Introduction to Geo sciences
Dr. Olympa Baro
        Assistant Professor
   Department of Civil Engineering
            NIT Silchar
             Unit 2: Minerology
Book of reference: A textbook of geology by P K Mukerjee
• Minerology is a branch of geology, which deals with the
  various aspects related to minerals such as their
  individual properties their mode of formation and mode
  of occurrence
• Minerals are a substances that must meet five
  requirements:
   – naturally occurring
   – inorganic
   – solid
   – definite chemical composition
   – ordered internal structure
• "Definite chemical composition" means that all
  occurrences of that mineral have a chemical composition
  that varies within a specific limited range
• "Ordered internal structure" means that the atoms in a
  mineral are arranged in a systematic and repeating
  pattern
Study of crystals:
• Within the mineral kingdom 98% of the minerals are
  crystalline
• The branch of mineralogy dealing with the study of
  crystals is known as crystallography
• Crystals are solids bounded by smooth, more or less
  plane surfaces arranged in a regular pattern and are
  formed due to operation of inter atomic forces at the
  time of consolidation of the mass from fluid state
  under favorable conditions
• A mineral possessing both the external form
  and internal atomic structure is said to be a
  perfect crystal
• If a mineral has acquired the internal atomic
  structure only without the development of the
  corresponding external form it is called
  crystalline
• If a mineral has developed neither external
  form nor internal atomic structure it is called
  as amorphous
Fundamental difference       between    crystal   and
  amorphous substance:
• In a crystal (or crystalline) there exists a regular
  arrangement of atoms in space
• An amorphous substance exhibits a haphazard and
  random disposition of atoms
Important terms:
• Faces: the smooth surfaces bounding a crystal
• Edges: the straight lines along which the adjacent
  faces meet
• Solid angle: when three or more faces meet at a
  point
                              Fig: Crystal faces, edges
                              and solid angle
• Interfacial angle: angle subtended between the
  normals drawn on the two faces of a crystal
             Symmetry in crystals
• A systematic and regular arrangement of faces, edges, etc., of
  a crystal in space is defined as symmetry
1. Plane of symmetry: It is an imaginary plane
which passes through the centre of a crystal
which divides it into two equal portions which
are exactly the mirror images of each other
How many planes of symmetry will a cube have?
Fig: parallel and diagonal planes of symmetry
2. Axis of symmetry : An axis of symmetry or axis of rotation is
an imaginary line, passing through the crystal such that when
the crystal is rotated about this line, it presents the same
appearance more than once in one complete revolution
   –       Four fold or tretragonal symmetry
   –       Three fold symmetry or trigonal symmetry
   –       Two fold or binary symmetry
                                                      A
       A
3. Centre of symmetry: It is an imaginary point in the
crystal that any line drawn through it intersects the
surface of the crystal at equal distance on either side
  Physical properties of minerals
• The physical characteristics of minerals
  include traits which are used to identify and
  describe mineral species
• These traits include colour, streak, lustre,
  density, hardness, specific gravity, cleavage,
  fracture, lustre, form and structure
Colour:
• The colour of a mineral is produced by the
  wavelengths of light reflected not absorbed by a
  mineral
• The presence of minute impurities effects the
  colour of a mineral
• For example even the smallest impurity in quartz
  such as additional trace elements or gaps or any
  kind of inclusions causes lowest absorptions and
  consequently causes resulting colour
  Fig: Different colours of quartz due to inclusions of one mineral within the host
                                         mineral
• Colour of a mineral is by no means a dependable or
  distinguishable character
Streak
• Streak is the color of the mineral in powdered
  form.
• Streak shows the true color of the mineral.
• The streak of metallic minerals tends to appear
  dark because the small particles of the streak
  absorb the light hitting them.
• Non-metallic particles tend to reflect most of the
  light so they appear lighter in color or almost
  white.
• Because streak is a more accurate illustration of
  the mineral’s color, streak is a more reliable
  property of minerals than color for identification.
Streak Test
• To test the streak color of a mineral you need a streak plate. A
  streak plate is just a ceramic, unglazed tile. To test a mineral
  rub the specimen across the tile as if trying to make a scratch.
  Observe the color the residue left on the tile.
                        Fig: Streak of minerals
Hardness
• Hardness is a measure of the mineral’s resistance
  to scratching.
• Mohs scale which is a set of 10 minerals of known
  hardness is used to measure hardness of
  unknown minerals.
• The softest mineral, talc, has a Mohs scale rating
  of one. Diamond is the hardest mineral and has a
  rating of ten.
• Softer minerals can be scratched by harder
  minerals because the forces that hold the crystals
  together are weaker and can be broken by the
  harder mineral.
Cleavage
• Cleavage is the tendency of a mineral to break
  along certain planes to make smooth surfaces.
• A mineral that naturally breaks into perfectly flat
  surfaces is exhibiting cleavage.
• Not all minerals have cleavage. A cleavage
  represents a direction of weakness in the crystal
  lattice.
• Cleavage is the result of weaker bond strengths or
  greater lattice spacing across the plane in
  question than in other directions within the
  crystal.
Fracture:
• If the mineral contains no planes of weakness, it will break
  along random directions called fracture. Several different
  kinds of fracture patterns are observed.
• Conchoidal fracture - breaks along smooth curved surfaces.
• Fibrous and splintery - similar to the way wood breaks.
• Hackly - jagged fractures with sharp edges.
• Uneven or Irregular - rough irregular surfaces.
                           Fig: Conchoidal fracture
Fig: Splintery fracture.
                                         Fig: Hackly fracture
                           Fig: Uneven fracture
Specific Gravity
• Specific Gravity of a mineral is a comparison or ratio of the
  weight of the mineral to the weight of an equal amount of
  water.
• The weight of the equal amount of water is found by finding
  the difference between the weight of the mineral in air and
  the weight of the mineral in water.
Magnetism
• Magnetism is the characteristic that allows a mineral to
  attract or repel other magnetic materials. It can be difficult to
  determine the differences between the various types of
  magnetism, but it is worth knowing that there are distinctions
  made.
 Luster
 • Luster refers to the general appearance of a mineral
   surface to reflected light. Two general types of luster
   are designated as follows:
1. Metallic - looks shiny like a metal. Usually opaque
    and gives black or dark colored streak.
2. Non-metallic - Non metallic lusters are referred to as
  a)    vitreous - looks glassy - examples: clear quartz,
        tourmaline
  b)    resinous - looks resinous - examples: sphalerite, sulfur.
  c)    pearly - iridescent pearl-like - example: apophyllite.
  d)    greasy - appears to be covered with a thin layer of oil -
        example: nepheline.
  e)    silky - looks fibrous. - examples - some gypsum,
        serpentine, malachite.
   f)   adamantine - brilliant luster like diamond.
Fig: Greasy lustre (Chrysocolla)   Fig: Adamantine Luster (Anglesite)
Crystalline Structure
• Mineral crystals occur in various shapes and sizes. The
  particular shape is determined by the arrangement of the
  atoms, molecules or ions that make up the crystal and
  how they are joined. This is called the crystal lattice.
• There are degrees of crystalline structure, in which the
  fibers of the crystal become increasingly difficult or
  impossible to see with the naked eye or the use of a hand
  lens.
• Microcrystalline and cryptocrystalline structures can only
  be viewed using high magnification.
• If there is no crystalline structure, it is called amorphous.
  However, there are very few amorphous crystals and
  these are only observed under extremely high
  magnification.
•   A small group of a repeating pattern of the
    atomic structure is known as the unit cell of the
    structure.
•   A unit cell is the building block of the crystal
    structure and it also explains in detail the entire
    crystal structure and symmetry with the atom
    positions along with its principal axes.
•   The length, edges of principal axes and the angle
    between the unit cells are called lattice constants
    or lattice parameters.
               Crystal Systems
•   A Crystal System refers to one of the many
    classes of crystals, space groups, and lattices.
    In crystallography terms, lattice system and
    crystal, the system are associated with each
    other with a slight difference. Based on their
    point groups crystals and space groups are
    divided into seven crystal systems.
Triclinic System:
•   It is the most unsymmetrical crystal system. All three
    axes are inclined towards each other, and they are of
    the same length.
•   Some standard Triclinic Systems include Labradorite,
    Amazonite, Kyanite, Rhodonite, Aventurine Feldspar,
    and Turquoise.
Monoclinic System:
•   It comprises of three axes where two are at right angles
    to each other, and the third axis is inclined.
•   All three axes are of different length. Based on the inner
    structure the monoclinic system includes Basal
    pinacoids and prisms with inclined end faces. Some
    examples include Diopside, Petalite, Kunzite, Gypsum,
    Hiddenite, Howlite, Vivianite and more.
•   Orthorhombic System:
•   It comprises of three axes and is at right angles to
    each other. There are different lengths.
•   Based on their Rhombic structure the orthorhombic
    system includes various crystal shapes namely
    pyramids, double pyramids, rhombic pyramids, and
    pinacoids. Some common orthorhombic crystals
    include Topaz, Tanzanite, Iolite, Zoisite, Danburite
    and more.
Hexagonal System:
•   It comprises four axes. The three
    a1, a2 and a3 axes are all
    contained within a single plane
    (called the basal plane) and are at
    120°. They intersect each other at
    an angle of sixty degrees. The
    fourth axis intersects other axes
    at right angles.
•   Crystal shapes of hexagonal
    systems include Double Pyramids,
    Double-Sided Pyramids, and
    Four-Sided Pyramids. Example:
    Beryl, Cancrinite, Apatite, Sugilite,
    etc.
Trigonal System:
• Angles and axis in a trigonal system
  are similar to Hexagonal Systems.
• At the base of a hexagonal system,
  there will be six sides. In the
  trigonal system there will be three
  sides.
• Crystal shapes in a trigonal system
  include three-sided pyramids,
  Scalenohedral and Rhombohedra.
  Some typical examples include
  Ruby, Quartz, Calcite, Agate,
  Jasper, Tiger’s Eyes and more.
Tetragonal Systems:
•   It consists of three axes. The main axis varies in length; it
    can either be short or long. The two-axis lie in the same
    plane and are of the same length.
•   Based on the rectangular inner structure the shapes of
    crystal in tetragonal include double and eight-sided
    pyramids, four-sided prism, trapezohedrons, and pyrite.
Cubic System:
•   Cubic system is the most symmetrical one out of
    the seven crystal system.
•   All three angles intersect at right angles and are
    of equal length.
•   Crystal shapes of a cubic system based on inner
    structure (square) include octahedron, cube, and
    Hexaciscoherdron. Example: Silver, Garnet, Gold,
    and Diamond.