Safety Data Sheet

Page 1 of 9
LOCTITE® 495™ ADHESIVO INSTANTANEO SUPER
SDS No. : 427632
BONDER® V001.8
Revision: 15.03.2016
printing date: 16.04.2017

Section 1. Identification of the substance/preparation and of the company/undertaking

Product name: LOCTITE® 495™ ADHESIVO INSTANTANEO SUPER BONDER®

Other means of identification: LOCTITE 495 ADH INST 90G ES

Product code: IDH270913
Recommended use of the chemical and restrictions on use

Intended use: Adhesive

Identification of manufacturer, importer or distributor

Importer: Henkel Malaysia Sdn Bhd 46th Floor, Menara TM, Jalan Pantai Baharu, 59200 Kuala Lumpur, Malaysia. Phone
:+ 603 22461000 Fax : + 60322461188

E-mail address of person ap-ua-psra.sea@henkel.com

responsible for Safety Data
Sheet:

Emergency information: FOR EMERGENCIES ONLY (Spill, major leak, Fire, Exposure, or Accident). Call
CHEMTREC: +1 703-741-5970

Section 2. Hazards identification

GHS Classification:

Hazard Class Hazard Category Target organ

Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2
Specific target organ toxicity - Category 3 respiratory tract irritation
single exposure

GHS label elements:

Hazard pictogram:

Signal word: Warning

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V001.8 LOCTITE® 495™ ADHESIVO INSTANTANEO
SUPER BONDER®

Hazard statement: H315 Causes skin irritation.

H319 Causes serious eye irritation.
H335 May cause respiratory irritation.

Precaution:

Prevention: P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash hands thoroughly after handling.
P280 Wear eye protection/face protection.
P280 Wear protective gloves.

Response: P302+P352 IF ON SKIN: Wash with plenty of water.

P304+P340+P311 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or doctor/ physician.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.

Storage: P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Disposal: P501 Dispose of contents/container to an appropriate treatment and disposal facility in

accordance with applicable laws and regulations, and product characteristics at time of
disposal.

Section 3. Composition / information on ingredients

Substance or Mixture:
Mixture

Declaration of hazardous chemical:

Hazard component CAS-No. Content GHS Classification

Ethyl 2-cyanoacrylate 60- 100 % Skin corrosion/irritation 2
7085-85-0 H315
Serious eye damage/eye irritation 2
H319
Specific target organ toxicity - single exposure 3
H335
Hydroquinone < 0.1 % Acute toxicity 4; Oral
123-31-9 H302
Serious eye damage/eye irritation 1
H318
Skin sensitizer 1
H317
Germ cell mutagenicity 2
H341
Carcinogenicity 2
H351
Acute hazards to the aquatic environment 1
H400
Chronic hazards to the aquatic environment 1
H410
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V001.8 LOCTITE® 495™ ADHESIVO INSTANTANEO
SUPER BONDER®

Section 4. First aid measures

Inhalation: Move to fresh air, consult doctor if complaint persists.

Skin contact: Do not pull bonded skin apart. It may be gently peeled apart using a blunt object such as a
spoon, preferably after soaking in warm soapy water.
Cyanoacrylates give off heat on solidification. In rare cases a large drop will generate
enough heat to cause a burn.
Burns should be treated normally after the adhesive has been removed from the skin.
If lips are accidentally stuck together apply warm water to the lips and encourage
maximum wetting and pressure from saliva inside the mouth.
Peel or roll lips apart. Do not try to pull the lips apart with direct opposing action.

Eye contact: If the eye is bonded closed, release eyelashes with warm water by covering with wet pad.
Cyanoacrylate will bond to eye protein and will cause periods of weeping which will help
to debond the adhesive.
Keep eye covered until debonding is complete, usually within 1-3 days.
Do not force eye open. Medical advice should be sought in case solid particles of
cyanoacrylate trapped behind the eyelid cause any abrasive damage.

Ingestion: Ensure that breathing passages are not obstructed. The product will polymerise
immediately in the mouth making it almost impossible to swallow. Saliva will slowly
separate the solidified product from the mouth (several hours).

Indication of immediate medical See section: Description of first aid measures

attention and special treatment
needed:

Section 5. Fire fighting measures

Suitable extinguishing media: Foam, extinguishing powder, carbon dioxide.
Fine water spray

Specific hazards arising from the In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides
chemical: (NOx) can be released.

Special protection equipment and Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA).
precautions for firefighters:

Section 6. Accidental release measures

Personal precautions: Ensure adequate ventilation.

Environmental precautions: Do not let product enter drains.

Clean-up methods: Do not use cloths for mopping up. Flood with water to complete polymerization and
scrape off the floor. Cured material can be disposed of as non-hazardous waste.

Section 7. Handling and storage

Handling: Ventilation (low level) is recommended when using large volumes
Use of dispensing equipment is recommended to minimise the risk of skin or eye contact

Storage: For optimum shelf life store in original containers under refrigerated conditions at 2 - 8°C
(35.6 - 46.4 °F)
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V001.8 LOCTITE® 495™ ADHESIVO INSTANTANEO
SUPER BONDER®

Section 8. Exposure controls / personal protection

Components with specific control parameters for workplace:

ETHYL CYANOACRYLATE Value type Time Weighted Average (TWA):

7085-85-0
ppm 0.2
Remarks ACGIH
ETHYL CYANOACRYLATE Value type Time Weighted Average (TWA):
7085-85-0
ppm 0.2
Remarks MY OEL
HYDROQUINONE Value type Time Weighted Average (TWA):
123-31-9
mg/m3 1
Remarks ACGIH
HYDROQUINONE Value type Time Weighted Average (TWA):
123-31-9
mg/m3 2
Remarks MY OEL

Respiratory protection: Ensure adequate ventilation.

An approved mask or respirator fitted with an organic vapour cartridge should be worn if
the product is used in a poorly ventilated area
Filter type: A (EN 14387)

Hand protection: Chemical-resistant protective gloves (EN 374).

Suitable materials for short-term contact or splashes (recommended: at least protection
index 2, corresponding to > 30 minutes permeation time as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
Suitable materials for longer, direct contact (recommended: protection index 6,
corresponding to > 480 minutes permeation time as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
This information is based on literature references and on information provided by glove
manufacturers, or is derived by analogy with similar substances. Please note that in
practice the working life of chemical-resistant protective gloves may be considerably
shorter than the permeation time determined in accordance with EN 374 as a result of the
many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the
gloves should be replaced.

Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk
of splashing.
Protective eye equipment should conform to EN166.

Body protection: Wear suitable protective clothing.

Protective clothing should conform to EN 14605 for liquid splashes or to EN 13982 for
dusts.

Engineering controls: Ensure good ventilation/extraction.

Hygienic measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while
working. Good industrial hygiene practices should be observed.

Section 9. Physical and chemical properties

Appearance: colourless to yellowish
liquid
Odor: No data available.
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V001.8 LOCTITE® 495™ ADHESIVO INSTANTANEO
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Odor threshold (CA): No data available.

pH: No data available.
Melting point / freezing point: No data available.
Specific gravity: No data available.
Boiling point: > 149 °C (> 300.2 °F)
Flash point: 80 - 93 °C (176 - 199.4 °F)
Evaporation rate: No data available.
Flammability (solid, gas): No data available.
Lower explosive limit: No data available.
Upper explosive limit: No data available.
Vapor pressure: < 700 mbar
(no method; 50 °C (122 °F))
Vapor density: No data available.
Density: No data available.
Solubility: No data available.
Partition coefficient: n- No data available.
octanol/water:
Auto ignition: No data available.
Decomposition temperature: No data available.
Viscosity: No data available.

VOC content: <3%

(2010/75/EC)

Section 10. Stability and reactivity

Reactivity/Incompatible Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and
materials: alcohols.
Chemical stability: Stable under recommended storage conditions.
Conditions to avoid: Stable under normal conditions of storage and use.
Hazardous decomposition None if used for intended purpose.
products:

Section 11. Toxicological information

Symptoms of Overexposure: EYE: Irritation, conjunctivitis.

SKIN: Redness, inflammation.
RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness.

Acute oral toxicity:

Ethyl 2-cyanoacrylate Value type LD50

7085-85-0 Value > 5,000 mg/kg
Species rat
Method OECD Guideline 401 (Acute Oral Toxicity)
Hydroquinone Value type LD50
123-31-9 Value 367 mg/kg
Species rat
Method OECD Guideline 401 (Acute Oral Toxicity)
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SUPER BONDER®

Acute dermal toxicity:

Ethyl 2-cyanoacrylate Value type LD50

7085-85-0 Value > 2,000 mg/kg
Species rabbit
Method OECD Guideline 402 (Acute Dermal Toxicity)

Skin corrosion/irritation:

Ethyl 2-cyanoacrylate Result slightly irritating

7085-85-0 Exposure time 24 h
Species rabbit
Method OECD Guideline 404 (Acute Dermal Irritation / Corrosion)

Serious eye damage/irritation:

Ethyl 2-cyanoacrylate Result irritating

7085-85-0 Exposure time 72 h
Species rabbit
Method OECD Guideline 405 (Acute Eye Irritation / Corrosion)

Respiratory or skin sensitization:

Ethyl 2-cyanoacrylate Result not sensitising

7085-85-0 Test type
Species guinea pig
Method
Hydroquinone Result sensitising
123-31-9 Test type Guinea pig maximisation test
Species guinea pig
Method

Germ cell mutagenicity:

Ethyl 2-cyanoacrylate Result negative

7085-85-0 Type of study / Route of administration bacterial reverse mutation assay (e.g Ames test)
Metabolic activation / Exposure time
Method OECD Guideline 471 (Bacterial Reverse Mutation Assay)
Ethyl 2-cyanoacrylate Result negative
7085-85-0 Type of study / Route of administration mammalian cell gene mutation assay
Metabolic activation / Exposure time with and without
Method OECD Guideline 476 (In vitro Mammalian Cell Gene
Mutation Test)
Ethyl 2-cyanoacrylate Result negative
7085-85-0 Type of study / Route of administration in vitro mammalian chromosome aberration test
Metabolic activation / Exposure time with and without
Method OECD Guideline 473 (In vitro Mammalian Chromosome
Aberration Test)
Hydroquinone Result negative
123-31-9 Type of study / Route of administration bacterial reverse mutation assay (e.g Ames test)
Metabolic activation / Exposure time with and without
Method EU Method B.13/14 (Mutagenicity)

Repeated dose toxicity:

Hydroquinone Result NOAEL=>= 250 mg/kg

123-31-9 Route of application oral: gavage
Exposure time / Frequency of treatment 14 days5 days/week. 12 doses
Species rat
Method OECD Guideline 407 (Repeated Dose 28-Day Oral
Toxicity in Rodents)
Hydroquinone Result LOAEL=<= 500 mg/kg
123-31-9 Route of application oral: gavage
Exposure time / Frequency of treatment 14 days5 days/week. 12 doses
Species rat
Method OECD Guideline 407 (Repeated Dose 28-Day Oral
Toxicity in Rodents)
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V001.8 LOCTITE® 495™ ADHESIVO INSTANTANEO
SUPER BONDER®

Section 12. Ecological information

General ecological information: Biological and Chemical Oxygen Demands (BOD and COD) are insignificant.

Ecotoxicity: Do not empty into drains / surface water / ground water.

Toxicity:

Hydroquinone Value type LC50

123-31-9 Value 0.638 mg/l
Acute Toxicity Study Fish
Exposure time 96 h
Species Oncorhynchus mykiss
Method OECD Guideline 203 (Fish, Acute Toxicity Test)
Hydroquinone Value type EC50
123-31-9 Value 0.134 mg/l
Acute Toxicity Study Daphnia
Exposure time 48 h
Species Daphnia magna
Method OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test)
Hydroquinone Value type EC50
123-31-9 Value 0.335 mg/l
Acute Toxicity Study Algae
Exposure time 72 h
Species Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata)
Method OECD Guideline 201 (Alga, Growth Inhibition Test)
Hydroquinone Value type EC 50
123-31-9 Value 0.038 mg/l
Acute Toxicity Study Bacteria
Exposure time 30 min
Species
Method

Persistence and degradability:

Ethyl 2-cyanoacrylate Result

7085-85-0 Route of application aerobic
Degradability 57 %
Method OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test)
Hydroquinone Result readily biodegradable
123-31-9 Route of application aerobic
Degradability 75 - 81 %
Method EU Method C.4-E (Determination of the "Ready" BiodegradabilityClosed
Bottle Test)

Bioaccumulative potential / Mobility in soil:

Ethyl 2-cyanoacrylate LogKow 0.776

7085-85-0 Temperature 22 °C
Method EU Method A.8 (Partition Coefficient)
Hydroquinone LogKow 0.59
123-31-9 Temperature
Method EU Method A.8 (Partition Coefficient)

Section 13. Disposal considerations

Product

Method of disposal: Cured adhesive: Dispose of as water insoluble non-toxic solid chemical in authorised
landfill or incinerate under controlled conditions.
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Dispose of in accordance with local and national regulations.

Contribution of this product to waste is very insignificant in comparison to article in
which it is used

Packaging

Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as
chemically contaminated waste in an authorised legal land fill site or incinerated.
Disposal must be made according to official regulations.

Section 14. Transport information

Road transport ADR:

Not dangerous goods

Railroad transport RID:

Not dangerous goods

Inland water transport ADN:

Not dangerous goods

Marine transport IMDG:

Not dangerous goods

Air transport IATA:

Class: 9
Packing group: III
Packaging instructions (passenger): 964
Packaging instructions (cargo): 964
UN no.: 3334
Label: 9
Proper shipping name: Aviation regulated liquid, n.o.s. (Cyanoacrylate ester)
Additional Information: Primary packs containing less than 500ml are unregulated by this
mode of transport and may be shipped unrestricted.

Section 15. Regulatory information

Regulatory Information: Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous
Chemicals) Regulations 2013 [P.U.(A) 310/213]
Industry Code of Practice on Chemicals Classification and Hazard Communication

Global inventory status:

Regulatory list Notification

TSCA yes
NDSL yes
IECSC yes
ISHL (JP) yes
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V001.8 LOCTITE® 495™ ADHESIVO INSTANTANEO
SUPER BONDER®

Section 16. Other information

Disclaimer: This information is based on our current level of knowledge and relates to the product in
the state in which it is delivered. It is intended to describe our products from the point of
view of safety requirements and is not intended to guarantee any particular properties.