Summer Worksheet
Summer Worksheet
Summer Worksheet
Chemistry IGCSE
Date:
Time:
(a) Show, by calculation, that the empirical formula of this compound is CBrF3
(2)
(b) The diagram shows the displayed formula of a molecule of Halon 1301.
Draw a dot-and-cross diagram to show all the outer electrons in this molecule.
(2)
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Q2.
This question is about carbon and its compounds.
(a) (i) Draw a dot-and-cross diagram to show the outer shell electrons in a molecule of carbon dioxide,
CO2
(2)
(ii) The atoms in carbon dioxide are held together by covalent bonds.
Describe the forces of attraction in a covalent bond.
(2)
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(ii) Explain why diamond has a much higher melting point than C60 fullerene.
Refer to structure and bonding in your answer.
(5)
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Q3.
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(ii) Calculate the relative atomic mass (Ar) of this sample of copper.
Give your answer to three significant figures.
(3)
Ar of copper = ...........................................................
(b) When copper(II) carbonate is heated, copper(II) oxide and carbon dioxide are formed.
(i) What is the name of this type of reaction?
(1)
A decomposition
B neutralisation
C oxidation
D reduction
(c) A student uses this apparatus to find the value of x in the formula CuSO 4.xH2O
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Q4.
(a) Chlorine, bromine and iodine are elements in the Periodic Table.
Explain how the position of these elements in the Periodic Table depends on their
electronic configurations.
(2)
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(b) Chlorine reacts with methane to form CH 3Cl and HCl
(i) State the condition necessary for this reaction.
(1)
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(ii) Give the equation for this reaction.
(1)
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(iii) The bonds in a molecule of CH3Cl are covalent.
Explain, in terms of electrostatic attractions, what is meant by a covalent bond.
(2)
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(iv) Draw a dot-and-cross diagram for a molecule of CH 3Cl
Show only the outer electrons of the atoms.
(2)
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Q5.
Complete the table by choosing a gas from the box that matches the information.
You may use each gas once, more than once, or not at all.
(4)
(b) A teacher uses this apparatus to determine the percentage of oxygen in a sample of air.
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(ii) Give a reason why the remaining gas is allowed to cool before its volume is recorded.
(1)
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(iii) At the start of the experiment, the total volume of air in the apparatus is 138 cm 3.
At the end of the experiment, the volume of gas remaining is 108 cm 3.
Calculate the percentage of oxygen in the sample of air.
Assume that all the oxygen has reacted.
(2)
percentage of oxygen = ........................................................... %
Q6.
(c) The table shows the electronic configurations of a fluorine atom and a chlorine atom.
Explain the relative reactivities of fluorine and chlorine using the information in the table.
(4)
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Q7.
A student uses this method to investigate the reaction of dilute hydrochloric acid with zinc.
(b) The diagram shows the thermometer readings for this reaction.
Complete the table, giving all values to the nearest 0.1°C.
(3)
(c) Another student repeats the method using five different metals to compare their
reactivity.
(i) This student uses a polystyrene cup instead of a glass beaker.
Explain why a polystyrene cup is better than a glass beaker in this investigation.
(2)
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(ii) Give three factors that the student should keep constant in this investigation.
(3)
1 ..........................................................................................................................................
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3 ..........................................................................................................................................
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(ii) Predict the temperature change for iron.
(1)
Q8.
B 6
C 13
D 81
B 78
C 81
D 84
(i) Give the number of protons and the number of neutrons in one atom of the thallium-
205 isotope.
(2)
number of
protons ...........................................................................................................................
number of
neutrons .........................................................................................................................
Q9.
The diagram shows the positions of some elements in the Periodic Table.
Q10.
A student is provided with a bottle containing a colourless solution X.
The student does some experiments on samples of solution X to try to show that it is dilute
sulfuric acid.
(a) The student knows that the products of the electrolysis of dilute sulfuric acid are
hydrogen and oxygen.
She carries out the electrolysis using this apparatus.
(i) Suggest why the student does not use zinc electrodes in her experiment.
(1)
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(ii) State what is observed at both the anode and the cathode during the electrolysis.
(1)
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(iii) Which of these tests shows that the gas formed at the cathode is hydrogen?
(1)
A a glowing splint relights
B a burning splint gives a squeaky pop
C a burning splint goes out
D limewater turns cloudy
(b) Describe a test to show that solution X contains sulfate ions.
(2)
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(c) The student then does a titration to see if the concentration of the dilute sulfuric acid is
0.10 mol/dm3.
She measures 25.0 cm3 of potassium hydroxide solution into a conical flask, and then
adds a few drops of indicator solution.
(i) Name the piece of apparatus the student should use to measure 25.0 cm 3 of the
potassium hydroxide solution.
(1)
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(ii) The concentration of potassium hydroxide in the solution is 0.125 mol/dm 3.
Calculate the amount, in mol, of KOH in 25.0 cm 3 of this solution.
(2)
She uses a pencil to draw a line and label A, B, C and U on chromatography paper.
The diagram shows the appearance of the paper before and after the experiment.
(a) (i) Describe the method that the student could have used to obtain her results.
(3)
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(ii) Describe the composition of food colouring U.
(2)
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(iii) Suggest why food dye A does not move in the experiment.
(1)
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Rf value = ...........................................................
(c) The student repeats the experiment using solvent X instead of water.
(i) Solvent X produces a flammable vapour.
Give a safety precaution that the student should take when using solvent X.
(1)
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(ii) Suggest why the Rf value of food dye C might be greater when solvent X is used
instead of water.
(1)
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Q13.
(a) (i) Identify the ion that makes the sodium hydroxide solution alkaline.
(1)
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(ii) What is a possible pH of ammonia solution?
(1)
A 3
B 6
C 11
D 14
(b) When ammonia solution reacts with sulfuric acid, a neutralisation reaction occurs and
ammonium sulfate forms.
(i) How does the sulfuric acid act in this reaction?
(1)
A as a neutron donor
B as a neutron acceptor
C as a proton donor
D as a proton acceptor
(ii) The diagram shows a beaker containing some ammonia solution and a few drops of
phenolphthalein indicator.
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(ii) Calculate the relative formula mass of ammonium sulfate, (NH 4)2SO4
(1)
mass = ........................................................... g
Q14.
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(b) Explain two improvements to the student's method so that more accurate results are
obtained.
(4)
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(c) The student makes the improvements and repeats the titration.
The sulfuric acid has a concentration of 0.600 mol/dm 3.
The sodium hydroxide solution has a concentration of 1.50 mol/dm 3.
This is the equation for the reaction.
2NaOH + H2SO4 → Na2SO4 + 2H2O
Calculate the volume, in cm3, of sulfuric acid that the student needs to completely react
with 25.0 cm3 of the sodium hydroxide solution.
(3)
(d) The student plans to obtain pure dry crystals of hydrated sodium sulfate.
They add the calculated volume of sulfuric acid to 25.0 cm 3 of the sodium hydroxide
solution to form sodium sulfate solution.
Describe what the student should do to obtain pure dry crystals of hydrated sodium
sulfate from the solution.
(4)
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Q15.
This question is about the three halogens, bromine, chlorine and iodine.
(a) Give the number of protons and the number of neutrons in an atom of iodine-127
(2)
number of protons
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number of neutrons
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Ar ...........................................................
Calculate the minimum mass of chlorine needed to form 26.7 g of aluminium chloride.
[for Cl2 , Mr = 71 for AlCl3 , Mr = 133.5]
(3)
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Q16.
Answer the questions with a cross in the boxes you think are correct . If you
change your mind about an answer, put a line through the box and then mark
your new answer with a cross .
Q .........................................................................................................................................
R .........................................................................................................................................
Q17.
(b) The diagram shows two methods used to prevent iron from rusting.
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(ii) Give the name of method B.
(1)
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(iii) Explain how method B prevents iron from rusting even when the zinc coating is
damaged.
(2)
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Q18.
(a) Solid oxides of copper can be reduced by reacting them with methane gas.
Complete the equation for the reaction between copper(II) oxide and methane.
Include state symbols.
(2)
............CuO(............) + ............CH4(............)
→ ............Cu(............) + ............CO2(............) + ............H2O(............)
(b) A teacher uses this apparatus to demonstrate the reaction between a different oxide of
copper and methane.
(i) The teacher heats the oxide of copper until the reaction is complete.
The table shows the teacher's results.
Use the teacher's results to show that the empirical formula of this oxide of copper is
Cu2O
(4)
(ii) The teacher wears safety glasses and a lab coat during the demonstration.
Give one other safety precaution that she should take.
(1)
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(ii) State why carbon monoxide should not be released into the atmosphere.
(1)
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(iii) Calculate the maximum mass, in tonnes, of iron that can be produced when 30.0
tonnes of iron(III) oxide are reacted with an excess of carbon.
[1 tonne = 1.0 × 106 g]
(4)
Q19.
(b) When iron reacts with dilute sulfuric acid, the products are iron(II) sulfate and hydrogen.
(i) Give a chemical equation for the reaction between iron and sulfuric acid.
(1)
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(ii) Give a test for hydrogen.
(1)
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(d) Give the reason why no reaction occurs when iron is added to magnesium sulfate
solution.
(1)
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Q20.
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(b) A teacher uses this apparatus in a fume cupboard to demonstrate the electrolysis of
lead(II) bromide.
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(iv) The teacher stops heating the mixture and allows it to solidify.
Suggest why the lamp stays alight.
(1)
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Q21.
(a) Describe how solutions of lead nitrate and potassium bromide can be used to make a
pure, dry sample of lead(II) bromide.
(4)
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(b) A solution containing 0.150 mol of lead(II) nitrate is reacted with an excess of potassium
bromide solution.
A mass of 49.6 g of pure, dry lead(II) bromide is produced.
Show, by calculation, that the percentage yield of lead(II) bromide is 90.1%.
[for PbBr2, Mr = 367]
(2)
(c) A student investigates the change in electrical conductivity as dilute lead(II) nitrate
solution is added to dilute potassium bromide solution.
This is the student's method.
Step 1 add 50 cm3 of potassium bromide solution to a beaker
Step 2 measure the electrical conductivity of the solution
Step 3 add 10 cm3 of lead(II) nitrate solution to the beaker
Step 4 stir the mixture
Step 5 measure the electrical conductivity of the mixture
Repeat steps 3, 4 and 5 until a total of 50 cm 3 of lead(II) nitrate solution has been added.
The table shows the student's results.
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(iv) Suggest a mistake the student could have made to cause the anomalous result.
(1)
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(v) Further 10 cm3 volumes of lead(II) nitrate are added to the beaker so the lead(II) nitrate
is in excess.
Predict what will happen to the conductivity of the mixture when the lead(II) nitrate is in
excess.
(1)
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(d) The diagram shows the electrolysis of molten lead(II) bromide, PbBr 2
This is the ionic half-equation for the formation of bromine at electrode A.
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Q22.
The table gives the electronic configurations of atoms of hydrogen, lithium and chlorine.
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(b) Explain why lithium chloride has a higher melting point than hydrogen chloride.
Refer to structure and bonding in your answer.
(5)
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Q23.
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Q24.
(b) The diagram shows methane burning in air. It also shows how the two gases formed are
collected and tested.
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(ii) Describe how anhydrous copper(II) sulfate is used to test for water.
(2)
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(iii) Explain the change in appearance of the limewater.
(3)
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Q25.
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Q26.
Solutions of silver nitrate and potassium chloride react together to make the insoluble salt,
silver chloride.
(b) Give two more steps that will produce a pure, dry sample of silver chloride.
(2)
Step 4 ...................................................................................................................................
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Step 5 ..................................................................................................................................
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(c) Acidified silver nitrate solution is used to test for chloride ions.
Give a reason why hydrochloric acid is not used to acidify silver nitrate solution.
(1)
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(d) The chemical equation for the reaction between solutions of silver nitrate and potassium
chloride is
mass = ........................................................... g
Q27.
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(b) A solution of sodium chloride can be electrolysed using this apparatus.
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(ii) Explain how hydrogen gas forms at the negative electrode.
(3)
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(i) Use the equation and the values in the table to calculate the enthalpy change, ΔH, for
the reaction.
Include a sign in your answer.
(3)
ΔH = ........................................................... kJ
(ii) Complete the diagram to show the energy levels of the reactants and products, and
the enthalpy change, ΔH.
(3)
(a) Explain two mistakes that the student makes when setting up the apparatus.
(4)
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(i) Complete the chromatogram for food colouring A by adding and labelling the dyes.
(2)
(ii) Give a reason why the blue dye has a larger R f value than the yellow dye.
(1)
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