Mercedes-Benz DBL 6714

Company Standard Date published: 2015-09

Total no. of pages (including annexes): 22
Person in charge: Walter Illi
E-mail: walter.illi@daimler.com
Plant: 050; Dept.: TF/VBT
Date of translation: 2015-12 Phone: +49 (0)7031-90 77867

Negative List – Constituents of Process Materials

Foreword

This DBL is intended to put concrete specifications in place with regard to the employer's test
requirements in accordance with the German Hazardous Materials Ordinance ("Gefahrstoffverordnung")
and to facilitate the avoidance of disproportionate or inadmissible environmental impacts.

This edition supersedes the previous edition 2013-07 of this Standard.

Application note:
In line with the scope, application of the present version of this Standard is binding for new vehicle
projects or components for which no concept/basic specifications or component requirement specifications
have been approved yet at the date of issue of this version.
The respective contract documents regulate the mandatory application of the present version
of this Standard by the supplier.

Changes

In comparison with edition 2013-07, the following changes have been made:

− Adaptation to the current statutory requirements

− Integration of VKIS-VSI-IGM List of Substances for Metal Working Fluids According to DIN 51385

NOTE: This translation is for information purposes only.

The German version shall prevail above all others.

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Contents

1 Scope ............................................................................................................................................... 2
2 Normative references ....................................................................................................................... 3
3 Terms and definitions ....................................................................................................................... 4
4 General requirements ....................................................................................................................... 5
4.1 General clause ................................................................................................................................. 5
4.2 Obligations to provide documentation and evidence ....................................................................... 7
4.3 Time frame for product adjustments................................................................................................. 7
5 Abbreviated material designation for documentation ....................................................................... 8
Annex A (normative) Declarable and prohibited constituents ....................................................................... 9

1 Scope

This Supply Specification governs specific requirements with regard to the following process materials
in particular:

- Water-miscible process materials:

Water-miscible cooling lubricants/metal-forming lubricants, anti-corrosion additives,
cleaning agents, water-based hydraulic fluids, quenching media

- Non-water-miscible process materials:

Non-water-miscible cooling lubricants/metal-forming lubricants, lubricants for machine lubrication
(oils, greases), hydraulic oils, lubricants for materials handling technology, quenching oils,
spray oils

- Preservatives and disinfecting cleaning agents:

Water-miscible preservatives for post-conservation of cooling lubricants, as constituents of cooling
lubricants and skin cleaning agents (pre-conservation); disinfecting cleaning agents, disinfectants

- Temporary anti-corrosion agents, cold cleaning solvents

- Solvents in process materials, but also as constituents of other working materials

- Process materials: includes all substance groups indicated above

This DBL also applies to non-process materials or other working materials provided that the application
restrictions and environmental and work safety requirements are not governed in other specifications.

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2 Normative references

The following referenced documents are indispensable for the application of this document.
For dated references, only the edition cited applies. For undated references, the latest edition
of the referenced document (including any changes) applies.

DBL 8585 General Requirements –

Environmental Protection, Hazardous Substances, Dangerous Goods –
Negative Substance List for the Selection of Materials
DBL 6565 General Technical Supply Specifications for Process Materials and Service
Products
DBL 6880 Paste Against Fretting Oxidation
DIN 51385 Lubricants – Processing Fluids for Forming and Machining of Materials –
Terms
DIN 51527-1:1987-05 Testing of Petroleum Products – Determination of Polychlorinated Biphenyls
(PCB) – Preparation by Liquid Chromatography and Determination
of 6 Selected PCB Compounds by Gas Chromatography Using an Electron
Capture Detector
DIN EN ISO 15088 Water Quality – Determination of the Acute Toxicity of Waste Water
to Zebrafish Eggs (Danio Rerio)
DIN 51827:1989-01 Testing of Lubricants – Determination of Lead Content of Lubricating
Greases – Determination by Atomic Absorption Spectrometry (AAS) after
Incineration
DIN ISO 15597 Petroleum and Related Products – Determination of Chlorine and Bromine
Content – Wavelength-Dispersive X-Ray Fluorescence Spectrometry
(ISO 15597:2001)
DIN 51391-2 Testing of Lubricants – Determination of the Content of Additive Elements –
Analysis by Wavelength-Dispersive X-Ray Spectrometry (XRS)
DIN 51391-1:1997-08 Testing of Lubricants – Determination of the Content of Additive Elements –
Part 1: Determination by Atomic Absorption Spectrometry
(DIN 51391-1: 1997-08)
DIN 51413-3:1988-10 Testing of Liquid Petroleum Products – Determination of Aromatics by Gas
Chromatography
DIN 51391-3 Testing of Lubricants – Determination of the Content of Additive Elements –
Part 3: Direct Determination of Barium, Calcium, Magnesium and Zinc
Content of Lubricants by Inductively Coupled Plasma/Optical Emission
Spectroscopy (ICP OES)
DIN EN 13723 Petroleum Products – Determination of Low Lead Contents in Gasolines
by Wavelength-Dispersive X-Ray Fluorescence Spectrometry (XRF)
DIN 51378 Testing of Mineral Oils – Determination of Carbon-Type Composition

Laws, regulations and directives:

AltölV Altölverordnung (Waste Oil Ordinance)

BeKGS 220 Safety Data Sheet
ChemVerbotsV Ordinance on Bans and Restrictive Measures for the Marketing of Hazardous
Substances, Preparations and Products according to the Chemicals Act
(Chemikalienverbots-Verordnung – Chemicals Prohibition Ordinance)
GefStoffV Gefahrstoffverordnung (Hazardous Substances Ordinance)
GGVSEB German Regulation on the National and International Carriage of Dangerous
Goods by Road, Rail, and Inland Waterways
TRGS 611 Restrictions on the Use of Water-Miscible or Water-Mixed Cooling Lubricants
Whose Employment Can Result in the Formation of N-Nitrosamines
TRGS 615 Restrictions on the Use of Corrosion Inhibitors Whose Employment Can
Result in the Formation of N-Nitrosamines
TRGS 900 Occupational Exposure Limit Values
TRGS 907 List of Sensitizing Substances and Activities Using Sensitizing Substances
TRGS 552 Technical Rules for Hazardous Substances – N Nitrosamines

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TRGS 401 Risks Resulting from Skin Contact – Identification, Assessment, Measures
TRGS 557 Dioxine (Dioxins)
TRGS 905 Technical Rules for Hazardous Substances – Directory of Carcinogenic,
Mutagenic or Teratogenic Substances
TRGS 910 Risk-Related Concept of Measures for Activities Involving Carcinogenic
Hazardous Substances
VKIS-VSI-IGM List of Substances for Metal Working Fluids According to DIN 51385
List of Substances

Regulation (EU) No. 528/2012 – Regulation of the European Parliament and of the Council
of 22 May 2012 Concerning the Making Available on the Market and Use of Biocidal Products.

Regulation (EC) No. 1272/2008 Regulation of the European Parliament and of the Council
of 16 December 2008 on Classification, Labelling and Packaging of Substances and Mixtures

Directive 2006/11/EC of the European Parliament and of the Council of 15 February 2006
on Pollution Caused by Certain Dangerous Substances Discharged into the Aquatic Environment
of the Community

Regulation (EC) No. 1907/2006 of the European Parliament and of the Council of 18 December 2006
Concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH),
Establishing a European Chemicals Agency

IP 346/92 Methods of Test for Petroleum and its Products – Part 346: Determination of Polycyclic
Aromatics in Unused Lubricating Base Oils and Asphaltene Free Petroleum Fractions – Dimethyl
Sulphoxide Extraction Refractive Index Method

Directive 2003/53/EC of the European Parliament and of the Council of 18 June 2003 amending
for the 26th time Council Directive 76/769/EEC relating to restrictions on the marketing and use
of certain dangerous substances and preparations (nonylphenol, nonylphenol ethoxylate and cement)

US-EPA Method Validation Study 20, Method 610 (Polynuclear Aromatic Hydrocarbons)

AbwV Ordinance on Requirements for the Discharge of Waste Water into Waters
(Rahmen-Abwasser VwV)

3 Terms and definitions

ATP Adaptation to Technical Progress

Working materials All materials and mixtures that are used
Annex XIV "List of Substances Subject to Authorization"
Annex XVII "Restrictions in the Production, Introduction to the Market and Use of Certain
Hazardous Substances, Preparations, and Products"
BekGS Bekanntmachung zu Gefahrstoffen (Announcement on Hazardous Materials)
CLP Classification, Labelling and Packaging of Substances and Mixtures
CoRAP Community Rolling Action Plan
DFG Deutsche Forschungsgemeinschaft
ECHA European Chemicals Agency
EC European Community; with the coming into force of the Lisbon Treaty on 1 December
2009, the European Union (EU) has become the legal successor of the EC
EU European Union
EEC European Economic Community
GefStoffV Gefahrstoffverordnung (Hazardous Substances Ordinance)
GGVSEB Ordinance on the Domestic and International Transport of Dangerous Goods by Road,
Rail and Inland Waterways
IGM Industriegewerkschaft Metall (Industrial Union of Metalworkers)
KSS Kühlschmierstoff (cooling lubricant)
MHLW Ministry of Health, Labour and Welfare (Japan)
PT Product Type

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PACT Public Activities Coordination Tool

PT/T Powertrain Technology Factory
REACH Registration, Evaluation, Authorization, and Restriction of Chemicals

DR Directive
RMOA Risk Management Option Analysis
Sunset date Date(s) from which a substance listed in Annex XIV of the REACH Regulation shall no
longer be used within the EU unless an authorization by the ECHA is granted
SVHC Substance of Very High Concern
TF/V Technology Factory for MBC Assembly Plants / Process Development and Materials
TRGS Technical Rules for Hazardous Substances (Technische Regeln für Gefahrstoffe)
US-EPA United States Environmental Protection Agency
VKIS Verbraucherkreis Industrieschmierstoffe (User Group, Industrial Lubricants)
VO Regulation, ordinance (Verordnung)
VOC Volatile Organic Compound[s]
VSI Verband der Schmierstoff-Industrie e. V.
(German Association of the Lubricant Industry)

4 General requirements

For safety requirements, homologation (in particular, exhaust emissions) and quality, the existing statutory
requirements and laws shall be complied with. In addition, the relevant requirements of the Daimler Group
apply.

All materials, procedures, processes, components, and systems shall conform to the current statutory
requirements regarding regulated substances and recyclability.

With respect to its delivery or services, the supplier shall comply at all times with all the latest versions
of applicable statutory regulations regarding environmental protection, hazardous substances, dangerous
goods, work safety, and transportation. The supplier confirms that it has read the environmental protection
guidelines of the Daimler Group and shall comply with their contents in all its activities.

General: Substances and mixtures subject to German or European statutory restrictions or prohibitions
shall only be contained in accordance with these specifications in supplied or employed products.

The latest applicable edition of DBL 8585 shall be observed.

4.1 General clause

The concentrations of the elements/compounds listed in the table under Section 5 are limited for reasons
of environmental protection, protection of health and process technology.

The hazardous substances classified in the latest edition of Regulation (EC) No. 1272/2008
(CLP Regulation) as

- carcinogenic, mutagenic, toxic for reproduction, acute toxic category 1, 2 and 3,

specifically target-organ toxic (single exposure) category 1 and specifically target-organ toxic
(repeated exposure) category 1, and

- acute aquatic toxic, chronic aquatic toxic and hazardous to the ozone layer

shall be avoided on principle.

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The hazardous substances classified in the latest version of Regulation (EC) No. 1907/2006 (REACH)

- as PBT (persistent, bioaccumulative, and toxic), vPvB (very persistent and very bioaccumulative),
and materials with similarly alarming properties (e.g. endocrine disruptors)

shall be avoided on principle.

In authorized exceptional cases, the substance shall be declared in each case irrespective
of the concentration.
The points indicated above apply even where the hazardous substances are not listed explicitly
in the following negative list (table in Section 5).

The supplier shall comply with the requirements contained in this negative list in combination
with the requirements of the relevant material DBLs. In case of any change
to the composition/classification, the decisive constituents shall be reported without further request.

Process materials shall not contain a larger quantity of prohibited substances than the contamination
generated during their production process. Deviations from the limits specified in Section 5 shall
be approved as part of the approval process for already approved and newly sampled products
by the Materials Engineering department and the environmental and work safety units of the concerned
plants or the Daimler Group environmental protection unit. For any process materials not regulated
by a DBL, approval shall be granted in accordance with rules and regulations specific to the plant,
e.g. by the work safety or environmental protection departments of the plant where the materials are used.
Limit values shall apply to process materials in their as-supplied condition. All substances contained
as part of a formulation which are governed by the laws on hazardous substances/environment
(e.g. German Hazardous Materials Ordinance, water legislation) or which require special care in handling
shall be declared, irrespective of the concentration of the respective substances in the mixture.

An EC safety data sheet for the mixture in accordance with Annex II of Regulation (EC) No. 1907/2006
(REACH) and BekGS 220 shall be submitted. Constituents shall be declared in accordance
with the requirements of DBL 6565, even if no notification is required according to Regulation (EC)
No. 1272/2008 (CLP Regulation) and the rules of the TRGS series. As part of the approval process
with regard to environmental and work safety impact, complete information on the formulation shall
be reported to the units responsible for environmental protection and work safety. Refer to DBL 6565
for the procedure. In the case of biocides, indicate whether approval has been granted
for the corresponding product type (indicate approval number).

The omission of a substance from the following list in Annex A does not imply that this substance
has general approval; rather, its status shall be checked on a case-to-case basis.

The classification and labeling of substances and mixtures shall be performed according
to the specifications of Regulation (EC) No. 1272/2008 (CLP Regulation).

Regulation (EC) No. 1907/2006 (REACH)

Daimler AG assumes that suppliers are aware of their obligations under Regulation (EC)
No. 1907/2006 (REACH), and that these obligations are fulfilled.

Registration and non-authorization of substances

The supplier shall ensure that substances, and substances in mixtures, requiring registration
or authorization are only supplied to Daimler if they have been registered according to Art. 5 and Art. 6
or Art. 7(1) of the Regulation (EC) No. 1907/2006 (REACH) for use at Daimler, or have been authorized
in accordance with Art. 55 ff.
If substances requiring registration/authorization have not been registered or substances in Annex XIV
of Regulation (EC) 1907/2006 (REACH) have not been registered/approved for the contractually intended
uses, the supplier shall contact the REACH representative of Daimler AG directly:
reach-kontakt@daimler.com.

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Rule for substances listed in Annex XIV of Regulation (EC) No. 1907/2006 (REACH),
as such or in mixtures
In general, substances listed in Annex XIV of Regulation (EC) No. 1907/2006 (REACH) shall be avoided
when considered for use for the first time or when a mixture is newly developed.
Where the use of such substances is indispensable, such use is subject to the prior approval in writing
by the department responsible for the product at Daimler. The supplier shall provide evidence
of the approval by ECHA for the specific use and of the safe handling to the department responsible
for the product no later than at the time when the sunset date is reached.

The use of substances on the REACH candidate list should also be avoided, if possible, as a precautionary
measure when a substance or the new development of a mixture is considered for use for the first time,
provided that alternatives exist under the technical and economic constraints.
For the latest overviews of the candidate list and Annex XIV, refer to the ECHA website at:

- http://echa.europa.eu/web/guest/candidate-list-table and
- http://echa.europa.eu/REACH/authorisation_under_REACH/authorisation_list_en.asp.

Where a currently supplied substance is listed in Annex XIV of Regulation (EC) No. 1907/2006 (REACH)
or where a currently supplied mixture contains a substance listed in Annex XIV, the supplier shall inform
the department responsible for the product directly in order to initiate plans for substitution or, if applicable,
authorization of the respective substance and provide evidence of safe handling. In the case
of a substitution, the supplier shall supply an updated safety data sheet in each case.
Suppliers of sales products shall liaise with the responsible sales contact of Daimler AG in this respect.

Other rules
Where process materials are classified as classes 1 to 9 of the Ordinance on the Domestic
and International Transport of Dangerous Goods by Road, Rail and Inland Waterways (GGVSEB,
in its latest version) as a result of their constituents, the specified measures with regard to packaging,
labeling, declaration, and transportation shall be observed.

Process materials of water contamination class 3 are prohibited in principle. Any exceptions are subject
to the approval of the departments in the plants or headquarters with responsibility for health,
environment and material-related approvals.

Any constituents recognized as sensitizing in accordance with TRGS 907 and skin-absorbent materials
in accordance with TRGS 900 shall be revealed. Animal raw materials shall be declared.

In addition, the latest version of the VKIS-VSI-IGM List of Substances for Metal Working Fluids According
to DIN 51385 shall apply. This can be downloaded from www.vkis.org.

4.2 Obligations to provide documentation and evidence

On request, the supplier shall provide Daimler AG with information regarding compliance with statutory
obligations to provide documentation or evidence (e.g. VOC values).

4.3 Time frame for product adjustments

Where product adjustments are required due to changes in laws, classifications, technical specifications
etc., the following deadlines shall apply:

Samples of all products shall be submitted after notification of a required product adjustment
within the following periods:

"to be targeted in the short term" within 12 months

"to be targeted" within 24 months
"to be targeted in the long term" within 48 months

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5 Abbreviated material designation for documentation

Not applicable.

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Annex A (normative)
Declarable and prohibited constituents
LR = Legally Regulated
FA = For Assessment
FI = For Information

wm = water-miscible (concentrate)
wg = water-mixed (solution, emulsion)
nw = non-water-miscible (oil)

ppm = parts per million, represents the number 10−6

Declaration = A substance indicated with “Declaration” shall be declared irrespective of the concentration. The indicated concentrations in the column "Limit value"
represent maximum values which may only be exceeded subject to the agreement of the Materials Engineering department; otherwise, the product will be rejected.
Prohibition = No substances classified as "Prohibited" shall be used, on general principle. Where a limit value is indicated, the substance shall only be contained
in the form of contamination resulting from the manufacturing process below the limit value indicated. These substances shall not be added deliberately.
Prohibition with exception = Substances with classification "Prohibited with exceptions" shall also not be used on general principle; well-founded exceptions may
be agreed with the Materials Engineering department, however.

Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
1,2-benzisothiazol-3(2H)-one 2634-33-5 Process materials Prohibited with 25th ATP to Regulation ≤ 10 ppm Exceptions for application without skin contact
220-120-9 exceptions (EC) No. 1999/45/EC or application concentration < 500 ppm following
discussions with the Materials Engineering
department possible.
1,3,5-tris(2-hydroxyethyl) 4719-04-4 Preservatives and Declaration FI 25th ATP to Regulation Application concentration ≤ 0,1 %
hexahydro-1,3,5-triazine (HHT) disinfecting cleaning (EC) No. 1999/45/EC
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agents
1,3-bis(hydroxymethyl)urea 140-95-4 Preservatives and Prohibited LR Shall no longer be used as a biocidal agent
205-444-0 disinfecting cleaning for PT 13 due to lack of a dossier according
agents to EC biocide directive
1,4-dioxane 123-91-1 Solvents Declaration FA ≤1%
204-661-8
1-aminopropan-2-ol (Isopropanolamine) 78-96-6 Water-miscible process Declaration FI
201-162-7 materials
Hexan-1-ol 111-27-3 Solvents Declaration FA ≤ 25 %
203-852-3

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Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
1-hydroxyethane-1,1-diphosphonic acid 2809-21-4 Water-miscible process Declaration FI Registration dossier
and its Na and K salts, HEDP 7414-83-7 materials according to REACH
1-phenoxy-2-propanol 770-35-4 Preservatives and Prohibited LR Shall no longer be used as a biocidal agent
212-222-7 disinfecting cleaning for PT 13 due to lack of a dossier according
agents to EC biocide directive
Declaration in the event of other process
materials.
2-(2-aminoethoxy)ethanol (diglycolamine) 929-06-6 Process materials Declaration FI Registration dossier DNEL: 0,67 mg/m³
according to REACH
2,4-dinitrotoluene (2,4-DNT) 121-14-2 Process materials Prohibited with LR REACH Annex XIV SVHC (subject to authorization), sunset date:
204-450-0 exception 2015-08-21
2,6-di-tert-butyl p-cresol 128-37-0 Process materials Declaration FI
(butylhydroxytoluene (BHT)) 204-881-4
2-amino-2-methyl-1-propanol (AMP) 124-68-5 Water-miscible process Declaration FI Ensure the absence of 2-methylamino-2-methyl-
204-709-8 materials 1-propanol (MAMP) (27646-80-6); a low-MAMP
variant < 0,8 % is also available
2-bromo-2-nitropropane-1,3-diol 52-51-7 Water-miscible process Prohibited LR TRGS 611 ≤ 10 ppm
200-143-0 materials
2-butanonoxim 96-29-7 Process materials Declaration FI DBL 8585
2-hexyl-1-decanol 2425-77-6 Water-miscible process Declaration FI
219-370-1 materials
2-methoxyethyl acetate 110-49-6 Solvents Prohibited LR Regulation (EC) No. Repr. 1B with H360-FD
203-772-9 1272/2008
2-methyl-4-isothiazolin-3-one MIT (MI) 2682-20-4 Preservatives and Declaration FA 28th ATP to Regulation < 0,3 % (HPLC/DC)
(2-methyl-2,3-dihydroisothiazol-3-one) 220-239-6 disinfecting cleaning (EC) No. 1999/45/EC to be targeted: Authorization only as biocide (no pre-
agents prohibition conservation of water-miscible products);
≤ 10 ppm exceptions possible in agreement with
the Materials Engineering department.
Application concentration of mixture
CMI/MI 3:1 CAS 55965-84-9 < 15 ppm (wg)
2-methylamino-2-methyl-1-propanol 27646-80-6 Water-miscible process Prohibited LR TRGS 611 < 0,2 % Contamination in 2-amino-2-methyl-1-propanol
(MAMP) 220-239-6 materials (AMP) (124-68-5), see there
2-octyl-2H-isothiazol-3-one 26530-20-1 Process materials Declaration FA 24th ATP to Regulation < 10 % Application concentration of 0,05 %
247-761-7 (EC) No. 1999/45/EC shall not be exceeded.
2-phenoxy-1-propanol 4169-04-4 Preservatives and Prohibited FI Shall no longer be used as a biocidal agent
disinfecting cleaning for PT 13 due to lack of a dossier according
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agents to EC biocide directive

2-phenoxyethanol (phenyl glycol) 122-99-6 Process materials Declaration FI
204-589-7
4-(2-nitrobutyl)-morpholine 2224-44-4 Water-miscible process Prohibited LR TRGS 611 ≤ 10 ppm Shall no longer be used as a biocidal agent
materials for PT 13 due to lack of a dossier according
to EC biocide directive
4,4’ dimethyloxazolidine 51200-87-4 Preservatives and Prohibited LR TRGS 611 < 0,2 %
257-048-2 disinfecting cleaning
agents

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Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
4,4’-diaminodiphenylmethane (MDA) 101-77-9 Process materials Prohibited with LR REACH Annex XIV SVHC (subject to authorization), sunset date:
202-974-4 exception 2014-08-21
4,5-dichloro-2-methyl-4-isothiazolin-3-one, 26542-23-4 Preservatives and Prohibited ≤ 10 ppm (HPLC/DC)
4,5-dichloro-2-methyl-1,2-thiazol-3-one disinfecting cleaning
agents
5-chloro-2-methyl-4-isothiazolin-3-one (CMI), 26172- 55-4 Preservatives and Prohibited with 28th ATP to Regulation ≤ 10 ppm application concentration
5-dichloro-2-methyl-1,2-thiazol-3-one disinfecting cleaning exceptions (EC) No. 1999/45/EC mixture of related products permitted only with
agents DIN EN ISO 15088 acute toxicity > 10 ppm in waste water (zebrafish
eggs (Danio rerio)
(HPLC/DC)
exceptions possible in agreement with the
Materials Engineering department (authorization
only as biocide (no pre-conservation of water-
miscible products)).
Application concentration of mixture CMI/MI 3:1
CAS 55965-84-9 to be below 15 ppm (R43
labeling) (wg)
5-chloro-2-methyl-4-isothiazolin-3-one: 55965-84-9 Preservatives and Declaration FA 28th ATP to Regulation ≤ 15 ppm application concentration
2-methyl-4-isothiazolin-3-one; disinfecting cleaning (EC) No. 1999/45/EC Risk of skin sensitization
CMI:MI (mixture) agents Not suitable for pre-conservation
5-tert-butyl-2,4,6- trinitro-m-xylene 81-15-2 Process materials Prohibited with LR REACH Annex XIV SVHC (subject to authorization), sunset date:
(musk xylene) 202-974-4 exception 2014-08-21
Adsorbable organic halogen compounds Process materials Prohibited with Determination of test Compounds influencing the AOX value in waste
(AOX) exceptions method according water shall not be present in the fresh product
to indirect discharger or formed during storage or use.
regulation (test in waste Exceptions specified in agreement
water) with the Materials Engineering department
AbwV Annex 40 For waste water limit value, see AbwV
Amides releasing secondary amines Process materials Prohibited LR TRGS 611 ≤ 0,2 %
Amines, volatile Process materials Declaration FI DBL 8585
Amines, primary and tertiary, free and Process materials Declaration FI
masked, with and without labeling
requirement
Amines, secondary, Process materials Prohibited with TRGS 552 Exceptions specified in agreement
which do not form carcinogenic N- exceptions TRGS 611 with the Materials Engineering department
nitrosamines of cat. 1A or 1B,
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but a CMR substance of cat. 2

Amines, secondary, which form Process materials Prohibited LR TRGS 611 ≤ 0,2 %
carcinogenic N-nitrosamines of cat. 1A
or 1B
Antimony and antimony compounds Process materials Prohibited ≤ 0,01 % Exceptions for non-water-miscible process
(determined as Sb) with exceptions to be targeted materials to be specified in agreement
in the short term: with the Materials Engineering department
≤ 10 ppm
Aromatics, total Process materials Declaration IR according to Brandes < 14 %
(DIN 51413 Part 3)
DIN 51378 < 10 %

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Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
Azo dyes Process materials Prohibited Azo dyes can release cancer-causing aromatic
amines by the reductive cleavage of azo groups.
Barium and barium compounds Non-water-miscible Declaration FI DIN 51391- 1:1997-08 ≤ 2 ppm Barium salts with the exception of barium sulfate.
(determined as Ba) process materials (AAS) Limit values may be exceeded in individual cases
DIN 51391- 2 (XRS) in agreement with the Materials Engineering
DIN 51391- 3 (ICP) department provided that no waste water
AbwV contamination occurs when used as intended
Barium and barium compounds Water-miscible process Prohibited DIN 51391- 1:1997-08 ≤ 10 ppm
(determined as Ba) materials (AAS) ≤ 2 ppm (wg)
DIN 51391-3 (ICP)
AbwV
Base oils, not sufficiently severely refined Process materials Prohibited Requirement: base oils sufficiently severely
refined (e.g. "severely hydrotreated";
"severely solvent-refined")
Benzo-(a)-pyrene (BaP) 50-32-8 Process materials Prohibited TRGS 905 ≤ 3 ppm Method: IP 346/92
(as indicator substance for polycyclic TRGS 910
aromatic HC (PAH/PAK)) 21st ATP Regulation
(EC) No. 1999/45/EC
29th ATP Regulation
(EC) No. 1999/45/EC
Benzene 71-43-2 Process materials Prohibited with LR GefStoffV, Annex. IV, ≤ 10 ppm Exceptions specified in agreement
200-753-7 exceptions No. 4 with the Materials Engineering department
REACH Annex XVII
Benzotriazole/derivates 95-14-7 Process materials Declaration FA ≤1% In exceptional cases higher contents (< 10 %)
202-394-1 possible following agreement with the Materials
Engineering department. Substituted
benzotriazoles: to be declared.
Benzotriazoles, substituted Process materials Declaration FA ≤1% In exceptional cases higher contents (< 10 %)
e.g. tolyltriazole 29385- 43-1 possible following agreement with the Materials
Engineering department. Substituted
benzotriazoles: to be declared.
Benzyl alcohol 100-51-6 Water-miscible process Prohibited Only for cleaning agents and cleaning additives.
materials
Benzyl butyl phthalate (BBP) 85-68-7 Process materials Prohibited LR REACH Annex XIV ≤ 10 ppm SVHC (subject to authorization), sunset date:
201-622-7 2015-02-21
Bis(2-ethylhexyl) phthalate (DEHP) 117-81-7 Process materials Prohibited LR REACH Annex XIV ≤ 10 ppm SVHC (subject to authorization), sunset date:
: Michal Tomek, 2020-01-16

204-211-0 2015-02-21
Bis(2-methoxyethyl) phthalate 117-82-8 Process materials Prohibited REACH candidate list ≤ 10 ppm SVHC
204-212-6
Lead and lead compounds Process materials Prohibited with DIN 51827:1989-01 ≤ 10 ppm Determination of exceptions in agreement with
(determined as Pb) exceptions (AAS) for lubricating greases and the Materials Engineering department
greases DBL 6864.20: No exceptions for water-miscible cooling
< 0,5 % lubricants
to be targeted
in the short term:
< 0,1 %

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Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
Lead and lead compounds Water-miscible process Prohibited DIN EN 13723 ≤ 10 ppm
(determined as Pb) materials
Lead chromate 7758-97-6 Process materials Prohibited with LR REACH Annex XIV SVHC (subject to authorization), sunset date:
231-846-0 exception 2015-05-21
Lead chromate molybdate sulfate red 12656-85-8 Process materials Prohibited with LR REACH Annex XIV SVHC (subject to authorization), sunset date:
(C. I. Pigment Red 104) 235-759-9 exception 2015-05-21
Lead sulfochromate yellow 1344-37-2 Process materials Prohibited with LR REACH Annex XIV SVHC (subject to authorization), sunset date:
(C.I. Pigment Yellow 34) 215-693-7 exception 2015-05-21
Borates, others Process materials Declaration FA
Boric acid 10043-35-3 Process materials Declaration FI 1st ATP to Regulation ≤ 5,5 % SVHC,
233-139-2 (EC) No. 1272/2008 Declaration mandatory for 0,1 % or above
(11113-50-1 REACH candidate list
234-343-4)
Boric acid derivatives Process materials Declaration FI
Boric compounds, organic Process materials Declaration FI
Butyldiglycol (2-(2-butoxyethoxy)-ethanol) 112-34-5 Water-miscible process Declaration FI
203-961-6 materials
Butyl glycol (2-butoxyethanol) 111-76-2 Water-miscible process Declaration FI
203-905-0 materials
Carbendazim (2- 10605-21-7 Process materials Prohibited 29th ATP to Regulation ≤ 0,1 % Shall no longer be used as a biocidal agent
(Methoxycarbonylamino)benzimidazole) 234-232-0 (EC) No. 1999/45/EC for PT 13 due to lack of a dossier according
to EC biocide directive.
Chlorobenzene 108-90-7 Preservatives and Prohibited with ≤ 10 ppm Exceptions possible in agreement with the
203-628-5 disinfecting cleaning exceptions Materials Engineering department
agents
Chloroacetic acid amide 79-07-2 Preservatives and Prohibited ≤ 10 ppm (HPLC/DC)
(2-chloracetamide) 201-174-2 disinfecting cleaning
and conversion products agents
Chlorine content (total chlorine) Process materials Declaration DIN ISO 15597 (XRS) ≤ 0,1 % Exceptions: chlorinated paraffins (see below)
(for < 0,1 % chlorine) Other exceptions determined in agreement with
the Materials Engineering department:
- Drawing lubricants < 0,2 %
- Pre-conserved fully synthetic water-miscible
cooling lubricants < 0,2 %
Chlorinated paraffins, 85535-84-8 Process materials Prohibited LR ChemVerbotsV SVHC
short-chain (C10-C13) (SCCPs) REACH candidate list
: Michal Tomek, 2020-01-16

Directive 2006/11/EC
Chlorinated paraffins, 85535-86-0 Process materials Declaration FI AltölV ≤ 0,2 %
long-chain (from C18) (LCCPs)
(chloroalkanes)
Chlorinated paraffins, 85535-85-9 Process materials Declaration FI 30th ATP to Regulation ≤ 0,2 % Application only where technically necessary
medium-chain (C14-C17) (MCCPs) (EC) No. 1999/45/EC (e.g. forming stainless steel) and as per
1st ATP to Regulation agreement.
(EC) No. 1272/2008 During machining critical due to higher aerosol
AltölV formation.

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Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
Distillates from petroleum, hydrotreated, 64742-47-8 Process materials Declaration FI
light
Distillates from petroleum, hydrotreated, 64742-48-9 Process materials Declaration FI
heavy
Diacetone alcohol (4-hydroxy-4-methyl- 123-42-2 Solvents Prohibited
pentan-2-one) 204-626-7
Diarsenic pentaoxide 1303-28-2 Process materials Prohibited with LR REACH Annex XIV SVHC (subject to authorization), sunset date:
215-116-9 exception 2015-05-21
Diarsenic trioxide 1327-53-3 Process materials Prohibited with LR REACH Annex XIV SVHC (subject to authorization), sunset date:
215-481-4 exception 2015-05-21
Dibutyl phthalate (DBP) 84-74-2 Process materials Prohibited LR REACH Annex XIV ≤ 10 ppm SVHC (subject to authorization), sunset date:
(di-n-butyl phthalate) 201-557-4 2015-02-21
Dicyclohexylamine 101-83-7 Process materials Declaration TRGS 552 Use in high-temperature processes, e.g.
202-980-7 TRGS 611 quenching processes (temperature in the outlet
≥ 30 °C) only possible in agreement between the
Materials Engineering department and the work
safety unit.
Diethanolamine (DEA) or other secondary 111-42-2 Process materials Prohibited FI TRGS 611 ≤ 0,2 % DEA For water-miscible cooling lubricants
alkanolamines 203-868-0 or other secondary and forming (limit according to TRGS 611).
amines These limit values also apply to secondary
amines which may form under application
conditions (e.g. by hydrolysis) in significant
quantities from other compounds.

TRGS 615 ≤ 0,2 % DEA or For cleaning agents and other materials,
other secondary in particular water-miscible anti-corrosion agents,
amines VCI anti-corrosion agents.
According to TRGS 615, these limit values apply
to the individual raw materials of the mixture.
Diethylene glycol (2,2´-oxydiethanol) 111-46-6 Process materials Declaration FI
203-872-2
Diisobutyl phthalate (DIBP) 84-69-5 Process materials Prohibited LR REACH Annex XIV ≤ 10 ppm SVHC (subject to authorization), sunset date:
201-553-2 2015-02-21
Dipropylene glycol (1,1´-oxy-di-2-propanol, 110-98-5 Process materials Declaration FI Can impair ultrafiltration.
2,2´-dihydroxydipropyl ether)
Dipropylene glycol (isomer mixture) 25265-71-8 Process materials Declaration FI
: Michal Tomek, 2020-01-16

246-770-3
Dodecan-1-ol 112-53-8 Water-miscible process Declaration FI
203-982-0 materials
Odorants Process materials Declaration FI TRGS 401 Undesired as masking products. Odorants shall
nevertheless be declared irrespective
of the concentration. Skin-sensitizing effect
of some odorants
Ethylbenzene 100-41-4 Process materials Declaration FI DBL 8585,
MHLW (Japan)

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Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
Ethylendiamine 107-15-3 Water-miscible process Prohibited ≤ 10 ppm Declaration in the event of other process
203-468-6 materials materials.
Ethylenediaminetetraacetic acid (EDTA) 60-00-4 Process materials Prohibited AbwV Annex 40 ≤ 1 ppm Assurance of safe levels in waste water
200-449-4 by values below the detection limits
EDTA and its salts (e.g. sodium Process materials Prohibited AbwV Annex 40 ≤ 1 ppm Assurance of safe levels in waste water
ethylenediaminetetraacetate / 64-02-8 by values below the detection limits
tetra sodium salt EDTA)
Colorants Process materials Declaration FI
Fatty alcohol ethoxylate C12-C15, Process materials Declaration FI
linear with <5 EO
Fatty alcohol ethoxylate C12-C15, linear, Process materials Declaration FI
5-10 EO
Formaldehyde (free) as contamination 50-00-0 Preservatives and Prohibited with FA Regulation (EC) No. Justified use possible in agreement with Materials
or through release from formaldehyde 200-001-8 disinfecting cleaning exceptions 1272/2008 Engineering department and environmental
depot substances agents 6th ATP to CLP and work safety units. Residual content of free
Regulation formaldehyde in biocidal product shall then
be declared.
Total aromatics content Process materials Declaration FI IR according to Brandes
(DIN 51413-3:1988-10)
≤ 14 %
DIN 51378 ≤ 10 %
Glutaraldehyde 111-30-8 Process materials Prohibited 25th ATP to Regulation ≤ 10 ppm Shall no longer be used as a biocidal agent
203-856-5 (EC) No. 1999/45/EC for PT 13 due to lack of a dossier according
to EC biocide directive
Glycerol 56-81-5 Process materials Declaration FI
200-289-5
Halogenated hydrocarbons Process materials Prohibited ≤ 10 ppm
(tetrachloroethene, 1, 1, 1 trichloroethane,
dichloromethane, perchloroethylene, CFC)
Halogenated phenols (in particular Process materials Prohibited ≤ 10 ppm Chromatographic
trichlorophenol, tetrachlorophenol, (HPLC/DC)
pentachlorophenol )
Hexabromocyclododecane (HBCDD) 3194-55-6 Process materials Prohibited with LR REACH Annex XIV SVHC (subject to authorization), sunset date:
25637-99-4 exception 2015-08-21
134237-50-6
(alpha)
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134237-51-7
(beta)
134237-52-8
(gamma)
Hexadecan-1-ol 36653-82-4 Water-miscible process Declaration FI
253-149-0 materials
Hexane 110-54-3 Process materials Declaration FA Regulation (EC) No. <5%
203-777-6 1272/2008, Annex VI
Hexylene glycol (2-methyl-2,4-pentanediol) 107-41-5 Water-miscible process Declaration FI
203-489-0 materials

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Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
Hydrazine Process materials Prohibited REACH candidate list ≤ 10 ppm
- anhydrous 302-01-2 substance
- hydrazine solution 64 % 7803-57-8
- hydrazine solution 55 % 10217-52-4
206-114-9
Hydroquinone (1,4-dihydroxybenzene) 123-31-9 Process materials Declaration FI DBL 8585
Iodocarbamates Preservatives and Declaration FI
e.g. 3-iodo-2-propynyl butylcarbamate 55406-53-6 disinfecting cleaning
(IPBC) (IPBC) agents
Isocyanates Process materials Declaration FI DBL 8585
Isothiazolinones (all) Preservatives and Declaration Regulation (EC) No. Generally not authorized for skin cleaning agents.
disinfecting cleaning /Prohibited 1272/2008
agents
Isotridecanol (isotridecan-1-ol) 27458-92-0 Water-miscible process Declaration FI
248-469-2 materials
Complexing agents, relevant for waste Process materials Declaration FI
water treatment (except EDTA)
Copper and copper compounds Process materials Prohibited with DIN 51391-1:1997-08 ≤ 10 ppm Exceptions for non-water-miscible process
(determined as Cu) 7440-50-8 exceptions (AAS) materials to be specified in agreement
231-159-6 with the Materials Engineering department
Mesityl oxide (4-methyl-3-penten-2-one) 141-79-7 Solvents Prohibited
205-502-5
Metals - other metals than the ones Process materials Prohibited with ≤ 10 ppm Exceptions specified in agreement with the
indicated here with atomic number >20 exceptions Materials Engineering department
Methanol 67-56-1 Solvents Prohibited with ≤ 10 ppm Exceptions (< 3 %) to be determined in
200-659-6 exceptions agreement with the Materials Engineering
department
Methylene-bis-morpholine 5625-90-1 Process materials Prohibited LR TRGS 611 ≤ 0,2 %
(bis(morpholino)methane) 227-062-3
Monoethanol amine (MEA) (free) 141-43-5 Process materials Declaration FI TRGS 907 929 For > 1 % a skin protection study shall
205-483-3 be presented.
The proportion of free MEA shall be declared in
each case and agreed with the Materials
Engineering department, so that the MAK value
(maximum concentration at the workplace)
for methanolamine is not exceeded where
: Michal Tomek, 2020-01-16

the material is used in central systems

(volume < 500 m³).
Recommended inhibitor according to TRGS 611
Morpholine and morpholine compounds 110-91-8 Process materials Prohibited TRGS 611 ≤ 0,2 %
releasing morpholine (morpholine)
N-based formaldehyde donors (N formals) Preservatives and Declaration FI Free formaldehyde only permitted in equilibrium
disinfecting cleaning concentration.
agents NMR spectroscopy
Constituents and contents to be declared.

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Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
N-based formaldehyde donors (N formals), 7747-35-5 Preservatives and Declaration FI Free formaldehyde only permitted in equilibrium
e.g. 5-ethyl-3,7-dioxa-1-aza-bicyclo[3.3.0]- disinfecting cleaning concentration.
octane agents NMR spectroscopy
Constituents and contents to be declared.
N-based formaldehyde donors (N formals), 66204-44-2 Preservatives and Declaration FI Free formaldehyde only permitted in equilibrium
e.g. N,N-methylene-bis(5-methyl- disinfecting cleaning concentration.
oxazolidine agents NMR spectroscopy
Constituents and contents to be declared.
N,N-dimethylformamide 68-12-2 Solvents Declaration FI Regulation (EC) No. ≤ 0,5 %
200-679-5 1907/2006 (REACH)
Regulation (EC) No.
1272/2008
Sodium pyrithione (Na salt) 3811-73-2 Preservatives and Declaration FI ≤ 5 % (wm)
223-296-5 disinfecting cleaning
15922-78-8 agents
240-062-8
N-butyl-1,2-benzisothiazolin-3-one (BBIT) 4299-07-4 Preservatives and Declaration FI
disinfecting cleaning
agents
N-cyclohexyl-hydroxydiazen-1-oxide, 66603-10-9 Process materials Prohibited GefStoffV < 10 ppm Shall no longer be used as a biocidal agent
potassium salt for PT 13 due to lack of a dossier according
to EC biocide directive
Nitrosating agent
Nickel and nickel compounds Process materials Prohibited with 1st ATP to Regulation ≤ 10 ppm Exceptions in agreement with the Materials
(determined as Ni) exceptions (EC) No. 1272/2008 Engineering department
Nitrates Preservatives and Prohibited < 50 ppm (wm)
disinfecting cleaning
agents
Nitrilotriacetic acid (NTA) 139-13-9 Process materials Prohibited ≤ 1 ppm
and its salts (NTA)
205-355-7
(NTA)
Nitrite and compounds releasing nitrites Process materials Prohibited with GefStoffV, Annex II, No. ≤ 20 mg nitrite/l (wg) application concentration ;
exceptions 4 In VCI materials (temporary corrosion protection)
TRGS 611 in agreement with Materials Engineering
department permitted.
: Michal Tomek, 2020-01-16

In products with vapor corrosion inhibitors (VCI)

no more than 1,0 % nitrite or max. 0,1 % of other
nitrosation agents shall be present.
Merckoquant/Reflectoquant (measuring method)
Nitrosamines Process materials Prohibited TRGS 611
TRGS 615
VKIS-VSI-IGM
List of Substances
N-methylol-chloracetamide 2832-19-1 Preservatives and Prohibited ≤ 10 ppm
220-598-9 disinfecting cleaning
agents

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Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
N-methyl-2-pyrrolidone (NMP) 872-50-4 Process materials Declaration FI
N-nitroso-diethanolamine 1116-54-7 Process materials Prohibited TRGS 611 < 0,1 ppm Test method according to Sommer,
214-237-4 TRGS 615 Eisenbrand (gas chromatography with thermal
VKIS-VSI-IGM energy analyzer)
List of Substances
N-nitroso compounds Process materials Prohibited TRGS 611 Until further notice, N-nitroso-diethylamine shall
TRGS 615 be regarded as indicator substance.
VKIS-VSI-IGM
List of Substances
Nonylphenol and nonylphenol ethoxylates 25154-52-3 Process materials Prohibited LR Regulation (EC) ≤ 0,1 % SVHC
(nonylphenol) No. 1272/2008
9016-45-9 Regulation (EC)
(nonylphenol No. 552/2009 (REACH
ethoxylate) Amendment Regulation)
Directive 2003/53/EC
Directive 2006/11/EC
REACH Annex XVII
N-phenyl-1-naphthylamine 90-30-2 Process materials Declaration FA ≤1%
(N-phenyl-alpha-naphthylamine) 201-983-0 to be targeted:
0,2 %
N-phenyl-2-naphthylamine 135-88-6 Process materials Prohibited Regulation (EC) ≤ 10 ppm
(n-phenyl-beta-naphthylamine) 205-223-9 No. 1272/2008
O-based formaldehyde donors (O formals) Preservatives and Declaration FI Free formaldehyde only permitted in equilibrium
disinfecting cleaning concentration.
agents NMR spectroscopy
Constituents and contents to be declared.
O-based formaldehyde donors 14548-60-8 Preservatives and Declaration FI Free formaldehyde only permitted in equilibrium
(O formals), e.g. benzyl alcohol- disinfecting cleaning concentration.
mono(poly)hemiformal agents NMR spectroscopy
Constituents and contents to be declared.
O-based formaldehyde donors 3586-55-8 Preservatives and Declaration FI Free formaldehyde only permitted in equilibrium
(O formals), e.g. 1,6-dihydroxy-2, disinfecting cleaning concentration.
5-dioxahexane agents NMR spectroscopy
Constituents and contents to be declared.
Octylphenol 140-66-9 Process materials Prohibited with ≤ 10 ppm Exceptions possible in agreement with the
exceptions Materials Engineering department
: Michal Tomek, 2020-01-16

Octylphenol ethoxylates Process materials Declaration FI Nonylphenol ethoxylates shall not be replaced
with octylphenol ethoxylates (recommendation
of the German Federal Environment Agency)
Oleic acid 112-80-1 Process materials Declaration FI
204-007-1
o-phenylenediamine 95-54-5 Process materials Prohibited ≤ 10 ppm
202-430-6
o-phenylphenol (OPP) 90-43-7 Process materials Declaration Provided no change to the current classification.
(biphenyl-2-ol)
o-phenylphenol, Na salt 132-27-4 Process materials Declaration Provided no change to the current classification.

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Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
o-phenylphenol, K salt 13707-65-8 Process materials Declaration Provided no change to the current classification.
Orthoboric acid, Na salt 13840-56-7 Process materials Declaration FA 1st ATP to Regulation ≤ 4,5 %
(EC) No. 1272/2008
REACH candidate list
Orthoboric acid, other salts Process materials Declaration FA
(e.g. potassium) 20786-60-1
p-(tert-butyl)benzoic acid 98-73-7 Process materials Prohibited Regulation (EC) ≤ 10 ppm
(4-tert-butylbenzoic acid) 202-696-3 No. 1272/2008
Polycyclic aromatic hydrocarbons Process materials Declaration FA 21st ATP to Regulation < 3 % (DMSO Base oils sufficiently severely refined
(EC) No. 1999/45/EC extract) (e.g. "severely hydrotreated"; "severely solvent-
29th ATP to Regulation refined"). Besides the total polycyclic aromatic
(EC) No. 1999/45/EC hydrocarbons, the DMSO extract normally
also contains fractions of other aromatic
hydrocarbon compounds that are relevant
with regard to occupational medicine.
IP 346/92 obligatory test method
Polycyclic aromatic hydrocarbons, Process materials Prohibited ≤ 0,1 % US-EPA 610 (test method)
carcinogenic (16 polycyclic aromatic
hydrocarbons acc. to US-EPA 610)
PCB content 1336-36-3 Process materials Prohibited AltölV ≤ 4 ppm DIN 51527-1:1987-05 (test method)
polychlorinated biphenyls - PCB 215-648-1
PCT content (61766-33-6) Process materials Prohibited AltölV ≤ 4 ppm
polychlorinated terphenyls - PCT 61788-33-8
Antibiotics/chemotherapeutics used Water-miscible process Prohibited ≤ 10 ppm
pharmaceutically/in human health materials
Phenol and phenol derivates 108-95-2 Process materials Prohibited with Regulation (EC) ≤ 10 ppm Chromatographic (HPLC/DC)
(phenol) exceptions No. 1272/2008 Exceptions for phenol derivates to be determined
in agreement with the Materials Engineering
department
Phenyldiamine, (N-substit.) Process materials Declaration FA Regulation (EC) ≤1%
(Phenylenediamine) No. 1272/2008 to be targeted:
Regulation (EC) 0,1 %
No. 552/2009 (REACH
Amendment Regulation)
Phthalates – chain length up to and Process materials Prohibited with REACH Annex XIV Prohibited for new approvals, exceptions in
including C11, branched and linear exceptions REACH Annex XVII agreement with the Materials Engineering
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REACH candidate list department and environmental and work safety

REACH CoRAP units;
REACH PACT (RMOA) Declaration in the event of old materials.
DFG classification
U.S. EPA Chemical
Action Plan
Phthalates – all other phthalates Process materials Declaration FA
Piperazine 110-85-0 Process materials Prohibited LR TRGS 611 ≤ 0,2 %
203-808-3
Polybrominated difurans (PBDF) Process materials Declaration FI DBL 8585

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Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
Polychlorinated dibenzodioxins and furans; 1746-01-6 Process materials Prohibited TRGS 905 ≤ 2 ppm in raw
main component 2,3,7,8-TCDD "dioxin“; TRGS 557 materials
total "TEQ"
Polyethylene glycols (average molar mass 25322-68-3 Process materials Declaration FI
200-400 or 600) 500-038-2
Polyfumaric acid dibutyl ester Process materials Declaration FI DBL 8585
Poly-α-olefins 68649-12-7 Process materials Declaration FI
p-tert-butoxybenzoic acid 13205-47-5 Process materials Prohibited ≤ 10 ppm
Sulfur hexafluoride 2551-62-4 Process materials Prohibited < 1 ppm The product shall not be contained or used in test
219-854-2 gases or as a production auxiliary in foundries
(cover of molten metals) (climate protection)
Heavy metals and heavy metal Process materials Prohibited with AbwV Annex 40 May be contained in turbine oils, greases,
compounds (with the exception of Cu, Ba, exceptions corrosion protection, among others. Exceptions
Zn, Sn) in agreement with the Materials Engineering
department
Silver 7440-22-4 Process materials Declaration FI
Silver compounds, inorganic Process materials Declaration FI
Silicone oils/Polydimethylsiloxanes 63148-62-9 Water-miscible process Prohibited with Organo-modified siloxanes normally authorized
(PDMS) materials exceptions (agreement with Materials Engineering
department).
Application related test methods of Materials
Engineering department, Process Material
Management team
Siloxanes, organomodified Declaration Use only in consultation with Materials
Engineering department
Other halogenated hydrocarbons Process materials Prohibited ≤ 10 ppm Exceptions for legacy products to be specified
or other halogenated compounds in special cases in agreement with the Materials
Engineering department
Other substances which may complex Process materials Prohibited with Only those complexing agents which are
heavy metals exceptions biodegradable or degradable by usual waste
water treatment methods are authorized.
The complexing effect shall not impair the metal
hydroxide precipitation of heavy metals during
waste water treatment. Relevant evidence shall
be submitted.
Exceptions in agreement with the Materials
: Michal Tomek, 2020-01-16

Engineering department
Tall oil distillates (e.g. DTO) 8002-26-4 Process materials Declaration FI Formation of skin-sensitizing oxidation products
(DTO)
Tetraborate, sodium salt 1330-43-4 Water-miscible process Declaration FA 1st ATP to Regulation Relevant statutory SVHC
12179-04-3 materials (EC) No. 1272/2008 concentration limit
1303-96-4 REACH candidate list value to be
1332-28-1 observed
Tetraborate, other salts 12045-78-2 Water-miscible process Declaration FA Registration dossier in analogy Manufacturer's classification: toxic
(e.g. potassium) 1332- 77-0 materials according to REACH with tetraborate, for reproduction cat. 2 [CLP Regulation]
sodium salt

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Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
Tetradecanol 112-72-1 Water-miscible process Declaration FI
204-000-3 materials
Thiabendazole 148-79-8 Process materials Prohibited LR Shall no longer be used as a biocidal agent
(2-(4'-thiazolyl)benzimidazole) 205-725-8 for PT 13 due to lack of a dossier according
to EC biocide directive
Animal sources Process materials Declaration FI
Toluene 108-88-3 Solvents Prohibited with Regulation (EC) ≤ 0,01 % Exceptions shall be specified in agreement
203-625-9 exception No. 1272/2008 to be targeted with the Materials Engineering department
Regulation (EC) in the long term: in special cases:
No. 552/2009 (REACH ≤ 10 ppm - Clear coats ≤ 0,1 %
Amendment Regulation)
Trichloroethylene 79-01-6 Solvents Prohibited LR REACH Annex XIV SVHC (subject to authorization), sunset date:
201-167-4 2016-04-21
Triethanolamine (2,2´,2´´-nitrilotriethanol) 102-71-6 Process materials Declaration FI
203-049-8
Triethylene glycol 112-27-6 Process materials Declaration FI
(2,2´-(ethylendioxy) diethanol) 203-953-2
Tri-o-cresyl phosphates: 78-30-8 Process materials Prohibited with Regulation (EC) No. ≤ 0,2 % Exceptions to be determined in agreement
mixture with esterified o-cresol (o,o,o-) exceptions 1272/2008 to be targeted: with the Materials Engineering department
201-103-5 replacement
by m/p- cresyl
compounds
(< 5 %)
Tricresyl phosphates: mixture with 78-32-0 Process materials Declaration FA <5%
esterified m/p-cresol (p,p,p-)
201-105-6
Tris(2-chloroethyl) phosphate (TCEP) 115-96-8 Process materials Prohibited with LR REACH Annex XIV SVHC (subject to authorization), sunset date:
204-118-5 exceptions 2015-08-21
Tris(hydroxymethyl)nitromethane 126-11-4 Preservatives and Prohibited with TRGS 611 ≤ 20 mg nitrite/l In VCI materials (temporary corrosion protection)
disinfecting cleaning exceptions (wg) in agreement with Materials Engineering
agents department, Process Material Management team,
permitted.
In products with vapor corrosion inhibitors (VCI)
no more than 1,0 % nitrite or max. 0,1 % of other
nitrosation agents shall be present.
Merckoquant/Reflectoquant (measuring method)
: Michal Tomek, 2020-01-16

Vinyl acetate 108-05-4 Process materials Declaration FI DBL 8585

Xylenes, isomer mixture, ortho, meta, para 1330-20-7 Solvents Declaration FA Regulation (EC) Xylenes total Exceptions for legacy products to be specified
95-47-6 (o) No. 1272/2008, < 12,5 % in special cases in agreement with the Materials
108-38-3 (m) Annex VI Engineering department
106-42-3 (p)
Zinc and zinc compounds Non-water-miscible Prohibited with ≤ 0,1 % Exceptions: DBL 6880.00, and in individual cases
(determined as Zn) process materials exceptions to be targeted in in agreement with the Materials Engineering
the short term: department provided that no waste water
≤ 0,02 % contamination occurs when used as intended
to be targeted: Test method: DIN 51391- 2 (XRS)
0,01 % DIN 51391-3 (ICP)

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DBL 6714:2015-09, page 22

Substance CAS No. Group Classification Reason Legal text, sources, Limit value Remark
EC No. code remarks (as-supplied
condition)
Zinc and zinc compounds Water-miscible process Prohibited ≤ 10 ppm Test method: DIN 51391-1 (AAS)
(determined as Zn) materials DIN 51391-3 (ICP)
Tin and tin compounds (determined as Sn) Process materials Prohibited with ≤ 0,01 % Exceptions for non-water-miscible process
exceptions to be targeted materials to be specified in agreement
in the short term: with the Materials Engineering department
≤ 10 ppm
: Michal Tomek, 2020-01-16

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