Dawson College
Solution Stoichiometry Laboratory #2
Fatima Ezzahra Boutannoura
2344428
Partner : Marwa Bouladjine
Angélique Fortier
202-NYA-05 section 21
Date performed: September 26th, 2023.
Date submitted: October 03rd, 2023.
Calculated Data:
1- Mass of dry product: 38.5560g – 38.3086g = 0,2484g
2- Moles of CaCl2 used: 0.2728mol/L x 0.0100L = 2.73x10^-3 mol
3- Moles of Na2CO3 used: 0.3330mol/L x 0.0103L = 3.43x10^-3 mol
4- Limiting reagent: CaCl2
5- Calculated mass of excess reagent remaining in the mixture after reaction:
−3 1 mol N a 2 CO 3 −3
a) 2.73 x 10 mol CaCl2 × =2.73 x 10 m ol Na 2 CO 3
1mol CaCl 2
b) 3. 43 x 10−3 mol−2.73 x 10−3 mol = 7.0x10−4 mol Na2 CO 3
−4 1 05. 99 g
c) 7 .0 x 10 mol Na2 CO 3 × =0.0 7420 g Na2 CO 3
1 mol
=0.27 3 2 g CaCO3
−3 1 molCaCO 3 100 ,09 gCaCO 3
6- Theoretical yield: 2.73 x 10 mol × ×
1 molCaCl 2 1 molCaCO 3
0.2484 g
7- % Yield: ×100=90.9 %
0.27 32 g
Pre-Laboratory Questions:
1- M.E.: Na2CO3(aq) + CaCl2(aq) ⟶ CaCO3(s) + 2NaCl(aq)
C.I.E.: 2Na+(aq) + (CO3) -(aq) + Ca2+(aq) + 2Cl-(aq) ⟶ CaCO3(s) + 2Na+(aq) + 2Cl-(aq)
N.I.E.: Ca2+(aq) + (CO3) –(aq) ⟶ CaCO3(s) or CaCO3(aq) ⟶ CaCO3(s)
Spectators: 2Na+, 2Cl-
2- M=n/V a) n = 0.1437M x 0.01L b) V = 0.001437mol/0.0725M
n=MxV n = 0.001437 mol V = 1.04 x 10−4
V=n/M
10.00mL
=0.01L
Post-Laboratory Questions:
1- If it wasn’t completely dissolved, we would not have had the concentration of the solution we
wanted to work with.
2- a) We want to make sure that there is no water left in the precipitate because we only want the
mass of CaCO3
b) If we omit this step, the experimental yield would not have been a 100% CaCO3, but CaCO3
plus water, which will give us a wrong % yield.
3- a) Adding a little bit of water helps us get rid of the solvent and only leaves the solute which is
CaCO3.
b) If we don’t do this step, when the precipitate will dry it wouldn’t only be CaCO3, but the
solvent too. So, by “rinsing” it we remove what we don’t want to dry with the solute.
4- a) ethanol is a substance that evaporates more easily than water, so by adding it we want to
make sure that when we put the precipitate in the oven it will dry quickly and completely.
b) the precipitate will take too much time to dry, and it might not even dry completely.
5- a) it should have the same number of moles as Na2CO3: 3.43 x 10−3 mol
−3 110.98 g
3.43 x 10 mol × =0.3807 g of CaCl 2
1 mol
b) No it will not influence the theoretical yield, because changing the mass influence the
experimental yield, instead we could say that it will influence the percentage yield.