Atomic Models for Science Students
Atomic Models for Science Students
a) Understand the structure of an atom in terms of a positive nucleus and negative electrons.
b) Understand the terms: atomic number, mass number, and isotopes, and use them to
represent different nuclides.
c) Understand the methods by which electrons are ejected from matter/atoms and how these
electrons are useful.
This deals with nuclear model of an atom. Just as bricks are the building blocks of a wall, an atom is the
building block of any piece of matter. When atoms join together, they form molecules. Similarly, the
molecules join to form big structures/objects around you.
The structure of an atom: Atomic structure refers to the arrangement of sub-atomic elements in the
atom. An atom is the smallest particle of an element that can take part in a chemical reaction. An atom
consists of three subatomic particles and these are;
i) Neutrons.
ii) Protons.
iii) Electrons.
An atom is made of a central part called the nucleus around which electrons rotate. The nucleus is
positively charged because it consists of protons which are positively charged and neutrons which have
no charge. The properties of the subatomic particles of an atom are as shown in the table below.
Note: The number of protons in the nucleus is equal to the number electrons around the nucleus and
since they have opposite charges the atom has no charge.
Mass number [atomic mass], A: This is the total number of protons and neutrons in the nucleus of an
atom.
A=z+n
A
If an atom of an element X is represented as Z X
A=z+n
Where A = 35 and z = 17
n = 35 – 17
= 18 neutrons
= Atomic number, z
= 17 electrons
Charged atoms
Recall that an electron carries a negative charge while protons carries positive charge. These two
charges are equal but opposite. When an atom has the same number of electrons and protons, it has
equal number of negative charges and positive charges. Therefore, the charges cancel and the atom is
said to be neutral atom and at times, an atom may gain or lose electrons.
Note:
a) If an atom loses an electron, it now has more protons than electrons and therefore, it acquire a
positive charge
b) If an atom gains an electron, it will have more electrons than protons and therefore, it acquire a
negative charge
c) Always remember that a charged atom is called an ion
A charge of negative two means that the element has gained two electrons
These are atoms of the same element with the same atomic number but different mass numbers.
Therefore isotopes of an element have the same number of protons and electrons and different number
of neutron.
A nuclide
A nuclide is the nucleus of an atom of a specific isotope. A nuclide is characterized by the number of
positively charged protons (Z), neutrons (N) and the energy state of the nucleus. Examples of nuclides
include:
(i) Chlorine-37, an isotope of chlorine: the nucleus consist of 17 protons and 20 neutrons
(ii) Sodium-23, an isotope of sodium: the nucleus consists of 11 protons and 12 neutrons
(iii) Chlorine-35, an isotope of chlorine: the nucleus consists of 17 protons and 18 neutrons
Electrons are normally ejected or released from metal surfaces (emissive surfaces) whenever they gain
sufficiently enough energy to overcome the attractive inward force of the positively charged nucleus.
They do it through the following methods;
THERMIONIC EMISSION
This is the process by which electrons are emitted from the metal surface by application of heat energy.
Applications of thermionic emission: Thermionic emission can be applied in the following devices;
Diode valves.
X-ray tube.
The diode valve: This is an electrical device that conducts electricity in one direction only. There are two
types of diodes and these are
i) Semi-conductor diode.
ii) Vacuum diode.
Thermionic diode valve: This is an electrical device that uses the principle of thermionic emission. This
is sometimes referred to as vacuum diode. It consists of the following;
i) Evacuated glass envelope to prevent electrons from colliding with air molecules.
ii) The anode which accelerates electrons emitted from the heated cathode.
iii) The cathode which emits electrons thermionically.
iv) The heater which heats the cathode electrically.
Illustration
Action of a diode:
When no voltage is applied across the anode and the cathode, the emitted electrons stay around the
cathode.
If the anode, A is positive with respect to the cathode, C, the electrons from the space charge are
attracted to the anode and this causes the flow of current.
The number of electrons emitted from the cathode depends on the voltage, that is the higher the
voltage the higher the temperature and more electrons are emitted hence the higher the current in the
circuit. When the voltage increases the current increases until its maximum value, Ia where any
increase in voltage will not increase the current. This maximum value is called saturation current.
RECTIFICATION:
This is a process of changing an alternating current to direct current by use of a diode. There are two
types of rectification and these are;
During the first half of the cycle when A is positive with respect to B, the anode is positive with
respect to the cathode and diode conducts.
During the next half of the cycle when B is positive with respect to A, the anode is negative with
respect to the cathode and the diode does not conduct.
No electrons are attracted to the anode and therefore no current flows through R.
Hence current flows through R during only one half of the cycle when A is positive with respect to B.
The graph of voltage against time for half wave is as shown below.
MODE OF ACTION
During the first half of the cycle when A is positive with respect to B, diode D2 conducts and
diode D1 does not conduct but current flows through R.
During the next half of the cycle when B is positive with respect to A diode D1 conducts and
diode D2 does not conduct but current flows through R.
Hence current flows through R during both cycles and therefore both cycles are rectified giving a
full wave rectification.
b) Using four diodes:
MODE OF ACTION
During the positive half of the cycle when A is positive with respect to B diodes D1 &D3 conducts
and diodes D2 &D4 do not conduct but current flows through R.
During the negative half of the cycle when B is positive with respect to A diodes D2 &D4 conduct
and diodes D1&D3 do not conduct but current flows through R.
Hence current flows through R during both cycles and therefore both cycles are rectified giving a
full wave rectification.
The graph of voltage against time for full wave is as shown below
ii) The cathode: It emits electrons when heated electrically by the heater
iii) The grid: It controls the number of electrons reaching the anode and therefore controls the
brightness of the spot on the screen. The grid is at a negative potential with respect to the cathode
iv) The anodes: These are used to accelerate the electrons produced by the cathode. The anodes
are at a positive potential with respect to the cathode.
2. Deflecting system:
It consists of two pairs of metal plates and these are X – plates and Y – plates. The Y – plates are
horizontal and deflect the beam of electrons vertically while the X – plates are vertical and deflect
the beam of electrons horizontally.
4. Time base: This is a special circuit that generates p.d which rises steadily to a certain value and
falls rapidly to zero. This provides a saw-toothed voltage to X-plates. Hence the time base is used to
generate a saw-toothed voltage. Vertical motion of the beam causes the beam to travel across the
screen and horizontal motion of the beam provides the wave form of the beam on the screen.
Note:
The time base is connected to the X – plates and causes the spot to move from left to right called
linear sweep and the spot returns to the left before it starts the next sweep called fly back.
vii) No potential difference is applied to the Y-plates and time base off
Uses of C.R.O:
It is very accurate.
It is bulky.
It is expensive.
It is portable.
It is cheap.
X – RAYS:
These are short wave length electromagnetic waves which are produced when cathode rays are
stopped by a heavy metal.
A low voltage is applied across the cathode and electrons are emitted thermionically and a concave
focusing cathode focuses the electrons onto the target.
The high potential difference applied across the cathode and the anode accelerates electrons across
the vacuum and on reaching the target, 99% of the kinetic energy of electrons is converted into heat
while 1% of kinetic energy of elections is turned into X–rays.
The heat generated at the target is cooled by means of copper cooling fins or running water and then
conducted away by conduction and radiation.
The X – ray tube is evacuated to prevent cathode rays from colliding with air particles [air resistance]
hence allowing free movement of electrons in the tube.
The tungsten is used because it has a high melting point that can withstand the heated generated
when electrons hit the target.
Intensity is the strength or power of X – rays. The intensity of X – rays in an X – ray tube is proportional
to the number of electrons reaching the target. The number of electrons produced is determined by the
filament current. Therefore the higher the filament current the higher the intensity of the X – rays since
more electrons are emitted with high filament current.
Penetration power is the ability to enter matter. The penetration power of X – Rays depends on the
kinetic energy of electrons reaching the target. The penetration power of X – Rays is determined by the
high potential difference across the X – Ray tube. The higher the accelerating voltage the faster the
electrons produced and the greater the kinetic energy of electrons hence the higher the penetration
power of X–Rays produced.
Types of X- Rays:
i) Soft X – rays.
ii) Hard X – rays.
Soft X– Rays:
These are types of X – rays produced when a low potential difference is used.
Hard X – Rays:
These are types of X – rays produced when a high potential difference is used.
Properties of X – rays:
They readily penetrate matter. Penetration is least with materials of high density
Uses of x – rays:
Uses of X-Rays can be characterized as medical uses and industrial uses Medical uses:
They are used to treat cancerous diseases and other malignant growth in the human
Industrial uses:
They are used to detect cracks in metal castings and welded joints.
Dangers of x – rays:
They can cause deep seated burns due to their greater penetration power.
NUCLEAR PROCESSES
a) Understand the processes of nuclear fission and fusion and the associated energy changes.
b) Understand the spontaneous and random nature of nuclear decay and interpret decay data in
terms of half-life.
c) Know the applications of radioactivity and the dangers associated with exposure to
radioactive materials.
d) Understand and appreciate that there are significant social, political and environmental
dimensions associated with use of nuclear power.
Definition:
This is a process in which energy is produced. Nuclear processes, includes; fusion, fission, and
radioactive decays of unstable binding energies.
NB:
1. the total number of neutrons plus protons does not change in any nuclear process
2. Strong and weak nuclear interactions determine nuclear stability and processes.
i) Nuclear fusion.
ii) Nuclear fission.
Nuclear fusion:
This is a process by which two light nuclei combine to form a heavy nucleus with release of energy. It
takes place at the sun, stars and in the hydrogen bomb. Example Two Deuterium nuclei combine to form
Helium -3(tritium) and a neutron with release of energy
Nuclear fission:
This is the splitting of a heavy nucleus into two nuclei with release of energy. It takes place in nuclear
reactors and in the atomic bombs.
Example
Splitting of uranium-236 to form Barium (Ba) and Krypton (Kr) with release of energy
Conditions for nuclear fission:
Examples:
236 = 144 + y + 2 92 = x + 36 + 0
236 = 146 + y 92 = x + 36
y = 90 x = 56
235 + 1 = 144 + 90 + 2A 92 + 0 = 56 + 36 + 2z
236 = 234 + 2A 92 = 92 + 2z
2 = 2A 0 = 2z
A=1 z=0
X is a neutron
NB: The number of radioactive nuclei that decay per unit time is called activity
NUCLEAR REACTOR:
The diagrams below shows a nuclear reactor that produces electricity by nuclear fission;
How electricity is produced from the nuclear reactor:
The uranium rod undergoes fission and fast neutrons are produced as a result. The neutrons collide with
other atoms and the energy possessed by the neutrons changes to heat energy. The heat energy is then
absorbed by the coolant and is made to heat water to produce steam. The steam then drives the
turbines connected to a generator and electricity is produced.
Note: that in thermal power plants, the fossil fuels burn coal, oil or natural gas to generate heat. In a
nuclear energy plant, heat is produced by a chain reaction of nuclear fissions.
Social, political and environmental issues associated with use of nuclear power
Economic development and population increase are boosting a new process of energy demand all
around the world. Whereas fossil fuels represent the cheapest sources of energy however they are big
environment polluters. Nuclear energy fulfils three of the main objectives that should be pursued for a
steady development:
Remember the body that regulates the use of nuclear energy is called the international atomic energy
agency (IAEA). IAEA defines nuclear and radiation accident as “a nuclear event that has led to significant
consequences to people, the environment or the facility. Examples includes; lethal effects to individuals,
large radioactivity release to the environment, reactor core melt.
i) Control rods are made of boron or cadmium and they control the fission rate that is they
absorb neutrons that would initiate a fission reaction.
ii) The moderator is made of graphite or heavy water at very high pressure and it is used to
slow the neutrons there by making them to be absorbed by the uranium atoms
iii) Coolant is made of water at very high pressure, liquid sodium or carbon-dioxide and is used
to absorb heat from the reactor core.
iv) Uranium rods are made of uranium and they are as fuel which contains uranium-235. The atoms
of uranium undergo fission and produce energy
iv) The concrete shield absorbs any radiation from the fission fragments or from the fuel
directly.
NOTE:
Heavy water at very high pressure is used instead of ordinary water as a moderator because heavy
water does not absorb the neutrons since it contains deuterium atoms and high pressure
prevents it from boiling and high pressure prevents it from boiling and thus not turning into a vapor.
RADIOACTIVITY:
Many significant activities in nature take place around us and are unnoticed. Emission and
absorption are some of the phenomena that go unnoticed when it takes place in the atom.
Radioactivity is one such property of the matter where the emission of energetic sub-atomic particles
take place spontaneously. In this concept, we will learn more about radioactivity.
Definition:
This is the spontaneous (uncontrolled) disintegration (separation) of unstable nucleus to form a
stable nucleus with emission of radiations. Radioactivity is not affected by eternal factors like
temperature and pressure and it mainly occurs due to unstable nature of some isotopes which will
make them decay as a result in order to reduce the size or become more stable.
There are three radiations emitted by radioactive nucleus and these are;
Alpha particle, α:
Alpha particles have a mass number of 4 and atomic number of 2 and carry a positive charge.
Properties of alpha particles:
They are slightly deflected by both magnetic and electric fields because of their large mass.
Beta particle, β:
A beta particle is a high speed electron emitted from the nucleus of a radioactive atom. Beta
particles have no mass number and carry a negative charge . A beta particle is produced as a
result of one of the neutrons changing to a proton
They are easily deflected by both magnetic and electric fields because they are lighter.
They have greater penetrating power than alpha particles because of their high speed.
Gamma rays, γ:
Gamma ray is high energy electromagnetic radiation of very short wave length emitted from the
nucleus of the radioactive substance. Gamma rays have no mass number and carry no charge.
Gamma rays are produced when an excited atomic nucleus loses energy and the energy is given out
as gamma rays.
They are not deflected by both magnetic and electric fields since they are not charged.
Alpha particles have the least penetrating power and can be stopped by a thick sheet of paper. Beta
particles have greater penetrating power than alpha particles and can be stopped by a thin sheet of
aluminum while gamma rays have the greatest penetrating power and can be stopped by thick block
of lead
Alpha particles produce straight traces because they are heavy and they cause greater ionization of
the gases through which they pass. Beta particles produce irregular and light traces while gamma
rays do not produce any trace when the radiations are in a cloud chamber detector.
When the radiations from a radioactive nucleus are passed through a strong electric field the beta
particle s are deflected towards a positive plate showing that they carry a negative charge. Alpha
particles are deflected towards a negative plate in the direction opposite to that of beta particles
showing that alpha particles carry a positive plate. The gamma rays are not deflected at all showing
that they carry no charge.
When the radiations from a radioactive nucleus are passed through a strong magnetic field the beta
particles are deflected according to Fleming’s right hand rule showing that they carry a negative
charge. Alpha particles are deflected to the direction opposite to that of beta particles showing that
alpha particles carry a positive charge but heavier than beta particles. The gamma rays are not
deflected at all showing that they carry no charge.
Radioactive decay:
This is the process of spontaneous break down of radioactive nuclide. A radioactive nuclide is an
atomic species of a radioactive substance which continuously breaks down with emission of
radiations.
a) Alpha decay: When a nuclide undergoes an alpha decay, it loses two protons and two neutrons.
Therefore its mass number reduces by four and its atomic number reduces by two and the
daughter nuclide is two steps to the left in the periodic table.
Given that a radioactive element, ZAX undergoes an alpha decay to form element Y. Then the
nuclear reaction equation is given by
c) Beta decay:
When a nuclide undergoes beta decay its mass number does not change but its atomic
number increases by one and the daughter nuclide is one step to the right in the
periodic table. This is because electrons do not exist inside the nucleus but can be
produced when a neutron changes into a proton and an electron, the proton then
remains in the nucleus hence increasing the atomic number and an electron is lost from
the nucleus.
Given that a radioactive element, ZAA undergoes a beta decay to form element Y. Then
the nuclear reaction given by
Task:
a) Thorium-234 undergoes a beta decay. Write down its decay equation and
identify the daughter nuclide.
b) If the under-listed nuclides undergo beta decay, write down the decay
equations and identify the daughter nuclides. Hint: you may need a periodic
table
1. Zinc-65
2. Iodine-127
3. Tungsten-184
c) Gamma decay:
Gamma rays are not particles, therefore when nuclide emits gamma rays its
atomic number and its mass number do not change but the nucleus becomes
more stable.
Given that a radioactive element, ZAA undergoes a gamma decay to form a
stable element X. Then the nuclear reaction equation is given by
This is the time taken for a radioactive element to decay to half its original value. Half-life is measured in
seconds, minutes, hours, days, weeks, months and years. Half-life is not affected by physical factors like
temperature and pressure and half-life is different for different radioactive nuclides.
A block of radioactive material will contain many trillions of nuclei and not all nuclei are likely to decay
at the same time since the decay is spontaneous. It is not possible to say which particular nucleus will
decay next. But given that there are so many of them, it is possible to say that a certain number will
decay in a certain time. Although scientists cannot tell when half the unstable nuclei in a sample will
have decayed.
Note: that the decay process is exponential and can be represented by the graph shown below. And
exponential decay means that the higher the number of undecayed nuclides in the sample, the greater
the rate of decay of the sample.
Task:
a) Medical uses:
Radiations are used in radiotherapy [in treatment of cancerous cells] that is gamma rays are
usually used to destroy cancer cells.
b) Industrial uses:
Radioactive elements are used as tracers in identifying oil leakages in oil pipes.
Radioactive elements are used to measure the thickness of the metal sheet.
Radioactive elements are used as level indictor that is to check the filling packets of soap
powders.
c) Agricultural uses:
Radioactive elements are used as tracers to study the uptake of fertilizers by plants.
d) Carbon dating:
Carbon dating forms a radioactive carbon-dioxide which is taken up by plants in the manufacture
of carbohydrates by photosynthesis. When plants are cut down the atoms will start to decay by
emission of beta particles and by measuring the residue and half-life the age of the ancient
containing carbon can be estimated.
You should not eat or drink where radioactive sources are in use.