Safety Information

Name of Chemical/Product

GRAUER & WEIL (INDIA) LIMITED

Akurli Road, Kandivli (East),
MUMBAI – 400 101 - INDIA
Tel. : 91-22-56993000 Fax : 91-22-56993010 /11

1. PRODUCT AND COMPANY IDENTIFICATION

General Chemical Name/Product : Zinthobrite CLZ 942 M

Formula : Not Applicable
CAS Number : Not Applicable
Other name : None
Manufacturer Name/Distributor : Grauer & Weil (India) Limited
Address : Akurli Road, Kandivli (East),
Mumbai – 400 101. India
Phone : 91 22 – 5699 3000
Fax : 91 22 – 5699 3031
E-mail : hq@growel.com
Emergency Phone : 91 22 – 5699 3000

2. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Name Concentratio CAS Number

n
1. Sodium Bezoate 10 % 532-32-1
2. Sodium – 2- ethyl hexyl sulphate 30 % 126-92-1

3. Fatty alcohol ethoxylate 25% -

4. Sodium Napthalene Sulphonate 2% 36290-04-7
5. DM water Balance 7732-18-5

3. PHYSICAL AND CHEMICAL PROPERTIES

1. Melting Point : Undetermined

2. Boiling Point : Approx. 1000C
3. Density : 1.090 – 1.115 gm/cc at 300C
4. Pressure : Undetermined
5. Sticky(SG) : 1.090 – 1.115 gm/cc at 300C
6. Solubility in water : Fully soluble
7. Chemical State : Liquid at 300C
8. Color and Smell : Pale yellow to brown liquid and characteristic odour
9. Ignition points : Undetermined
10. Temperature get by itself : Undetermined
11. Testing Procedure Undetermined
12. Other information : None
 4. HAZARDS IDENTIFICATION –

Main Hazards :
1. Eye Contact : Can cause irritation
2. Ingestion : Can cause irritation
3. Inhalation : Mist or vapor may irritate respiratory tract.
4. Skin Contact : Can cause burns, irritations and rash
5. Other Health Effects : Nothing specific.

5. FIRST AID MEASURES

1. Eye Contact : Flush eyes with plenty of water. Hold lids apart to
ensure flushing of entire surface to prevent or relieve
irritation. If irritation persists, seek medical attention.
2. Ingestion : Never give anything by mouth to an unconscious person,
obtain immediate medical attention. If vomiting occurs
spontaneously, keep airway clear. If swallowed give
large amounts of water and induce vomiting. Seek
immediate medical attention.
3. Inhalation : Remove person from contaminated area. If breathing has
stopped, resuscitate and administer oxygen if available.
Seek immediate medical attention
4. Skin Contact : Immediately wash contaminated skin with plenty of
water. Remove contaminated clothing and footwear.
Wash clothing before reuse. Discard footwear if it can
not be decontaminated. If irritation continues, seek
medical attention.

6. FIRE FIGHTING MEASURES

1. Flash Point : Not applicable

2. Auto Ignition : Product is not self igniting
3. Flammable Range : Not flammable in nature, but if involved in a fire, it will
generate toxic oxides of carbon. In the presence of
water, material may react with amphoteric metals (such
as aluminium, zinc or tin) generating hydrogen gas
which will burn or explode if ignited
4. Extinguishing Media : Water fog or spray / carbon dioxide / foam
5. Special Fire-Fighting : Wear NIOSH approved full protective clothing &
self-contained breathing apparatus. Keep containers cool
to prevent rupture and release of material.

7. ACCIDENTAL RELEASE MEASURES

1. Step to taken if material us : Avoid contact with skin, eyes and clothing. Wear
released or spilled protective equipment. Do not inhale dust. Sweep or
shovel up into plastic-lined steel containers and cover.
2. Pollution Protection : Not a severe pollutant. Dilute with plenty of water
3. Protection for spilled of : Flush the spill area with plenty of water and neutralise
chemical with dilute acids like acetic acid & collect the washings
in a specified container. Dispose of in accordance with
local, state and national regulations.
 8. HANDLING AND STORAGE

1. Storage : Store in cool & dry place (preferably within 25-350 C

under closed condition to avoid any contaminations).
Keep away from acids and organic compounds. Loosen
cover cautiously when opening.
2. Handling : Emergency eye wash and safety shower should be
available. Wash thoroughly after handling.
3. Protective practices during : Wear NIOSH approved full protective clothing &
maintenance of self-contained breathing apparatus. Keep containers cool
contaminated equipment to prevent rupture and release of material
4. Special Precaution : Store above freezing temperature

9. EXPOSURE CONTROLS/PERSONAL PROTECTION

1. Ventilation and : Local exhaust recommended

Engineering Controls
2. Respiratory Protection : Use NIOSH approved respirator whenever necessary
3. Eye Protection : Chemical safety goggles / face shield
4. Skin Protection : Chemically resistant coveralls, hat & shoes or boots
5. Other Protective : Use Neoprene / natural rubber glooves
equipment

10. STABILITY AND REACTIVITY

1. Chemical Stability : Stable

2. Conditions to avoid : Stable under normal conditions. Avoid moisture and
heat.
3. Material with which : Acids and oxidizers.
chemical mixture is
incompatible
4. Reactivity :
a) Hazardous If involved in a fire, it will generate toxic oxides of
decomposition products carbon and miscellaneous organic vapours.
b) Hazardous Will not occur.
Polymerization

11. TOXICOLOGICAL INFORMATION

1. Toxicity Data : Non-toxic in nature.

2. Carcinogenicity : The product have been found not to be carcinogenic
3. Irritancy of Product : Mildly irritating to contaminated tissues depending on
the duration of contact
4. Sensitization of Product : The components of this products are not known to be
sensitiziers
5. Reproductive Toxicity : No reproductive toxicity is expected in humans
information
6. Mutagenicity : The product is not expected to cause any mutagenic
effects in human
7. Embryotoxicity : The product is not expected to cause embroytoxic effects
in human.
8. Teratogenicity : The product is not expected to cause teratogenic effects
in human.
9. Biological Exposure : No data are available.
Indicates

12. ECOLOGICAL INFORMATION

1. Environmental Stability : Naturally stable

2. Effect of Material on : Product is known to have non-toxic effects.

Plants or Animals
3. Effect of Chemical on : Product is known to have non-toxic effects.
Aquatic Life
4. Mobility : The components of this product are inert and hence do
not present any hazard of mobility.
5. Persistence and : All components of this product are known to be
Biodegradability biodegradable.
6. Potential to : No data are currently available
Bioaccumulations
7. Ozone-Depletion Potential : Not applicable

13. DISPOSAL CONSIDERATION

1. Unused Product/ Empty : Wash thoroughly the empty packing material / drum /
Container carbouys and collect the washings in suitable containers
& dispose the same in accordance with the local, state
and national regulations.
2. Disposal Information : Dispose of in accordance with local, state and national
regulations. For major spills consult Grauer & Weil (I)
Ltd., for necessary action.

14. TRANSPORT INFORMATION

1. International Maritime Organization Shipping Information (IMO) :

UN-Number :
Packaging group :
Label :
EmS No. :
MFAG No. :
IMDG Class
Addit Description of :
goods

2. International Air Transport Association Shipping Information (IATA) :

UN-Number :
Packaging group :
Label :
EmS No. :
MFAG No. :
 IMDG Class :
Addit Description of :
goods
Additional Information : No dangerous goods in-accordance with the above
orders.

15. REGULATORY INFORMATION

1. Designations according The product is not subjected to identification

to EC guidelines regulations under EC directives and the Ordinance
on Hazardous Materials (GefStoffV).
Observe the normal safety regulations when
handling chemicals.
2. National regulations : R 51 / 53 Water hazard class 2 (Self-assessment) :
hazardous for water

16. OTHER INFORMATION

Abbreviations for R phrases
10 Flammable 2 / 25 Toxic by inhalation and if swallowed
21 Harmful in contact with skin 34 Causes burns, 35 Causes severe burns
23 / 24/ 25 Toxic by inhalation, in 36 / 38 Irritating to eyes and skin.
contact with skin and if swallowed
R 51 / 53 Toxic to aquatic 48 / 22 Harmful : danger of series damage of
organisms, may cause long-term skin by prolonged exposure if swallowed.
adverse effect in aquatic
environment.
Safety phrases
26 In case of contact with eyes, 36 / 37 Wear suitable protective clothing and
rinse immediately with plenty of gloves.
water and seek medical advice.
45 In case of accident or if your 60 This material and its container must be
feel unwell, seek medical advice disposed as hazardous waste.
immediately.

DISCLAIMERS : The information in this MSDS was obtained from sources

which we believe are reliable. However, the information is provided without any
warranty, express or implied, regarding its correctness. The conditions or methods
of handling storage, use and disposal are beyond our control and may be beyond
our knowledge, for this and other reasons, we do not assume responsibility and
expressly disclaim liability for loss, damage or expense out of or in any way
connected with the handling storage, use or disposal of the product.