CHEMICAL REACTIONS AND EQUATIONS
●   A complete chemical equation represents the reactants, products and their physical state
       symbolically.
   ●   Following observations helps us to determine whether a chemical reaction has taken place:
          o   Change in state
          o   Change in colour
          o   Evolution of a gas
          o   Change in temperature.
   ● Some of the examples of chemical reactions in everyday life:
        o Photosynthesis
        o Aerobic Cellular Respiration
        o Combustion of wood
        o Rusting of iron
        o Metathesis
        o Digestion
        o Cooking an egg
        o Souring of milk
        o Rotting bananas
   ● Exothermic reactions are reactions or processes that release energy, usually in the form of
     heat or light.
   ● Reactions in which energy is absorbed are known as endothermic reactions.
Balanced Chemical Equations
   ● Mass can neither be created nor destroyed in a chemical reaction. That is, the total mass of
     the elements present in the products of a chemical reaction has to be equal to the total
     mass of the elements present in the reactants.
   ● The number of atoms of each element remains the same, before and after a chemical
     reaction. Some of the examples of balanced equations:
     Zn + H2SO4 → ZnSO4 + H2
     3Fe + 4H2O → Fe3O4 + 4H2
Types Of Chemical Reactions
Combination Reaction
   ● In a combination reaction two or more substances combine to form a new single Substance.
     Example of combination reaction:
     Calcium oxide reacts vigorously with water to produce slaked lime (calcium hydroxide)
     Releasing a large amount of heat
     CaO (s) + H2O (l) → Ca (OH)2 + Heat
   ● A solution of slaked lime produced by the above reaction is used for white washing wall.
NOTE: Calcium hydroxide reacts slowly with the carbon dioxide in air to form a thin layer of calcium
carbonate on the walls. Calcium carbonate is formed after two to three days of whitewashing and
gives a shiny finish to the walls. It is interesting to note that the chemical formula for marble is also
CaCO3.
Decomposition Reaction
   ● Decomposition reactions are opposite to combination reactions. In a decomposition
       reaction, a single substance decomposes to give two or more substances.
   ● In this reaction, you can observe that a single reactant breaks down to give simpler products.
       This is a decomposition reaction.
       2FeSO4(s) Heat → Fe2O3(s) + SO2(g) + SO3(g)
   ● Decomposition of Silver bromide into silver and chlorine by light.
   ● Silver bromide used in black and white photography.
   ● Decomposition of calcium carbonate to calcium oxide and carbon dioxide on heating is an
       important decomposition reaction used in various industries. Calcium oxide is called lime or
       quick lime. It has many uses – one is in the manufacture of cement. When a decomposition
       reaction is carried out by heating, it is called thermal decomposition.
Displacement Reaction
   ● It is a reaction between an element and a compound. When they react, one of the elements
     of the compound- reactant is replaced by the element-reactant to form a new compound
     and an element.
     Fe + CuSO4 → FeSO4 + Cu
   ● In this reaction, iron has displaced or removed another element copper from copper
     sulphate solution. This reaction is known as displacement reaction.
Double Displacement Reactions
  ● When two compounds react, if their ions are interchanged, then the reaction is called
      double displacement reaction. The ion of one compound is replaced by the ion of another
      compound.
      Na2SO4 (aq) + BaCl2 (aq) → BaSO4 (s) + 2NaCl (aq)
Precipitation Reactions
   ● When aqueous solutions of two compounds are mixed, if they react to form an insoluble
      compound and a soluble compound, then it is called precipitation reaction. Because the
      insoluble compound, formed as one of the products, is a precipitate and hence the reaction
      is so called.
   ● Precipitation reactions produce insoluble salts.
Neutralisation Reaction
   ● When an acid and a base react together to form salt and water, it is known as neutralization
      reaction.
       HCl + NaOH → H2O + NaCl
Oxidation and Reduction
Oxidation
   ● The chemical reaction which involves addition of oxygen or removal of hydrogen or loss of
     electrons is called oxidation.
     2 Mg + O2 → 2MgO (addition of oxygen)
     CaH2 → Ca + H2 (removal of hydrogen)
     Fe2+ → Fe3+ + e− (loss of electron)
Reduction
   ● The chemical reaction which involves addition of hydrogen or removal of oxygen or gain of
     electrons is called reduction.
      2 Na + H2 → 2 NaH (addition of hydrogen)
      CuO + H2 → Cu + H2O (removal of oxygen)
      Fe3+ + e− → Fe2+ (gain of electron)
Redox Reactions
   ● Generally, the oxidation and reduction occurs in the same reaction (simultaneously). If one
      reactant gets oxidized, the other gets reduced. Such reactions are called oxidation-reduction
      reactions or Redox reactions.
      2 PbO + C → 2 Pb + CO2
      Zn + CuSO4 → Cu + ZnSO4
 Oxidation                                           Reduction
 Addition of oxygen                                  Removal of oxygen
 Removal of hydrogen                                 Addition of hydrogen
 Loss of electron                                    Gain of electron
Oxidation and Reduction Agents
   ● Substance that loses oxygen or gains hydrogen is known as an oxidizing agent.
   ● Substance that loses hydrogen or gains oxygen is known as a reducing agent.
   ● Compounds with oxygen atom are called oxidizing agent and compounds with hydrogen
     atom are called reducing agent.
   ● Some compounds can act as either oxidizing agents or reducing agents. One example is
     hydrogen gas, which acts as an oxidizing agent when it combines with metals and As a
     reducing agent when it reacts with non- metals.
Oxidation reactions in daily life
   ● The shining surface of metals tarnishes due to the formation of respective metal oxides on
       their surfaces. This is called corrosion.
   ● The freshly cut surfaces of vegetables and fruits turn brown after some time because of the
       oxidation of compounds present in them.
Rancidity
   ● When oils and fats or foods containing oils and fats are exposed to air, they get oxidized due
       to which the food becomes stale and gives a bad taste or smell. This is called Rancidity.
   ● Following ways to preventing rancidity:
         o Adding antioxidants
         o Refrigerating
         o Storing food in airtight containers with nitrogen gas
Common Name and Formula of Chemical Compounds
  Chemical Compounds                 Chemical formula                   Common names
  Calcium oxide                      Cao                                Quick lime
  Calcium hydroxide                  Ca(OH)2                            Slaked lime
  Calcium carbonate                  CaCO3                              Limestone
 Trichloro Methane              CHCl3                          Chloroform
 Calcium Oxychloride            CaOCl2                         Bleaching powder
 Sodium hydrogencarbonate       NaHCO3                         Baking soda
 Sodium carbonate               Na2CO3                         Washing soda
 Calcium sulphate hemihydrate   CaSO4 .1/2H2O                  Plaster of paris
 calcium sulfate dihydrate      CaSO .2H2O                     Gypsum
 Acetic acid                    CH3COOH                        Vinegar
 Silicon Oxide                  SiO2                           Sand
 Methane                        CH4                            Marsh Gas
 Nitrous oxide                  N2O                            Laughing Gas
 Deuterium Oxide                D2O                            Heavy water
 Solid Carbondioxide            CO2                            Dry ice
 Calcium Carbonate              CaCo3                          Chalk
 Sulphuric Acid                 H2SO4                          Oil of vitriol
 Zinc sulphate                  ZnSO4                          White Vitriol
 Copper sulphate                CuSO4.5H2O                     Blue Vitriol
 Sodium hydroxide               NaOH                           Caustic Soda
 Potassium carbonate            K2CO3                          Potash Ash
 Mercurous chloride             Hg2Cl2                         Calomel
 Sucrose                        C12H22O11                      Sugar
 Silver nitrate                 AgNO3                          Lunar caustic
 Ethyl Alcohol                  C2H6O                          Alcohol
 Hydrochloric acid              HCl                            Muriatic acid
Chemical Compounds and Formula
Chemical Compounds                              Chemical formula
Sodium chloride                                 NaCl
Zinc sulphate                                   ZnSO4
Glucose                                         C6H12O6
Ferric oxide                                    Fe2O3
Ferrous sulphate                                FeSO4
Lead oxide                                      PbO
Lead nitrate                                    Pb(NO3)2
silver chloride                                 AgCl
Silver bromide                                  AgBr
Sodium sulphate                                 Na2SO4
Chemical Bonding
Attraction between atoms, ions or molecules that enables the formation of chemical compounds is
called chemical bonding.
Types Of Chemical Bonding
   ● Ionic bond - Chemical bond formed between two atoms due to transfer of electron from one
     atom to the other atom.
   ● Covalent bond - A covalent bond is a chemical bond that involves the sharing of electron
     between two atoms.
   ● Metallic bond - Metallic bond is the force of attraction between metal ions to a number of
     electrons within its sphere of influence.