GT 7
GT 7
F F F 3F
A) B) C) D)
4m 6m 2m 17m
2. The distance between two parallel plates of a capacitor is a. A conductor of thickness b
(b < a) is inserted between the plates as shown in the figure. The variation of effective
capacitance between the plates of the capacitors as a function of the distance (x) is best
represented by
A)
B)
D)
C)
05-01-24_JEE-MAIN_Q’P
3. One mole of an ideal monoatomic gas is taken through a cyclic process ABCA as shown
in the P-V diagram. The efficiency (in percentage) of the cyclic process is
A) 8.33 B) 12.33 C)16.33 D) 20.33
4. Two infinitely long conductors carrying equal currents are shaped as shown . The short
sections are all of equal lengths. The point P is located symmetrically with respect to the
two conductors. The magnetic field at point P due to any one conductor is B. The total
magnetic field at point P is
A) zero B) B C) 2B D) 2B
5. At the initial moment three point A,B and C are on a horizontal plane along a straight
line such that AB = BC . Point A begins to move upward with a constant velocity ‘v’ and
point C downward without any initial velocity at a constant acceleration ‘a’. If the point
begin to move simultaneously, then the initial velocity and acceleration of point B for all
the three particles to be constantly on same straight line must be:
v a v a
A) upwards, downwards B) upwards, upwards
2 2 2 2
v a v a
C) downwards, downwards D) downwards, upwards
2 2 2 2
05-01-24_JEE-MAIN_Q’P
6. Assertion (A): The magnetic field at the center of the current carrying circular coil
shown in the fig. is zero.
Reason (R): The magnitudes of magnetic fields are equal and the directions of magnetic
fields due to both the semicircles are opposite.
A) Both A and R are true but R is the correct explanation of A
B) Both A and R are true but R is not the correct explanation of A
C) A is true but R is false
D) A is false but R is also false
7. A particle projected at an angle grazes the inclined surface BC at point P as shown.
Find the time required to reach P from O.
A) TA TB 500 C B) TA TB 500 C
C) TA TB 500 C D) TB TA 500 C
05-01-24_JEE-MAIN_Q’P
9. A large plane mirror with its bottom on the floor is tilted at an angle 30° to the vertical.
A boy whose eyes are at height √3 m above the floor is standing in front of the mirror.
At what maximum distance (in m) from mirror should the boy be to see his full image in
mirror?
A) 1m B) 2m C) 2.3m D) 1.5m
10. A heavy nucleus X having mass number 200 gets disintegrated into two small fragments
Y and Z of mass numbers 80 and 120 respectively. If binding energy per nucleon for the
parent atom X is 6.5 MeV and for daughter nuclei Y and Z are 7 MeV and 8 MeV
respectively. Energy released in the decay will be
11. Which of the following circuits will provide a full wave rectification of an AC input?
A) B)
C) D)
05-01-2_JEE-MAIN_Q’P
12. A vessel of volume of V0 is evacuated by means of a piston air pump. One piston stroke
captures the volume V 0.2V0 . If process is assumed to be isothermal then find the
1
minimum number of strokes after which pressure in the vessel becomes Pinitial .
1.728
A) 2 B) 3 C) 5 D) 7
13. A balloon of volume V, contains a gas whose density is and the density of the air at
the earth’s surface is 15 . If the envelope of the balloon be of weight w but of negligible
volume. Find the acceleration with which it will begin to ascend.
7Vg w 2Vg w
A) g B) g
Vg w Vg w
14Vg w 7Vg w
C) g D) g
Vg w Vg w
14. Assertion (A): A small body suspended by a light spring, perform SHM. When the entire
system is immersed in a non-viscous liquid, the period of oscillation does not change.
Reason (R): The angular frequency of oscillation of the particle does not change.
15. A satellite is revolving around the earth in an orbit such that it time period of revolution
as same as that of earth and it revolve in same sense as of earth. To make it escape from
gravitational field of earth, its velocity must be increased by
List-I List-II
Phase difference between current and ; current leads
A. 1. 2
voltage in a purely resistive AC circuit
voltage
Phase difference between current and ; current lags
C. 3. 2
voltage in a pure capacitive AC circuit
voltage
Choose the most appropriate answer from the options given below:
A) 6R 2 k 0 B) 5R 2 k 0 C) 7R 2 k 0 D) None of these
05-01-24_JEE-MAIN_Q’P
18. If a string of length fixed at both ends vibrates with a standing wave
2
y Asin x sin 2t in resonance. Then the minimum time (from t=0) after which
energy is maximum at mid-point of string will be –
1 1 1 1
A) sec B) sec C) sec D) sec
4 5 8 6
19. Figure shows the graph of stopping potential versus the frequency of a photosensitive
metal. The plank’s constant and work function of the metal are (V and 0 are two
different constant.)
(3V)e (2V)e
A) Wc (2V)e; h B) Wc (2V)e; h
0 0
(3V)e (2V)e
C) Wc (3V)e;h D) Wc (3V)e; h
0 0
20. There are two bulbs B1 (P, V), B2 (P,2V) their rated power and voltages are mentioned
W1
with them. Calculate the ratio of consumed power ?
W2
25 4 10 4
A) B) C) D)
4 25 4 10
05-01-24_JEE-MAIN_Q’P
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
21. A system of two planks and a sphere of radius R is in motion as shown in figure. Radius
of the sphere is R and there is no slipping anywhere. It is given that R 2a 0 where
is angular acceleration of sphere and acceleration of upper block is a 1 ka 0 where k is a
+ve constant then the value of k will be
22. In the system shown, the mass m 2 kg oscillates in a circular arc of amplitude 600 .
The minimum value of coefficient of friction between mass = 8 kg and surface of table
to avoid slipping is . Then find 10 .
23. Consider a circuit with an alternating source and contains inductor and capacitor. Given
reading of A 1 and A 2 as 3 ampere and 5 ampere respectively. Find the magnitude of
reading of A in ampere.
24. The electric field associated with e.m. waves in vacuum is given by
E ˆi40cos kz 6 108 t , where E, z and t are in volt/m, meter and seconds
29. A vertical capillary tube with inside radius 0.25 mm is submerged into water so that the
length of its part protruding over the water surface is equal to 25 mm. Surface tension of
water is 73 x 10-3 N/m and angle of contact is zero degree for glass and water,
acceleration due to gravity is 9.8 m/s². Then value of 10R approximately (in mm) is
(where R is radius of meniscus and h is height of water in capillary tube)
30. In the figure, if a parallel beam of white light is incident on the plane of the slits
kd
S1 & S2 then the distance of the central maxima on the screen from O is . Find the
8
value of k. Assume D d,d .
05-01-24_JEE-MAIN_Q’P
CHEMISTRY MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31. There are four elements 'p', 'q', 'r' and 's' having atomic numbers Z-1, Z, Z+1 and Z+2
respectively. If the element 'q' is an inert gas, select the correct answers from the
following statements.
(i) 'p' has most negative electron gain enthalpy in the respective period.
32. The following are some statements related to VA group hydrides. INCORRECT
statement is:
B) Xe does not have the lowest first ionization enthalpy in its group
C) The first ionization enthalpy of element with atomic number 37 is lower than that of
the element with atomic number 38.
D) The first ionization enthalpy of Ga is higher than that of the d-block element with
atomic number 30.
05-01-24_JEE-MAIN_Q’P
34. Which one of the following statements is incorrect?
D) Silver nitrate on heating decomposes to give two types of paramagnetic gases along
with a residue.
Reason (R): Complexes where the iron is in the (III) oxidation state are generally more
stable than those in (II) oxidation state.
B) Assertion is True, Reason is True; Reason is NOT a correct explanation for Assertion
C) Assertion is True, Reason is False
D) Assertion is False, Reason is True
37. Which of the following statements is CORRECT?
A) In the formation of dioxygen from oxygen atoms, 10 molecular orbitals will be
formed.
B) All the molecular orbitals in the dioxygen will be completely filled.
C) Total number of bonding molecular orbitals will not be same as total number of anti-
bonding orbitals in dioxygen.
D) Number of filled bonding orbitals will be same as number of filled anti bonding
orbitals.
05-01-24_JEE-MAIN_Q’P
38. Yellow coloured solution of metal ion [which belongs to group-III of basic radicals] +
SCN Blood red colour solution.
OHC COOH
A) 5-cyano-3-formylcyclohex-3-en-1-carboxylic acid
B) 3-cyano-5-formylcyclohex-4-ene-1-carboxylic acid
C) 5-cyano-3-oxocyclohex-3-ene-1-carboxylic acid
D) 5-carboxy-3-formylcyclohex-2-ene-1-carbonitrile
Br2 , NaHCO3
40 A , Major organic product
OH OH O
O O
Br
O O
A) Br B)Br C) D) Br
HBr
(Excess)
O
Br
O OH Br
A) B)
Br Br Br OH
C) D)
43. Analyse the following reaction sequence:
O
44. The nitrogen atom in each of the following tertiary amines may be removed as trimethyl
amine by repeated Hoffmann eliminations (exhaustive methylation followed by heating
with moist Ag2O). Which of the amines requires the greater number of such Hoffmann
sequences to accomplish complete removal of nitrogen.
A) B) C) D)
(ii) Ni–Cd cell (b) does not involve any ion in solution and is used in hearing aids.
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
51. Total number of geometrical isomers for the square planar complex [RhCl(CO)
(PPh3)(NH3)] is /are _______ .
52. The total number of compounds having pp bonding among the molecules given
below are ________ .
53. Find the number of resonating structures of the given carbanion where negative charge is
on 2 carbon.
N
–
CH2
54. From which position does NO2+ replace a hydrogen from the following compound
predominantly?
H
N
1 O
2
3 4
5 8
6 7
55.
+ + + +
N 2 Cl N2 Cl N2 Cl
N Cl
2
NO2 O 2N NO2
I. II. III. IV.
+
N +N Cl
2 Cl 2
V. VI.
CH3
CH3 CH3
Find the sum of molar masses (in g) of byproducts (if any) formed in above reactions
58. A light of wavelength 200nm falls upon a surface and two different wavelength photons
λ = 800nm and λ =400nm are emitted from the surface. 80% of the energy absorbed is
re-emitted in the form of photon. Number of photons emitted as λ = 800nm is 3 times
that of number of photons emitted as λ = 400nm. If the ratio of total absorbed photon to
total emitted photon is x. then find the numerical value of (12.8x)
59. When 1 mole of an ideal gas at 20 atm and 15 L volume expands such that the final
pressure becomes 10 atm and volume is 60 L. The entropy change of the process in
Find the value of B. [antilog (0.15) = 1.413] (Given : 1 A 10, log 2 0.3 )
05-01-24_JEE-MAIN_Q’P
MATHEMATICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
61. Let C be the set of all complex numbers and
z z
R z1 , z2 C C : 1 2 is real
z1 z2
Then, on C, R is a
62. Let A be a 3 3 real matrix such that A I 2 BBT , where BT is transpose of column
matrix B, whose sum of the squares of elements is unity. Given the statements
A) 0 B) 1 C) 2 D) 3
63. If is real and 2 2 x 2 2 x 1 for all real x, then belongs to the interval
A) 24 B) 4 C) 6 D) 1
05-01-24_JEE-MAIN_Q’P
65. Let S {1, 2,3,4,5,6,7} .A subset of A is selected from ‘S’ and now keeping back
elements in S, again a subset of S,B is selected. Let E1 event that
A B {1,2,3,4,5}, E2 event that A B {1,2}, if
E a 1 b
P 2 a, b N G.C.D of a, b 1 ,then equals___
E1 b 10 a
A) 2 B) 3 C) 4 D) 5
x2 y2
66. Let H n : 1 , n N . Let k be the smallest even value of n such that the
1 n 3 n
eccentricity of H k is a rational number. If l is the length of the latus rectum of H k , then
21l is equal to
67. Two adjacent sides of parallelogram ABCD are given by AB 2iˆ 10ˆj 11kˆ and
AD ˆi 2ˆj 2kˆ . The side AD is rotated by an acute angle in the plane of the
parallelogram so that AD becomes AD ' . If AD ' makes a right angle with the side AB,
then the cosine of the angle is given by
8 17 1 4 5
A) B) C) D)
9 9 9 9
2
a b ab
a, b N ,then the value of
2 52
A) 2 B) 5 C) 10 D) 20
tan x cot x
t dt
69. dt
1/ e t 1 t
2
1/ e
1 t 2
8 16 13 11
A) B) C) D)
3 3 3 3
71. The curve passing through the point 0, / 4 satisfying the differential equation
dy
x sin 2 y x 3 cos 2 y is
dx
1 2 3 2 1 2 3 2
A) tan y
2
x 1 e x / 2
2
B) tan y
2
x 1 e x / 2
2
1 2 3 2 1 2 3 2
C) tan y
2
x 1 e x
2
D) tan y
2
x 1 e x
2
72. Statement – 1: If a,b,c are non zero real numbers such that
G.P.
Statement – 2: A series is in A.P. as well as in G.P. if all the terms in the series are equal
and non zero.
73. If a1 , a2 , a3 and a4 are the coefficients of any four consecutive terms in the expansion of
a1 a2 a3
1 x , then are in
n
, ,
a1 a2 a2 a3 a3 a4
A) AP B) GP C) HP D) AGP
74. x1 , x2 ,...........x10 are ten observations such that x i 50 and x x i j 1100 1 i j 10 , then
A) 5 B) 10 C) 5 D) 10
05-01-24_JEE-MAIN_Q’P
75. Match the following
Column I Column II
If tan is the G.M. between sin and cos
A) P) 1
then 2 4 sin 2 3sin 4 sin 6 can be
A) A – S; B – P; C – R; D – P B) A – P; B – R; C – P; D – S
C) A – P; B – P; C – R; D – S D) A – R; B – D; C – P; D – S
76. Let
23 1 33 1 n3 1
Pn . ........... ; n 2,3, 4......
23 1 33 1 n3 1
Then lim
n
Pn is equal to
1 7 3 2
A) B) C) D)
2 11 4 3
A) f is differentiable at x = 0 if a2 0
78. Let A, B and C be finite sets such that A B C and each one of the sets AB, BC
and C A has 100 elements. The number of elements in A B C is
A x, y Z Z : x 2 2
y2 4
B x, y Z Z : x 2 y 2 4 and
C x, y Z Z : x 2 2
y 2 4
2
If the total number of relations from A B to A C is 2p , then the value of p is
A) 16 B) 49 C) 25 D) 9
80. Let A,B and C be three events such that the probability that exactly one of A and B
occurs is 1 k , the probability that exactly one of B and C occurs is 1 2k , the
probability that exactly one of C and A occurs is 1 k and the probability of all A, B
and C occur simultaneously is k 2 , where 0 k 1 . Then the probability that at least one
of A, B and C occur is
1 1
A) Greater than B) Exactly equal to
2 2
1 1 1 1
C) Greater than but less than D) Greater than but less than
8 4 4 2
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
81. P is a point satisfying arg z= / 4 , such that sum of its distances from two given points
k
0,1 and 0, 2 is minimum, then P must be 1 i . Then numerical value of k is _____
3
82. The number of ways can 14 identical toys distributed among three boys so that each one
n
gets atleast one toy and no two boys get equal number of toys is n, then is equal
10
to____
05-01-24_JEE-MAIN_Q’P
83. Let P be an interior point of a triangle ABC such that PA 2PB 3PC 0 . Then the ratio
84. The number of values of x at which the function f x x 1 x 2/3 has extremum values is
π π
If the complete solution set of the inequality cosec1 x 2 cosec 1 x cosec 1 x
2
85. is
6 3
(, a] [b, ) , then (a b) is equal to
86. A straight line L with negative slope passes through the point (8, 2) and cuts the positive
coordinate axes at points P and Q. Then the absolute minimum value of OP+OQ as L
varies (Where O is the origin) is
1 1 1 1
tan 1 2
tan 1 2
tan 1 2
tan 1 2
.... (if x>0) is
1 x x 3 3x x 7 5x x 13 7x x
100
tan 1 2 , then a b ____
1 ax bx
88. Let the curve C be the mirror image of the parabola y 2 4x with respect to the line
x y 4 0 . If A and B are the points of intersection of C with the line y 5 , then the
5 x8 7 x 6 1
89. If f x dx, x 0 f 0 0 and f 1 , then the value of K is ______
x 2
1 2x
7 2 K
90. Suppose x1 and x2 are the point of maximum and the point of minimum respectively of
the function f x 2 x 3 9ax 2 12a 2 x 1 respectively, a 0 then for the equality x12 x2
to be true the value of ‘a’ must be
Sec: MODEL-A,B&C Date: 05-01-24
Time: 3 HRS
JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 D 2 C 3 A 4 A 5 A
6 A 7 C 8 A 9 A 10 C
11 D 12 B 13 C 14 A 15 B
16 A 17 B 18 A 19 A 20 A
21 5 22 5 23 2 24 2 25 3
26 1 27 3 28 120 29 6 30 3
CHEMISTRY
31 D 32 D 33 D 34 C 35 B
36 A 37 A 38 D 39 A 40 D
41 B 42 B 43 C 44 A 45 D
46 C 47 C 48 D 49 B 50 A
51 3 52 5 53 4 54 3 55 4
56 3 57 4 58 5 59 27 60 5
MATHEMATICS
61 B 62 D 63 B 64 B 65 B
66 D 67 B 68 B 69 C 70 D
71 C 72 A 73 A 74 C 75 C
76 D 77 C 78 C 79 C 80 A
81 2 82 6 83 3 84 2 85 1
86 18 87 101 88 4 89 4 90 2
05-01-24_JEE-MAIN_KEY&SOL
SOLUTIONS
PHYSICS
1.
F 2T 2ma 1
3T 4ma 2
2a 1 3a 2
solving we get
3F
a2
17m
A 0 A0
cc x (a b x)
2. c 1 2
c1 c2 A0 A 0
x (a b x)
A0
c independent of x
(a b)
1 PV
3. Wcyclic V0P0 0 0
2 2
For theprocess AB,P KV PV 1 constant
Molar heat capacity of the gas in the process AB,
R 3R R
C Cv 2R
(1 x) 2 2
Q AB nCT n2R(4T0 T0 ) 6nRT0 6P0 V0
Q BC 0 and Q CA 0
Wcyclic P0 V0
The efficiency of the cyclic process, 100 100
Qsup plied 2 6P0 V0
25
8.33%
3
4. By the symmetry, B total 0
5. Let us observe the motion of A and B relative to C.
AA BB
2d d
05-01-24_JEE-MAIN_KEY&SOL
1 2
AA vt at
BB 2
2 2
Vt 1 2
BB' at
2 4
V
is initially speed of B w.r.t C as well as ground.
2
a
is acceleration of B w.r.t C
2
aB/ g aB/C aC/ g
a 1
a a
2 2
6. Conceptual
7. v cos u cos
u cos
v
cos
v sin u sin gt
u cos sin
u sin gt
cos
u cos sin u sin cos
gt
cos
u sin
t
g cos
8. m1s1T1 m 2s 2 T2
Since m1s1 m 2s 2
T1 T2
9.
3
tan 2
D
10. Q (80 7) (120 8) (200 6.5) MeV 220 MeV
11. By the property of full wave rectifier
n
V0
12. Pfinal Pinitial
V0 V
w
13. 15Vg Vg w V a
g
14Vg w
a g
w Vg
05-01-24_JEE-MAIN_KEY&SOL
14. Time period of a spring mass system will remain constant when fluid is non-viscous.
15. v c 2v 0 1.414 v 0 % increase in orbital
v0 v0
velocity 100 41.4%
v0
16.
A) phase difference between current and voltage in a purely resistive AC circuit is zero.
B) phase difference between current and voltage in a pure inductive AC circuit is ; current lags
2
voltage.
C) phase difference between current and voltage in a pure capacitive AC circuit is ; current leads
2
voltage.
X XL
D) phase difference between current and voltage in an LCR series circuit is tan 1 C .
R
1 1
17. R 2B1 B2 3R 2
2 2
d R dB1 3R 2 dB2
2
dt 2 dt 2 dt
R 2 3R 2
.2K 0 4K 0
2 2
emf 5R 2 K 0
18. At node, energy is maximum when all particle reach to there extreme position.
19. Vs tan . C
4V tan . 2 0 C
10V tan . 4 0 C
3V
6V 20 tan tan
0
Wc
4V 6V
e
Wc (2V)e
(3V)e
h
0
05-01-24_JEE-MAIN_KEY&SOL
20.
v2 V 2
w1 P
R v2
P
2
V 4V 2 .P 4P
w2 .4R
5R 25V 2 25
21.
a 0 a cm R........1
a1 a cm R....... 2
Solivng equation 1 & 2
a 1 a 0 2R 4a 0
a 1 5a 0
K 5.00
22. Tension of rope is maximum at lowest point
mv 2
Tmax mg ........(1)
By energy conservation,
1
mg mv2 v g
2 2
From (1),
m(g)
Tmax mg Tmax 2mg
For 8 kg block, Tmax f L
2mg (8g)
4g (8g)
0.5
23.
Phasor diagram
05-01-24_JEE-MAIN_KEY&SOL
I8 I C I L 5 3 2A
24. E E0 cos kz t i
6 108
k 2
Vwave 3 108
P02 V
25. I
2B
P02 340
102
2 1.6 105
320 160
P0
34 17
P0 3
p 2 hc hc h2
26.
2m 2m 2
h 6.60 1034 11
31
1011 m 1.2pm
2mc 2 9.1 10 3 10 91
8
27. Consider prism of mass 4 m by joining 4 prism given in question.Total MOI of this system will be
4m
2
2a ma 2
I 4I prism I prism
6 3
28. R Th. C, R Th is the Thevenin’s resistance at the capacitor terminals.
R Th 8 (20 (9 (70 30)) 20 k
0.12 s
2T cos
29. h 59.6mm
rg
Here h is greater than protruding part of tube hence water will rise to maximum length of tube such
hr
that radius of meniscus is given by R
l
30. White spot on screen would be central maxima
Where
d d 3d
x 0 y
2 8 8
05-01-24_JEE-MAIN_KEY&SOL
CHEMISTRY
31. As 'q' is noble gas, p, r and s having atomic number Z-1, Z+1 and Z+2 should belong to halogen,
alkali metal and alkaline earth metal respectively. As halogen has one electron less than stable noble
gas configuration it has greater tendency to accept an additional electron forming anion. Alkaline
earth metal having valence shell configuration ns2 exists in +2 oxidation state.
32. VA group hydrides: (a) reducing properties increases down the group.
(b) Basic nature decreases down the group.
(c) Thermal stability decreases down the group.
(d) Bond angles decreases down the group.
34. Mn2O7: multiple bonds
AgNO 3 Ag NO 2 O 2
5 6 7
V O Cr2 O Mn O 4
2
2
7
When I is oxidized by MnO4 in alkaline medium, I converts into IO3
37. Conceptual
38. Yellow coloured solution of metal ion belonging to basic radicals of group-III → Fe³ is metalion
Fe+3 + SCN– → [Fe(SCN)2]+ (Red solution) + other species
Fe+3 + C2O42– → [Fe(C2O4)3] (stable complex)
Fe3+ + F– → [FeF6]3- (stable complex)
F- and C2O42– are stronger ligand than SCN–.
Hg2+ forms stable complex with SCN–
39. Conceptual
41. X = 1-Bromo 1,2-dimethylcyclopentane, Y= 1,2 -dimethylcyclopentene,
Z = Heptane -2,6 –dione
43. Decarboxylation of betaketo acid after ester hydrolysis
44.
CH 3
N
3 2
N
N (CH 3 )2 CH 3
N
1 2
1.413 10 3
2 2
H
Ka
C 0.08
24.957 10 2.4957 105
6
05-01-24_JEE-MAIN_KEY&SOL
MATHS
61. Since 0, 0 R, R is not reflexive, we have
z1 z2
z1 , z2 R is real
z1 z2
z2 z1
is real z2 , z1 R
z1 z2
Therefore R is symmetric,
Since 0, z R and z , 0 R , but 0, 0 R there fore R is not transitive. Hence R is not an
equivalence relation.
63 Suppose that 2 2 x 2 2 x 1 0
For all real x,
2 2 0 and 2 4 2 2 0
2
2 1 0 and 5 2 8 4 0
2 1 and 2 5 2 0
2
2 1 and 2
5
These inequalities imply
2
2,
5
64. Note that every solution of f x x is also a
solution of f f x x
f x x x 2 4 x 3 0 x 3 or 1
Therefore, 3 and 1 are roots of f x x , also
f f x x x 2 3 x 3 3 x 2 3 x 3 3 x
2
x 4 6 x3 12 x 2 10 x 3 0
Since 3 and 1 are roots of f x x , then are roots of
f f x x also and therefore.
f f x x x 3 x 1 x 2 2 x 1 x 3 x 1
3
Then
tan x 2 1
F ' x sec x
1 tan x
2
cot x 1 cot x
2 cos ec 2 x
tan x 1 / cot x =0
Therefore F is a constant function. Now
1 1
t 1
F dt dt
4 1/ e 1 t 1/ e t 1 t
2 2
1
t2 1
1/ e t 1 t 2 dt log e t 1/e
1
= 0 0 log e e =1
Hence F x 1
70. The two curves intersect at 4, 4 which is a vertex of the given square. Therefore
4
Required area (Shaded portion ) = 2 x
1
4 2
x 2 1
dx 2 1 1 = 2 x 3/ 2 x3 1
4 4
1
4 3 1 12 2
Y
(1,4)
(4,4)
y2 4x
x2 4 y
(1,1)
(2,1)
O 1 2 4 X
4 1 28 56 112 56 12
8 1 64 8 1 = 1
3 12 3 12 12
44 11
12 3
71. The given equation is
dy
sec 2 y x 2 tan y x3
dx
Put tan y z , Therefore
dz
2 x z x3 (Linear in z)
dx
The integrating factor is
I.F = e
2 xdx 2
ex
Therefore
ze x x 3e x dx c
2 2
05-01-24_JEE-MAIN_KEY&SOL
1 2 x2
x 2 e x xdx c x e 2 x dx c
2
2
1 1
tet dt c where t x 2 et t 1 c
2 2
1 x2 2
e x 1 c
2
So
1
tan y x 2 1 ce x
2
2
The curve passes through 0, / 4 . This implies
1 3
1 c c
2 2
1 2 3 x2
Therefore tan y x 1 e
2 2
72. 3 a 2 b 2 c 2 1 2 a b c ab bc ca 0
a 1 b 1 c 1 a b b c c a 0
2 2 2 2 2 2
a=b=c=1
73. Let a1 , a2 , a3 , a 4 be the coefficients of rth, r 1 th , r 2 th and r 3 th terms, respectively.
Then
a1 n Cr 1 , a2 n Cr , a3 n Cr 1 , a4 n Cr 2
We know that
n
CK n K 1
n
CK 1 K
Therefore
a2 n r 1 a n 1
1 2
a1 r a1 r
a3 n r a n 1
1 3
a2 r 1 a2 r 1
a4 n r 1 a n 1
1 4
a3 r 1 a3 r 2
And hence
a1 a3 r r2 r 1 a2
2 2
a1 a2 a3 a4 n 1 n 1 n 1 a2 a3
74. x x
2 2
2 x1 x j 300;
x 2
1
30
1 i
10
2
x12 x1
; 30 25 5
10 10
75. (A) tan 2 sin cos sin cos 3
(1 sin 2 ) (1 3sin 2 ) 3sin 4 sin 6
cos 2 (1 sin 2 )3 cos 2 cos 6 cos 2 sin 2 1
(B) sin 400 sin(600 200 )
3 1
2sin 200 cos 200 cos 200 sin 200
2 2
05-01-24_JEE-MAIN_KEY&SOL
4cos 20 3 cot 20 1
0 0
2 2
(D) sin 2 sin 2 .... sin = 5
18 18 2
76. We have
k 3 1 k 1 k k 1 k 1
2
k 2 k 1
k 3 1 k 1 k 2 k 1 k 1 k 12 k 1 1
For k 2,3,.............n Therefore
2 1 3 1 4 1 n 2 n 1 7 13 21 n2 n 1
Pn , , ..... . . . .........
2 1 3 1 4 1 n n 1 3 7 13 n 1
2
n 1 1
1 2 3 n 2 n 1 7 13 21 n n 1
2
= . . ..... . . . .....
n n 1 3 7 13 n 1 n 1 1
2
3 4 5
2 n2 n 1 2 1
1
n n 1 3 3 n n 1
2 2
Therefore lim Pn 1 0
n 3 3
3
77. We have seen that x is not differentiable at x 0 , Whereas x is differentiable at x 0 . Also
2
x x 2 is differentiable for all real x. If a2 0 , then
f x a0 x a1 x a3
3 2
80.
81.
B 0, 2
A 0,1
yx
A ' 1, 0
PA PB will be minimum
Where A and A ' are mirror image
A ' , P, B are collinear equation of line A ' B : 2x+y=2 Solve A ' B with y =x
2 2
x , y
3 3
2
P 1 i
3
k 2
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82. Number of ways to distribute at least one toy to each 141 C31 13 C2 78
If toys are distributed in the following way then two will get equal number of toys
No.of ways
3!
1 1 12 3ways
2!
2 2 10 3 ways
338 3 ways
446 3 ways
554 3 ways
662 3 ways
Required number of ways = 78-18= 60
83.
88.
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5x 7
8 6
5 x 7 x 8
6
89. 14 1 1 dx 1 1 2 dx
x 5 7 2 2 5 7
x x x x
1 1
Put 2 5 7 t
x x
5 x 7 x dx dt
6 8
dt 1
c
t2 t
x7
f x 7 c
2 x x2 1
1
f 0 0 C 0 f 1 k 4
4
90. 6 x 2 3ax 2a 2
= 6 x a x 2a ; a 0
x = a is point of maxima
x = 2a is point of minima
a 2 2a
a 0 or a 2
But a 0 a 2