MOCK TEST – 3
1. Match the following
Buoyancy Forces
P. Reynolds number 1.
Viscous forces
Inertial forces
Q. Grashoff number 2.
Viscous forces
Grashoff number
R. Rayleigh number 3.
Re ynolds number
(a) P-1, R-3 (b) Q-1, R-3 (c) P-2, Q-1 (d) Q-2, R-1
Ans: (c)
2. If the critical radius of insulation (critical thickness) for cylinder is 10mm, then what is the
critical radius of insulation for sphere?
(a) 2 cm (b) 5 mm (3) 2 mm (d) 5 cm
Ans: (c)
k
Sol: Cylinder =
h
2k
Sphere = 2 10 20 mm 2cm
h
3. In a gas absorption process, HtG 0.24mand L / mG 1.2, then H toG will be _____(in m).
Ans: 1.5
H TL
Sol: H toG H TG
L / mg
0.24
0.3 1.5m
1.2
4. Effective Knudsen diffusivity
S1: is independent of pressure
S2: Varies directly with square root of temperature
S3: Varies inversely with square root of molecular weight
(a) S1 & S2 are correct (b) S1 & S3 are correct
(c) All are correct (d) None of these
Ans: (c)
5. The exit conversion of reactant of ‘A’ for zero order reaction taking places in a CSTR for the
following data will be _______
Data:
Rate constant = 0.5 mol/min /lt
Feed concentration = 2 mol/ lt
Feed flow rate = 0.25 lt/min
Reactor volume = 2 lt
Ans: 100
T V XA
Sol:
CAO FA0 rA
V
XA rA
FAO
2 1
= 0.5 2
2.25 2 0.5
6. What is the ratio of reaction rate on particle 1 (Size L1=12mm) to the reaction rate on particle 2
(Size L2= 3cm) if the reaction takes place in the regime of strong diffusion resistance? (Given
that effectiveness factor for particle 1 is 0.12)
(a) 4 (b) 0.48 (c) 2.5 (d) 0.03
Ans: (c)
1
Sol:
mL
0.12 strong per diffusion
1 L 2
2 L1
30 5
= 2.5
12 2
7. In the manufacture of urea, bluret ( NH2CONHCONH2 ) formation is kept minimum because it
(a) Is explosive
(b) Decomposes urea into CO2, N2, & H2O
(c) Contains only 4 wt%, N2
(d) Toxic to animals
Ans: (d)
8. Which type of soaps has excellent property to remove soil and grease?
(a) Cationic type (b) Anionic type (c) Non-ionic type (d) Both (a) & (b)
Ans: (c)
9. A distillation column costs Rs. 50,000. Life time and scrap value are 6 years and 0 respectively.
Assuming effective compound interest of 11% per year, what will be the capitalized cost of the
distillation column?
(a) 11,083 (b) 23,156 (c) 90,195 (d) 107,446
Ans: (d)
50K
Sol: Cc 50x
1 0.116 1
=107,446
10. Stability analysis of a control system can be done by using frequency response method, which
type of input to be specified?
(a) Step input (b) Ramp input (c) Sinusoidal input (d) no input
Ans: (c)
11. Arrange the following in decreasing order of their emissivities.
I. Smooth glass II. Plaster III. aluminum IV. Concrete
(a) I, II, III, IV (b) I, II, IV,III (c) I, III,IV,II (d) I, III,II,IV
Ans: (b)
12. Which of the following statements is correct for a Schmidt number of value 2?
(a) Mass diffusivity is two times the momentum diffusivity
(b) Thermal diffusivity is two times the momentum diffusivity
(c) Momentum diffusivity is two times the mass diffusivity
(d) Momentum diffusivity is two times the thermal diffusivity
Ans: (c)
13. If LMTD correction factor for a heat exchanger is 0.81, then I is ____ to design that equipment
(a) Desirable (b) Not desirable (c) Cant say (d) None of these
Ans: (b)
Sol: For F7 (LMTD correction factor) value above 0.80, hence is not desirable to design the heat
exchanger
14. What are the dryness fraction values for a liquid just starts boiling and for the vapour which is
formed after complete vaporization?
(a) 0,1 (b) 1,0 (c) Between 0 and 1 (d) Greater than 1
Ans: (a)
mv
Sol: Dryness fraxtion x
mv ml
Fir liquid just starts boiling m=0, x=0
For vapour formed after complete vaporization
mv
m2 1
ml mv
15. The percentage of Na 2SO4 present in one mole of Na 2SO4 .5H2O will be _____ than t5he
percentage of Na 2SO4 present in Na 2SO4 10H2O
(a) Greater (b) Less (c) Equal (d) None
Ans: (a)
142
Na 2SO4 .5H 2o 100 62
232
142
Na 2SO4 in Na 2SO4 .10H 2O 100
312
= 44
16. Which of the following statements is correct, if the slope of operating line is ‘m’ times the slope
of equilibrium line?
(a) HTU>HETP (b) HETP>HTU (c) HETP=HTU (d) Depends on ‘m’
Ans: (c)
Sol: if operating line is parallel to equal line, than HETP is greater than HTU
17. Hydrolysis of oil and fats with _____ gives a mixture of glycerol and fatty acid, whereas the
hydrolysis of oil and fats with _____ gives a mixture of glycerol and soap.
(a) Acid, Alkali (b) Alkali, Acid (c) Acid, water (d) none of these
Ans: (a)
Sol: Glycerol+3NaoH Glycerol+3R-COONa
With the acid and water they will give glycerol and fatty acid
18. What is the order of a reaction for ammonia fabrication from the nitrogen and hydrogen ?
(a) 2 (b) 1 (c) 0 (d) cannot say
Ans: (d)
Sol: Unless it is mentioned Reaction is elementary or not
We cant say
19. The half life period of a first order irreversible reaction is a
(a) Constant (b) Function of initial concentration
(c) Function of temperature (d) none of these
Ans: (c)
rR k
20. For the parallel reaction given below, the quantity is given by 1 , then which of the
rS k2
following is correct for the product distribution of the above reaction?
R
K1
A
K2 S
K1
(a) The product distribution is fixed by
K2
(b) The product distribution is unaffected by using the type of ractor.
(c) Both A & B
(d) None of these
Ans: (c)
21. Find the area |in mm2| of openings in one screen (Taylor series) such that area of openings in the
next smaller opening is 10mm2 ________
Ans: 20
A2
Sol: 2 A 2 2 10 mm2 20
A1
22. A large body A of emissive power 180 W/m2 and absorptivity 0.6 enclosed a small body B of
emissive power 190 W/m2 and are in thermal equilibrium with their environment. Find the
absorptivity of smaller body ‘B’ __________
Ans: 0.63
EA EB E B A
Sol: B
A B EA
190 0.6
B 0.63
180
23. Which of the following material will have the same temperature profile shown in the figure
during heat transfer?
(a) Insulating body (b) Low conductivity fluid
(c) High conductivity fluid (d) none of these
Ans: (b)
Sol: Low conductivity fluid have the same temperature
24. A steam pipe of thermal conductivity 0.65 W/m.K and diameter 120 mm is placed horizontally
in air 320C such that heat is lost from steam pipe. Calculate the heat transfer coefficient if the
Nusselt number is 30 and thermal conductivity of air is 0.04 W/m.k
(a) 7 W/m2.K (b) 16 W/m2.K (c) 10 W/m2.K (d) 22W/m2 K
Ans: (c)
hD
Sol: Nu=
K
h 120 103
30
0.04
h= 10W/m2.K
25. Find the value of Lewis number for a mass transfer process for which Reynold’s number is
16000, Schmidt number =840 and Prandtl number = 400.8________
Ans: 2.094
Sc 840
Sol: Le 2.094
Pr 400.8
26. In a falling rate period, the rate of drying is directly proportional to (t) n. find the value of ‘n’ if ‘t’
is the thickness of material
(a) 1 (b) -2 (c) -1 (d) 2
Ans: (b)
1
Sol: Rate of drying
thickness
2
27. Which of the following statement is correct about Knudsen diffusion?
(a) Mean free path of the gas molecules is greater than the pore diameter
(b) Gaseous collisions are more frequent that collision of molecules with pore walls
(c) Catalytic reaction requires more activation than homogeneous reaction
(d) For irreversible reaction rate always decreases with temperature
Ans: (a)
Sol: For Knudsen diffusion mean path > pore diameter
28. The half life of a reaction is given:
t1/2 23/2 1 .2CAC3/2
What is the order of the reaction ?
5 3 1
(a) (b) (c) 3 (d)
2 2 2
Ans: (a)
Sol: t1/2CAO1n
3
1 n
2
Order of reaction n=5/2
29. A gaseous phase reaction 3P Q where 60 mole% P and 40 mole % inerts , find the expansion
factor
(a) -0.2 (b) 0.4 (c) 0.2 (d) -0.4
Ans: (d)
Sol: 3P Q
VA1 VA0 0.2 0.6
A 0.4
V A0 1
30. Which of the following statement is correct about membrane to produce caustic soda?
(a) Chlorine contaminated caustic soda is produced
(b) Electric energy consumption is more than the mercury process
(c) Very high purity brine required
(d) Low cost and long life time of the membrane
Ans: (c)
31. A horizontal rectangular channel has a discharge of 8.0 m3s/m width of the channel. In a
hydraulic jump occurring in this channel, the depth before and after the jump is 0.5 m and 4.75 m
respectively. Calculate the energy loss in the jump
(a) 8.365m (b) 8.653m (c) 8.563m (d) 8.065m
Ans: (b)
q 8
Sol: V1 16m / s
g1 0.5
8
V2 1.684m / s
4.15
V12 V2
Z 1 ZL
2g 2g
L 8.653m
32. Triple glazed windows shown below are used in much closed climates. Calculate the R-value for
the window, if the thermal conductivity of air at normal room temperature is approximately
0.015 Btu/h.ft0F and the thermal conductivity of window glass is 0.78W/mK.
(a) 2.8 (b) 8.2 (c) 3.6 (d) 4.2
Ans: (a)
Sol: K glass = 0.78 0.37782 645 Btu/h.ft0F
0.08
R glass 0.0148
12 0.45
0.25 /12
Rair= 1.3889
0.015
R value = 3 R glass+2 Rair
=2.8
33. A duct carries hot waste gas from a process unit to a pollution control device. The duct cross
section is 4ft 4ft and it has a surface temperature of 1400C. ambient air at 200C blows across
the duct with a wind speed of 10 m/s. the rate of heat loss per meter (in W/m) of duct length will
be __________.
(assume data: Kinematic viscosity is 2.15 106 ; Nu 0.1202Re0.654 )
Conductivity K= 0.0293, (in SI units)
Ans: 9800
140 20
Sol: Tf = 800 C
2
1.22 10
Ri= 5.674 105
2.15 106
Nu=0.1202 Ri0.654=6965
H=16.7 W/m
A= 4 1.22 10 4.88m 2
q= HAT 167 4.88 144.20 9800W / m
34. The atmospheric air is a mixture of nitrogen and oxygen in the mole ratio 79:21. It is required to
separate 1 mol /sec of air at 1 bar 300K into its pure components at 1 bar and 300K. the
minimum power (kW) required to separate the air will be _____________
(Surroundings are at 300K and treat air as an ideal gas)
Ans: 1.282
Sol: Entropy change due to mixing
s R x i ln x i si se
Wmin= RTo x i ln x i
= 8.314 300 0.79ln 0.79 0.21ln 0.21
= 1281.9 J/s
Min power required = 1.28W
35. A crystallizer is changed with 7500kg of aqueous solution at 104 0C containing 29.6% by weight
of anhydrous Na 2SO4 . the solution is then cooled to 200C. during this operation, 5% of water is
lost by evaporation and Glauber’s salt crystallizes. Solubility at 200C = 194g Na2SO4/100h water
Molecular weight of Glauber’s salt (Na2SO4.10H2O)=142+180=322
The yield of crystals in kgs will be ________
Ans: 3749.5
Sol: Na 2SO4 % 7500 0.296 2220kg
H2O percent= 7500-2250=5280 kg
H2O lost = 5280 0.05 264kg
H2O remaining = 5280-264=5016 kg
Let
X= kg of Glauber salt crystallizer
X Y
Y= wt of the solution Na2SO4 balance = 2220 142 19.4
322 1194
X Y
H2O balance = 5016= 180 100
322 199.4
Solving X=3749.5 kg
Y=3486.5 kg
36. What is the rate constant value for second order reaction, if the initial concentration is
mol
5 104 and is decreased by 40% in 50 min?
lit
[Consider as decomposition of a gas]
(a) 13.33 (b) 26.67 (c) 38.93 (d) 46.64
Ans: (b)
Sol: IInd order
1 1
Kt
CA CAO
t=30 min
2 104
K 26.66 mol1 min 1
3 250
37. Match the following amines given in List- I with their usage in List – II
List – I List – II
P. Monomethyl amine 1. Used in the manufacturing of
dimethyl formamide and
acetaamide
Q. Dimethyl amine 2. Used to form cholin chloride,
biocies and slimicides
R. Trimethylamine 3. Used in explosive, insecticides
and surfactants
(a) P-3, Q-2, R-1 (b) P-2, Q-3, R-1 (c) P-1, Q-2, R-3 (d) P-3, Q-1, R-2
Ans: (d)
38. Match the following humidity measuring apparatus in List-I with their functioning in List – II
List – I List – II
P . Direct chemical Method 1. Measurement done using the
electrical conductivity
Q. Hygrometer method 2. Measurement done using the
dry bulb and wet bulb
temperatures
R. Sling psychrometer method 3. Measurement based on
expansion and contraction of
materials like hair, wood, animal
membrane and paper
S. Dew point method 4. Measurement done using
chemical like H2SO4, P2O5 etc
(a) P-2, Q-1, R-4,S-3 (b) P-3, Q-2, R-1, S-4
(c) P-4, Q-3, R-2, S-1 (d) P-1, Q-3, R-2, S-4
Ans: (c)
39. A power plant taps steam superheated by geothermal energy at 505K (the temperature of the hot
resorvoir) and uses the steam to do work in turning the turbine of an electric generator. The
steam is then converted back into water in a condenser at 323K (the temperature of the cold
reservoir), after which the water pumped back into the ground where it is heated again. The
output of the generator is 84MW. Calculate the minimum amount of rejected heat (in MJ) that
must be removed from the condenser every 24 hours?
(a) 1.288 107 (b) 2.818 107 (c) 8.128 107 (d) 1.822 107
Ans: (a)
W
Sol: Efficiency =
QA
Tc
= 1 0.36
Tn
W=Qn-Qc
W
2.33MW
effc
Qc 233 84
= 149 MW
149 24 3600 1.28 107 MJ
40. Match the following polymerization techniques in List –I that is mostly used for the preparation
of the polymers given in List- II
List – I List –II
P. Bulk polymerization 1. Used for preparation of polyvinyl
acetate
Q. Solution Polymarization 2. Used for commercial preparation
of polyvinyl chloride and polystyrene
R. Suspension polymerization 3. For preparation of high density
polyethylene and polypropylene
S. Emulsion polymerization 4. Methyl methacrykate to Plexiglas
(a) P-4, Q-3, R-1, S-2 (b) P-4, Q-3, R-2, S-1
(c) P-3, Q-4, R-1, S-2 (d) P-3, Q-4, R-2, S-1
Ans: (b)
41. Match the following model (List- I) which has proper residence time distribution (List -II)
List -I List – II
P. CSTR followed by PFR
1.
Q. PFR followed by CSTR
2.
R. CSTR with bypass
3.
S. PFR with bypass
4.
(a) P-1, Q-2, R-3 (b) Q-1, R-2, S-3 (c) R-2, S-3,P-4 (d) S-3, P-4, Q-1
Ans: (b)
42. (Brary lethenol(1) Methyl acetate (2)) mixture is given at pressure 200kPa and 80 0C
Data:
A B C
B
In P / kPa A
sat
Methanol 16.5938 35644.3 33.39
TC
Methyl Acetate 14.4015 2739.17 50.03
What will be the X2 mole reaction of methyl acetate? _________
Ans: 0.615
3644.3
Sol: in Psat 16.59
353 33.59
5.19
2739.17
In P2sat 14.4015
353 50.03
5.36
P1sat 180 kPa
P2sat 212.5kPa
P X1P1sat X2 P2sat
200 1 X2 180 X2 212.5
X2 = 0.615
43. In an oil refinery plant a heat exchanger of area 100cm2 was purchased in 1993 at a cost of Rs.
3,00,000. In 1999, another heat exchanger of area 20m2 was added. Marshall land swift index
was 1048.5 in 1993 and 1116.9 in 1999. If the cost scales as capacity 0.54, then evaluate the cost
of the 2nd evaporator __________.
Ans: 1,34,010
Sol: 1993 100cm3
C1 3,00,000
0.54
C2 20
C1 100
C2 0.4193 3,00,000
= 1,25,800
C1999 1,34,010
44. An evaporator cost of $10,000 has 8 years of life time. Find the book value of the unit at the end
of 4 years. (Use double declining method for depreciation)
(a) $7314 (b) $ 5126 (c) $ 3164 (d) $ 2347
Ans: (c)
2 2
Sol: f 0.25
N 8
P4 P0 1 f
n
= 104(0.75)4
= 3164
45. An object spherical shape of 3cm diameter at 1000C is suspended in air. The sphere is enclosed
by 10cm dome at 2500C, with absorptivity and emissivity of 1. The dome and sphere are
concentric. What is the radiative heat loss from sphere and dome? Given emissivity of the sphere
is 0.9.
(a) 2.8W, 133.27 W (b) 2.8W, 66.63W (c) 5.6W, 133.27W (d) 5.6W, 66.63 W
Ans: (b)
Sol: qsphere = 0.9 5.67 10 2 4 0.01512 373 4
= 2.7 W
qdone= 1 5.67 108 2 0.05 5234
2
= 66.63 W
46. Match the following monomer (List - I) with corresponding polymer (List - II)
List –I List –II
P- Chloroethene 1. Nylon
Q. Amide 2. Poly vinyl chloride
R. Ethene 3. Poly ethane
S. Ethylene
(a) P-2, Q-1, R-3 (b) P-3, S-2, R-1
(c) Q-3, R-1, S-2 (d) R-1, S-2, P-3
Ans: (a)
47. Which of the following reactions are endothermic?
(i) 2NH3 CO2 NH2CONH2 H2O
(ii) N2 2H2 2NH3 Haber process
(a) Neither (i) nor (ii) (b) Both (i) and (ii)
(c) Only i (d) Only ii
Ans: (a)
48. Let the inflation rate be 6% per year. If a person deposits Rs. 50,000 in a bank at 9% per annum
simple interest for 10 years, will this effectively protect the purchasing power of the original
principal?
(a) Purchasing power of the investment will not be protected
(b) Purchasing power of the investment will be protected
(c) Investment will be protected without any increment
(d) None of these
Ans: (d)
Sol: P 50000 1 0.09
10
= 118368
118368
P 66096
1 0.06
10
66096 > 50,000
49. If a bowl of liquid is heated at 1000C and it takes 40 minutes to evaporate, but if it is heated to
1500C, it needs only 20 minutes to evaporate. The activation energy for this process is ________
(Take in2= 0.69)
Ans: 18185
r2 t E1 1
Sol: ln ln 1
r1 t 2 R T1 T2
40 E 1 1
ln
20 8.314 373 423
E= 18185.05J/Kmol
50. A binary mixture of 10 Kg mol benzene and toluene containing 40-mol percent, benzene is to
distilled at atm pressure to recover 95% of the benzene. If the residue is 6 kg mol, then the
residue composition for toluene is __________
Ans: 0.967
Sol: 10=D+W
D=4
F *yf = D* yd W* x w W w 4 3.8 0.2
6 0.2
YW = 0.967
6