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Subject : Applied Thermodynamics
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Subject MS
Code : 3161910
Chapter : Refrigerant and Refrigeration cycles
Topic : Classification of Refrigerants
- Prof J. P. Solanki
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Refrigeration
Refrigeration is the Process of reducing and
maintaining temperature of a system below
surrounding by continuously removing heat from it.
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Unit of Refrigeration
A Ton of Refrigeration (1 TR) is defined as,
Refrigerating effect produced by melting of 1 ton ice from
and at 0o C in 24 hours.
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Refrigerant
Refrigerant is a substance,
Which absorbs heat from lower temperature and
dissipate it to higher temperature.
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Classification of Refrigerants
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Classification
Primary Refrigerants
Directly takes part in refrigeration system
Secondary Refrigerants
First Cooled by primary refrigerants and then
used for cooling purpose
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Halo Carbon
Halogen + Chlorine / Bromine / Fluorine
ASHRAE identified 42 Halo Carbon Compound
refrigerants
Only few of them are useful
Also Called Freons
Wide range of boiling point
Used for domestic, commercial and industrial
applications
e.g. R11, R12 or Freon-11, Freon-12
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Azeotrope Refrigerants
An Azeotrope refrigerant is a mixture of two
or more components that boil at the same
temperature.
Do not separate into their components with
change in pressure and temperature.
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Refrigerant Chemical
Azeotropic mixing refrigerants
number formula
R-500 73.8% R-12 and 26.2% R-152 CCl2F2/CH2CHF2
CHCIF2/CCIF2CF3
R-502 48.8% R-22 and 51.2% R-115
CHF3/CCIF3
R-503 40.1% R-23 and 59.9% R-13
CH2F2/ CCIF2CF3
R-504 48.2% R-32 and 51.8% R-115
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Inorganic Refrigerants
Used universally for refrigeration before Halo
Carbon was introduced
Refrigerant Chemical Use
Name Formula
Ammonia NH3 Ice Plants
Water H20 Steam Jet Refrigeration
Air - Aero plane
Carbon Dioxide CO2 Ship
Sulphur Dioxide SO2 Small Commercial Unit
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HydroCarbon Refrigerants
Organic Compounds
Highly Inflammable /explosive
e.g.
Ethane(R-170),
Propane(R-290),
Butane(R-600) etc.
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Water
Used if temperature required is above 0OC
Used in Air Conditioning Plant as secondary
refrigerant
Cheapest, less corrosive, high specific heat
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Brines
Brine = Water + Salt
Used if temperature required is below 0OC
Used in ice plant, cooling of meat and fish etc.
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Ethylene and
Propylene Glycol
Miscible in all proportion with water
Lowers the Freezing point
Non corrosive and Non electrolytic
Used as anti Freeze elements
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Halo Carbon Compounds
R-11, R-12, R-30 have low freezing point
Used for low temperature refrigeration
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