'6. Which of the following is/are coligative
: NCERT Based MCQs
ieee
ee ee
Pee
fo
:
@) Weter - Nitric acia Renan
(4) Benzene - Acetone ae wate
E solution that could be used in the blood steam
se Gon boiling point of a solution of INCERT Fo. 291
9 (mol vit. = 100) in 100 9 of water is (1) 0.48 mol (2) 032 moll.
(4) 0.45 mol.
'ATy: then the ebullioscopic constant of water is
INCERT Pg. 16] 8,
(1), Lowering in vapour pressure
@) Freezing point
@) Boiling point
(4) Both (2) & (3)
‘The average osmotic pr
8) 0.30 mot
AS molar solution of 1,50,
property?
[NCERT Pg. 15)
cessure of human blood i678
sntration of aqueous NaC}
is diluted from 1 litre to
'e normality of the resulting solution is
(1) 10047, @ at, 40 litres. Th
aT
0 (4) 1047, bees
(1) 0.25N @ 10N
3 The order of Ky values of A, B and C gases is @) 20N @ 05N
Ky,> Ku. Kg. Then, the Jer of
5 correct order of their 9, Which of the followin
ee worrcrnre ich of the following with respect to negative
solubility in a liquid at given temperature is deviation is correct? INCERT Pa. 13)
INCERT Pg. 71 4) AGeq <0 Ege)
<0, AHsa < {
Mee css ) se ie ? Bae
Oe AS gy <0 ‘
@ B>A>c 7 se oa
Bie-c>A | 2) AG gq, < 0; AHsy <0: 8857 © a
(= (@) AGga > 0: Bes 0: AS =O
(4) A>B>Cc
4, The effect of increase in
aqueous solution of a substan
the temperature of an
10.
INCERT Pg. 4]
(1) Decrease in its molality
(4) AGgg > 0, Hg > 0: ASgas? ©
The total vapour pressures Prorat
two volatile component
(in tort) for @
mixture of ts, A and Bis
given by:
Pi, = 220 - 110 Xp
sion of component, B is
(2) Increase in its molality
{@) Increase in its mole fraction where, Xz is mole frac
tu
(4) Decrease in its molarity ie i an a
ressure (in torr) of pure components,
By the molarity of a solution of sod chloride in jence, Pt
500 ml of syaver containing 5.85.9 0rsodu™ chloride and B are respectively INCERT Pg.
is [NCERT Pg. 4] (a) 110, 220 oa
(1) 0.25M (2) 220, 110 - \ ie
0M (@) 220, 320 a
(3) 20M (4) 220, 10
(4) 02M
8, Puse Road, New Delhi-110008. Phone : 011-47623456
Tower,
(RNCaiporate Orrico : have
eeEEN ee ae
following mixtures
se
at 30°C is INCERT Pg. 20] () HD and HNO,
@) 002M (@) H,0 and CoHs
9
(4) 008M pias oo
a HCl, and CH,— © — CH, ¢
ofthe folowing aqueous solution wil have th @ CHE), s
eee? Meer Ce I (4) n-hexane and n-heatane 4 @
!) 0.1 NaCl solution (2) 0.1 m Sugar solution (ech oto fotoning wll riot chey af sa: Man
10:1 m MgCl, solution (4) 0.1 m AICI, solution
0 Qk,
“4 tenmatessscononstien tenia OS ae
: Ty courvenone @) Leceenene” 6 Whkthoneof he fotlwng 92008 vl have mi
value ofK, (kbar) at same temperature in aquagy
@) Equal to one (@) Zer0 fare
®
is 25% in 2) CO,
15, If degree of dissociation of Al(SO,), is 25% in a oH @) ©0, :
solvent, then INCERT Pg, 24] are #0 14. Ani
oe ana pOon= expermment| Polina Point 7 in the case of osmosis, solvent molecules move ig the
(@) Normal osmotic pressure = 2 « experimental
is
‘osmotic pressure (1) Higher vapour pressure to lower vapour pressing
8) Normal molecular weight = 2 « experimental
(2) Higher concentration to lower concentration a
‘molecular weight
(@) Lower vapour pressure to higher vapour pressulg ®
15, Th
1 igher osmotic pressure
1) Normal tezig pont = 2 = experiments! Haher osmotic pressure to lower osmoig «
st
lad 8. Assuming salts to be 90% dissociated, which of a
(RSL Section - 5 following will have highest osmotic pressure? 4
Objective Type Questions (1) DecimolarAl,(SO,), @
‘Which of the following is correct about a solution 2) Decimotar Bac, «
showing positive deviation? (3) DecimateeNa,s r
(1) Vapour pressure observed will be the less than a . 16. 2
that calculated from Raoult's law (4) Asolution obtainec by mixing equal volumes of iS
(2) and (3) and filtering 4
{2) Minimum boiling azeotrope will be formed 9 Whict fol (
Baie. Nich of the following is not a colligative propefy®
tnt fs (
(4) AV, < 0 (1) Vapour pressure of pure liquid solvent
% (2) Elevation in boiling
2 On mixing 10 mi of ethanol with 10 mi of benzene are
the total volume of the solution is 8) Depression in freezing point
(1) > 20 mi (4) Osmotic pressure a
< 10. ‘
— 2) <20m Which ofthe folowing is correct fora solution shown
@) =20m Positive deviation fr
om Raoult’s law? 4
Vic > 0, AHpie >0 (2) AV ian <0, AH $0
(3) AVmig = 0, AH, 0 (4) AVyy > 0, AP
(4) Can't be predicted (1)
a hn
Tower, usa Road, New Dethi-t10005 Phone : 011-47623456)pressure of solvent and
re the moles of solute and,
@ Pam
my
oe
Te
. ‘ man,
Fg pain of Gt, CH,OH, CH,
Baron ave sore, 880, eave ate size
Which ofthe follow
ing will hav
(apour pressure at room temperature? mie
(t) Cots (2) CHOH
@) PP=Pxn,
P= 199% 135
(where xis the mole fraction of meth
are the vapour pressures of pure moth alconoh
pure ethyl alcohol at 40°C?
(1) 195 and 264 torr (2) 119 and 195 torr
(8) 119 and 264 tor (4) 384 and 195 torr
solvent decreased by 10.”
alconok.) What
and
@) CoH SNH, (4) C.HNO, 20. The vapour pressure of a!
/law> 43. Hany solute’ dimerises in water att atm pre of ig when @non-olatle solute was ced 6 >
Hanyehtecmensnwsi sangre «SN ae tn un foozo
Bipraaze a caare ciercy | teleeNtetetcareatge |
ninimum, ofA " @) 08 @ 06
aqueous (1) 50% 2) 30% Ske Oe
21. Wamofnon-volatie organic substance of
5% %
@ 2 (4) 100% mass Mis dissolved in 250 gm benzene. Molal
44, An aqueous solution freezes at-0.36°C. Ky and Ky tlevation constant of benzene is K,, Elevation in 8S
procter are 1.8 and 0.52°C -kg mot respectively oo
ve from then value of boling point of solution at 1 alm pressure ) aK,W
ressure E ey Soe
108" 01"
Bs (4) 101.04°C ) 100.1°C » KW
(@) 0.104°C (4) 100°C ® “aw
ressure
44. Therelationship between osmotic pressure (P)at278 22. The molal elevation constant for water Is
smotic Keuihen 10 g glucose (P,), 10.9 urea (P,) and 10.9 Tre reach Calouatethebolingotthescuton
fuerose (P,) are dissolved in 250 mi of water's made by dissolving 6.0 gm of urea in
: 200 gm of water
of the (t) P, > P2>P. Lael
> g } (4) 100.28°C @ 108°C
@) P,>P.>P. ae :
i) 2 (3) 028°C (@) 20028°C
@) P7 Ps? Ps 23, The graph plotted vapour pressure vs mole fraction,
is the graph for which of the folowing example
(4) P,> P2>P
we: 16, Arrange the followi aqueous solutionsin the order
nes of of their increasing boiling points
(i) 10-* M NaC! (i) 10° M Urea
erty? 0 pie?
(ii) 10° M MgCl, (v) 10° M NaCl
@ w
deal solution (avesee)
Bsc crmirt 0) an
4. Negativedeviaton —(W) ot
1000),
°
= W)
™ Foor,
(a afi), BG, eC, 0) @) a0), BA, 0,
) ali), ), 46) 4) a), BED fv.
se
, 4, The Henny’s law constant (K,) values of three
of goses (A.B, C) in water are 145, 2 107 and 35
bar, respectively. The solubility ofthese gases in
INEET-2024)
@B>crA
(4) A>B>C
ure ({1) vs concentration
ives a straight line with
ature at which
SECTION - C
Previous Years Questions
ce water follow the order
re () B>Arc
@a>cre
2 The plot of osmotic press’
(mol L~) for a solution gi
slope 25.73 L. bar mot". The tempe
the osmotic pressure measurement = done ©
[NEET-2024)
(083 L bar mot" K"")
(Use R=
(2) 310°C
(1) 37°c
(4) 12.05°C
@) 25.73°C
3, Which amongst the
electrolytes will have rinimury
point? Choose the correct option.
[NEET-2023 (Phase?)
(2) 1M NaCl
(4) 0.4 MKCI
es at the same temperature
NeeT-2022 (Phase2)]
following aqueous SolutONS of
elevation in boiling
(1) 0.1 M MgSO,
(8) 0.05 M NaCl
4, Ky, value for some gas
‘T are given:
ERB Coporate Ofte
Jo i Aakash Tower
g, Pusa Road,
(1) HoHO < cH, < 60, <
@) Ar< 00, < GH, < HCHO
@) Are CH, < CO, < HCHO
(@) HCHO < CO, < CH, Py? Pe
der of os ots
@) Pa> Ps > Po
() PL>P,>P, Pe Para
49460
; @
27 100 ml of 1 M NaOH is mixed with 60 m! of
TN'KOH solution. “Normality of mixture is
le traction—+
1) 1N 2) 0.5N vera e
Correct observation fo this solution
@) 0.25N 4) 2N ¢
(1), He 9 @) AS pyc: i
28 Mass of NaC! required to prepare 0.01 m aqueous B59
‘solution in 1 kg water is (3) AV ini 748 (4) All of these
m) 0.8859 436, Amixture of two quids A and 8 having boing poe
Grais 70°C. and baling point of Bis 100°C, dei
3 4) 5.889 at 101.2°C as single liquid, hence this mistursis
‘The vapour pressures of two iquids Aand Bare 100 Cy eee su
tn 16Dior respective, Tho ota vapour pressure Sie nal ton oo
{@) Non ideal solution showing —ve deviation
44 on (@) immiscible solution
150,00 torr (4) 199.33 tor 16. Vapour presstre diagram of some iquds pli
against temperature are shown below
30. The freezing point of a solution containing 0.4 g of st p
aceticacid in 40 g of benzene is lowered by 0.512°C. Pr 7s 8S
imal isthe degree of dimerisation of acetic acid? a
[Kbenzene) = 5.12 K kg mot") |
4) 60% 2 90% | E
(4) 60% 7
4 molar aqueous solution is__ ‘Most volatile liquid
nm aqueous solution Ma
4), More & Qe a1
Q) Less ack
(@) Equally ane
(4) Very less were
uring evaporation of iquid
{Wnt is he concentration of NO,-ions when equal ° a
yolumes of 0.1 MAGNO; and 0.1 MNaClare mixed (1) The temperature of liquid rises
together? sii (2) The temperature of liquid falls
(1) 0.1N (2) 0.
“ (0) The temperature of quid remains une
@ 005M @) 02M ‘
(4) The liquid molecules becomes inert
memmenncarmeate Once Aakash Tower, 8, Puse Road, New Dai
10008, Phone * 014471Point
49) Ne* moves from solution
Ato solution B S Baw
Both Na* and é Wich havi ih
a ee Bed we Tn tn a
ai ‘ ques sli
from solution (A
‘solution (B) ) to (3) Aqueous solution (4)
us elation () Ages slton
“a
t We
wc
9 Comect observation a
1
Freezing point of solution is marked a5
Ma ae
@c @ 0
O1MUrea 0.1MNaCl 0.1 M CaCl,
(1) Vapour pre:
pour pressure o'
45, varit Hoff factor for acaic acid in aqueous medium,
at infinite dilution is
s di
- (2 @4
va % 3
46. Correct order o freezing point of gven eaution
int is maximum for Il ho 0) Rr O BR
is minimum for It ; S02 co
ih 0.4 MINA
lution of sugar is taken in a beaker hve eee!
40.
@ tole v
Be cyatais a (y Leneii