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Samsung Tab Active Pro MSDS

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0% found this document useful (0 votes)
62 views22 pages

Samsung Tab Active Pro MSDS

Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 22

SAMSUNG SDI Co., Ltd.

Date: 23 May. 2019 Revision no.: 02


MODEL EB-BT545AB*

Safety Data Sheet


Regulation : In accordance with Regulation (EU) 2015/830 (REACH), Annex II, and OSHA 29 CFR
1910.1200

Section I – IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF


THE COMPANY/UNDERTAKING
Important Note: As a solid, manufactured article, exposure to hazardous ingredients is not expected with
normal use. This battery is an article pursuant to 29 CFR 1910.1200 and, as such, is not subject to the OSHA
Hazard Communication Standard requirement. The information contained in this Safety Data Sheet contains
valuable information critical to the safe handling and proper use of the product. This SDS should be retained
and available for employees and other users of this product.

1.1 Product identifier


Model name EB-BT545ABY
Substance name : Lithium-ion batteries
Synonyms :
Lithium-ion Cell, Lithium-ion Pack, Lithium-ion Battery, Li-Ion Cell, Li-Ion Pack, Li-Ion Battery
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses : Lithium-ion batteries
Uses advised against : Use for recommended use only
Further Information : Not available
1.3 Details of the supplier of the safety data sheet
Supplier : SAMSUNG SDI Co., Ltd.
Street address/P.O. Box : 150-20, Gongse-ro, Giheung-gu, Yongin-si, Gyeonggi-do, Korea
Country ID/Postcode/Place :
Telephone number : 1-800-424-9300: US and Canada / 1-703-527-3887: International
Responsible Department: Quality team
e-mail address of competent person responsible for the SDS : Not available
National contact : 1-800-424-9300: US and Canada / 1-703-527-3887: International
1.4 Emergency Telephone
: 1-800-424-9300: US and Canada / 1-703-527-3887: International
Opening hours : Not available
Other comments : Not available
1.5 Further Information
Battery-System: Lithium-ion (Li-ion)
Nominal Voltage: 3.80 V
Rated Capacity: 7.40 Ah
Wh rating: 28.12 Wh
Anode (negative electrode): based on intercalation graphite
Cathode (positive electrode): based on lithiated metal oxide (Cobalt)

Page 1 of 22
SAMSUNG SDI Co., Ltd.
Date: 23 May. 2019 Revision no.: 02
MODEL EB-BT545AB*

Remark:
The information and recommendations set forth are made in good faith and believed to be accurate as of
the date of preparation. SAMSUNG SDI Co., Ltd. makes no warranty, expressed or implied, with respect to
this information and disclaims all liabilities from reliance on it.

Section II – HAZARDS IDENTIFICATION

※ This is a product that fulfills a certain function in solid state with specific shape without discharging any
chemical substance in its use and has no obligation to write (M)SDS. Since this document contains the
precautions for safe handling related to its materials or chemical substances consisting of this product,
please note that these overall information is irrelevant to this product.

2.1 Classification of the substance or mixture


2.1.1 Classification according to Regulation (EC) No. 1272/2008 [CLP] and OSHA 29 CFR 1910.12
00 : Not classified
2.1.2 Additional information:
Classification of the substance or mixture.
Preparation Hazards and Classification: The product is a Lithium ion cell or battery and is therefore
classified as an article and is not hazardous when used according to the recommendations of the
manufacturer. The hazard is associated with the contents of the cell or battery. Under recommended
use conditions, the electrode materials and liquid electrolyte are non-reactive provided that the cell or
battery integrity remains and the seals remain intact. The potential for exposure should not exist
unless the cell or battery leaks, is exposed to high temperatures or is mechanically, electrically or
physically abused/damaged. If the cell or battery is compromised and starts to leak, based upon the
battery ingredients, the contents are classified as Hazardous.

Hazardous Materials Information Label (HMIS)


Health: Not available
Flammability: Not available
Physical Hazard: Not available

NFPA Hazard Ratings


Health: Not available
Flammability: Not available
Reactivity: Not available

2.2 Label elements


Hazard pictograms : Not applicable
Signal word : Not applicable
Hazard statement : Not applicable
Precautionary statements: Not applicable
Supplemental Hazard information (EU) : Not applicable

2.3 Other hazards :


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Date: 23 May. 2019 Revision no.: 02
MODEL EB-BT545AB*

Appearance, Color and Odor: Solid object with no odor.

Primary Routes(s) of Exposure: These chemicals are contained in a sealed enclosure. Risk of
exposure occurs only if the cell or pack is mechanically, thermally, electrically or physically abused to the
point of compromising the enclosure.
If this occurs, exposure to the electrolyte solution contained within can occur by inhalation, ingestion, eye
contact and skin contact.

Potential Health Effect(s):


Acute (short term): see Section 8 for exposure controls.
In the event that this cell or pack has been ruptured, the electrolyte solution contained within the cell
would be corrosive and can cause burns to skin and eyes.
Inhalation: Inhalation of materials from a sealed cell is not an expected route of exposure. Vapors
or mists from a ruptured cell may cause respiratory irritation.
Ingestion: Swallowing of materials from a sealed cell is not an expected route of exposure.
Swallowing the contents of an open cell can cause serious chemical burns to mouth, esophagus,
and gastrointestinal tract.
Skin: Contact between the cell and skin will not cause any harm. Skin contact with the contents of
an open cell can cause severe irritation or burns to the skin.
Eye: Contact between the cell and the eye will not cause any harm. Eye contact with the contents of
an open cell can cause severe irritation or burns to the eye.
CHRONIC (long term): see Section 11 for additional toxicological data.

Interactions with other chemicals: Immersion in high conductivity liquids may cause corrosion and
breaching of the cell or battery enclosure. The electrolyte solution inside of the cells may react with
alkaline (basic) materials and present a flammability hazard.

Potential Environmental Effects: Not Available.

Section III – COMPOSITION/INFORMATION ON INGREDIENTS


3.1 Mixture

Classification
REACH
Common Name according to
CAS No. EC No. Registration %[weight] Name
(Synonyms) Regulation(EC) No
No.
1278/2008(CLP)
12190-79-3 235-362-0 40~50 cobalt lithium dioxide
- Not available Not classified
7782-42-5 231-955-3 - 15~25 Graphite
Not available Not classified
7440-50-8 231-159-6 - 5~15 Copper
Not available Not classified
7429-90-5 231-072-3 - 1~10 Aluminium Pyr. Sol. 1, H250
Not available
Water-react. 2, H261
PP (Propyl
106-36-5 203-389-7 - 1~5 Flam. Liq. 3, H226
Propionate) Not available
Acute Tox. 4, H332

Page 3 of 22
SAMSUNG SDI Co., Ltd.
Date: 23 May. 2019 Revision no.: 02
MODEL EB-BT545AB*

9002-88-4 Not available - 1~5 Polyethylene


Not available Not classified
105-37-3 203-291-4 - 1~5 EP (Ethyl Propionate)
Not available Flam. Liq. 2, H225
EC (Ethylene
96-49-1 202-510-0 - 1~5
Carbonate) Not available Not classified

1344-28-1 215-691-6 - 1~5 Aluminium Oxide


Not available Not classified
LiPF6 (Lithium
21324-40-3 244-334-7 - 1~5
hexaflurophosphate) Not available Not classified

PC (Propylene
108-32-7 203-572-1 - 1~5
Carbonate) Not available Eye Irrit. 2, H319

1333-86-4 215-609-9 - 0.1~1 Carbon black


Not available Not classified
110-61-2 203-783-9 - 0.1~1 SN (Succinonitrile)
Not available Not classified
1120-71-4 214-317-9 - 0.1~1 1,3-propanesultone Not available Acute Tox. 4 *, H302
Acute Tox. 4 *, H312
Carc. 1B, H350

Further Information
Because of the cell structure the dangerous ingredients will not be available if used properly.
During charge process a lithium graphite intercalation phase is formed.

Section IV – FIRST-AID MEASURES

4.1 Description of first aid measures


Following eye contact :
- Rinse eyes with plenty of water for at least 15 minutes and seek medical attention.
Following skin contact :
- Remove contaminated clothing and wash before reuse.
- Immediately rinse contact area with plenty of clean water.
- Provide first aid to contacted area to prevent infection.
- Get medical attention.
Following inhalation :
- In case of inhalation of organic electrolyte mist, remove from exposure to fresh air.
- If necessary give oxygen. Get medical attention.
Following ingestion :
- In case of ingestion of electrolyte don’t induce vomiting.
- If patient is conscious and alert give 2~4 cupfuls of milk or water.
- Never give anything by mouth to an unconscious person.

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Date: 23 May. 2019 Revision no.: 02
MODEL EB-BT545AB*

- Get medical attention immediately.


Further Information :
- The following first aid measures are required only in case of exposure to interior battery components
after damage of the external battery casing.
- Undamaged, closed cells do not represent a danger to the health.
4.2 Most important symptoms and effects, both acute and delayed
Acute effects : Not available
Delayed effects : Not available
4.3 Indication of immediate medical attention and special treatment needed
- Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
themselves.

Section V – FIRE-FIGHTING MEASURES


5.1 Extinguishing media
- When the scale of the fire is small, use a HFC (hydrofluorocarbon) clean-agent fire extinguisher or
alcohol resistant foam fire extinguishers. (In case of battery overheating, wear protective gear and
immerse heated battery in water)
- In case of large fire, use large amount of water to extinguish.
5.2 Special hazards arising from the substance or mixture
- Flammable gas leaks before ignition and then the product ignites.
5.3 Advice for firefighters
- The ignited battery has a high temperature, so there is a risk of additional ignition even if the fire is
extinguished at early stage. Sprinkle a large amount of water until the battery temperature drops to
normal temperature.
- If the battery is ignited in multi-stacked condition, multi-stack should be disassembled and then
extinguished so that heat is not transferred between batteries
- In the event of a battery fire, cool it by spraying water directly on the battery.
- When handling a overheated battery, wear heat-resistant protective equipment.

Section VI – ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures


For non-emergency personnel
Protective equipment : Use personal protective equipment, see Section 8
Emergency procedures :
- In case of cell damage, possible release of dangerous substances and a flammable gas mixture.
- Eliminate all ignition sources.
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MODEL EB-BT545AB*

- Please note that materials and conditions to avoid.


- Battery may emit electrolyte if charging or discharging rates exceed manufacturer’s recommendations
or if pack has been breached.
- Move battery to well ventilated area to prevent gas accumulation.
For emergency responders
- Eliminate all ignition sources.
- Please note that materials and conditions to avoid.
- Move battery to well ventilated area to prevent gas accumulation.
6.2 Environmental precautions :
- Avoid release to the environment.
- Prevent entry into waterways, sewers, basements or confined areas.
6.3 Methods and material for containment and cleaning up
For containment : Not available
For cleaning up :
- Cover with Dry earth, DRY sand or other non-combustible material and put on the plastic sheet to
minimize spreading or contact with rain.
- Move battery to well ventilated area to prevent gas accumulation.
- Dispose in accordance with applicable local, state and federal regulations.
Other information: Not available
6.4 Reference to other sections
- See also sections 8 and 13 of the Safety Data Sheet.

Section VII – HANDLING AND STORAGE

7.1 Precautions for safe handling


- In case of cell damage, possible release of dangerous substances and a flammable gas mixture.
- The battery stores electrical energy and is capable of rapid energy discharge.
- Battery cell contents are under pressure.
- Handle battery carefully to avoid puncturing case or electrically shorting terminals.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions : Not available
Packaging materials : Not available
Requirements for storage rooms and vessels :
- Storage at room temperature (approx. 20℃) at approx. 40% of the nominal capacity
- Keep in closed original container.
7.3 Specific end use(s)

Recommendations : Not available


Industrial sector specific solutions : Not available

Page 6 of 22
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Date: 23 May. 2019 Revision no.: 02
MODEL EB-BT545AB*

Section VIII – EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters


Occupational Exposure limits
ACGIH Biological OSHA NIOSH
Name EU regulation
regulation exposure index regulation regulation

cobalt lithium dioxide Not applicable Not available Not applicable Not applicable Not applicable

TWA = 0.02
Cobalt, Co Not available TWA = 0.1 mg/m³ TWA 0.05 mg/m3 Not applicable
mg/m3

Graphite TWA = 2mg/m3 Not available Not applicable Not applicable Not applicable

TWA = 0.2
Copper Not available Not applicable Not applicable Not applicable
mg/m³ (fume)

TWA = 15 mg/m³
(Aluminum Metal
(as Al) Total TWA = 1 mg/m³
TWA = 1 mg/m³
dust) (Aluminum Metal
(respirable
Aluminium Not available TWA = 5 mg/m³ (as Not applicable
particulate
(Aluminum Metal Al),Respirable
matter)
(as Al) fraction)
Respirable
fraction)

PP (Propyl Propionate) Not applicable Not available Not applicable Not applicable Not applicable

Polyethylene Not applicable Not available Not applicable Not applicable Not applicable

EP (Ethyl Propionate) Not applicable Not available Not applicable Not applicable Not applicable

EC (Ethylene Carbonate) Not applicable Not available Not applicable Not applicable Not applicable

TWA = 15 mg/m³
(Aluminum Metal
(as Al) Total TWA = 1 mg/m³
TWA = 1 mg/m³
dust) (Aluminum Metal
(respirable
Aluminium Oxide Not available TWA = 5 mg/m³ (as Not applicable
particulate
(Aluminum Metal Al),Respirable
matter)
(as Al) fraction)
Respirable
fraction)

LiPF6 (Lithium
Not applicable Not available Not applicable Not applicable Not applicable
hexaflurophosphate)

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Date: 23 May. 2019 Revision no.: 02
MODEL EB-BT545AB*

PC (Propylene Carbonate) Not applicable Not available Not applicable Not applicable Not applicable

TWA = 3.5 mg/m³


Ca TWA = 0.1
TWA = mg PAHs/m3
3mg/m³ [Carbon black in
Carbon black (inhalable Not available TWA = 3.5 mg/m³ presence of Not applicable
particulate polycyclic
matter) aromatic
hydrocarbons
(PAHs)]

SN (Succinonitrile) Not applicable Not available Not applicable Not applicable Not applicable

1,3-propanesultone Not applicable Not available Not applicable Not applicable Not applicable

8.2 Exposure controls


8.2.1 Appropriate engineering controls :
Substance/mixture related measures to prevent exposure during identified uses:
- Avoid charging batteries in areas where hydrogen gas accumulate.
- Use local exhaust ventilation to maintain concentrations of hydrogen below the Lower Explosive
collect and transport flammable gases in ventilation systems.
- Insure proper ventilation is present and electrolyte mist and vapours.
Structural measures to prevent exposure:
- Avoid charging batteries in areas where hydrogen gas accumulate.
- Use local exhaust ventilation to maintain concentrations of hydrogen below the Lower Explosive
collect and transport flammable gases in ventilation systems.
- Insure proper ventilation is present and electrolyte mist and vapours.
Organisational measures to prevent exposure: Not available
Technical measures to prevent exposure:
- Insure proper ventilation is present and electrolyte mist and vapours.
8.2.2 Individual protection measures, such as personal protective equipment :
Eye and face protection
- Wear ANSI approved safety glasses with side shield during normal use.
- Wear NIOSH approved face shield with safety glasses and H.V protection during intentional
disassembly.
Skin protection
Hand protection
- Wear nitrile butyl rubber, neoprene, or PVC glove during battery component disassembly.
- Discard contaminated work clothing after one work day.
Other skin protection
- Wear protective clothing during battery component disassembly.

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MODEL EB-BT545AB*

- Discard contaminated work clothing after one work day.


Respiratory protection :
- None required during normal use.
- Wear NIOSH or European Standard EN 149 approved full or half face piece (with goggles)
respiratory protective equipment when necessary.
- In lack of oxygen(< 19.5%), wear the supplied-air respirator or self-contained oxygen breathing
apparatus.
- In case exposed to particulate material, the respiratory protective equipments as follow are
recommended; facepiece filtering respirator or air-purifying respirator, high-efficiency particulate
air(HEPA) filter media or respirator equipped with powered fan, filter media of use (dust, mist, fume)
8.2.3 Environmental exposure controls
Substance/mixture related measures to prevent exposure: Not available
Instruction measures to prevent exposure: Not available
Organisational measures to prevent exposure: Not available
Technical measures to prevent exposure: Not available

Section IX – PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties


Appearance
Description : Solid
Color : Not available
Odor : Odorless
Odor threshold : Not available
pH : Not available
Melting point/freezing point : Not available
Initial boiling point and boiling range : Not available
Flash point : Not available
Evaporation rate : Not available
Flammability (solid, gas) : Not available
Upper/lower flammability or explosive limits : Not available
Vapor pressure : Not available
Solubility (ies) : insoluble.
Vapor density : Not available
Relative density : Not available
Partition coefficient: n-octanol/water : Not available
Auto ignition temperature : Not available
Decomposition temperature : Not available
Viscosity : Not available
Page 9 of 22
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MODEL EB-BT545AB*

Explosive properties : Not available


Oxidizing properties : Not available
Molecular weight : Not available
9.2 Other information
Not available

Section X – STABILITY AND REACTIVITY

10.1 Reactivity
- Stable at ambient temperature.
10.2 Chemical stability
- There is no hazard when the measures for handling and storage are followed.
- Stable under normal temperatures and pressures.
10.3 Possibility of hazardous reactions
- Will not occur under normal conditions.
- In case of cell damage, possible release of dangerous substances and a flammable gas mixture.
- Containers may explode when heated.
- Fire may produce irritating and/or toxic gases.
- Some liquids produce vapors that may cause dizziness or suffocation.
- Inhalation of material may be harmful.
10.4 Conditions to avoid
- Keep away from heat/sparks/open flames/hot surfaces. No smoking.
- Friction, heat, sparks or flames
- Dusts or shavings from borings, turnings, cuttings, etc.
- Do not exceed manufacturer’s recommendation for charging or use battery for an application for which
it was not specifically designed.
- Do not electrically short.
10.5 Incompatible materials
- Avoid contact with acids and oxidizers.
- Keep away from any possible contact with water, because of violent reaction and possible flash fire.
- Handle under inert gas. Protect from moisture.
- Combustibles, reducing agents
10.6 Hazardous decomposition products
- None under normal conditions.
- Corrosive and/or toxic fume
- Material may produce irritating and highly toxic gases from decomposition by heat and combustion
during burning.
- Irritating and/or toxic gases

Page 10 of 22
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MODEL EB-BT545AB*

Section XI – TOXICOLOGICAL INFORMATION

※ This is a product that fulfills a certain function in solid state with specific shape without discharging any
chemical substance in its use and has no obligation to write (M)SDS. Since this document contains the
precautions for safe handling related to its materials or chemical substances consisting of this product,
please note that these overall information is irrelevant to this product.

11.1 Information on toxicological effects


Acute toxicity
Oral : Not classified (ATEmix = 194 mg/kg bw)
- Graphite : Rat LD50 > 2,000 mg/kg (female)(OECD Guideline 401)
- Copper : Rat LD50 > 2,500 mg/kg (Cupric oxide; read across)(OECD TG 423, GLP)
- Aluminum : Rat LD50 > 15,900 mg/kg (OECD TG 401)(Fumed alumina; read across)
- Propyl propionate : Rat LD50 = 11.7 mg/kg (OECD Guideline 401)
- Polyethylene : Rat LD50 > 2,000 mg/kg
- Ethyl propionate : Rat LD50 > 5,000 mg/kg (OECD Guideline 423, GLP)
- EC (Ethylene Carbonate) : Rat LD50 = 10,400 mg/kg (male) (OECD Guideline 401)
- aluminium oxide : Rat LD50 > 15,900 mg/kg (OECD Guideline 401)
- Lithium hexafluorophosphate(1-) : Rat LD50 = 50 ~ 300 mg/kg (Female)(OECD Guideline 423,
GLP)
- Propylene carbonate : Rat LD50 > 5,000 mg/kg (OECD TG 401, GLP)
- Carbon black : Rat LD50 > 8,000 mg/kg (male/female) (OECD Guideline 401)
- SN (Succinonitrile) : Rat LD50 = 300 ~ 2,000 mg/kg (female) (OECD Guideline 423, GLP)
- 1,3-propanesultone : Rat LD50 > 2000 mg/kg (OECD Guideline 401, GLP)
Dermal : Not classified (ATEmix = 106 mg/kg bw)
- Copper : Rat LD50 > 2,000 mg/kg (OECD TG 402, GLP)
- Propyl propionate : LD50 = 16 mg/kg (OECD Guideline 402)
- Ethyl propionate : Rat LD50 > 2,000 mg/kg (OECD Guideline 402, GLP)
- EC (Ethylene Carbonate) : Rat LD50 > 2,000 mg/kg (male/female) (OECD Guideline 402)
- Propylene carbonate : Rabbit LD50 > 20,000 mg/kg
- Carbon black : Rabbit LD50 > 3,000 mg/kg
- SN (Succinonitrile) : Rat LD50 > 2,000 mg/kg (male/female) (OECD Guideline 402, GLP)
- 1,3-propanesultone : Guinea pig LD50 = 700~1400 mg/kg
Inhalation : Not classified (ATEmix = 302 mg/kg bw)
- Graphite : Rat LD50 > 2 mg/L/4hr (male/female) (OECD Guideline 403)
- Aluminum : Rat LC50 > 0.888 mg/L/4hr (analytical) (OECD TG 403)
- Propyl propionate : Rat LT50 = 14031.58 ppm/6hr(OECD Guideline 403)
- EC (Ethylene Carbonate) : Rat LC0 = 730 mg/m³ /8hr
- aluminium oxide : Rat LD50 > 0.888 mg/L/4hr (OECD Guideline 403)
- Carbon black : Rat LD50 > 4.6 mg/m³/4hr
- SN (Succinonitrile) : Rat LC50 ≥ 2.67 mg/L/4hr (male/female) (OECD Guideline 403)
- 1,3-propanesultone : Rat LC0 > 1.3 mg/L/6hr (OECD Guideline 403)
Skin corrosion/ irritation : Not classified
- Graphite : In the skin irritation test using rabbits, the test material was not irritating. (OECD Guideline
404, GLP)
- Copper : In test on skin irritation with rabbits, skin irritations were not observed. (OECD TG 404,
Page 11 of 22
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GLP)
- Aluminum : Aluminium oxide caused slight erythema in 2/12 rabbits. The observed effects do not
lead to a classification. Aluminium oxide is, therefore, not considered to be a primary skin
irritant.(OECD TG 404)(Read across; aluminium oxide)
- Propyl propionate : In the skin irritation test using rabbits, the test material was not irritating.(OECD
Guideline 404)
- Polyethylene : No irritation was observed at the other two treated sites and no corrosive effects were
noted during the study using rabbits. The primary irritation index was calculated as 0.2 and
polyethylene was classified as a mild irritant.
- Ethyl propionate : In the skin irritation test using rabbits, the test material was irritating.(OECD
Guideline 439, GLP)
- EC (Ethylene Carbonate) : In the skin irritation test using rabbits, the test material was not classified.
(OECD Guideline 404, GLP)
- aluminium oxide : In the skin irritation test using rabbit, skin irritation was not observed.(OECD
Guideline 404)
- Lithium hexafluorophosphate(1-) : In the skin irritation test using human, the test material was
corrosive. (EU Method B.40, GLP)
- Propylene carbonate : In skin irritation test with rabbits, skin irritations were not observed. (OECD TG
404, GLP)
- Carbon black : In test on skin irritation with rabbits, skin irritations were not observed. (OECD
Guideline 404)
- SN (Succinonitrile) : In the skin irritation test using rabbits, the test material was not irritating. (OECD
Guideline 404)
- 1,3-propanesultone : In the skin irritation test using guinea pigs, the test material was corrosiv
e. (TOXICITY STUDIES OF 1,2-OXATHIOLANE,2,2-DIOXIDE WITH COVER LETTER DATED 0
9/01/92)
Serious eye damage/ irritation : Not classified
- Graphite : In the eye irritation test using rabbit, the test material was not irritating. (OECD Guideline
405, GLP)
- Copper : In test on skin irritation with rabbits, skin irritations were not observed. (OECD TG 405,
GLP)
- Aluminum : An eye irritation study of the aluminium oxide was performed in rabbits. No eye irritation/
corrosion effects were observed. (Read across; aluminium oxide)
- Propyl propionate : In the eyes irritation test using rabbits, the test material was not irritating.(OECD
Guideline 405)
- Polyethylene : Mild irritants were observed in eye irritation test with rabbits. (Score 11.7/110)
- Ethyl propionate : In the eyes irritation test using cattle, the test material was not irritating.(OECD
Guideline 437, GLP)
- EC (Ethylene Carbonate) : In the eye irritation test using rabbit, the test material was moderately
irritating. (OECD Guideline 405, GLP)
- aluminium oxide : The slight erythema was reversible, resolving by 48 hours post administration of
the test substance. The scores observed for cunjunctival erythema would not lead to a classification
under EU-CLP (Regulation (EC) 1272/2008)(OECD Guideline 405).
- Lithium hexafluorophosphate(1-) : In the eye irritation test using fertilised brown leghorn chicken
eggs, the test material was severely irritating. (GLP)
- Propylene carbonate : In eye irritation test with rabbits, eye irritations were observed. (OECD TG
405, GLP)
- Carbon black : In test on eyes irritation with rabbits, eyes irritations were snot observed. (OECD
Guideline 405)
- SN (Succinonitrile) : In the eye irritation test using rabbit, the test material was not irritating. (OECD
Guideline 405)

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- 1,3-propanesultone : In the eye irritation test using rabbits, the test material was corrosive. (T
OXICITY STUDIES OF 1,2-OXATHIOLANE,2,2-DIOXIDE WITH COVER LETTER DATED 09/01/
92)
Respiratory sensitization : Not classified
- Aluminum : Al2O3 was the least inflammatory material tested and led to only weak effects on the
mouse lung. (Read across; Aluminium oxide)
- aluminium oxide : In the respiratory sensitisation test using mouse, this material was not respiratory
sensitising.
- Carbon black : In respiratory sensitization test with mice(female), it did not induce respiratory
sensitization.
Skin sensitization : Not classified
- Graphite : In the skin sensitization test using mice, the test material was not skin sensitization.
(OECD Guideline 429, GLP)
- Copper : In maximization test on skin sensitization with guinea pig, skin sensitization was not
observed. (OECD TG 406, GLP)
- Aluminum : In test with guinea pigs, it can be concluded that aluminium oxide has no sensitisation
potential under the experimental conditions. (Read across; Aluminium oxide)
- Propyl propionate : In the skin sensitization test using mouse, this material was not skin
sensitizing.(OECD Guideline 429, GLP)
- Polyethylene : No reactions were observed in skin sensitization test with guinea pigs.
- Ethyl propionate : In the skin sensitization test, this material was not skin sensitizing.(OECD
Guideline 442D, GLP)
- EC (Ethylene Carbonate) : In the skin sensitization test using guinea pig, this material was not
classified. (OECD Guideline 406, GLP)
- aluminium oxide : In the skin sensitisation test using guinea pig, skin sensitisation was not observed.
- Lithium hexafluorophosphate(1-) : In the skin sensitization test using mice, the test material was not
skin sensitization. (OECD Guideline 429, GLP)
- Propylene carbonate : In patch-test with human, skin sensitizations were not observed.
- Carbon black : In skin sensitization test with guinea pig(female), it did not induce skin sensitization.
(OECD Guideline 406, GLP)
- SN (Succinonitrile) : In the skin sensitization test using mice, the test material was not classified.
(OECD Guideline 429, GLP)
- 1,3-propanesultone : In the skin sensitization test using guinea pigs, the test material was not
skin sensitizing. (OECD Guideline 406)
Carcinogenicity : Not classified
IARC
- Cobalt and inorganic compounds : Group 2B
- Carbon black : Group 2B
- Polyethylene : Group 3
- Carbon black : Group 2B
- 1,3-propanesultone : Group 2A
OSHA
- Carbon black : Present
- 1,3-propanesultone : Present
NTP
- Carbon black : Present
- 1,3-propanesultone : Present
ACGIH
- Cobalt and inorganic compounds : A3
- Aluminum : A4
- Carbon black : A3
- 1,3-propanesultone : A3

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KOREA-ISHL
- Cobalt and inorganic compounds : 2
- Carbon black : 2
- 1,3-propanesultone : 1B
EU
- 1,3-propanesultone : Carc. 1B
- Copper : EPA IRIS: D In carcinogenicity study with rat, tumor was not observed.
- Polyethylene : Fifty rats were implanted with polyethylene. In the polyethylene group, 23 developed
tumors (two of these were unrelated to the implants).
- Propylene carbonate : In carcinogenicity test with mice, there were no evidence of carcinogenic
effects. (OECD TG 451, GLP)
- Carbon black : Most of the tumours were benign squamous cysts, but a high incidence of
adenocarcinoma was also found in all groups. (OECD Guideline 451)
Mutagenicity : Not classified
- Graphite : Negative reactions were observed in vitro (Bacterial Reverse Mutation Assay(OECD
Guideline 471, GLP)).
- Copper : Negative reactions were observed in both in vitro(Ames test) and in vivo(DNA damage
and/or repair; unscheduled DNA synthesis, micronucleus assay). (GLP)
- Aluminum : Negative reactions were observed in vitro (mammalian cell gene mutation assay with
mouse lymphoma L5178Y cells(OECD TG 476, GLP)) and in vivo (micronucleus assay with rats
(OECD TG 474, GLP)). (Aluminium hydroxide, aluminium chloride, aluminum oxide; read across)
- Propyl propionate : Negative reactions were observed in vitro Bacterial Reverse Mutation
Assay(OECD Guideline 471, GLP).
- Polyethylene : Negative reactions were observed in Ames test using Salmonella typhimurium and
Escherichia coli.
- Ethyl propionate : Negative reactions were observed in vitro Bacterial Reverse Mutation
Assay(OECD Guideline 471, GLP).
- EC (Ethylene Carbonate) : Negative reactions were observed in vitro (mammalian cell gene mutation
assay (OECD Guideline 476, GLP)).
- aluminium oxide : In the mammalian erythrocyte micronucleus test, the results were positive for the
nano-sized materials(below 40nm) with evidence of a positive dose-response relationship for
MN(OECD Guideline 75). Positive reactions were observed in Mammalian Erythrocyte Micronucleus
Test(OECD Guideline 474, GLP).
- Lithium hexafluorophosphate(1-) : Negative reactions were observed in both in vivo (Mammalian
Erythrocyte Micronucleus test(OECD Guideline 474)) and in vitro (Bacterial Reverse Mutation
Assay(OECD Guideline 471, GLP)).
- Propylene carbonate : Negative reactions were observed both in vitro(DNA damage and repair
assay(OECD TG 482, GLP), bacterial reverse mutation assay(OECD TG 471, GLP)) and in
vivo(micronucleus assay(OECD TG 474, GLP)) .
- Carbon black : Negative reactions were observed in both in vitro(Bacterial Reverse Mutation Assay
test(OECD Guideline 471, GLP)and in vivo(DNA damage and/or repair test).
- SN (Succinonitrile) : Negative reactions were observed in both in vivo (Mammalian Erythrocyte
Micronucleus test(OECD Guideline 474, GLP)) and in vitro (Bacterial Reverse Mutation Assay(OECD
Guideline 471, GLP)).
- 1,3-propanesultone : Positive reactions were observed in in vivo test (Mammalian Erythrocyte
Micronucleus Test(OECD Guideline 474, GLP))
Reproductive toxicity : Not classified
- Copper : In reproductive toxicity with rats, there were no effects considered (up to 1500 ppm).
(OECD TG 416, GLP)
- Aluminum : No reproduction, breeding and early post-natal developmental toxicity was observed in
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rats at 1000 mg/kg bw for males and females. (OECD TG 422, GLP)(Aluminium chloride; read across)
- Propyl propionate : In the reproduction toxicity test using rat, no effects were observed.(OECD
Guideline 422)
- Ethyl propionate : No test item-related adverse effects for general toxicity effects and
reproductive/developmental effects were observed up to 1000 mg/kg.(OECD Guideline 422, GLP)
- aluminium oxide : In summary, clinical observations that were found associated with treatment, either
directly or secondary to renal failure, were poor coat, weight loss, diarrhea, and haematuria. However,
reproductive effects observed were not specified.(OECD Guideline 426 and OECD Guideline 452,
GLP)
- Lithium hexafluorophosphate(1-) : In the two-generation reproductive toxicity with rats, no effects
observed on reproductive toxicity. (male/female)(OECD Guideline 416, GLP)(OECD Guideline
414)(Information on major hydrolysis product of the registered substance (released rapidly on contact
with water/moisture))
- Propylene carbonate : In reproduction/developmental toxicity test with rats, no treatment-related
effects on reproduction were observed. (OECD TG 414, GLP)
- Carbon black : No adverse effects on the reproductive function are expected.(OECD Guideline 414)
Specific target organ toxicity (single exposure) : Not classified
- Copper : All animals showed expected gains in bodyweight over the study period and there were no
abnormalities noted at necropsy. (OECD TG 423, GLP)
- Aluminum : In test using rats, Clinical signs of depression, laboured respiration, piloerection and
hunched appearance was noted at the highest dose 15900 mg/kg. Macroscopic examination at the
end of the observation period did not reveal any aluminium-related changes of the internal organs of
the aluminium treated animals compared to the control group. (OECD TG 401)(Fumed alumina; read
across)
- Polyethylene : No test substance-related toxic effects were observed in an acute oral toxicity study
with rats.
- aluminium oxide : Inhalation of aluminium oxide at a concentration of 0.38 mg/L (380 mg/cu m) for 3,
7 or 15 minutes produced a time-dependent lung dilatory effect.
- Lithium hexafluorophosphate(1-) : Clinical signs observed during the study period were lethargy,
hunched posture, uncoordinated movements, piloerection at 300 mg/kg, hunched posture, piloerection
at 50 mg/kg. The surviving animals had recovered from the symptoms by Day 3.(OECD Guideline
423, GLP)
- Propylene carbonate : In acute oral toxicity with rats, acute toxicity were not observed. (OECD TG
401, GLP)
- Carbon black : No effect on endothelins or blood pressure was observed after exposure to carbon
black. There were also no effects on body temperature and activity of the animals.
- 1,3-propanesultone : In the acute oral toxicity test with rats, during days 4 and 13, dehydratio
n, decreased respiratory rate, gasping, laboured and noisy respiration were observed. (OECD G
uideline 401, GLP)
Specific target organ toxicity (repeat exposure) : Not classified
- Copper : In test with rats for 92 days, there were no mortalities or signs of clinical toxicity observed in
any of the test species during the duration of the study. Opthalmoscopic examinations revealed no
abnormalities at any dose level tested. At gross pathology, significant decreases in heart and kidney
weight were noted in the high dose males in the thymus and kidneys of high dose females. (GLP)
- Aluminum : On occasion workers chronically exposed to aluminum-containing dusts or fumes have
developed severe pulmonary reactions including fibrosis, emphysema and pneumothorax.
- Polyethylene : No significant adverse effects were observed in subchronic (90-day) oral toxicity study
with rats and dogs.
- Ethyl propionate : no test item-related adverse effects for general toxicity effects and
reproductive/developmental effects were observed.(OECD Guideline 422, GLP)
- aluminium oxide : In the repeated exposure of aluminium oxide, it is occurred to asbestosis to human
lung.

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- Lithium hexafluorophosphate(1-) : According to expert review of fluoride intake and effects on human
health, fluoride intake in drinking water at levels close to or above 4 mg/l is associated with dental
fluorosis and perhaps also bone fluorosis and/or weakening.; Damage to dental enamel recorded:
especially notable in young animals, which also showed atrophy of respiratory organs/tissues with
local oedema of bronchial mucosa. Older animals showed peribronchial hyperplasia. Animals around
1 year in age showed cavity formation in their bones.(Information on major hydrolysis product of the
registered substance (released rapidly on contact with water/moisture))(OECD Guideline 412)
- Propylene carbonate : In oral repeated-dose toxicity study with rats for 90 days, no treatment related
adverse effects were observed. (OECD TG 408, GLP)
- Carbon black : Mice were continuously fed various types of carbon black in massive quantities (10%
in diet) for 12 to 18 months. This led to no detectable changes from the normal in the organs and
tissues of the mice fed.
Aspiration Hazard : Not available

Section XII – ECOLOGICAL INFORMATION

※ This is a product that fulfills a certain function in solid state with specific shape without discharging any
chemical substance in its use and has no obligation to write (M)SDS. Since this document contains the
precautions for safe handling related to its materials or chemical substances consisting of this product,
please note that these overall information is irrelevant to this product.

12.1 Ecological toxicity


- Acute toxicity : Not classified (ATEmix = 0.20 mg/L)
- Chronic toxicity : Not classified
Fish
- cobalt lithium dioxide : 96hr-LC50 (other) = 54.1 mg/L (Read across; cobalt (II) chloride hexahydrate),
34d-NOEC ( Pimephales promelas) = 0.21 mg/L
- Graphite : 96hr-LC50 > 100 mg/L
- Aluminum : 96hr-LC50 > 218.64 mg/L (GLP)(Read across; aluminium chloride hexahydrate), 28d-
NOEC (Pimephales promelas) = 4.7 mg/L (Read across; aluminium sulphate)
- Propyl propionate : 96hr-LC50 = 10.8 mg/L 96h-NOEC=2.86mg/l (OECD Guideline 203, GLP)
- Ethyl propionate : 96hr-LC50 = 6.74 mg/L (OECD Guideline 203, GLP)
- EC (Ethylene Carbonate) : 96hr-LC50 > 100 mg/L (OECD Guideline 203, GLP)
- aluminium oxide : 96hr-LC50 = 1.16 mg/L (WoE, USEPA 1985), 7d-NOEC(Pimephales promelas) =
0.16 mg/L
- Lithium hexafluorophosphate(1-) : 96hr-LC50 = 51 ~ 193 mg/L Information on major hydrolysis product
of the registered substance (released rapidly on contact with water/moisture); 21d-NOEC = 4 mg F-/L
- Propylene carbonate : 96hr-LC50 > 1000 mg/L (GLP)
- Carbon black : 96hr-LC0 = 1000 mg/L (OECD Guideline 203, GLP)
- 1,3-propanesultone : 96hr-LC50(Leuciscus idus) = 420 mg/L (OECD Guideline 203, GLP)
Crustacean
- cobalt lithium dioxide : 48hr-EC50 (other) = 2.618 mg/L (GLP)(Read across; cobalt (II) chloride
hexahydrate), 42d-NOEC (Neanthes arenaceodentata) = 0.713 mg/L (ASTM Method E1562, GLP)
- Graphite : 48hr-EC50 > 100 mg/L
- Aluminum : 48hr-LC50 = 0.071 mg/L (Read across; CAS 13473-90-0), 8d-NOEC (Ceriodaphnia dubia)
= 4.9 mg/L (Read across; CAS 7784-13-6)
- Propyl propionate : 24hr-EC50 = 59.6 mg/L (OECD Guideline 202, GLP)
- Ethyl propionate : 48hr-EC50 = 25.5 mg/L (OECD Guideline 202, GLP), 21d-NOEC=1.3mg/L(OECD
Guideline 211)
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- EC (Ethylene Carbonate) : 48hr-EC50 > 100 mg/L (OECD Guideline 202, GLP)


- aluminium oxide : 48hr-EC50 = 1.9 mg/L ,21d-NOEC(Daphnia magna)= 0.076 mg/L(OECD Guideline
211, GLP)
- Lithium hexafluorophosphate(1-) : 48hr-LC50 > 100 mg/L (OECD Guideline 202, GLP);21d-
NOEC(Daphnia magna) = 10 mg/L (Information on major hydrolysis product of the registered
substance (released rapidly on contact with water/moisture)) (OECD guideline 202, GLP)
- Propylene carbonate : 48hr-EC50 > 1000 mg/L (OECD TG 202, GLP)
- Carbon black : 24hr-EC50 > 5600 mg/L (OECD Guideline 202, GLP)
- 1,3-propanesultone : 48hr-EC50(Daphnia magna) = 16 mg/L (OECD Guideline 202, GLP)
Algae
- cobalt lithium dioxide : 96hr-EC50 (other) = 71.314 mg/L (Read across; cobalt (II) chloride
hexahydrate), 96hr-NOEC (Dunaliella tertiolecta) = 4.672 mg/L
- Graphite : 72hr-EC50 > 100 mg/L
- Aluminum : 72hr-EC50 = 0.0169 mg/L (OECD TG 201), (Read across; CAS 13473-90-0)
- Propyl propionate : 96hr-EC50 > 1004 mg/L, 96h-NOEC=245mg/l(OECD Guideline 201, GLP)
- Ethyl propionate : 72hr-EC50 = 130 mg/L (Pseudokirchneriella subcapitata) (OECD Guideline 201,
GLP)
- EC (Ethylene Carbonate) : 72hr-EC50 > 100 mg/L (OECD Guideline 201, GLP), 72hr-
NOEC(Selenastrum capricornutum) = 100mg/L (OECD Guideline 201, GLP)
- aluminium oxide : 72h-NOEC(Pseudokirchneriella subcapitata) >= 0.044 mg/L (OECD Guideline 201,
GLP)
- Lithium hexafluorophosphate(1-) : 96hr-EC50 > 100 mg/L ; 96h-NOEC = 22 mg/L (OECD Guideline
201, GLP)
- Propylene carbonate : 72hr-EC50 > 900 mg/L (OECD TG 201, GLP)
- Carbon black : 72hr-EC50 > 10000 mg/L , 72hr-NOEC > 10,000mg/L (OECD Guideline 201, GLP)
- 1,3-propanesultone : 72hr-EC50(Desmodesmus subspicatus) > 320 mg/L (OECD Guideline 201,
GLP)
B. Persistence and degradability
Persistence
- Graphite : Low persistency (log Kow is less than 4 estimated.) (Log Kow = 0.78)
- Aluminum : Low persistency (log Kow is less than 4 estimated.) (Log Kow = 0.33) (estimated)
- EC (Ethylene Carbonate) : Low persistency (log Kow is less than 4 estimated.) (Log Kow = 0.11)
(20 °C, pH> 5.33 - < 5.79)(EU Method A.8, GLP)
- aluminium oxide : Low persistency (log Kow is less than 4 estimated.) (Log Kow = -0.83) (estimated)
- Lithium hexafluorophosphate(1-) : Low persistency (log Kow is less than 4 estimated.) (Log Kow =
0.354) (20 °C, pH > 6.5 - < 7.5)( OECD Guideline 107, GLP)
- Propylene carbonate : Low persistency (log Kow is less than 4 estimated.) (Log Kow = 0.0788)
- SN (Succinonitrile) : Low persistency (log Kow is less than 4 estimated.) (Log Kow = -0.99)
- 1,3-propanesultone : Low persistency (log Kow is less than 4 estimated.) (log Kow = -2.86 )
(QSAR)
Degradability : Not available
C. Bioaccumulative potential
Bioaccumulation
- cobalt lithium dioxide : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 23)
(Read across; 57CoCl)
- Graphite : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 2.433)
- Copper : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 0.02 ~ 20)
- Aluminum : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 3.162)
(estimated)
- EC (Ethylene Carbonate) : Bioaccumulation is expected to be low according to the BCF < 500 (BCF =
3.162) (estimated)
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- aluminium oxide : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 3.162)
(estimated)
- Lithium hexafluorophosphate(1-) : Bioaccumulation is expected to be low according to the BCF < 500
(BCF < 31)
- Propylene carbonate : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 3)
(Estimated)
- SN (Succinonitrile) : Bioaccumulation is expected to be low according to the BCF < 500 (BCF = 3)
(estimated)
- 1,3-propanesultone : Bioaccumulation is expected to be low according to the BCF < 500 (BCF
= 3.162) (estimated)
Biodegradation
- Propyl propionate : The test material is readily biodegradable.
- Polyethylene : As not well-biodegraded, it is expected to have high accumulation potential in living
organisms (= 0% biodegradation was observed after 28 days)
- Ethyl propionate : As well-biodegraded, it is expected to have low accumulation potential in living
organisms (66% ~ 68% biodegradation was observed after 28 days) Readily biodegradable: 66 - 68%
within 28 days (OECD 301 D, GLP)
- EC (Ethylene Carbonate) : As well-biodegraded, it is expected to have low accumulation potential in
living organisms (70% ~ 80% biodegradation was observed after 10 days) (OECD Guideline 301 A,
GLP)
- aluminium oxide : Not readily biodegradable(estimated)
- Lithium hexafluorophosphate(1-) : As well-biodegraded, it is expected to have low accumulation
potential in living organisms (= 86% biodegradation was observed after 28 days) (OECD Guideline 301
C, GLP)
- Propylene carbonate : As well-biodegraded, it is expected to have low accumulation potential in living
organisms (= 87.7% biodegradation was observed after 29 days) (OECD TG 301B, GLP)
- Carbon black : carbon black is an inorganic substance and will not biodegraded by microorganisms.
- SN (Succinonitrile) : As not well-biodegraded, it is expected to have high accumulation potential in
living organisms (= 45.1% biodegradation was observed after 4 days)
- 1,3-propanesultone : As well-biodegraded, it is expected to have low accumulation potential in l
iving organisms(89% biodegradation was observed after 28 days) (OECD Guideline 301E, GLP)
12.4 Mobility in soil
- EC (Ethylene Carbonate) : Low potency of mobility to soil. (Koc = 3.219) (estimated)
- aluminium oxide : Low potency of mobility to soil. (Koc = 0.1902) (estimated)
- Propylene carbonate : Low potency of mobility to soil. (Koc = 14) (Estimated)
- SN (Succinonitrile) : Low potency of mobility to soil. (Koc = 28) (estimated)
- 1,3-propanesultone : No potency of mobility to soil. (Koc = 16.8) (QSAR)
12.5 Results of PBT and vPvB assessment : Not available
12.6 Other adverse effects : Not available

Section XIII – DISPOSAL CONSIDERATION

13.1 Waste treatment methods


Product/Packaging disposal
- Consider the required attentions in accordance with waste treatment management regulation.
Waste codes / Waste designation according to LoW(2015) : 16-06-05
Waste treatment-relevant information

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- Waste must be disposed of in accordance with federal, state and local environmental control
regulations.
Sewage disposal-relevant information: Not available
Other disposal recommendations: Not available

Section XIV – TRANSPORTATION INFORMATION

※ If those lithium-ion batteries are packed with or contained in an equipment, then it is the responsibility
of the shipper to ensure that the consignment are packed in compliance to the latest edition of the IATA
Dangerous Goods Regulations section Ⅱ of either Packing Instruction 966 or 967 in order for that
consignment to be declared as NOT RESTRICTED (non-hazardous/non-Dangerous). If those lithium-ion
batteries are packed with or contained in an equipment, UN No. is UN3481.

14.1 UN Number : 3480


14.2 UN Proper shipping name : LITHIUM ION BATTERIES (including lithium ion polymer ba
tteries)
14.3 Transport Hazard class : 9
14.4 Packing group : II
14.5 Special provisions : 188, 230, 384
14.6 Packing instructions : P903
14.7 Environmental hazards : No
14.8 Special precautions for user
in case of fire : F-A
in case of leakage : S-I
14.9 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not
Available
14.10 IATA Transport : PI 965-Section IB
14.11 Package labels

Section XV – REGULATORY INFORMATION


15.1 Safety, health and environmental regulation/legislation specific for the substance or mixture
EU regulations
Authorisations and/or restrictions on use:
Authorisations: Not regulated
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Restrictions on use: Not regulated


Other EU regulations:
Candidate List of substances of very high concern for Authorisation
- 1,3-propanesultone : Regulated
Foreign Regulatory Information
External information :
U.S.A management information (OSHA Regulation) : Not regulated
U.S.A management information (CERCLA Regulation) :
- Copper : 5,000 lb
- 1,3-propanesultone : 10 lb
U.S.A management information (EPCRA 302 Regulation) : Not regulated
U.S.A management information (EPCRA 304 Regulation) : Not regulated
U.S.A management information (EPCRA 313 Regulation) :
- Cobalt, Co : Regulated
- Aluminium (metal) : Regulated
- Copper : Regulated
- Aluminium Oxide : Regulated
- 1,3-propanesultone : Regulated
Substance of Roterdame Protocol : Not regulated
Substance of Stockholme Protocol :
- LiPF6 (Lithium hexaflurophosphate) : Regulated
Substance of Montreal Protocol : Not regulated
15.2 Chemical safety assessment :
- No chemical safety assessment has been carried out for this product by the supplier.

Section XVI – OTHER INFORMATION EU

Product safety data sheet for PA0001N0006A/PA0001N0007A/PA001N0008A prepared in accordance


with Regulation (EU) 2015/830 (REACH), Annex II, and OSHA 29 CFR 1910.1200
16.1 Indication of changes
Date Updated : 14 Feb. 2019
Version : Rev. 02
16.2 Abbreviations and acronyms
ACGIH = American Conference of Government Industrial Hygienists
CLP = Classification Labelling Packaging Regulation ; Regulation (EC) No 1272/2008
CAS No. = Chemical Abstracts Service number
DMEL = Derived Minimal Effect Levels
DNEL = Derived No Effect Level
EC Number = EINECS and ELINCS Number (see also EINECS and ELINCS)
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EU = European Union
IARC = International Agency for Research on Cancer
ISHL = Industrial Safety & Health Law
NIOSH = National Institute for Occupational Safety & Health
NTP = National Toxicology Program
OSHA = European Agency for Safety and Health at work
PBT = Persistent, Bioaccumulative and Toxic substance
PNEC(s) = Predicted No Effect Concentration(s)
REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No
453/2010
STP = Sewage Treatment Plant
SVHC = Substances of Very High Concern
vPvB = Very Persistent and Very Bioaccumulative
UN = United Nations
MARPOL = International Convention for the Prevention of Pollution from Ships (IMO)
IBC = Intermediate Bulk Container
CERCLA = Comprehensive Environmental Response, Compensation & Liability Act (US)
EPCRA = Emergency Planning and Community Right-to-Know Act (US)
EINECS = European Inventory of Existing Commercial chemical Substances
ELINCS = European List of Notified Chemical Substances
16.3 Key literature reference and sources for data :
U.S. National library of Medicine (NLM) Hazardous Substances Data Bank (HSDB)
LookChem; http://www.lookchem.com/
IUCLID: http://ecb.jrc.ec.europa.eu/IUCLID-DataSheets/7631905.pdf
CHRIP(Chemical Risk Information Platform)
EPISUITE v4.11; http://www.epa.gov/opt/exposure/pubs/episuitedl.html
The Chemical Database -The Department of Chemistry at the University of Akron;
http://ull.chemistry.uakron.edu/erd/
ECOTOX: http://cfpub.epa.gov/ecotox/
International Chemical Safety Cards (ICSC): http://www.nihs.go.jp/ICSC/
National Chemical Information System (http://ncis.nier.go.kr)
Korea Dangerous Material Inventory Management System (http://hazmat.nema.go.kr)
REACH information on registered substances; https://echa.europa.eu/information-on-
chemicals/registered-substances
EU CLP; https://echa.europa.eu/information-on-chemicals/cl-inventory-database
NIOSH Pocket Guide; http://www.cdc.gov/niosh/npg/npgdcas.html
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans; http://monographs.iarc.fr
National Toxicology Program; http://ntp.niehs.nih.gov/results/dbsearch/
TOMES-LOLI® ; http://www.rightanswerknowledge.com/loginRA.asp
UN Recommendations on the transport of dangerous goods 17th
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American Conference of Governmental Industrial Hygienists TLVs and BEIs.


16.4 Classification and procedure used to derive the classification for mixtures according to
Regulation(EC) 1272/2008(CLP) : Not classified
16.5 Relevant H-statements : Not applicable
16.6 Training advice :
- Do not handle until all safety precautions have been read and understood.
16.7 Further information :
Data of sections 4 to 8, as well as 10 to 12, do not necessarily refer to the use and the regular handling of
the product (in this sense consult package leaflet and expert information), but to release of major amounts in
case of accidents and irregularities. The information describes exclusively the safety requirements for the
product (s) and is based on the present level of our knowledge. This data does not constitute a uarantee for
the characteristics of the product(s) as defined by the legal warranty regulations. "(n.a. = not applicable; n.d.
= not determined)"
The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor’s
safety data sheet.

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