Dmitri Mendeleev
Dmitri Mendeleev
Early life
Mendeleev was born in the village of Verkhnie
Aremzyani, near Tobolsk in Siberia, to Ivan Pavlovich
Mendeleev (1783–1847) and Maria Dmitrievna
Mendeleeva (née Kornilieva) (1793–1850).[3][4] Ivan
worked as a school principal and a teacher of fine arts,
Born Dmitri Ivanovich Mendeleev
politics and philosophy at the Tambov and Saratov
8 February 1834
gymnasiums.[5] Ivan's father, Pavel Maximovich
Verkhnie Aremzyani, Tobolsk,
Sokolov, was a Russian Orthodox priest from the Tver
Russian Empire
region.[6] As per the tradition of priests of that time,
Pavel's children were given new family names while Died 2 February 1907 (aged 72)
attending the theological seminary,[7] with Ivan getting Saint Petersburg, Russian Empire
the family name Mendeleev after the name of a local Alma mater Saint Petersburg Imperial
landlord.[8] University
Known for Predicting gallium, germanium
Maria Kornilieva came from a well-known family of
and scandium
Tobolsk merchants, founders of the first Siberian
printing house who traced their ancestry to Yakov Periodic table
Portraits of Maria Dmitrievna Mendeleeva and Ivan Pavlovich Mendeleev (c. early 19th century)
In 1849, his mother took Mendeleev across Russia from Siberia to Moscow with the aim of getting
Mendeleev enrolled at the Moscow University.[8] The university in Moscow did not accept him. The
mother and son continued to Saint Petersburg to the father's alma mater. The now poor Mendeleev family
relocated to Saint Petersburg, where he entered the Main Pedagogical Institute in 1850. After graduation,
he contracted tuberculosis, causing him to move to the Crimean Peninsula on the northern coast of the
Black Sea in 1855. While there, he became a science master of the 1st Simferopol Gymnasium. In 1857,
he returned to Saint Petersburg with fully restored health.
Between 1859 and 1861, he worked on the capillarity of liquids and the workings of the spectroscope in
Heidelberg. Later in 1861, he published a textbook named Organic Chemistry.[26] This won him the
Demidov Prize of the Petersburg Academy of Sciences.[26]
On 4 April 1862, he became engaged to Feozva Nikitichna Leshcheva, and they married on 27 April 1862
at Nikolaev Engineering Institute's church in Saint Petersburg (where he taught).[27]
Mendeleev became a professor at the Saint Petersburg Technological Institute and Saint Petersburg State
University in 1864,[26] and 1865, respectively. In 1865, he became a Doctor of Science for his
dissertation "On the Combinations of Water with Alcohol". He achieved tenure in 1867 at St. Petersburg
University and started to teach inorganic chemistry while succeeding Voskresenskii to this post;[26] by
1871, he had transformed Saint Petersburg into an internationally recognized center for chemistry
research.
Periodic table
In 1863, there were 56 known elements with a new element being
discovered at a rate of approximately one per year. Other scientists
had previously identified periodicity of elements. John Newlands
described a Law of Octaves, noting their periodicity according to
relative atomic weight in 1864, publishing it in 1865. His proposal
identified the potential for new elements such as germanium. The
concept was criticized, and his innovation was not recognized by Mendeleev's 1871 periodic table
the Society of Chemists until 1887. Another person to propose a
periodic table was Lothar Meyer, who published a paper in 1864
describing 28 elements classified by their valence, but with no
predictions of new elements.
I saw in a dream a table where all elements fell into place as required. Awakening, I
immediately wrote it down on a piece of paper, only in one place did a correction later seem
necessary.
— Mendeleev, as quoted by Inostrantzev[33][34]
Unaware of the earlier work on periodic tables going on in the 1860s, he made the following table:
Cl 35.5 K 39 Ca 40
Br 80 Rb 85 Sr 88
By adding additional elements following this pattern, Mendeleev developed his extended version of the
periodic table.[35][36] On 6 March 1869, he made a formal presentation to the Russian Chemical Society,
titled The Dependence between the Properties of the Atomic Weights of the Elements, which described
elements according to both atomic weight (now called relative atomic mass) and valence.[37][38] This
presentation stated that
1. The elements, if arranged according to their atomic weight, exhibit an apparent periodicity of
properties.
2. Elements which are similar regarding their chemical properties either have similar atomic
weights (e.g., Pt, Ir, Os) or have their atomic weights increasing regularly (e.g., K, Rb, Cs).
3. The arrangement of the elements in groups of elements in the order of their atomic weights
corresponds to their so-called valencies, as well as, to some extent, to their distinctive
chemical properties; as is apparent among other series in that of Li, Be, B, C, N, O, and F.
4. The elements which are the most widely diffused have small atomic weights.
5. The magnitude of the atomic weight determines the character of the element, just as the
magnitude of the molecule determines the character of a compound body.
6. We must expect the discovery of many yet unknown elements – for example, two elements,
analogous to aluminium and silicon, whose atomic weights would be between 65 and 75.
7. The atomic weight of an element may sometimes be amended by a knowledge of those of
its contiguous elements. Thus the atomic weight of tellurium must lie between 123 and 126,
and cannot be 128. (Tellurium's atomic weight is 127.6, and Mendeleev was incorrect in his
assumption that atomic weight must increase with position within a period.)
8. Certain characteristic properties of elements can be foretold from their atomic weights.
Mendeleev published his periodic table of all known elements and predicted several new elements to
complete the table in a Russian-language journal. Only a few months after, Meyer published a virtually
identical table in a German-language journal.[39][40] Mendeleev has the distinction of accurately
predicting the properties of what he called ekasilicon, ekaaluminium and ekaboron (germanium, gallium
and scandium, respectively).[41][42]
Mendeleev also proposed changes in the properties of some known elements. Prior to his work, uranium
was supposed to have valence 3 and atomic weight about 120. Mendeleev realized that these values did
not fit in his periodic table, and doubled both to valence 6 and atomic weight 240 (close to the modern
value of 238).[43]
For his predicted three elements, he used the prefixes of eka, dvi, and tri (Sanskrit one, two, three) in their
naming. Mendeleev questioned some of the currently accepted atomic weights (they could be measured
only with a relatively low accuracy at that time), pointing out that they did not correspond to those
suggested by his Periodic Law. He noted that tellurium has a higher atomic weight than iodine, but he
placed them in the right order, incorrectly predicting that the accepted atomic weights at the time were at
fault. He was puzzled about where to put the known lanthanides, and predicted the existence of another
row to the table which were the actinides which were some of the heaviest in atomic weight. Some people
dismissed Mendeleev for predicting that there would be more elements, but he was proven to be correct
when Ga (gallium) and Ge (germanium) were found in 1875 and 1886 respectively, fitting perfectly into
the two missing spaces.[44]
By using Sanskrit prefixes to name "missing" elements, Mendeleev may have recorded his debt to the
Sanskrit grammarians of ancient India, who had created theories of language based on their discovery of
the two-dimensional patterns of speech sounds (exemplified by the Śivasūtras in Pāṇini's Sanskrit
grammar). Mendeleev was a friend and colleague of the Sanskritist Otto von Böhtlingk, who was
preparing the second edition of his book on Pāṇini[45] at about this time, and Mendeleev wished to honor
Pāṇini with his nomenclature.[46][47][48]
The original draft made by Mendeleev would be found years later and published under the name
Tentative System of Elements.[49]
Dmitri Mendeleev is often referred to as the Father of the Periodic Table. He called his table or matrix,
"the Periodic System".[50]
Later life
In 1876, he became
obsessed with Anna
Ivanova Popova and began
courting her; in 1881 he
proposed to her and
threatened suicide if she
refused. His divorce from
Leshcheva was finalized
one month after he had
married Popova (on 2
April)[51] in early 1882.
Even after the divorce,
Mendeleev was technically
a bigamist; the Russian
Orthodox Church required
at least seven years before
lawful remarriage. His Dmitri Mendeleev's second wife,
divorce and the Anna
Dmitri Mendeleev in 1890 surrounding controversy
contributed to his failure to
be admitted to the Russian Academy of Sciences (despite his
international fame by that time). His daughter from his second marriage, Lyubov, became the wife of the
famous Russian poet Alexander Blok. His other children were son Vladimir (a sailor, he took part in the
notable Eastern journey of Nicholas II) and daughter Olga, from his first marriage to Feozva, and son
Ivan and twins from Anna.
Though Mendeleev was widely honored by scientific organizations all over Europe, including (in 1882)
the Davy Medal from the Royal Society of London (which later also awarded him the Copley Medal in
1905),[52] he resigned from Saint Petersburg University on 17 August 1890. He was elected a Foreign
Member of the Royal Society (ForMemRS) in 1892,[1] and in 1893 he was appointed director of the
Bureau of Weights and Measures, a post which he occupied until his death.[52]
Mendeleev also investigated the composition of petroleum, and helped to found the first oil refinery in
Russia. He recognized the importance of petroleum as a feedstock for petrochemicals. He is credited with
a remark that burning petroleum as a fuel "would be akin to firing up a kitchen stove with bank notes".[53]
In 1907, Mendeleev died at the age of 72 in Saint Petersburg from influenza, just 6 days short of his 73rd
birthday. His last words were to his physician: "Doctor, you have science, I have faith," which is possibly
a Jules Verne quote.[57]
Other achievements
Mendeleev made other important contributions to science. The Russian chemist and science historian Lev
Chugaev characterized him as
Mendeleev was one of the founders, in 1868, of the Russian Chemical Society. He worked on the theory
and practice of protectionist trade and on agriculture.
In an attempt at a chemical conception of the aether, he put
forward a hypothesis that there existed two inert chemical
elements of lesser atomic weight than hydrogen.[52] Of these two
proposed elements, he thought the lighter to be an all-penetrating,
all-pervasive gas, and the slightly heavier one to be a proposed
element, coronium.
Mendeleev is given credit for the introduction of the metric system to the
Russian Empire.[59]
Mendeleev studied the origins of petroleum origin; he concluded that Mendeleev Medal
hydrocarbons are abiogenic and form deep within the earth – see
Abiogenic petroleum origin. He wrote: "The capital fact to note is that
petroleum was born in the depths of the earth, and it is only there that we must seek its origin."[60]
In 1890 he resigned his professorship at St. Petersburg University following a dispute with officials at the
Ministry of Education over the treatment of university students.[64] In 1892 he was appointed director of
Russia's Central Bureau of Weights and Measures, and led the way to standardize fundamental prototypes
and measurement procedures. He set up an inspection system, and introduced the metric system to
Russia.[65][66]
He debated against the scientific claims of spiritualism, arguing that metaphysical idealism was no more
than ignorant superstition. He bemoaned the widespread acceptance of spiritualism in Russian culture,
and its negative effects on the study of science.[67]
Vodka myth
A very popular Russian story credits Mendeleev with setting the 40% standard strength of vodka. For
example, Russian Standard vodka advertises: "In 1894, Dmitri Mendeleev, the greatest scientist in all
Russia, received the decree to set the Imperial quality standard for Russian vodka and the 'Russian
Standard' was born"[68] Others cite "the highest quality of Russian vodka approved by the royal
government commission headed by Mendeleev in 1894".[69]
In fact, the 40% standard was already introduced by the Russian government in 1843, when Mendeleev
was nine years old.[69] It is true that Mendeleev in 1892 became head of the Archive of Weights and
Measures in Saint Petersburg, and evolved it into a government bureau the following year, but that
institution was charged with standardising Russian trade weights and measuring instruments, not setting
any production quality standards. Also, Mendeleev's 1865 doctoral dissertation was entitled "A Discourse
on the combination of alcohol and water", but it only discussed medical-strength alcohol concentrations
over 70%, and he never wrote anything about vodka.[69][70]
Commemoration
A number of places and objects are associated with the name and
achievements of the scientist.
Mendelevium, which is a synthetic chemical element with the symbol Md (formerly Mv) and the atomic
number 101, was named after Mendeleev. It is a metallic radioactive transuranic element in the actinide
series, usually synthesized by bombarding einsteinium with alpha particles.
The mineral mendeleevite-Ce, Cs6(Ce22Ca6)(Si70O175)(OH,F)14(H2O)21, was named in Mendeleev's
honor in 2010.[74] The related species mendeleevite-Nd,
[75]
Cs6[(Nd,REE)23Ca7](Si70O175)(OH,F)19(H2O)16, was described in 2015.
A large lunar impact crater Mendeleev, that is located on the far side of the Moon, also bears the name of
the scientist.
The Russian Academy of Sciences has occasionally awarded a Mendeleev Golden Medal since 1965.[76]
On 8 February 2016, Google celebrated Dmitri Mendeleev's 182nd Birthday with a doodle.[77]
Works
Менделеев Д. И. Периодический закон (DjVu) (http://runivers.ru/bookreader/book144952/
#page/3/mode/1up). Т. 1. // Собрание сочинений в 3 томах — М.: Издательство
Академии наук СССР — via Runivers
Менделеев Д. И. Растворы (DjVu) (http://runivers.ru/bookreader/book144957/#page/3/mod
e/1up). Т. 2. (DjVu)]. Т. 2. // Собрание сочинений в 3 томах — М.: Издательство
Академии наук СССР — via Runivers
Менделеев Д. И. Периодический закон. Дополнительные материалы (DjVu) (http://runiv
ers.ru/bookreader/book144965/#page/3/mode/1up). Т. 3. // Собрание сочинений в 3
томах — М.: Издательство Академии наук СССР — via Runivers
Менделеев Д. И. Ещё о расширении жидкостей (Ответ профессору Авенариусу) (http
s://nn.mi.ras.ru/?bi=125). — СПб.: Тип. В. Демакова, 1884. — 18 с.
Менделеев Д. И. Об опытах над упругостью газов (https://nn.mi.ras.ru/?bi=127).
Сообщение Д. И. Менделеева в Императорском Русском техническом обществе — 21
янв. 1881 г. — СПб., 1881. — 22 с.
Менделеев, Д. (1994) [1906]. Савинкин, А.Е. (ed.). К познанию России (https://www.rp-ne
t.ru/pdf/rvs/vypusk-7.pdf) (PDF). Российский военный сборник (in Russian). Vol. 7.
Москва: ГА ВС. pp. 174–231.
Менделеев Д. И. Дополнения к познанию России (https://nn.mi.ras.ru/?bi=146).
Посмертное издание. СПб.: А. С. Суворин, 1907. — 109 с. + I л. портрет.
Менделеев Д. И. Изоморфизм в связи с другими отношениями кристаллической
формы к составу (https://nn.mi.ras.ru/?bi=446). Диссертация, представленная при
окончании курса в Главном педагогическом институте студентом Д. Менделеевым. —
СПб., 1856. — 234 с.
Менделеев Д. И. О сопротивлении жидкостей и о воздухоплавании (http://e-heritage.ru/r
as/view/publication/general.html?id=42069948): Вып. 1. — СПб.: Тип. В. Демакова,
1880. — 80 с.: табл.
Менделеев Д. И. Заветные мысли (1905)
Менделеев Д. И. Попытка химического понимания мирового эфира (1902)
54 articles for the Brockhaus and Efron Encyclopedic Dictionary
See also
List of Russian chemists
Mendeleev's predicted elements
Periodic systems of small molecules
Notes
a. Before the 1917 reform of Russian orthography, his name was written Дмитрій Ивановичъ
Менделѣевъ
b. Russian: Дмитрий Иванович Менделеев, romanized: Dmitriy Ivanovich Mendeleyev; IPA:
[ˈdmʲitrʲɪj ɪˈvanəvʲɪtɕ mʲɪnʲdʲɪˈlʲejɪf] ⓘ
c. When the Princeton historian of science Michael Gordin reviewed this article as part of an
analysis of the accuracy of Wikipedia for the 14 December 2005 issue of Nature, he cited as
one of Wikipedia's errors that "They say Mendeleev is the 14th child. He is the 14th
surviving child of 17 total. 14 is right out." However in a January 2006 article in The New
York Times, it was noted that in Gordin's own 2004 biography of Mendeleev, he also had the
Russian chemist listed as the 17th child, and quoted Gordin's response to this as being:
"That's curious. I believe that is a typographical error in my book. Mendeleyev was the final
child, that is certain, and the number the reliable sources have is 13." Gordin's book
specifically says that Mendeleev's mother bore her husband "seventeen children, of whom
eight survived to young adulthood", with Mendeleev being the youngest.[24][25]
References
Citations
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0465027750. "Mendeleev seemed to have very few theological commitments. This was not
for lack of exposure. His upbringing was actually heavily religious, and his mother – by far
the dominating force in his youth – was exceptionally devout. One of his sisters even joined
a fanatical religious sect for a time. Despite, or perhaps because of, this background,
Mendeleev withheld comment on religious affairs for most of his life, reserving his few words
for anti-clerical witticisms ... Mendeleev's son Ivan later vehemently denied claims that his
father was devoutly Orthodox: "I have also heard the view of my father's 'church religiosity' –
and I must reject this categorically. From his earliest years Father practically split from the
church – and if he tolerated certain simple everyday rites, then only as an innocent national
tradition, similar to Easter cakes, which he didn't consider worth fighting against." ...
Mendeleev's opposition to traditional Orthodoxy was not due to either atheism or scientific
materialism. Rather, he held to a form of romanticized deism."
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Experts" (https://www.nytimes.com/2006/01/03/science/03comm.html). The New York
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26. Heilbron 2003, p. 509.
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Works cited
Gordin, Michael (2004). A Well-Ordered Thing: Dmitrii Mendeleev and the Shadow of the
Periodic Table (https://archive.org/details/wellorderedthing00gord). New York: Basic Books.
ISBN 978-0465027750.
Heilbron, John L. (2003). The Oxford Companion to the History of Modern Science. Oxford
University Press. ISBN 978-0-19-974376-6.
Further reading
Mendeleev, Dmitry Ivanovich; Jensen, William B. (2005). Mendeleev on the Periodic Law:
Selected Writings, 1869–1905. Mineola, New York: Dover Publications. ISBN 978-
0486445717.
Strathern, Paul (2001). Mendeleyev's Dream: The Quest For the Elements. New York: St
Martins Press. ISBN 978-0241140659.
Mendeleev, Dmitrii Ivanovich (1901). Principles of Chemistry (https://archive.org/details/princ
iplesofchem00menduoft). New York: Collier.
External links
Works by Dmitri Mendeleev (https://www.gutenberg.org/ebooks/author/46359) at Project
Gutenberg
Babaev, Eugene V. (February 2009). Dmitriy Mendeleev: A Short CV, and A Story of Life (htt
p://www.mendcomm.org/Mendeleev.aspx) Archived (https://web.archive.org/web/201708250
73835/http://www.mendcomm.org/Mendeleev.aspx) 25 August 2017 at the Wayback
Machine – 2009 biography on the occasion of Mendeleev's 175th anniversary
Babaev, Eugene V., Moscow State University. Dmitriy Mendeleev Online (http://www.chem.
msu.su/eng/misc/mendeleev/welcome.html)
Original Periodic Table (http://web.lemoyne.edu/~giunta/EA/MENDELEEVann.HTML),
annotated.
"Everything in its Place" (https://www.nytimes.com/library/magazine/millennium/m1/sacks.ht
ml), essay by Oliver Sacks
Dmitri Mendeleev's official site (http://www.dmitrimendeleev.com/)