SCH4U Lesson 18 Assignment: in This Assignment You Are Going To Continue Your Study of Acid-Base Equilibrium
SCH4U Lesson 18 Assignment: in This Assignment You Are Going To Continue Your Study of Acid-Base Equilibrium
In this assignment you are going to continue your study of Acid-Base Equilibrium
Instructions:
After completing the lesson action section, you are ready to complete your lesson assignment. Follow these steps:
a) In the textbox given, explain the strategy that you used to determine your answer.
b) Fill in your answer. The mark for each question is given at the introduction to the questions.
c) When finished answering all your questions, save your file and upload the file into the appropriate dropbox.
Part A (Terminology): Matching: (44) using your readings, match each term and the definition provided. The name of
the term is given in the table and the definitions are listed below. Match the name of the term and its corresponding
definition. As part of your answer, identify source of your information. Each question is worth 2 marks. One for the
matching and one mark for your proof.
____ 3. a ratio of the molecules that dissociate into ions at equilibrium to the initial concentration of the acid
E
Part B (Acid-Base Reactions): Multiple Choice: ( 38 marks) each question is worth 2 marks. One mark for the
strategy and one mark for the final answer.
Identify the choice that best completes the statement or answers the question. Your choices are given below the
text box. Make sure you include your strategy.
a. CO32–(aq)
b. CH3COO–(aq)
c. H2S (aq)
d. C6H5NH2 (aq)
e. none of the above
a. HClO4(aq)
b. HOCl(aq)
c. H2O(l)
d. H3O+(aq)
e. none of the above
a. HF(aq)
b. H2SO3(aq)
c. NO3–(aq)
d. NH4+(aq)
e. All of the above are Bronsted acids.
a. ionization
b. dissociation
c. association
d. a and b
e. a, b, and c
____ 7. In the autoionization of water, the concentration of hydronium ions _______ if the concentration of hydroxide
ions increases.
When the concentration of hydroxide ions (OH^-) increases (according to Le Chatelier’s Principle), the
equilibrium shifts to the left to counteract the increase in OH^- ions. As a result, the concentration of
hydronium ions (H3O^+) decreases to maintain equilibrium. So, if the concentration of hydroxide ions
increases, the concentration of hydronium ions decreases.
a. increases
b. decreases
c. stays the same
d. a or b
e. a, b, or c
____ 8. The notation H3O+ (aq) is sometimes simplified to which of the following?
The notation H3O+ (aq) represents the hydronium ion, which is formed when a water molecule accepts a
proton (H⁺ ion). But in many cases chemists simplify chemical equations, and the hydronium ion is often
represented simply as H+ (aq), indicating the presence of a proton in the aqueous solution. This notation
emphasizes the acidic nature of the solution.
a. H2O (l)
b. H+ (aq)
c. H- (aq)
d. OH+ (aq)
e. OH- (aq)
a. hydronium ions
b. hydroxide ions
c. oxygen ions
d. a and b
e. a, b, and c
a. H3O+
b. H2O+
c. HCl
d. Cl+
e. OH-
____ 11. In which of the following reactions does NH3 act as Bronsted acid?
Option c. NH3 releases a proton (H+ ion). And Na and NH2 combine. Bronsted acid: An H+ ion is lost.
a.
NH3(aq) + HCl (aq) → NH4Cl (aq)
b.
NH3 (aq) + H+ (aq)→ NH4+ (aq)
c.
NH3 (aq) + Na (s) → NaNH2 (aq) + H2 (g)
d.
NH3 (aq) + H2O (l)→ NH4+ (aq) + OH- (aq
e. NH3(g) can never act as acid.
____ 12. Use the following information to answer the next question.
The carbonate ion is a polyatomic ion having empirical formula CO32–. Salts containing the
carbonate ion are of great use both industrially and mineralogically. The reaction that takes
place with water is shown below:
H2O( ) + CO32–(aq) → HCO3–(aq) + OH–(aq)
____ 13. Which is not included in the Arrhenius theory of acids and bases?
a base ionizes in water to form OH- ions, not H+ ions.
____ 15. Use the following information to answer the next question.
Hydrogen cyanide, HCN(l), is a pale blue, highly volatile liquid. It exists as gas above 26oC. It
reacts with water to form H3O+(aq) and CN–(aq).
Which of the following pairs are conjugate acid base pairs of the reaction of hydrogen cyanide, HCN(l) with
water?
HCN(l), is a pale blue, highly volatile liquid. It exists as gas above 26 C. It
o
reacts with water to form H3O (aq) and CN (aq).
____ 16. Use the following information to answer the next question.
Carbonic acid, H2CO3(aq), is a chemical substance which plays an important
role in controlling the pH of body fluids. In aqueous solution it produces
HCO3–(aq) and CO32–(aq) as shown below:
H2CO3(aq) + H2O( ) → H3O+(aq) + HCO3–(aq)
a. strong acid
b. amphiprotic substance
____ 17. Use the following information to answer the next question.
Consider the dissociation of an acid in water as
HA(aq) + H2O( ) →H3O+(aq) + A–(aq)
Which of the following statements about the above ionization reaction is correct?
A higher value of Ka indicates a stronger acid because it corresponds to a higher concentration of
H3O+(aq) ions formed upon dissociation
a. The greater the value of the ionization constant, the higher the concentration of H3O+(aq)
and the stronger the acid.
b. The lower the value of the ionization constant, the higher the concentration of H3O+(aq)
and the stronger the acid.
c. The greater the value of the ionization constant, the lower the concentration of H3O+(aq)
and the weaker the acid.
d. The lower the value of the ionization constant, the lower the concentration of H3O+(aq)
and the stronger the acid.
e. There is no relationship between the ionization constant and the concentration of
H3O+(aq).
____ 18. Use the following information to answer the next question.
Consider the following reaction:
H2O(l) + NH3 (aq) → NH4+(aq) + OH– (aq)
____ 19. Use the following information to answer the next question.
The following reaction illustrates how the hydrogen carbonate ion,
HCO3–(aq), can behave as an acid:
HCO3–(aq) + NH3(aq) → NH4+(aq) + CO32–(aq)
In the reaction where the hydrogen carbonate ion is an acid, which of the following statements is correct at
equilibrium?
a. a strong acid
b. a strong base
c. an acid in reaction (i) and as a base in reaction (ii)
d. a base in reaction (i) and as an acid in reaction (ii)
e. a weak base
____ 22. Use the following information to answer the next question.
Consider the following reaction:
NH4+(aq) + H2O(l) → H3O+(aq) + NH3 (aq)
→ H2CO3(aq) + Cl–(aq)
→ NH4+(aq) + CO32–(aq)
Classify hydrogen carbonate ion, HCO3–(aq), according to Bronsted-Lowry theory of acids and bases
.
An amphiprotic substance can react with both acids and bases. When reacting with an acid, it
acts as a base by accepting a proton. And when reacting with a base, it acts as an acid by
donating a proton.
The hydrogen carbonate ion (HCO3–(aq)) is an amphiprotic substance that can act as both an
acid and a base according to the Bronsted-Lowry theory.
2. (six marks) Use the following information to answer the next question.
The carbonate ion is a polyatomic ion having empirical formula CO32–. Salts containing the
carbonate ion are of great use both industrially and mineralogically. The reaction that takes
place with water is shown below:
H2O( ) + CO32–(aq) → HCO3–(aq) + OH–(aq)
Explain how you know the conjugated acid base pairs for this reaction.
H2O(l) + CO3^2-–(aq) → HCO3–(aq) + OH–(aq)
According to the Bronsted-Lowry theory of acids and bases, water (H2O) acts as an acid by donating a proton (H+) to the carbonate ion
(CO3^2–), which acts as a base by accepting the proton
. This proton transfer leads to the formation of bicarbonate ion (HCO3–) and hydroxide ion (OH–).
In this context, the acid, H2O, serves as the proton donor, resulting in the formation of the hydroxide ion (OH–), which is the conjugate base
of the acid, H2O. the base, CO3^2- acts as the proton acceptor, leading to the formation of the bicarbonate ion (HCO3–), which is the
conjugate acid of the base, CO3^2
the conjugate acid-base pairs in this reaction are:
[H2O (l), OH- (aq)] and [CO3^2- (aq), HCO3-(aq)]
Classify and describe the strength of CH3COOH(aq) and CH3COO–(aq) as a strong or weak acid, and as a
strong or weak base. Justify your reasoning.
CH3COOH as an acid:
(CH3COOH) is a weak acid. It only partially dissociates in water to form hydronium ions
(H3O+) and acetate ions (CH3COO–). This is because the equilibrium lies more towards the
reactants side, indicating incomplete dissociation. So, CH3COOH is classified as a weak acid.
CH3COO– as a base:
(CH3COO–) is the conjugate base of acetic acid. While it is a weak base, it has a slightly
greater tendency to accept a proton compared to other weak bases. However, it still does not
accept protons as effectively as strong bases. This is due to the equilibrium position favoring
the formation of undissociated CH3COOH. Therefore, CH3COO– is classified as a stronger,
but still weak base.
4. (eight marks) Consider the following equilibrium reaction in which the initial concentrations of all chemical
species are equal:
NH4+(aq) + CH3COO–(aq) →CH3COOH(aq) + NH3(aq)
Explain the direction of equilibrium, and state which substances will be in the highest concentration at
equilibrium.
Acetic acid (CH3COOH) is a stronger acid than ammonium ion (NH4+)
Acetate ion (CH3COO-) is a stronger base than ammonia (NH3)
Since acetic acid is a stronger acid than ammonium ion, it will have a greater tendency
to donate a proton. As a result, the equilibrium will lie to the left, favoring the
formation of the weaker acid and base pair (NH4+ and CH3COO-). Therefore, at
equilibrium, the concentrations of NH4+ and CH3COO- will be higher compared to the
concentrations of CH3COOH and NH3.
5. (three marks) If the pH of a solution is 2.00, what is the concentration of hydronium ions if the pH is
doubled?(show your work)
3. (six marks) Use the following information to answer the next question.
A solution is prepared by dissolving 4 g of sodium hydroxide,
NaOH(s), in enough water to make 1.0 L of solution.
MATCHING
MULTIPLE CHOICE
SHORT ANSWER
1. ANS:
According to the Bronsted-Lowry theory of acids and bases, substances capable of both donating a proton and
accepting a proton are amphiprotic substances. Hydrogen carbonate ion, HCO3–(aq) is an amphiprotic
substance.
→ +
In the above reaction, on the left side of the equation NH4+(aq) donates a proton and acts as an acid and
CH3COO–(aq) accepts a proton and acts as a base. While on the right hand side of the equation,
CH3COOH(aq) acts as an acid and NH3(aq) acts as a base. Comparing the reactive strengths of acids,
CH3COOH(aq) is a stronger acid than NH4+(aq) so the equilibrium will lie to the left and the concentration of
NH4+(aq) and CH3COO–(aq) will be higher at equilibrium.
PROBLEM
1. ANS:
1.0 × 10–4.
Concentration of NaOH(aq) = =
= 0.1 mol/L
Concentration of NaOH(aq) = =
= 0.1 mol/L