Delaware River Aeration Solutions
Delaware River Aeration Solutions
          Alternative
                    Oxygenation
                             Possibilities LargePollutedRivers
  The idea of artificial or induced aeration of regionalwater quality control agency,the Dela-
polluted rivers has been developing fairly ware River Basin Commission,        and by the sub-
rapidly in recent years. Analysts have com- missionin 196.6of a special report highlighted
pared the possibilitiesof induced aeration to   by the commissionerof the former Federal
the standard approachesof advanced effluent Water Pollution Control Administration [1966].
treatment and low flow augmentation [Kneese            More recent studies are now available [Wright
and Bower, 1968; Davis, 1968]. Tests and cost          and Porges, 1970']. About 40 miles of the tidal
studies of prototype equipment under scien-            section of the Delaware   suffers at times from
tifically controlledconditionshave demonstrated insufficientdissolvedo.xygen(DO) (Figure 1).
the applicability of instream aeration to situa-The oxygendeficiencyinterfereswith important
tions on small polluted rivers, especiallythe   runs of anadromousfish, besidesimpairing the
PassaicRiver [Whipple et al., 1969; Hunter      quality of the river for recreational and living
and Whipple,1970; Imho#, 1968; Tarassovet       purposes.The adopted water quality standard
al., 1969;DavidsonandBradshaw,1970; Whip-       will require bringing the minimum daily aver-
ple et al., 1970]. Meanwhile the Ruhrverband age DO levelsup to 3.5 rag/1 at a costof about
and more recentlythe Miami Conservancy   Dis- $40 million annually. Annual cost estimatesof
trict have installedaeratorsand are beginning $46 million and $34.4 million correspondto two
to obtain operatingresults.This paper describes given objectives between which the adopted
tests of prototype aeration equipment on a water quality standardslie [Wright and Porges,
major river, the Delaware Estuary, and dis- 1970]. Comparisonof these two objectivesin-
cussesmethods of determining transfer effici- dicates that adding the last 1.0 mg/1 of DO
ency, suitable aerator systemdesign,and rela- to the critical section of the river will add about
tive costs.                                     $9.3 million to systemcostsannually.Sincesuch
                                                great costs are projected for the officially
        TI-IE DELA•VARB ESTUARY PROBLEM
                                                adopted plan and sincethat plan is so clearly
   The lower Delaware River, known as the defined,the Delaware obviouslyconstitutesan
Delaware Estuary, has been recognizedas a ideal area for investigatingpossiblealternatives
majo,r water quality problemarea by the crea- for achieving given water quality objectives.
tion of the nation's only fully empowered         The Delaware River is more than •-mile
                                                 566
                                          Artificial Aeration o• Rivers                                567
wide in the critical section,is tidal and heavilytion downstreamthrough which all or most of
navigated,and has a channelmore than 40 feet     the aerated water may be assumedto pass, as
deep. Design and operating conditionsfor such     determined by observing the flow patterns
a river must be quite differentfrom those for    through fluorescentdye tracing. Differences in
a small river like the Passaic or from those for the total DO passingthrough the control sec-
aeration lagoonsand treatment plants, in which tion before and after the aerator is put into
aeration equipmentis commonlyused.This fact operation were attributed to the aerator, subject
was dramatically emphasizedwhen, on the day to verification from an upstream section that
after its installation, the frame of the surface the DO from upstream had not changed.This
aerator was buckled by waves in a sudden approach may be expressedas follows.
squall. The aerator had to be removed,hastily       Considera small area A At, within which the
redesigned,and rebuilt. The main test pro-       DO concentrationsmay be considereduniform.
gram was carried out during the summerof 1969' These concentrationsare representedby C•. If
in the area adjacent to the pier of the Camden the velocity of flow for the small area AA• is
sewage treatment plant. Figure 2 shows the       V•, then the massrate of oxygenpassingthro.ugh
1969 test site, with the surface aerator operat- the area is C•V• A At. The total mass rate for
ing. In June 1970 further tests of air diffusers the control section M is then
were conductedfrom a pier of the Philadelphia
Port Authority to extend the range of tests of
diffuser equipment to deeper water.              Let C• be the DO concentration before and
                                                          C/   the DO concentration after the aerator is
    AERATOR   OXYGEN   TRANSFER   PROCEDURES
                                                          put into operation. The oxygen uptake rate
  The aerators tested in the Delaware            River    due to the aerator U can be computedby
are shown in operation in Figures 3 and 4.
Methods of evaluatingthe oxygentransfer (up-                            =    (c,' - c,)
take) rate for such aeratorson small rivers are           under the assumption that there are no sig-
based on differencesin the total oxygencarried            nificant velocity changesat the control section
by the stream crosssectionsabove and below                before o.rafter the aerator is put into operation.
the aerator at any given time [Whipple et al.,               The oxygen transfer rate for the aerator
1969]. A different method is required for large           under test conditions R, can then be determined
rivers. This method is based on a control sec-            by
   mg/l
     DO                      [                    [
              Zone
                2 --i• __
                        Zone
                           3 • [ Zone
                         ____       4 _•__                                    Zone
                                                  I                 I
   '•
        x                          k
                                                  '[, stream 'l
                                                         eriteri•
                                                             ',   '/
                              I   k          k        Mi•mum
              M•mu •fiy •             •       k [ average
therefore expected that for • diffuser the ef-      rioned phasesof oxygen transfer, i.e., spray
ficiency o,f oxygen transfer would be propor-       aerationand turbulent mixing.
tional to the depth of submergence,   the size.of      In this study aera.torswere operated and
the bubbles, the airflow ra.te, a.nd the surfa.ce   data were collectedonly on outgoing tides to
turbulence [Eckenfelder, 19'5.9; Eckenfelder        avoid the effects of tidal   current   a.nd channel
and Ford, 1968].                                    asymmetry.At ea.chcrosssectionboth upstream
   For mechanical aerators oxygen transfer to       and downstrea.m from the aerator       velocities at
the Wa.teroccurs.
               both in the sprayedwater and         va.rio,uspo,sitionsa.nddepths were obtainedby
in the turbulent mixing zone [Eckenfelder and       current meter, and correspondingDO readings
Ford, 1968]. Investigation of the process of        were measuredby oxygenprobescalibratedby
spray aeration shows that oxygen transfer is        frequent Winkler tests. The a,verageDO con-
related to' the size of the water droplets          centra,tionfor a sectionwas obtainedby weight-
[Carver, 1969']. For surface entrainment aera-      ing the various point readingsaccordingto. the
tors the efficiencyo,f .oxygentransfer generally    velocities.,and the DO increment.was obtained
decreaseswith increasingaeration basin volume       by equation 2'.
but increaseswith increasingwater depth for           For the deepwater air diffuser tests under-
basins o,f co.nsta.ntdiameter [Garland, 1969].      taken at the Philadelphiasite in June 1970, the
To date, however, no information is available       proceduresdescribedabove were impracticable
concerningindependentevaluatio.nof the rela-        beca.use of the much smaller aerator      ma•fold
tive importance of each of the two. aforemen-       used. Therefore the oxygen absorption was
570                                                           WHIPPLE         AND        YU
      F--i(C,)•(2•P.
            92)(fi).
                CmI
                  (TF)(o•
                     )                            C8was correctedfor pressure,whichin turn was
                                                  evaluated at the midpoint of the depth of sub-
.:.
                                        ........
                                            ::•i•!!i•::•::i
                                                 ........
                     :....::?•::..                                      :•.::•::::•.:.
....
                                                        CorrectedFlow               % O• in                   % O•
   Sample No.                 Header Depth               Rate, scfm                SpentAir                  Absorbed
             1                    12'3"                      93.0                      20.8                      1
             2                    12'3"                      93.0                      19.9                      6.5
             3                    12'3"                      44.0                      20.06                     5.6
             4                    12'3"                      44.0                      20.4                      3.6
             5                    12'3"                      16.3                      19.9                      6.5
             6                    12'3"                      16.4                      19.91                     6.5
             7                    38'3"                      19.7                      20.7                      1.8
             8                    38'3"                      19.7                      19.07                    11.3
             9
         10                       38'3"                      53.7                      19.6                       8.2
         11                       38'3"                      53.5                      18.9                  -----12.3
         12                       38'3"                      99.4                      19.3                      10.0
         13                       38'3"                      99.4                      19.7                       7.7
         14                       25'                        17.9                      20.1                       5.3
         15                       25'                        17.9                      19.8                       7.1
         16                       25'                        49.6                      19.6                        8.2
         17                       25'                        49.6                      19.7                        7.7
         18                       25'                        49.6                      19.7                        7.7
         19                       25'                        94.1                      20.3                       4.2
         20                       25'                        92.9                      19.4                       6.0
mergence. According to laboratory tests car-                        ever,the smallnumberof testsand the difficult
ried out by J. V. Hunter but not yet reported,                      conditionsfor measuringresultsreducethe con-
both a and • valueswere found to be 1.0.                            fidence that       can be accorded to these results.
                                                                      Many more data were obtainedwith the dif-
                 OXYGEN     TRANSFER      I•SULTS
                                                                    fuser    aerator     than    were   obtained   with   the
  Owing to a late start of the tests and the con-                   mechanicalaerator. To supplementresultspre-
sequencesof storm damage,only four complete                         viously obtainedon the PassaicRiver at depths
sets of results were obtained for the mechanical                    of about 8 feet, tests were performed at the
aerator, which is only a fraction of the data                       Camden site at depths varying between 11.0
previoudy obtained in shallower water. The                          and 16.9 feet becauseof the tidal range. At the
computedoxygentransfer rate at standard con-                        Philadelphiasite tests o.f a similar but shorter
ditions varied from 1.29 to 4.50 lb/hp hr, the                      diffuser were made at 12.3, 25, and 38.3 feet.
average being 3.06 lb/hp hr as comparedwith                         A summary of the results is given in Table 1.
an average of 2.12 lb/lap hr obtained on the                        A study of these data showsthem to be quite
PassMe River.             Some increase in the transfer             consistentdespitethe differentperiodsof time
rate might be expectedbecauseof the greater                         and     methods      of    measurement   involved.    The
volume of water affected in a deep river and                        proportion of oxygen absorbed obviously in-
the probability of a reducedtendency for re-                        creaseswith depth,but the increaseis muchless
circulation of previously aerated water. How-                       than proportionate,particularly at the greater
572                                     •I-IIPPLE   AND YU
2.0
                                                             1970DELAWARE
                                                                      DATA
          1.5
0.5
                                10                    2o                        3o                         0
                                            Depthof Submergence,ft
ß Imhoff
2O
                         --•
                         -
                          •
                                  _•Rutgers,
                                             Saran
                                                tubes}
                                                    Bewtra
                                             Sparget s     &
                                                    Nicholas
                                                  Passaic
                         -
                         -
                                    (D Rutgers,   Delaware
                         --
                                          (gas samples)
                                       -•    Rutgers,            Delaware
                                                 (mass balance)
               o
                                                                            ß
               •    lO
               o
, ,
4 5 6 7 8 9 10 20 30 4o
Diffuser Submergence, Ft
                                  Fig. 6. Oxygenabsorption
                                                         versusdiffusersubmergence.
recentlyinstalleda groupof four electricdrive                                   wouldneedto be far enoughout into the water
surface   aerato.rs           on the        Miami        River        near      that natural currents and tides would disperse
Dayton, Ohio.Theseaeratorshave a relatively                                     the water throughoutthe affectedcrosssec-
small high-speedimpeller mountedin the cen-                                     tion of the river. This requirementis,essential
ter of a doughnut-shaped   plastic float. They                                  because research on anadromous fish of the
appearto have efficienciesroughlycomparable                                     Delaware indicates that these fish do not per-
to those covered in this report. They are                                       ceivelow oxygenwatermasses,  andwhenthey
moored to cablesstrung acrossthe river, up-                                     beginto suffocate
                                                                                                they reactrandomly,  ,being
stream and downstream (Figure 8).                                               as apt to swimdeeperinto the bad area as to
   On a large highly developedriver like the withdraw [Dorfman and Westman,1970].
 Delaware,'the requirements  of navigationare    Aerators create strong local turbulencein
 controlling.The most practicablemooringar-    the  river, and dispersion
                                                                        studieson the-'•Dela-
 rangement  for a surfaceaeratorappearsto be ware basedon fluorescentdye tracingof,aerator
'threepile clusters,
                   eachconnected  to the aera- effects have shown that the' aerated water
 tor by cables(Figures9 and 10). Electricserv- would extend out from each side to. the center
 ice wouldbe providedby submarine     cable.It of the river within 5.7 miles of the aeration
 appears that the mostsatisfactorygeneralplan  site (GeorgeMattingly of PrincetonUniversity
 is to spacethe aerationsitesof oneor several  and  John  B. McCall,P. W. Anderson, and John
 unitsalong'eachbank'of the river in' areas Murphyof the U.S. Geological     Survey,unpub-
 wherenavigationSusage  will allow.Suchunits lisheddata, 1969).
574                                             WHIPPLE   AND ¾U
SYSTEM COSTS
                                                             Somemajor studieshavepreviouslybeencon-
      b                                                   ducted on the Delaware Estuary, and a great
                                                          deal of information        has been made available
                                                          throughcooperatingagencies.
                                                                                    A systemanalysis
                                                          of BOD and DO conducted for this project
                                                          gave resultssimilar to those of the other in-
                                                          vestigators;i.e., to increasethe general
  Fig. 7. Ruhrverband surface aerator. (a)                mum level of DO from 3.0 to 4.0 mg/1 through-
Elevation. (b) Plan. A, aerator impellers; F,             out the 40-mile critical area would require the
floats; S, drive shafts.                                  additionof 350,000poundsof additionaloxygen
                                          Artificial Aeration o• Rivers                                        575
                                          ,.               Channel
                                                             •.   • --__
                                    To
                                  shore
Pile cluster
daily. A system of aerators to accomplishthis              ½/lb. If the mean cost for a complete system
taskwouldrequireat least50 aerationsites were 5.0 ½/lb, the total annualcostof adding
of various sizes,dependingon the differing re-             the last rag/1of DO wouldbe about$2,400,000,
quirements of the various sections.For reasons             rather than the $9,300,000indicatedby present
already outlined both mechanical and diffuser              estimates based on effluent treatment             alone.
aerators would be required. Cost estimatesare              These costs would be materially reduced if
based on an equipment life of 15 years, a                  oxygenwere addedat a lower level of concen-
socialinterest rate of 6%, and an averageop-               tration, say, at a minimum level of 2.0--3.0
erating period of 6 months, 3 months at half               mg/1.
time (12 hr/day) and 3 months at full time
                                                                   OXYGEN   •)IFFUSION       POSSIBILITIES
(24 hr/day). For surfaceaerators,oxygencosts
are indicatedto be 4.0 4/lb for three-unit sites,            Possibilitiesof raising the DO level by dif-
4.6 4/lb for two-unit sites,and 6.6 4/lb for one-          fusionof pure oxygenhave been reportedboth
unit sites.For diffuseraeratorsthe pier end unit           for rivers [ChemicalWeek, 1969; Amberg et al.,
illustrated   would   furnish     additional   dissolved   1969']and, in muchmore detail, for wastetreat-
oxygen at 4.4 4/lb in 30 feet of water, other              ment plants [Union Carbide Corporation,
types of diffuser installations costing 5.5-9.3            1970]. Although such possibilitieshave not
576                                          WHIPPI•E Al•D •
been fully explored,particularly with respectto        bulence created by aerators, which causes
cost, studiesunderway indicate that for water          dispersioneffectsmuch greater than those oc-
30-40 feet deep, oxygendiffusionmay provide            curring in the natural stream. If this excess
an economical alternative     to air diffusion under   turbulence picked up into suspensionheavy
the conditionsassumed.However, further work            recent depositsof fine clay, silt, and organic
would be required to determineoptimal design           sludge,the long-term advantage of removing
aspects since there are several alternative            such bottom deposits would very likely be
methodsof oxygen•ation.
                     Alsoit wouldbe neces-             overcomeby the possibleshort-run harm done
sary to make an entirely different dispersion          to biosystems.However, the critical section of
analysis since the dispersion analysis made            the Delaware River, like that of most other
for the aeratorswould not be applicable.               major rivers, is heavily used for navigation.The
                                                       aeration systemsconsideredwould be lesspow-
             Ei•VIRONMENTAL     ASPECTS
                                                       erful and create less disturbancethan the pro-
   Induced oxygenationof rivers acts only to           pellers of tugs and other craft using the river
eliminate DO deficiencyand must be planned             in large numbers.The area involved is mainly
as part of a comprehensivepollution control            30 feet deep or more, over sandy bottoms or
program to be effective. A natural ecosystem           sediment deposits long since consolidatedand
can be completelydestroyedor badly unbal-              resistantto. erosionby turbulenceof this magni-
anced by chemical residues,heat, blankets of           tude. It doesnot appear that there will be sub-
sludge, or excessivenutrients regardlessof the         stantial adverse secondary environmental ef-
DO level of the water. The primary effectsof           fects, but there will be large, immediate, and
river aeration and oxidation systems can be            favorableprimary effects.
very favorable both to biosystemsand to, rec-
                                                                    IN STITUTIONAL   ASPECTS
reational values,provided that they are used
as a supplementto a general program of waste             The   German     Ruhrverband    was established
treatment.                                             by federal legislationprior to World War I to
  The secondaryenvironmentaleffectsof river            provide a satisfactorysystemof water quality
aeration are less apparent. As discussedabove,         control for the Ruhr valley as a whole. Mu-
either aerators or oxygenatorscan be operated          nicipal and industrial interests that pay the
without any substantialdanger of direct local-         expensesof the program are representedon the
ized damage to fish life. The main environ-            Ruhrverband governing board. Accordingly
mental changeis the high degreeof river tur-           when the governing board decided after a
Pier
Fig. 12. Diffuser aeratorat pier end. (a) Elevation. (b) Plan.
to state water quality standards.The Miami      ing the validity of our hastily adoptedwater
Conservancy District has determined that it     quality standardsand the extent to which re-
will not be possibleto meet state standardsof quiredDO levelsshouldbe enforced.Whenever
water quality by means of secondary waste the degree of enforcementcontemplatedwill
treatment alonebecauseof the great population requiretreatment in excess, of normal secondary
and industrial growth in the basin. In addition standards,instream aeration will probably be
advancedwaste treatment, lo,wfio.w augmenta- found less expensive,often by large margins.
tion or induced oxygenationwill be required, Other technologicalalternativesshouldalso be
and the last alternative was estimated to be    considered. Institutions should be developed
the least expensiveby far. Accordinglyin the through which such alternatives.can be con-
fall of 19'70a group of four aeratorswas placed sidered and adopted where warranted; other-
in the river and commencedoperation. These wise massive resource misalloqationsmay re-
aeratorswere financedby effluentchargesto be sult.
paid by municipalities
                     and industriesthat would  Acknowledgments. Important contributions to
otherwise have had to resort to advanced waste
                                             this work were made by Drs. J. V. Hunter and
treatment.                                   F. W. Dirtman of Rutgers University, Dr. G. E.
   Of course,questionsmay be raised concern- Mattingly of Princeton University, and Mr.
                                          Artificial Aeration o• Rivers                                 579
F. P. Coughlan, Jr., of Hazen and Sawyer, Con-             Federal Water Pollution Control Administration,
sultants,New York City.                                      Delaware Estuary comprehensive study, Pre-
  Most of the analysis on which this article was             liminary report and findings, Philadelphia,
based was supported by the Environmental Pro-                Pennsylvania, 1966.
tection Agency, Water Quality Office, through              Garland,
                                                                 C. F., Research
                                                                              ontheinfiuenc•e
                                                                                          of basin
demonstration project 16080 DUP, 'Oxygen Re-                 volume and geometry on performance of sur-
generation of Polluted Rivers,' and by the De-               face-entrainment aerators, paper presented at
partment of Conservation and Economic Develop-               1969 American Society of Mechanical Engi-
ment, State of New Jersey.                                   neers/American Institute of Chemical Engineers
                                                             Stream Pollution Abatement Conference, Rut-
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                                                             1969.
Amberg, H. R., I). W. Wise, and T. R. Aspitarte,
  Aeration   of   streams   with   air   and   molecular   Hunter, J. V., and W. Whipple, Jr., Evaluating
                                                             instream aerators of polluted rivers, J. Water
 oxygen, Tappi, 52(10), 1866-1871,1969.
                                                             Pollut. Contr. Fed., •2(8), 249-262, 1970.
Association of River Authorities, Yearbook, 15
                                                           Imhoff, K. R., Oxygen management and artificial
  Great College Street, Westminster, London,
                                                             reaeration in the area of Baldeney Lake and
 SWl, England, 1968.                                         the lower Ruhr River, Gas Wasser•ach,Beil.,
Barnhart, E. L., Transfer of oxygen in aqueous               109, 936, 1968.
  solutions,J. Sanit. l•'ng. Div., Amer. $oc. Civil        Kneese, A. V., and B. T. Bower, Managing Water
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                                                            Quality: Economics, Technology, Institutions,
Bewtra, J. K., and W. R. Nicholas, Oxygenation
                                                            Johns Hopkins Press, Baltimore, Maryland,
 from diffused air in aeration tanks, J. Water               1968.
 Pollut. Contr. Fed., 36(10), 1195-1224,1964.
                                                           Tarassov, V. J., H. J. Perlis, and B. Davidson,
Carver, C. E., Oxygen transfer from falling water
                                                             Optimization o,f a classof river aeration prob-
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 Eng., 95(SA2), 239-251, 1969.
                                                             parameter control theory, Water Resour. Res.,
Chemical Week, For rivers breathing room, 131-               5(3), 563-573, 1969.
  132, June 1969.
                                                           Union Carbide Corporation,Investigationof the
Craine, L. E., Water managementinnovationsin                use of high purity oxygen aeration in the con-
  England, Resourcesfor the Future, Washing-
 ton, D.C., 1969.
                                                            ventional activated sludge process,186 pp.,
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  state optimal design of artificial induced aera-
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                                                            827-837, 1970.
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  Potomac estuary, Johns Hopkins Press, Balti-
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  more, Maryland, 1968.
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Doffman, D., and J. Westman, Responses of
                                                            Federal Scientific and Technical Information,
  some anadromous fishes to varied oxygen con-              Springfield,Virginia).
  centrations and increased temperatures, 2,
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                                                           Whipple, W., Jr., F. P. Coughlan,and S. L. Yu,
                                                            Instream aerators for polluted rivers, J. Sanit.
  ResourcesResearch Institute, Rutgers Univer-
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Eckenfelder, W. W., Absorption of oxygen from              Wright, J. F., and R. Porges,Water quality plan-
  air bubbles in water, J. Sanit. Eng. Div., Amer.          ning and management experiencesof the Dela-
 $oc. Civil Eng., 85(SA4), 89-99, 1959.                     ware River Basin Commission, Proc. 5th Int.
Eckenfelder, W. W., and D. L. Ford, New con-
                                                            Water Pollut. Res. Conf., pp. I-3/1-I-3/17,
  cepts in oxygen transfer and aeration, in Ad-              1970.
  vances in Water Quality Improvement, edited
 by E. F. Gloyna and W. W. Eckenfelder, 513                     (ManuscriptreceivedJanuary 11, 1971;
  pp., University of Texas Press, Austin, 1968.                      revised February 16, 1971.)