Physics Students' LED Project
Physics Students' LED Project
2021-2022
BSc Physics
                                                            1
               Table of Contents
➔ Introduction ………………………………………………….. 3
    ❖ Experiment ………………………………………… 26 - 31
        ● Aim …………………………………………… 26
        ● Apparatus ……………………………….. 26
        ● Diagram ………………………………….. 26
        ● Procedure …………………………………. 27
        ● Observations …………………………… 28
        ● Observation Table …………………… 29
        ● Calculation ……………………………… 31
        ● Graphs ……………………………………. 34
        ● Result ………………………………………. 36
➔ Conclusion …………………………………………………… 37
➔ References ………………………………………...…………. 38
                                             2
● Introduction
                                                                                 3
● Theory
❖ Semiconductors :
  A semiconductor material is one whose electrical properties lie in between
  those of insulators and good conductors. Examples are : germanium and
  silicon. In terms of energy bands, semiconductors can be defined as those
  materials which have almost an empty conduction band and almost filled
  valence band with a very narrow energy gap (of the order of 1 eV) separating
  the two.
  Types of Semiconductors:
  Semiconductor may be classified as under:
A. Intrinsic Semiconductors
  An intrinsic semiconductor is one which is made of the semiconductor
  material in its extremely pure form. Examples of such semiconductors are:
  pure germanium and silicon which have forbidden energy gaps of 0.72 eV and
  1.1 eV respectively. The energy gap is so small that even at ordinary room
  temperature; there are many electrons which possess sufficient energy to
  jump across the small energy gap between the valence and the conduction
  bands.
                                                                            4
     Alternatively, an intrinsic semiconductor may be defined as one in which the
     number of conduction electrons is equal to the number of holes.
     Schematic energy band diagram of an intrinsic semiconductor at room
     temperature is shown in fig. below -
 B. Extrinsic Semiconductors
     Those intrinsic semiconductors to which some suitable impurity or doping
     agent or doping has been added in extremely small amounts
      (about 1 part in 108) are called extrinsic or impure semiconductors.
     Depending on the type of doping material used, extrinsic semiconductors can
     be subdivided into two classes:
            I ) N-type semiconductors &
            II ) P-type semiconductors.
I.   N-type Semiconductors
     This type of semiconductor is obtained when a pentavalent material like
     antimony (Sb) is added to pure Silicon crystal. As shown in Fig. below, each
     antimony atom forms covalent bonds with the surrounding four Silicon atoms
     with the help of four of its five electrons. The fifth electron is superfluous and
     is loosely bound to the antimony atom.
     Hence, it can be easily excited from the valence band to the conduction band
     by the application of electric field or increase in thermal energy. It is seen
                                                                                     5
      from the above description that in N-type semiconductors, electrons are the
      majority carriers while holes constitute the minority carriers.
                                                                                      6
● Majority & Minority Charge Carriers
                                                                              7
❖ P-N Junction Diode :
  A p-n junction diode is a two-terminal or two-electrode semiconductor
  device, which allows the electric current in only one direction while blocks
  the electric current in opposite or reverse direction. If the diode is forward
  biased, it allows the electric current flow. On the other hand, if the diode is
  reverse biased, it blocks the electric current flow. P-N junction semiconductor
  diode is also called as p-n junction semiconductor device.
  In n-type semiconductors, free electrons are the majority charge carriers
  whereas in p-type semiconductors, holes are the majority charge carriers.
  When the n-type semiconductor is joined with the p-type semiconductor, a
  p-n junction is formed. The p-n junction, which is formed when the p-type
  and n-type semiconductors are joined, is called a p-n junction diode.
   For designing the diodes, silicon is more preferred over germanium.The p-n
  junction diodes made from silicon semiconductors work at higher
  temperatures when compared with the p-n junction diodes made from
  germanium semiconductors.
                                                                                 8
  If the p-n junction diode is reverse biased, it blocks the electric current flow.
  Under reverse biased conditions, the p-type semiconductor is connected to
  the negative terminal of the battery whereas; the n-type semiconductor is
  connected to the positive terminal of the battery.
  The basic symbol of the p-n junction diode under forward bias and reverse
  bias is shown in the below figure.
                                                                                 9
  terminal is the source of positive charge carriers (holes), the positive charge
  carriers (holes) begin their journey at anode terminal and travel through the
  diode and end at cathode terminal.
                                                                              10
p-type semiconductor get attracted towards the negative terminal. The free
electrons from the negative terminal cannot move towards the positive
terminal because the wide depletion region at the p-n junction resists or
opposes the flow of free electrons.
                                                                            11
● V/I characteristics
● Forward Characteristics
    When the diode is forward biased and applied voltage is increased from zero
    hardly any current flows through the device in the beginning. It is so because
    the external voltage is being opposed by the internal barrier voltage VB
    whose value is 0.7 V for Si and 0.3 V for Ge. As soon as VB is neutralized,
    current through the diode increases rapidly with increasing applied battery
    voltage. It is found that as little a voltage as 1.0 V produces a forward
    current of about 50 mA.
● Reverse characteristic
    When the diode is reverse biased majority carriers are blocked and only
    a small current (due to minority carriers) flows through the diode. As the
    reverse voltage is increased from zero, the reverse current very quickly
    reaches its maximum or saturation value I0 which is also known as leakage
    current. It is of order of nano ampere (nA) for Si and micro ampere (µA) for
    Ge. When reverse voltage VBR, the leakage current suddenly and
    sharply increases, the curve indicating zero resistance at this point.
                                                                                   12
● Advantages of p-n junction diode
   ➨It is much smaller and cheaper.
   ➨It needs only a small voltage to operate.
   ➨It requires no time to warm up to produce the current carriers since
     it is a semiconductor, thus can be operated with a low voltage source.
   ➨It can be used as a switch.
                                                                              13
❖ Light Emitting Diode (LED) :
  A Light Emitting Diode (LED) is an optical semiconductor device that emits
  light when voltage is applied. In other words, LED is an optical
  semiconductor device that converts electrical energy into light energy.
  The symbol of LED is similar to the normal p-n junction diode except that it
  contains arrows pointing away from the diode indicating that light is being
  emitted by the diode.
  LEDs operate only in forward bias condition. To create an LED, the n-type
  material should be connected to the negative terminal of the battery and
  p-type material should be connected to the positive terminal of the battery. In
  other words, the n-type material should be negatively charged and the p-type
  material should be positively charged.
  The construction of LED is similar to the normal p-n junction diode except
  that gallium, phosphorus and arsenic materials are used for construction
  instead of silicon or germanium materials.
  When the Light Emitting Diode (LED) is forward biased, free electrons in the
  conduction band recombines with the holes in the valence band and release
  energy in the form of light.
  The process of emitting light in response to the strong electric field or flow of
  electric current is called electroluminescence.
                                                                                14
● Working of LED
  When the Light Emitting Diode (LED) is forward biased, the free electrons
  from the n-side and the holes from the p-side are pushed towards the
  junction.
  When free electrons reach the junction or depletion region, some of the free
  electrons recombine with the holes in the positive ions. We know that positive
  ions have less number of electrons than protons. Therefore, they are ready to
  accept electrons. Thus, free electrons recombine with holes in the depletion
  region. In the similar way, holes from p-side recombine with electrons in the
  depletion region.
                                                                              15
  conduction band releases energy in the form of light before they recombine
  with holes in the valence band. And thus the LED glows.
● Advantages of LED
  ➨The brightness of light emitted by LED is depends on the current flowing
  through the LED. Hence, the brightness of LEDs can be easily controlled by
  varying the current. This makes it possible to operate LED displays under
  different ambient lighting conditions.
  ➨Light emitting diodes consume low energy.
  ➨LEDs are very cheap and readily available.
  ➨LEDs have longer lifetime.
  ➨LEDs operates very fast. They can be turned on and off in very less time.
  ➨LEDs do not contain toxic material like mercury which is used
    in fluorescent lamps.
  ➨LEDs can emit different colors of light.
● Disadvantages of LED
   ➨LEDs need more power to operate than normal p-n junction diodes.
   ➨Luminous efficiency of LEDs is low.
   ➨Cannot withstand high reverse voltage.
                                                                               16
❖ Visible Light Spectrum :
  Light is the electromagnetic radiation that occurs within a specific section of
  the electromagnetic spectrum. The term essentially refers to the visible light,
  it is the light that is distinguishable and visible to naked human eye and it is
  also responsible for the sense of light.
  The wavelengths of the visible light range between 400-700 nanometers, this
  is between the infrared having longer wavelengths and the ultraviolet having
  shorter wavelengths. The wavelength of the visible light indicates that its
  frequency is approximately 430-750 terahertz (THz).
  The light speed in the vacuum is 299,792,458 metres per second as per the
  experiment. The visible light like other forms of the electromagnetic radiation
  moves at this speed specifically in the vacuum.
  In physics, the definition of light often refers to the electromagnetic radiation
  having any wavelength, regardless of if it’s visible or not. The light exhibits
  both particle nature and wave nature and the occurrence of this phenomenon
  is described as light's dual nature.
  Light doesn’t necessarily travel in the straight line but it travels in transverse
  waves. The wave that is made of oscillation when moving and that occurs
  perpendicular to direction of energy transfer is known as the transverse
  waves.
● Wavelength
                                                                                 17
energy. On the other hand, waves are the form of energy where
electromagnetic radiation takes on when it is propagating.
Wavelength is the distance between two consecutive crests or two consecutive
troughs in a transverse wave.
                                                                           18
❖ Band Gap Energy :
  A band gap is the distance between the valence band of electrons and the
  conduction band. Essentially, the band gap represents the minimum energy
  that is required to excite an electron up to a state in the conduction band
  where it can participate in conduction. The lower energy level is the valence
  band, and thus if a gap exists between this level and the higher energy
  conduction band, energy must be input for electrons to become free. This
  energy is called Band Gap Energy.It is denoted by Eg. The size and existence
  of this band gap between conductors, semiconductors, and insulators is
  shown in the figure below.
                                                                              19
the amplitude of atomic vibrations increases, leading to larger interatomic
spacing. LEDs usually emit photons with energy close to and slightly larger
than the band gap of the semiconductor material from which they are made.
Therefore, as the band gap energy increases, the LEDs colour changes from
infrared to red, red to violet, then to UV.
The table below lists the band gap energy of various semiconductors at room
temperature :-
As   the band gap energy is understood to be the width of the energy gap
between conduction and valence band.
For single-photon processes, the optical wavelength corresponding to a given
band gap energy Eg can be calculated as
                                 λ = hc/Eg
or numerically as 1.235 divided by the band gap energy in electron volts,
obtaining the band gap wavelength in units of micrometers.
                                                                         20
❖ Newton's Ring Method :
  Newton's rings is a phenomenon in which an interference pattern is created
  by the reflection of light between two surfaces; a spherical surface and an
  adjacent touching flat surface. It is named after Isaac Newton, who
  investigated the effect in 1666. When viewed with monochromatic light,
  Newton's rings appear as a series of concentric, alternating bright and dark
  rings centered at the point of contact between the two surfaces. When viewed
  with white light, it forms a concentric ring pattern of rainbow colors, because
  the different wavelengths of light interfere at different thicknesses of the air
  layer between the surfaces.
                                                                               21
  When crest of the first wave falls on the crest of second wave and trough of
  the first wave falls on the trough of the second wave and then the resultant
  wave is the vector sum of the amplitude of the two superimposing waves
  which is equal to sum of the amplitude of two waves, this is known as
  Constructive Interference.
  When crest of the first wave falls on the trough of second wave and trough of
  the first wave is falls on the crest of the second wave and the resultant wave is
  the vector sum of the amplitude of the two superimposing waves which is
  equal to the difference in amplitude of two waves, this is known as
  Destructive Interference.
  Constructive interference occurs when the phase difference between the
  waves is a multiple of 2π, whereas destructive interference occurs when the
  phase difference is an odd multiple of π.
                                                                                22
These two reflected rays are coherent, hence they will interfere and produce a
system of alternate dark and bright rings with the point of contact between
the lens and the plate at the center. And thus Newton’s rings are formed.
In general, the path difference between the reflected light beams which are
undergoing interference (for oblique incidence) is given by
where the additional path difference of λ/2 is because one of the interfering
beams is reflected from film to glass surface.
Also, θ is the angle of incidence. For normal incidence θ=0° and hence, the
path difference will be
                                                                            23
  In the interference pattern bright fringe will be formed if the path difference
  is equal to integral multiple of wavelength of light, i.e.,
  Let LOL' be the plano-convex lens placed on a glass plate. Plano-convex lens
  appears as part of the circle of radius R.
  Here, radius R is known as radius of curvature of plano-convex lens.
                                     th
  Suppose r is the radius of some n bright ring having thickness t.
  Using the property of a circle. from above figure), we can write
         EP × P F = P O × P Q,
              2
         ⇒ r n = t × ( 2R − t )
              2               2
         ⇒ r n = ( 2Rt − t )
                                                                              24
   Since R >> t, t2 can be neglected therefore
                       2
                      r n ≈ 2Rt                                      ......…………. (5)
                                                                        th
   Using rn = Dn /2, we can write following relation for diameter of n , ring as
             2             2
          D n = 2r n = nλR/µ                                         ....….……….. (7)
                                       th
   Similarly,the diameter of some m dark fringe will be
             2
          D      m   = nλR/µ                                         ....….……….. (8)
                      2        2
          λ = [D n − D m/4R(n − m)] × µ                              ..…………….. (9)
● An alternative and better method is to plot n ( no. of fringes) along the x-axis
         2
   and D on the y-axis. Then the slope of the straight line, tan (ϕ) will give the
   wavelength as
λ = tan (ϕ) / 4R
                                                                                   25
● Experiment
❖ Aim :
❖ Apparatus :
❖ Formula :
                              th
 Where, Dn = diameter of n ring,
                                th
          Dm = diameter of m ring,
          m & n = an integer number (of the rings)
          R = radius of curvature of the curved face of the plano-convex lens.
                                         Eg = hc/λ
 Where, λ = wavelength of light,
                                                 -34     2
          h = planck's constant ( 6.626 × 10           m kg / s),
          c = speed of light ( 3 × 10⁸ m / s).
                                                                                 26
❖ Diagram :
❖ Procedure :
● Level the traveling microscope table and set the microscope tube in a vertical
    position. Find the vernier constant (least count) of the horizontal scale of the
    traveling microscope.
●   Clean the surface of the inclined glass plate G, the lens C and glass plate P.
● Place them in position as shown in above figure and as discussed in the
    description of apparatus.
● Place the arrangement in front of the LEDs so that the height of the center of
    the glass plate G is the same as that of the center of the LED.
● Adjust the position of the traveling microscope so that it lies vertically above
    the center of lens C.
● Focus the microscope, so that alternate dark and bright rings are clearly
    visible.
● Slide the microscope to the left till the cross wire lies tangentially at the
                      th
    center of the n        dark ring. Note the reading on the vernier scale of the
    microscope.
                                                                                     27
●   Slide the microscope backward with the help of the slow motion screw and
    note the readings when the cross-wire lies tangentially at the center of the
    dark rings, respectively.
● Keep on sliding the microscope to the right and note the reading when the
                                                                                       th
    cross-wire again lies tangentially at the center of the 1st, 2nd and till the n
    dark rings, respectively.
● Remove the plano-convex lens C and find the radius of curvature of the
    surface of the lens in contact with the glass plate P accurately using a
    spherometer.
● Find the diameter of each ring from the difference of the observations taken
    on the left and right side of its center.
                                                                     2    2
● Take any two diameters and perform the calculations for D n−D            m   (m<n) as
    directed and calculate the value of wavelengths of the LEDs.
● Finally, calculate the Band Gap Energy Eg using the relation between the
    wavelength and band gap energy and thereafter determine the semiconductor
    material used in LED.
❖ Observations :
          = 0.05 cm / 50 div
          = 0.001 cm
                                                                                       28
❖ Observation Table :
                st
    1)      1         5      24     5.024   4.7   42      4.742   0.282   0.0795
                nd
    2)      2         5      45     5.045   4.7   23      4.723   0.322   0.1036
                rd
    3)      3         5      64     5.064   4.7   06      4.706   0.358   0.1281
                th
    4)      4         5      83     5.083   4.6   89      4.689   0.394   0.1552
                th
    5)      5         5      97     5.097   4.6   72      4.672   0.425   0.18062
                th
    6)      6        5.1     09     5.109   4.6   62      4.662   0.447   0.1998
                st
    1)      1         5      21     5.021   4.7   64      4.764   0.257   0.0660
                nd
    2)      2         5      39     5.039   4.7   42      4.742   0.297   0.0882
                rd
    3)      3         5      55     5.055   4.7   22      4.722   0.333   0.1108
                th
    4)      4         5      72     5.072   4.7   13      4.713   0.359   0.1288
                th
    5)      5         5      93     5.093   4.7   03      4.703   0.390   0.1521
                th
    6)      6        5.1     00     5.100   4.6   93      4.693   0.407   0.1656
                                                                             29
Yellow color LED :
               st
  1)       1          5      07     5.007   4.7   81      4.781   0.401   0.0510
              nd
  2)      2           5      22     5.022   4.7   61      4.761   0.369   0.0681
               rd
  3)       3          5      44     5.044   4.7   39      4.739   0.335   0.0930
               th
  4)       4          5      61     5.061   4.7   26      4.726   0.305   0.1122
               th
  5)       5          5      80     5.080   4.7   11      4.711   0.261   0.1361
               th
  6)       6          5      97     5.097   4.6   96      4.696   0.226   0.1608
               st
  1)       1          5      21     5.021   4.7   71      4.771   0.250   0.0625
              nd
  2)      2           5      32     5.032   4.7   49      4.749   0.283   0.0800
               rd
  3)       3          5      49     5.049   4.7   34      4.734   0.315   0.0922
               th
  4)       4          5      63     5.063   4.7   29      4.729   0.334   0.1115
               th
  5)       5          5      75     5.075   4.7   09      4.709   0.366   0.1339
               th
  6)       6          5      83     5.083   4.6   96      4.696   0.387   0.1497
                                                                             30
❖ Calculations :
      ● Eg = hc/λ
                             -34               8                      -10
            = [ 6.626 × 10         × ( 3 ×10 )] / 6416 × 10
                            -16
            = 19.878 × 10          / 6416
                              -19
            = 3.0981 × 10            J
                                      -19
      ● Eg (eV) = Eg / 1.6 × 10
                                     -19                 -19
                 = 3.0918 × 10              / 1.6 × 10
                                                                            -19
                 = 1.936 eV …...….. where, 1.6 × 10                               eV(charge of electron )
      ● Eg = hc/λ
                             -34               8                      -10
            = [ 6.626 × 10         × ( 3 ×10 )] / 5317 × 10
                            -16
            = 19.878 × 10          / 5317
                              -19
            = 3.7272 × 10            J
                                      -19
      ● Eg (eV) = Eg / 1.6 × 10
                                     -19                 -19
                 = 3.7272 × 10              / 1.6 × 10
                                                                            -19
                 = 2.329 eV …...….. where, 1.6 × 10                               eV(charge of electrons )
                                                                                                             31
3. for, Yellow LED :
                     2   2
      ●   λred = [D n − D m /4R(n − m)]
              = [ 0.1361 - 0.0681 / 4×100×(5-2)]
              = 0.068 /1200
                              -5                                -10
              = 5.666 × 10 cm ~ 5666 × 10                             m
              = 5666 A°
      ● Eg = hc/λ
                             -34                8                     -10
            = [ 6.626 × 10         × ( 3 ×10 )] / 5666 × 10
                             -16
            = 19.878 × 10          / 5666
                              -19
            = 3.5082 × 10              J
                                       -19
      ● Eg (eV) = Eg / 1.6 × 10
                                       -19                -19
                 = 3.5082 × 10               / 1.6 × 10
                                                                            -19
                 = 2.190 eV …...….. where, 1.6 × 10                               eV(charge of electron )
      ● Eg = hc/λ
                             -34                8                     -10
            = [ 6.626 × 10         × ( 3 ×10 )] / 4491 × 10
                             -16
            = 19.878 × 10          / 4491
                             -19
            = 4.426 × 10           J
                                       -19
      ● Eg (eV) = Eg / 1.6 × 10
                                    -19                 -19
                 = 4.426 × 10              / 1.6 × 10
                                                                            -19
                 = 2.766 eV …...….. where, 1.6 × 10                               eV(charge of electron )
                                                                                                            32
❖ Graphs :
                                                33
● for, Yellow LED :
                                                34
Calculations from Graph :-
  ● λ of Red LED :
                     λ = tan (ϕ) / 4R
                      = 0.0246 / 4 × 100
                                 -5              -15
                      = 6.15 ×10 cm ~ 6150 × 10
                      = 4491 A°
  ● λ of Green LED :
                     λ = tan (ϕ) / 4R
                      = 0.0202 / 4 × 100
                                 -5              -15
                      = 5.05 ×10 cm ~ 5050 × 10
                      = 5050 A°
  ● λ of Yellow LED :
                     λ = tan (ϕ) / 4R
                      = 0.0221 / 4 × 100
                                     -5            -15
                      = 5.525 ×10 cm ~ 5525 × 10
                      = 5525 A°
  ● λ of Blue LED :
                     λ = tan (ϕ) / 4R
                      = 0.0176 / 4 × 100
                                -5           -15
                      = 4.4 ×10 cm ~ 4400 × 10
                      = 4400 A°
                                                         35
❖ Result :
                                                                36
● Conclusion
                                                                              37
● References
2.   Young, Hugh D.; Freedman, Roger A. (2012). University Physics, 13th Ed. Addison
     Wesley. p. 1178. ISBN 978-0-321-69686-1.
38