonia capacity will increase by 1.7 Mt N from
         1995 to the year 2000, some 36 % of which will be achieved through plant
         debottlenecking. New technologies make it possible to increase plant capacity by
         some 28 %.
         Latin America
         In Argentina, PASA plans to build a new complex. It could be located at Bahia
         Bianca close to the gas source and to an export port. Return fieight is available there
         f?om the rail cars used to transport grains to Argentina's main export port. The
         alternative location would be the region of Rosario in the heart of the consumption
         area but accessible only by smaller ships.
         Africa
         No progress has been reported recently in Nigeria concerning the project for the
         doubling of the NAFCON ammonia and urea capacity which has been considered for
         a long time already. The additional urea capacity would be 0.2 Mt N.
         Near East
         The implementation of a urea and export ammonia complex to be built in Oman in
         the frame of a joint-venture with an Indian company, could be firher delayed due to
         financial problems, particularly concerning the high cost of hf?astructure. On the
         other hand, we understand that in Qatar a Qafco IV project is being considered and
         a decision could be taken soon. A project at Abu Dhabi is also under consideration
         but not included in the forecast.
         Iraq is an important potential exporter of urea but we cannot predict when the
         embargo on Iraqi exports will be lifted. These plants are included in our forecast.
         The total urea capacity is 0.8 Mt N.
3rd SNAMPROGETTI WORLDWIDE                                                                                      PAPER 1
UREA USERS SYMPOSIUM                                                                                            Page 10
Sorrento-Italy,June 18-22, 1996
         South Asia
         India commissioned three new ammonia-urea complexes in 1994/95 and has
         announced a very impressive list of new plants.
         Four urea plants and six ammonia plants are under construction. Two of the
         ammonia plants are replacing older capacity. The four new urea plants will use
         ammonia produced from naphta or a combination of naphta and natural gas as a
         feedstock, in view of the demand for natural gas for other purposes.
         In addition, eight new ammonia-urea projects, also to be based mainly on naphta, are
         being considered.
         A feature of the new projects is that many of them will use other feedstocks than
         natural gas. Many of the existing gas-based plants are already shifting their boilers to
         other sources of energy, primarily naphta and fbel oil but also liquefied natural gas,
         LNG,near the West coast. We understand that the first four urea plants will receive
         naptha at concessional prices from local refineries. The other plants will have to be
         supplied with imported naphta at the market price. The price of imported naptha
         would be considerably higher than that of local naptha, which is already higher than
         that of natural gas. It is therefore not certain that all these plants will materialize. For
         our forecasts we assume that the first four urea plants and a small expansion of
         existing units will be commissioned as planned between 1996 and 1998. However,
         our forecast assumes that none of the plants in table 4.2. will be commissioned
3rd SNAMPROGETTI WORLDWIDE                                                           PAPER 1
UREA U S E R S S Y M P O S I U M                                                     Page 11
Sorrento-Italy,June 18-22, 1996
         during the period of the forecasts, i.e. to the year 2000. The forecast potential
         production for the year 2000 may therefore be understated.
         The project for a gas pipeline fiom Oman to India has been shelved but a project for
         a gas pipeline fiom Qatar or Iran to India via Pakistan is being considered. Imports
         of LNG will probably start in a less distant future.
         Socialist Asia
         In China, we understand that work is in progress concerning the modernization of
         the medium-scale urea plants. The objective is to increase output, improve quality
         and reduce energy consumption. Most of these plants are coal-based and improved
         gasification techniques will make it possible not only to reduce coal consumption but
         also to use local coal qualities rather than anthracite transported fiom distant mines.
         The output of these medium-scale urea plants is already increasing.
         The Fudao project, the fist ammonia-urea complex to be built on Hainan island, is
         expected to be commissioned at Basauo in 1996 or 1997. The building of a second
         ammonia-urea complex, using second-hand equipment, has reportedly been
         approved by the Chinese authorities.
         We understand that a decision will probably be taken soon as regards the integrated
         project in Vietnam for a power plant and ammonia-urea complex. The urea capacity
         will be 0.3Mt N. It is not yet included in our forecast.
         TRADE AMMONIA
         This paper concerns the urea situation but the supplyldemand balance for ammonia
         traded as such cannot be disregarded. Some producers can lower their fertilizer
         production in order to increase the availability of ammonia for sale, and vice-versa.
3rd SNAMPROGE'ITI WORLDWIDE                                                        PAPER 1
UREA USERS SYMPOSIUM                                                               Page 12
Sorrento-Italy,June 18-22, 1996
         The main increases will take place in Trinidad and Venezuela, due to the
         commissioning of 4 new or second-hand plants, in North America with the
         recommissioning of 2 second-hand plants and the debottleneclcing of many existing
         units, and in the Middle East due to the commissioning of new plants.
         The available supply of trade ammonia will be reduced by about 1.3 Mt N due to the
         commissioning of downstream units, for the production of urea or UAN solution at
         sites where there currently is an ammonia surplus for sale.
         The net increase in trade ammonia supply is therefore expected to amount to about
         2.5 Mt N by the year 2000. The figure is probably understated as we suspect that a
         sigmficant number of projects for plant debottlenecking have not been announced
         yet. On the other hand, certain ammonia projects could still be delayed or
         abandoned.
         As regards demand, the most sigmficant increase in ammonia import demand since
         1988 has been in the US Gulf,mostly for DAP production. However, this increase
         was largely offkt by the decrease in West European import demand. Future
         increases in ammonia import demand will be in the Far East (primarily Taiwan,
         Republic of Korea, Thailand and possibly Japan), the US Gulf and North a c a .
         Increases in the US Gulf and Morocco are for DAP production and ammrnonia
         would be required for new DAP and NPK plants in Jordan, Vietnam and Thailand.
         Otherwise the increasing requirements in the Far East are mostly for industrial          .. .
         applications. As a whole, the additional demand of trade ammonia could amount to
         about 1.4 Mt N by the year 2000. This may be optimistic as it assumes a full use of
         the new capacities.
         Based on the above calculation, trade ammonia supply could grow faster than
         demand and could result in a capacity surplus of about 1.1 Mt N, i.e. about 1.3 Mt
         ammonia.
3rd SNAMPROGE'ITI WORLDWIDE                                                         PAPER 1
UREA USERS SYMPOSIUM                                                                Page 13
Sorrento-Italy,June 18-22, 1996
-A SUPPLYIDEMAND BALANCES
         If some of the projects are delayed (Argentina, Oman, Venezuela, the relocation of a
         plant in the UAE) and if the embargo is not lifted on Iraqi exports, the world supply
         surplus would only amount to 1.7 Mt N or 3 % in the year 2000.
         The surplus could be slightly higher if all Indian projects were implemented. Also,
         there is a long list of additional projects being considered. Past experience has
         shown that in certain regions, in the Arabian Gulf particularly, ammonia-urea
         complexes can be built in a rather short period of time, at sites where all the
         i&astructure is in place, and that their capacity use rates can reach 100 % in less
         than 24 months. More urea could therefore become available by the year 2000 than
         anticipated in this study.
         An agronomic problem with urea, in both solid form and as UAN solution, is the
         loss of nitrogen following application. If the urea is incorporated in the soil
         immediately after spreading, losses are minimal, but if this is not the case, they can
         be substantial. This applies especially to calcareous soils, and in the tropics in the
         case of flooded rice fields and crops which are not tilled, such as banana, sugar cane,
                                                                                                   J
3rd SNAMPROGETII WORLDWIDE                                                           PAPER 1
UREA U S E R S SYMPOSIUM                                                             Page 14
Sorrento-Italy,June 18-22, 1996
         oil palm, rubber and 'others. Volatilization losses under such conditions are estimated
         at 15% to 20% of the amount of nitrogen applied.
         On rice, under flooded soil conditions, losses through denitrification may be high,
         particularly when flooding and drying out alternate.
         For both economic and environmental reasons it is evidently desirable to reduce this
         loss. Much can be done by improving the agricultural techniques but there is also
         scope for improved products.
         Granular urea is recognized to increase the nitrogen efficiency and yield potential of
         the crops. The demand for granular urea is greatest in countries where bulk blending
         or aerial application is important. However, the cost of granular urea is higher than
         that of priJled urea. Hence, in developing countries, where bulk blending and aerial
         application are not common, and where f m sizes tend to be much smaller than in
         the US, there is an unwillingness to pay the premium and the use of granular urea
         has not developed sigmficantly. Furthermore, skill is required on the part of the
         h e r s in order to exploit the advantages of the product, and the advisory services
         are usually inadequate.
         Large size "super-granules" have also been shown to be effective for rice. Apart
         &om the higher cost of the product, their placement, manual or by means of simple
         equipment, is labour intensive. They too have had limited success to date.
         Controlled-release urea products have substantial agronomic advantages, especially
         in tropical countries, in regions with light-textured soils under heavy rainfall or
         irrigation, where N losses are high. Controlled-release fertilizers are also less
         sensitive to air humidity and temperate fluctuation, hence easier to store, and are less
         susceptible to leaching in the soil.
         However, the share of the world fertilizer market accounted for by controlled-
         release fertilizers is only about 0.1%. This is because they cost much more than the
         traditional products. Their use is increasing slowly on high value cash crops, in
         horticulture, vegetables in the tropics, but not on the main agricultural crops.
         Nitrification inhibitors are effective in reducing losses under certain conditions, but
         apart &om the cost and the question of the technique of use, the presently available
         products have not given satisfictory results on high-temperature soils. However, an
         interesting possibility is the application of urea, or UAN solution, amended with a
         urease inhibitor, which should permit a substantial reduction in nitrogen losses. In
         the spring of 1996, IMC Global introduced onto the US market, the urease inhibitor
         AGROTAIN, based on N (n-butyl) thiophosphoric triamide. There is a tremendous
         potential for urease inhibitors in world agriculture, for both economic reasons and
         for protection of the environment, and it will be interesting to follow the
         development of this product.
         Acknowledgement: 'Fedhers and Raw Materiels Supply and SupplyDemand Balances' by P.L.
         Louis. /FA, presented at the 64th /FA Annuel Conference heM in W n in May 1996.
    3 rd SNAMPROGETII WORLDWIDE                                                           PAPER 1
    UREA U S E R S SYMPOSIUM                                                              Page 15
    Sorrento-Italy,June 18-22, 1996
i
             The efficiency of nitrogen fertilizers and the loss of nitrogen to the air and to water,
             are receiving adverse publicity and we anticipate that this problem will receive
             increasing attention during the coming years. The solution to this problem will
             require considerable investment, not only in the research and development of new
             products and their use, but also in advising farmers on how to use them effectively.