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Q1. A. State Heisenberg’s uncertainty principle. Drive
expression for wavelength through de Brouglie
equation.
B. Interpret the Blackbody Radiation Phenomena. Also
explain the photoelectric effect with the help of neat
diagram.
eye
A. Define a Semiconductor and classify its types.
Explain why extrinsic semiconductors are required?
B. Describe Doping. Name two types of extrinsic
semiconductors formed due to doping in Intrinsic
semiconductors.
Q3. A. Elaborate the Energy band theory with a diagram
and how it is used to classify various elements.
B. Draw the energy band diagram of extrinsic and
intrinsic semiconductors.
C. Illustrate the energy bands of Gallium Arsenide and
silicon.
Q4. Explain e-k diagram. Give the significance of e-k
diagrams.
Q5. Define Fermi Level.
TREE EEEQ6. Interpret the significance of designing of resistors.
Q7. Interpret semiconductors being negative
Tan Ue Reelin mel Cirle Ya
Q8. Discuss 1. Drift Current, 2. Diffusion Current, 3.
Mobility, 4. Resistivity 5. sheet resistance.
Add these in above definition. [Contrast between
diffusion current and drift current?
State the relation between resistivity and mobility.
Classify the significance of sheet resistance]
Q9. Write down the expression for drift and diffusion
current.
In a P type silicon sample the hole concentration is
2.25x10"15/cm. what is electron concentration.
Q10. When atoms share electrons, what type of bonding
it is called?
Q11. What is the atomic structure of silicon?
Q12. How can you classify solids on the basis of
conductivity? Give examples also.
Q13. How can you describe the concepts of quantum
mechanics that are imp for the study of
semiconductors?|| Heisenberg Uncertainty Priavelpole, —
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then _P2 mV =|Black body Rodation 2
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Khe vediation® (ght) tha Hrikes fk To sloy
In thermal equilibyium , Ih mut eit redia-
tm ab Dame vale os It obsorbt, th Ty a
black body aio yodlates tu)
fouy elicd taith a tempevatuve obove fhe
absolte zevo , Cmits Light af alt
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fem st da talled black b radiotion.
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ment 4 boller; ony abfed that give of
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and & thes more efheuive In producing °
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Photoelectric effet tas discovered by Halluiachs
ors Aucessfutly explained thvovelically fy Etarteln-What Are Semiconductor:
A semiconductor material is defined by its ability to conduct
electricity and its conductivity properties lie between conductor Eile}
insulator.
Under specific conditions, Semiconductors have the ability to act
either as a pure conductor or a pure insulator.
Moreover, semiconductors(after creating a PN junction) can also
control the direction of the flow of electrical charges, which is not the
case with conductors(as they allow current to flow in both
directions).What is a Semiconductor?
@P> A semiconductor is a materi
@> Semiconductor Examples are:
whose conductivity properties lie between the conductor and insulator.
icon, Germanium, Gallium Arsenide etc.
tts asa eS
Semiconductor
| a a
Extrinsic
a
Uiveheit
co
stands for negative (free electrons)
@> “p" stands for positive (holes)Instrinsic semiconductor Extrinste semiconductor
(1) | It is a tetravalent pure erystal. (1) | It is the tetravalent crystals with impurity of th
third and fourth group of periodic table.
(2) | Its electrical conductivity Is low, (2)| Its electrical conductivity is high.
(3) | Its electrical conductivity depends on (3) | Its electrical conductivity depends on the
temperature, temperature plus the amount af doping
impurity.
(4) | Ata given temperature the number of (4) | The -type semiconductor have a majority charg
free electrons and the number of holes cartier elecirons and p-type semiconductor hav
fare equal. @ majority charge carrier holes.
2, = my, 2. In n-type n, > n, and in p-type n, < My,Energy band theory in solids
Ina single isolated atom, the electrons in each orbit have definite energy associated with it. But in case of
all the atoms are close to each other, so the energy levels of outermost orbit electrons are affected by the
neighboring atoms.
The electrons in same orbit exhibits different energy levels. The grouping of this different energy levels is called
energy band.
The energy levels of inner orbit electrons are not much affected by the presence of neighboring atoms.
Important energy bands in solids
Band energy
The conduction band electrons
are not bound to the nucleus of
ator. The energy associated with
forbidden band is called energy
Forbidden gp gap and it is measured in unit
electron volt (eV).
electrons present in the valence bane
are loosely bound to the nucleus of
atom
Classification of materials based on forbidden gap
+Insulators
The materials which does not allow the flow of electric current through them are called as insulators. Insulators
are also called as poor conductors of electricity.
Empty conduction band
Band energy a
Forbidden gap Around ISev
Electron
Full valence
Rubber, wood, diamond, plastic are some examples of insulators.Conductors
The materials which easily allow the flow of electric current through them are called as conductors. Metals such as
copper, silver, iron, aluminum etc. are good conductors of electricity.
Band energy oe
Almost full conduction band
No forbidden gap {|
Electron
“Semiconductors
The material which has electrical conductivity between that of a conductor and an insulator is called as
semiconductor. Silicon, germanium and graphite are some examples of semiconductors.
Band
and ener8Y almost empty conduction band
Forbidden gap
‘Almost full valence
band
Electron
The resistance of semiconductor decreases with increase in temperature.Direct and Indirect Band Gap Semiconductors
The band gap represents the minimum energy difference between the top of the valence band and the bottom
of the conduction band, However, the top of the valence band and the bottom of the conduction band are not
generally at the same value of the electron momentum.
Ina direct band gap semiconductor, the top of the valence band and the bottom of the conduction band occur
at the same value of momentum.
essen Pang
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ses A
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‘a photon can provide the energy to produce an electron-hole pair.
Each photon of energy £ has momentum p = E /¢, where cis the velocity of light.
Momentum will be very small for a photon
‘A photon of energy £, where E, is the band gap energy, can produce an electron-hole pair in a direct band
gap semiconductor quite easily, because the electron does not need to be given very much momentum.
Inan indirect band gap semiconductor, the maximum energy of the valence band occurs at a different value
of momentum to the minimum in the conduction band energy:
band gap
Energy
an electron must also undergo a significant change in its momentum for a photon of energy E, to produce an
electron-hole pair in an indirect band gap semiconductor. This is possible, but it requires such an electron to
interact not only with the photon to gain energy, but also with a lattice vibration called a phonon in order te
either gain or lose momentum.
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dbtetnel by valuing Schyoedingey's equation 4
=p liana of Ek _dlagvara. += Be:
© Ek dingyan indtentes band gap (Cg), nthich a
the dipper nce bn eneray between the top of
Valence boned and _bettom off _cewtudfien bands.
@® The _die-grom dimonstretter_ Electron (Kole) mobile
© the diagram esplains. ekectron (hole) efpective mans:.
@ the didgiam 2
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the
_ Akectey are _epvebly, et yk aoa she= Fermi Level and Fermi Energy “il
Enrico Fermi, the physicist who first proposed Fermi level. It is imporlant in determining the
electrical and thermal propertics of solids.
‘The term “Fermi level" comes from Fermi-Dirac statistics. which describes a distribution of particles
over energy states in systems consisting of fermions (electrons) that obey the Pauli exclusion principle.
temperature. Fermi level is also defined as the work done to add an electron to the system.
in the band gap, approximately in the middle of
In semiconductors the position of the Fermi level is
the band gap.
és Fermi level is the highest chergy state occupied by electrons in a material at absolute zero
‘The value of the Fermi level at absolute zero temperature (-273.15 °C) is known as the Fermi energy.
Itis also the maximum kinetic encegy an electron can attain at T=OK, Fermi energy is constant for each
solid, The Fermti energy is-a concept in quantum mechanics usually referring to the enorgy difference
between the highest and lowest occupied single-particle statcs in a quantum systcm of nonsinteracting
fermions at absolute zero temperature.Resistor colour code
*Carbon Composition Resistor ~ Made of carbon
dust or graphite paste, low wattage values
‘Film or Cermet Resistor - Made from conductive
metal oxide paste, very low wattage values
-Wire-wound Resistor ~ Metallic bodies for heatsin
mounting, very high wattage ratings
“Semiconductor Resistor ~ High frequency/precisic
|
surface mount thin film technology |What Is The Difference Between Positive And Negative
Temperature Coefficients Of Resistance?
+ Temperature coefficients of resistance (TCR) can be positive or
negative, influencing how materials react to temperature changes
+ Positive TCR materials, like metals, increase electrical resistance with
tising temperature due to increased atomic vibrations leading to more
electron collisions
+ Negative TCR materials, often semiconductors, show decreased
electrical resistance as temperature i increases, thanks to more charge
carriers and enhanced carrier mobility
+ The differences between positive and negative TCRs impact material
selection, temperature compensation, and temperature sensing in
‘electrical engineering applications
Resistance Change (Q)
aR(+)
are)
J _—————
Positive Slope
Tempers —p Temperature —p
i Memperature
Negative change (C)
Slope
NTC Tharristr PIC Thrristr
m.com |Diffusion current
“The process by which, charge carers (electrons or hoes) in a semiconductor moves from a region of higher
concentration toa region of lower concentration is called ciffusion.
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‘Concentration gradient
The diffusion curent density is rectly propertional to the concentration gradient. Concentration gracfent isthe
difference in concentration of electrons holes ina given area.
‘The concentration gradient for n-type semiconductor is given by
an
hee Where = aftson cient dnsty due to
i tlecrons
‘The concentration gradient for p-ype semizonductr is even by
«i
Ie ax 4 = fusion current deity due to holes
an
Jam 40D. Where 0, ithe citfuson coetcent of electrons
ap
Ip= ~ Doge
Drift curent
The flow of charge carro, which is due to the applied voltage or electric fed is elle ditt current.
The average velocity that an electron or hole achieved —
{due tothe applied voltage or elect ff called crift
velocity &
ft volocity of electrons
VE HE itt volocity of holes
rmobiity of electrons
¥
mobiity of holes
pplied lect fil
Te diftcament deny dus to ee lcs gen by |
Se “
and the dit erent dry du oss en by
“haem
total eft extent density
‘The total current density due to elactzons isthe sum of drift and difusion
currents.
4J,= Drift current + Diffusion current
= Dsift current + Diffusion current
‘The total curent density due to electrons and holes is given by
sclera,MODE
The mobility of the electron is the drift velocity of the electron in presence of a unit amount of electric
field.
Mobility of holes is the ability of movement of holes in the semiconductor in presence of an external
electric field.
Why is the mobility of free electron greater than the mobility of hole?
Resistivity is the opposite of conductivity, it’s a measure of how effectively a
material slows down the flow of electricity.
Insulators have a high resistivity rating. Materials such as metals and other
conductors have a low resistivity rating.
Poor conductiviy Good conductivily
Good resiativity Poot reslativty
Electricians use special
tools with insulated
oper haired handles made of
materials with a high
resistivity rating-
Poor conductivity Good onducthity like rubber.
Geodeesaivty Poorest
Electrical Resistivity
Electrical resistivity is the reciprocal of electrical conductivity. It is the measure of the ability of a material to
‘oppose the flow of current.
‘Metals are good conductors of electricity. Hence, they have low resistivity.
The insulators like rubber, glass, graphite, plastics, etc. have very high resistivity when compared to the metallic
conductors.
“The third type is the semiconductor which comes in between the conductors and insulators. Their resistivity
decreases with the increase in temperature andis also affected by the presence of impurities in them,> Increase the Length, flow of electrons
impeded
> Increase the cross-sectional Area, flow
enhanced
Sheet Resistance Rg
-—
R, is the resistance when W=L (unit of Rs in ohms/square)
R,=2
t
Sheet resistance (also known as surface resistance or surface resistivity) isa common electrical property used to
characterise thin flms of conducting and semiconducting materials. It is a measure of the lateral resistance
through a thin square of material, ie. the resistance between opposite sides of a square. The key advantage of
sheet resistance over other resistance measurements is that it is independent of the size of the square -
enabling an easy comparison between different samples. Another advantage is that it can be measured directly
using a four-point probe.Atomic StructureElectrical Properties of solids
Introduction to Electrical Properties
Apart from general physical characteristics like density and rigidity,
solids depict another important property called Conductivity.
Conductivity is defined as the measure of a solid to ease the flow of
electrons and conduct electricity. The values of conductivity are
diverged and vary from 107° to 10’. The unit of conductivity is ohm! m°
‘ypes of Solids
BAEC Rar iu aunty eck teursi hc)
flow through them.
Diets Matt suka gcse Cee
* have low conductivities Le. they do not practically allow the
électric circuit to flow through them
* The electrical conductivity isin order 107° — 107 ohm* m*
Brean neutered
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On the basis of conductivity solids are classified into three types,
namely:
+ Conductors
+ Insulators
+ Semiconductors= ——= - expeeloll vole In
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