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CHEMISTRY 9701/31
Paper 3 Advanced Practical Skills 1 May/June 2023
MARK SCHEME
Maximum Mark: 40
Published
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of the
examination. It shows the basis on which Examiners were instructed to award marks. It does not indicate the
details of the discussions that took place at an Examiners’ meeting before marking began, which would have
considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner Report for
Teachers.
Cambridge International will not enter into discussions about these mark schemes.
Cambridge International is publishing the mark schemes for the May/June 2023 series for most
Cambridge IGCSE, Cambridge International A and AS Level and Cambridge Pre-U components, and some
Cambridge O Level components.
These general marking principles must be applied by all examiners when marking candidate answers. They should be applied alongside the
specific content of the mark scheme or generic level descriptors for a question. Each question paper and mark scheme will also comply with these
marking principles.
the specific content of the mark scheme or the generic level descriptors for the question
the specific skills defined in the mark scheme or in the generic level descriptors for the question
the standard of response required by a candidate as exemplified by the standardisation scripts.
Marks awarded are always whole marks (not half marks, or other fractions).
marks are awarded for correct/valid answers, as defined in the mark scheme. However, credit is given for valid answers which go beyond
the scope of the syllabus and mark scheme, referring to your Team Leader as appropriate
marks are awarded when candidates clearly demonstrate what they know and can do
marks are not deducted for errors
marks are not deducted for omissions
answers should only be judged on the quality of spelling, punctuation and grammar when these features are specifically assessed by the
question as indicated by the mark scheme. The meaning, however, should be unambiguous.
Rules must be applied consistently, e.g. in situations where candidates have not followed instructions or in the application of generic level
descriptors.
Marks should be awarded using the full range of marks defined in the mark scheme for the question (however; the use of the full mark range may
be limited according to the quality of the candidate responses seen).
Marks awarded are based solely on the requirements as defined in the mark scheme. Marks should not be awarded with grade thresholds or
grade descriptors in mind.
1 Examiners should consider the context and scientific use of any keywords when awarding marks. Although keywords may be present, marks
should not be awarded if the keywords are used incorrectly.
2 The examiner should not choose between contradictory statements given in the same question part, and credit should not be awarded for
any correct statement that is contradicted within the same question part. Wrong science that is irrelevant to the question should be ignored.
3 Although spellings do not have to be correct, spellings of syllabus terms must allow for clear and unambiguous separation from other
syllabus terms with which they may be confused (e.g. ethane / ethene, glucagon / glycogen, refraction / reflection).
4 The error carried forward (ecf) principle should be applied, where appropriate. If an incorrect answer is subsequently used in a scientifically
correct way, the candidate should be awarded these subsequent marking points. Further guidance will be included in the mark scheme
where necessary and any exceptions to this general principle will be noted.
For questions that require n responses (e.g. State two reasons …):
The response should be read as continuous prose, even when numbered answer spaces are provided.
Any response marked ignore in the mark scheme should not count towards n.
Incorrect responses should not be awarded credit but will still count towards n.
Read the entire response to check for any responses that contradict those that would otherwise be credited. Credit should not be
awarded for any responses that are contradicted within the rest of the response. Where two responses contradict one another, this
should be treated as a single incorrect response.
Non-contradictory responses after the first n responses may be ignored even if they include incorrect science.
Correct answers to calculations should be given full credit even if there is no working or incorrect working, unless the question states ‘show
your working’.
For questions in which the number of significant figures required is not stated, credit should be awarded for correct answers when rounded
by the examiner to the number of significant figures given in the mark scheme. This may not apply to measured values.
For answers given in standard form (e.g. a 10n) in which the convention of restricting the value of the coefficient (a) to a value between 1
and 10 is not followed, credit may still be awarded if the answer can be converted to the answer given in the mark scheme.
Unless a separate mark is given for a unit, a missing or incorrect unit will normally mean that the final calculation mark is not awarded.
Exceptions to this general principle will be noted in the mark scheme.
Multiples / fractions of coefficients used in chemical equations are acceptable unless stated otherwise in the mark scheme.
State symbols given in an equation should be ignored unless asked for in the question or stated otherwise in the mark scheme.
1(a) I Single table to show results for five experiments (volume of FA 1, volume of water, time and rate) 8
IV Three additional volumes chosen with intervals not less than 5 cm3
AND all volumes of FA 1 not less than 15.00 cm3
Accuracy marks
Time for 20.00 cm3 of FA 1
Calculate ratio: to two decimal places
Time for 40.00 cm3 of FA 1
1(b) I Rate on y-axis and volume of FA 1 on x-axis with unambiguous labels or units 4
II Linear scales (starting at 0,0) chosen so that the graph occupies at least half the available length for both axes
1(c) Yes / directly proportional and as straight line through / close to origin 1
OR no / not directly proportional and line not through origin / curve
1(d) M1 Line drawn at 12.50 cm3 and line drawn across to rate axis 2
OR marks on rate and volume axes within half a small square
Accuracy marks
Correct all temperatures to nearest .5 °C. Calculate T for supervisor and for candidate.
T = initial temperature – lowest / highest temperature in table
Calculate the difference, between supervisor and candidate values
AND
2(b)(iii) M1 Shows attempt at use of Hess’ law / energy level diagram / reverse equation (H =H1 – H2) 2
M2 Correct answer to 2–4 significant figures with appropriate sign
3(a)(ii) 1
yes no
3(b)(ii) 2
test observations
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2
2 Which statement explains why calcium has a higher melting point than barium?
A Calcium cations are smaller than barium cations and have a stronger attraction to the
delocalisedelectrons.
B The structure of calcium is partly giant molecular.
C Therearemoredelocalisedelectronsincalciumthaninbariumasithasalowerionisation
energy.
D There is greater repulsion between barium atoms as they have more complete electron
shellsthancalciumatoms.
3 Three statements about potassium and chlorine and their ions are listed.
1 The atomic radius of a potassium atom is greater than the atomic radius of a chlorine
atom.
2 The first ionisation energy of potassium is greater than the first ionisation energy of
chlorine.
3 The ionic radius of a potassium ion is greater than the ionic radius of a chloride ion.
4 For which equilibrium do both of the equilibrium constants Kc and Kp have no units?
C N2O4(g) 2NO2(g)
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3
–1
5 Calciumcarbide,CaC2,reactswithwater,asshown.Thedatabelowtheequationshow,inkJmol ,
thestandardenthalpiesofformationofthecompoundsinvolved.
6 Inthesodiumchloridelatticethenumberofchlorideionsthatsurroundeachsodiumioniscalled
thecoordinationnumberofthesodiumions.
Whatarethecoordinationnumbersofthesodiumionsandthechlorideionsinthesodiumchloride
lattice?
A 4 6
B 6 4
C 6 6
D 8 6
histidine
H H 2 H
1 H N O
C
H
N C C C C
3
C N H H O H
1 2 3
8 The Contact process takes place at a pressure between 100 000 Pa and 200 000 Pa. A catalyst is
used.
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5
If the concentration of propanone is increased, keeping the total reaction volume constant, the
initial rate of the reaction also increases.
A 14 B 15 C 16 D 17
13 In this question you should assume that the gas formed behaves as an ideal gas.
3 –3
A 1.7 g sample of Mg reacts with 50.0 cm of 2.2 mol dm HCl at 303 K and 110 400 Pa.
14 Chlorine dioxide, Cl O2, reacts with aqueous sodium hydroxide to produce water and a mixture of
two sodium salts, NaCl O2 and NaCl O3.
What effect does this have on the number of molecules with the most probable energy and on the
number of molecules with higher energy?
A decreases decreases
B decreases increases
C increases decreases
D increases increases
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7
16 For which compound is there the greatest percentage loss of mass on strong heating?
17 The solids sodium chloride and sodium iodide both react with concentrated sulfuric acid at room
temperature.
With NaI, the products are NaHSO4, HI, I2, SO2, H2O, S and H2S.
18 SiO2 has a melting point of 1713 °C. It reacts with hot NaOH(aq) to form sodium silicate, Na2SiO3,
and water.
chemical structure
behaviour of SiO2 of SiO2
A amphoteric giant
B amphoteric simple
C acidic giant
D acidic simple
19 Element X has the second largest atomic radius in its period. An atom of X has three occupied
electron shells only.
A 5 B 7 C 9 D 14
20 Which emission from an internal combustion engine contributes to the erosion of marble statues?
A carbon monoxide
B nitrogen
C nitrogen dioxide
D unburnt hydrocarbons
21 The diagram shows the melting points of eight elements with consecutive atomic numbers.
D
melting
point / K
C
A
B
atomic number
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9
22 The boiling points of Br2, ICl and IBr are given in the table.
• whytheboilingpointofIClisgreaterthanBr2
• whytheboilingpointofIBrisgreaterthanICl ?
2+ 2+
23 A solution contains both Mg (aq) and Sr (aq) at the same concentration.
The solution is divided into two equal portions. Aqueous sodium hydroxide is added dropwise to
one portion. Dilute sulfuric acid is added dropwise to the other portion.
24 Structural isomerism and stereoisomerism should be considered when answering this question.
If a molecule contains two non-identical chiral carbon atoms, four optical isomers exist.
A 4 B 5 C 9 D 13
26 An organic molecule W contains 3 carbon atoms. It requires 4.5 molecules of oxygen for complete
combustion.
A propane
B propanoic acid
C propanone
D propan-1-ol
27 Which equation represents a reaction that proceeds through initiation, propagation and termination
steps?
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11
28 Structuralisomerismandstereoisomerismshouldbeconsideredwhenansweringthisquestion.
Asetofisomerichydrocarbons
• allcontain14.3%bymassofhydrogen
• allreactwithbrominebyaddition,0.280gofeachhydrocarbonreactingwith0.799gof
bromine.
A 1 B 3 C 4 D 5
29 Which row describes the solvent used and type of reaction occurring when bromoethane reacts
with NaOH to form ethene?
A ethanol elimination
B ethanol substitution
C water elimination
D water substitution
30 Whichrowdescribesthetypeofreactionthatoccurswhenpropan-1-olreactstoformthenamed
carbon-containingproduct?
32 How many structurally isomeric secondary alcohols are there with the molecular formula C5H12O?
A 1 B 2 C 3 D 4
33 Which reagent:
• canconfirmthepresenceofacarbonylgroupinanorganiccompound
• doesnotdistinguishbetweenaldehydesandketones?
A acidified K2Cr2O7
B 2,4-DNPH reagent
C Fehling’s reagent
D LiAl H4
34 Which compound gives a positive test with alkaline aqueous iodine and does not show optical
isomerism?
A CH3COCH2CH2OH
B CH3CH2CH(OH)CHO
C CH3COCH(OH)CH3
D (CH3)2C(OH)CHO
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13
35 TwosamplesofcompoundXweretreatedseparatelywithdifferentreagentswhichwereaddedin
excess.
Theproductsofthesetworeactionsareshown.
OH O
OH
reaction 1
OH O O
O
compound X OH OH
reaction 2
OH
reaction 1 reaction 2
A hot acidifiedsodiumdichromate VI Na
B hot acidifiedsodiumdichromate VI NaBH4
C Tollens’reagentfollowedbyHCl (aq) Na
D Tollens’reagentfollowedbyHCl (aq) NaBH4
37 Which ester may be hydrolysed to produce two products, one of which may be reduced to the
other?
A CH3CH2CO2CH3
B CH3CH(CH3)CO2CH2CH(CH3)2
C CH3CH2CO2CH(CH3)2
D (CH3)2CHCO2CH(CH3)2
38 Two compounds, X and Y, are mixed and a little concentrated H2SO4 is added.
ester Z
O
O
O
O O
X Y
A CH3CH2OH CH(CO2H)3
B CH3CH2OH CH3CO2CH2CH(OH)CH2OCOCH2CH3
C CH3CO2H CH3CH2CO2CH2CH(OH)CH2OH
D CH3CO2H CH2(OH)CH(OH)CH2(OH)
–CH2–CH=CH–CH2–CH2–CH=CH–CH2–
A CH2=CH2
B CH3CH=CH2
C CH3CH=CHCH3
D CH2=CH–CH=CH2
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15
40 There are two naturally occuring isotopes of bromine. One isotope has 44 neutrons. The other
isotopehas46neutrons.
12 1
Ignoringfragments,howmanypeaksarethereinthemassspectrumoftribromomethane, C HBr3?
A 2 B 3 C 4 D 6
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The Periodic Table of Elements
8&/(6
Group
1 2 13 14 15 16 17 18
1 2
H He
hydrogen helium
Key 1.0 4.0
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
6.9 9.0 relative atomic mass 10.8 12.0 14.0 16.0 19.0 20.2
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23.0 24.3 3 4 5 6 7 8 9 10 11 12 27.0 28.1 31.0 32.1 35.5 39.9
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39.1 40.1 45.0 47.9 50.9 52.0 54.9 55.8 58.9 58.7 63.5 65.4 69.7 72.6 74.9 79.0 79.9 83.8
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85.5 87.6 88.9 91.2 92.9 95.9 – 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
0-
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
132.9 137.3 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium nihonium flerovium moscovium livermorium tennessine oganesson
– – – – – – – – – – – – – – – – –
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
138.9 140.1 140.9 144.4 – 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.1 175.0
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232.0 231.0 238.0 – – – – – – – – – – –