Revision date: 10/05/2021 Revision: 6 Supersedes date: 30/04/2019

SAFETY DATA SHEET

Denso Primer D (UK)
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name Denso Primer D (UK)

UFI UFI: 7AJR-QSUE-NS07-7XYK

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Rust-preventing primer.

1.3. Details of the supplier of the safety data sheet

Supplier Winn & Coales (Denso) Ltd
Denso House
Chapel Road
West Norwood
SE27 0TR
+44 (0)208 670 7511
mail@denso.net

1.4. Emergency telephone number

Emergency telephone +44 (0)208 670 7511 (M-F, 8-5 GMT)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Flam. Liq. 3 - H226

Health hazards Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Irrit. 2 - H315

Environmental hazards Not Classified

2.2. Label elements

Hazard pictograms

Signal word Warning

Hazard statements H226 Flammable liquid and vapour.

H312+H332 Harmful in contact with skin or if inhaled.
H315 Causes skin irritation.

1/9
Revision date: 10/05/2021 Revision: 6 Supersedes date: 30/04/2019

Denso Primer D (UK)

Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P261 Avoid breathing vapour/ spray.
P264 Wash contaminated skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTRE/doctor if you feel unwell.
P321 Specific treatment (see medical advice on this label).
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/ container in accordance with national regulations.

Contains xylene

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Bitumen 30-60%
CAS number: 8052-42-4 EC number: 232-490-9

Classification
Not Classified

xylene 30-60%
CAS number: 1330-20-7 EC number: 215-535-7

Classification
Flam. Liq. 3 - H226
Acute Tox. 4 - H312
Acute Tox. 4 - H332
Skin Irrit. 2 - H315

The full text for all hazard statements is displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Get medical advice/attention if you feel unwell. Show this Safety Data Sheet to the medical
personnel.

2/9
Revision date: 10/05/2021 Revision: 6 Supersedes date: 30/04/2019

Denso Primer D (UK)

Inhalation Remove affected person from source of contamination. Move affected person to fresh air and
keep warm and at rest in a position comfortable for breathing. Maintain an open airway.
Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trained
personnel may assist affected person by administering oxygen. Place unconscious person on
their side in the recovery position and ensure breathing can take place.

Ingestion Rinse mouth thoroughly with water. Remove any dentures. Give a few small glasses of water
or milk to drink. Stop if the affected person feels sick as vomiting may be dangerous. Do not
induce vomiting unless under the direction of medical personnel. If vomiting occurs, the head
should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. Move affected person to fresh air and keep warm and at rest in a
position comfortable for breathing. Place unconscious person on their side in the recovery
position and ensure breathing can take place. Maintain an open airway. Loosen tight clothing
such as collar, tie or belt.

Skin contact Wash skin thoroughly with soap and water. Do not use organic solvents.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 10 minutes.

Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue. If it is
suspected that volatile contaminants are still present around the affected person, first aid
personnel should wear an appropriate respirator or self-contained breathing apparatus. Wash
contaminated clothing thoroughly with water before removing it from the affected person, or
wear gloves. It may be dangerous for first aid personnel to carry out mouth-to-mouth
resuscitation.

4.2. Most important symptoms and effects, both acute and delayed
General information See Section 11 for additional information on health hazards. The severity of the symptoms
described will vary dependent on the concentration and the length of exposure.

Inhalation A single exposure may cause the following adverse effects: Headache. Nausea, vomiting.
Central nervous system depression. Drowsiness, dizziness, disorientation, vertigo. Narcotic
effect.

Ingestion Gastrointestinal symptoms, including upset stomach. Fumes from the stomach contents may
be inhaled, resulting in the same symptoms as inhalation.

Skin contact Repeated exposure may cause skin dryness or cracking.

Eye contact May cause temporary eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder
or water fog. Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture

Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.
Flammable liquid and vapour. Vapours may be ignited by a spark, a hot surface or an ember.
Vapours may form explosive mixtures with air. Fire-water run-off in sewers may create fire or
explosion hazard.

3/9
Revision date: 10/05/2021 Revision: 6 Supersedes date: 30/04/2019

Denso Primer D (UK)

Hazardous combustion Thermal decomposition or combustion products may include the following substances:
products Harmful gases or vapours.

5.3. Advice for firefighters

Protective actions during Avoid breathing fire gases or vapours. Evacuate area. Keep upwind to avoid inhalation of
firefighting gases, vapours, fumes and smoke. Ventilate closed spaces before entering them. Cool
containers exposed to heat with water spray and remove them from the fire area if it can be
done without risk. Cool containers exposed to flames with water until well after the fire is out.
If a leak or spill has not ignited, use water spray to disperse vapours and protect men stopping
the leak. Control run-off water by containing and keeping it out of sewers and watercourses. If
risk of water pollution occurs, notify appropriate authorities.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing. Firefighter's clothing conforming to European standard EN469 (including helmets,
protective boots and gloves) will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions No action shall be taken without appropriate training or involving any personal risk. Keep
unnecessary and unprotected personnel away from the spillage. Wear protective clothing as
described in Section 8 of this safety data sheet. Follow precautions for safe handling
described in this safety data sheet. Wash thoroughly after dealing with a spillage. Ensure
procedures and training for emergency decontamination and disposal are in place. Do not
touch or walk into spilled material.

6.2. Environmental precautions

Environmental precautions Large Spillages: Inform the relevant authorities if environmental pollution occurs (sewers,
waterways, soil or air).

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills
immediately and dispose of waste safely. Approach the spillage from upwind. Flush
contaminated area with plenty of water. Wash thoroughly after dealing with a spillage.
Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health
hazards. See Section 12 for additional information on ecological hazards. For waste disposal,
see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in
Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs.
Handle all packages and containers carefully to minimise spills. Keep container tightly sealed
when not in use. Avoid the formation of mists. The product is flammable. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. In use may
form flammable/explosive vapour-air mixture. Vapours may accumulate on the floor and in
low-lying areas. Use explosion-proof electrical, ventilating and lighting equipment. Use only
non-sparking tools. Take precautionary measures against static discharges. Do not handle
until all safety precautions have been read and understood. Do not handle broken packages
without protective equipment. Do not reuse empty containers.

4/9
Revision date: 10/05/2021 Revision: 6 Supersedes date: 30/04/2019

Denso Primer D (UK)

Advice on general Wash promptly if skin becomes contaminated. Take off contaminated clothing. Wash
occupational hygiene contaminated clothing before reuse. Do not eat, drink or smoke when using this product.
Wash at the end of each work shift and before eating, smoking and using the toilet. Change
work clothing daily before leaving workplace.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store away from incompatible materials (see Section 10). Store in accordance with local
regulations. Eliminate all sources of ignition. Take precautionary measures against static
discharges. Earth container and transfer equipment to eliminate sparks from static electricity.
Keep away from oxidising materials, heat and flames. Keep only in the original container.
Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protect
containers from damage. Bund storage facilities to prevent soil and water pollution in the
event of spillage. The storage area floor should be leak-tight, jointless and not absorbent.

Storage class Flammable liquid storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
Long-term exposure limit (8-hour TWA): WEL 500 ppm 1210 mg/m³
Short-term exposure limit (15-minute): WEL 1500 ppm 3620 mg/m³

Bitumen
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³ fume
Short-term exposure limit (15-minute): WEL 10 mg/m³ fume
xylene
Long-term exposure limit (8-hour TWA): WEL 50 ppm 220 mg/m³
Short-term exposure limit (15-minute): WEL 100 ppm 441 mg/m³
Sk, BMGV
WEL = Workplace Exposure Limit.
Sk = Can be absorbed through the skin.
BMGV = Biological monitoring guidance value.

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate ventilation. Personal, workplace environment or biological monitoring may
controls be required to determine the effectiveness of the ventilation or other control measures and/or
the necessity to use respiratory protective equipment. Use process enclosures, local exhaust
ventilation or other engineering controls as the primary means to minimise worker exposure.
Personal protective equipment should only be used if worker exposure cannot be controlled
adequately by the engineering control measures. Ensure control measures are regularly
inspected and maintained. Ensure operatives are trained to minimise exposure. The
engineering controls also need to keep gas, vapour or dust concentrations below any lower
explosive limits. Use explosion-proof ventilating equipment.

5/9
Revision date: 10/05/2021 Revision: 6 Supersedes date: 30/04/2019

Denso Primer D (UK)

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. Personal protective equipment for eye and face protection should
comply with European Standard EN166. Unless the assessment indicates a higher degree of
protection is required, the following protection should be worn: Tight-fitting safety glasses.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. The most suitable glove should be
chosen in consultation with the glove supplier/manufacturer, who can provide information
about the breakthrough time of the glove material. To protect hands from chemicals, gloves
should comply with European Standard EN374. Considering the data specified by the glove
manufacturer, check during use that the gloves are retaining their protective properties and
change them as soon as any deterioration is detected. Frequent changes are recommended.

Other skin and body Appropriate footwear and additional protective clothing complying with an approved standard
protection should be worn if a risk assessment indicates skin contamination is possible.

Hygiene measures Provide eyewash station and safety shower. Contaminated work clothing should not be
allowed out of the workplace. Wash contaminated clothing before reuse. Clean equipment
and the work area every day. Good personal hygiene procedures should be implemented.
Wash at the end of each work shift and before eating, smoking and using the toilet. When
using do not eat, drink or smoke. Preventive industrial medical examinations should be carried
out. Warn cleaning personnel of any hazardous properties of the product.

Respiratory protection Respiratory protection complying with an approved standard should be worn if a risk
assessment indicates inhalation of contaminants is possible. Ensure all respiratory protective
equipment is suitable for its intended use and is ‘CE’-marked. Check that the respirator fits
tightly and the filter is changed regularly. Gas and combination filter cartridges should comply
with European Standard EN14387. Full face mask respirators with replaceable filter cartridges
should comply with European Standard EN136. Half mask and quarter mask respirators with
replaceable filter cartridges should comply with European Standard EN140.

Environmental exposure Keep container tightly sealed when not in use.

controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Dark-coloured liquid.

Colour Dark brown.

Odour Solvent.

Odour threshold Not available.

pH Not relevant.

Melting point Not available.

Initial boiling point and range >137°C

Flash point 24°C

Evaporation rate No information available.

Vapour pressure No information available.

Vapour density No information available.

Relative density 0.94

Solubility(ies) Insoluble in water.

Soluble in the following materials: Aromatic solvents. Hydrocarbons. Organic solvents.

6/9
Revision date: 10/05/2021 Revision: 6 Supersedes date: 30/04/2019

Denso Primer D (UK)

Partition coefficient Not relevant.

Auto-ignition temperature No information available.

Decomposition Temperature Not available.

Explosive properties Not considered to be explosive.

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

Volatile organic compound This product contains a maximum VOC content of 398 g/l.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity See the other subsections of this section for further details.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended. Stable under the
prescribed storage conditions.

10.3. Possibility of hazardous reactions

Possibility of hazardous The following materials may react strongly with the product: Oxidising agents.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid heat, flames and other sources of ignition. Containers can burst violently or explode
when heated, due to excessive pressure build-up. Static electricity and formation of sparks
must be prevented. Do not pressurise, cut, weld, drill, grind or otherwise expose containers to
heat or sources of ignition.

10.5. Incompatible materials

Materials to avoid Oxidising materials. Acids - oxidising.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended. Thermal decomposition or
products combustion products may include the following substances: Harmful gases or vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - dermal
ATE dermal (mg/kg) 1,100.0

Acute toxicity - inhalation

ATE inhalation (vapours mg/l) 11.0

SECTION 12: Ecological information

12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
Partition coefficient Not relevant.

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

7/9
Revision date: 10/05/2021 Revision: 6 Supersedes date: 30/04/2019

Denso Primer D (UK)

12.6. Other adverse effects

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible. Reuse or recycle
products wherever possible. This material and its container must be disposed of in a safe
way. Disposal of this product, process solutions, residues and by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation and
any local authority requirements. When handling waste, the safety precautions applying to
handling of the product should be considered. Care should be taken when handling emptied
containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners
may retain some product residues and hence be potentially hazardous.

Disposal methods Do not empty into drains. Dispose of surplus products and those that cannot be recycled via a
licensed waste disposal contractor. Waste, residues, empty containers, discarded work
clothes and contaminated cleaning materials should be collected in designated containers,
labelled with their contents. Waste packaging should be collected for reuse or recycling.
Incineration or landfill should only be considered when recycling is not feasible.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 1263

UN No. (IMDG) 1263

UN No. (ICAO) 1263

UN No. (ADN) 1263

14.2. UN proper shipping name

Proper shipping name PAINT
(ADR/RID)

Proper shipping name (IMDG) PAINT

Proper shipping name (ICAO) PAINT

Proper shipping name (ADN) PAINT

14.3. Transport hazard class(es)

ADR/RID class 3

ADR/RID classification code F1

ADR/RID label 3

IMDG class 3

ICAO class/division 3

ADN class 3

Transport labels

14.4. Packing group

ADR/RID packing group III

8/9
Revision date: 10/05/2021 Revision: 6 Supersedes date: 30/04/2019

Denso Primer D (UK)

IMDG packing group III

ICAO packing group III

ADN packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

EmS F-E, S-E

ADR transport category 3

Emergency Action Code •3Y

Hazard Identification Number 30

(ADR/RID)

Tunnel restriction code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.2. Chemical safety assessment

Inventories
Canada - DSL/NDSL
DSL

US - TSCA
Present.

SECTION 16: Other information

Revision date 10/05/2021

Revision 6

Supersedes date 30/04/2019

SDS number 4601

Hazard statements in full H226 Flammable liquid and vapour.

H312 Harmful in contact with skin.
H315 Causes skin irritation.
H332 Harmful if inhaled.

9/9