Safety data sheet
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 08.04.2019 Version: 1.0
Product: GARDOBOND ACCLERATOR 14
(ID no. 30723693/SDS_GEN_00/EN)
Date of print 13.04.2019
1. Identification
Product identifier
GARDOBOND ACCLERATOR 14
Recommended use: Surface treatment agent
Not recommended use: None known
Details of the supplier of the safety data sheet
Company:
Chemetall India Pvt. Ltd
Gat No. 569 Village-Koregaon Bhima,
Pune Nagar Road Tal Shirur (Ghodnadi)
Pune 412 216 MAHARASHTRA, INDIA
Tel: +91 2137 618104
Fax: +91 2137 253128
Email: sunil.rane@basf.com
Emergency telephone number
Telephone: +49 1802273112
Telefax number: +91 2137 253128
2. Hazards Identification
Classification of the substance or mixture
According to UN GHS criteria
Acute Tox. 4 (oral)
Eye Dam./Irrit. 2A
Aquatic Acute 1
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 08.04.2019 Version: 1.0
Product: GARDOBOND ACCLERATOR 14
(ID no. 30723693/SDS_GEN_00/EN)
Date of print 13.04.2019
For the classifications not written out in full in this section the full text can be found in section 16.
Label elements
Globally Harmonized System, UN (GHS)
Pictogram:
Signal Word:
Warning
Hazard Statement:
H319 Causes serious eye irritation.
H302 Harmful if swallowed.
H400 Very toxic to aquatic life.
Precautionary Statements (Prevention):
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P273 Avoid release to the environment.
P270 Do not eat, drink or smoke when using this product.
P264 Wash with plenty of water and soap thoroughly after handling.
Precautionary Statements (Response):
P330 Rinse mouth.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you
feel unwell.
P391 Collect spillage.
P337 + P313 If eye irritation persists: Get medical advice/attention.
Precautionary Statements (Disposal):
P501 Dispose of contents/container to hazardous or special waste collection
point.
According to UN GHS criteria
Hazard determining component(s) for labelling: Sodium nitrite
Other hazards
According to UN GHS criteria
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 08.04.2019 Version: 1.0
Product: GARDOBOND ACCLERATOR 14
(ID no. 30723693/SDS_GEN_00/EN)
Date of print 13.04.2019
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.
3. Composition/Information on Ingredients
Substances
Not applicable
Mixtures
Chemical nature
inorganic
aqueous solution
Hazardous ingredients (GHS)
According to UN GHS criteria
Sodium nitrite
Content (W/W): >= 30 % - < 50 % Ox. Sol. 2
CAS Number: 7632-00-0 Acute Tox. 3 (oral)
EC-Number: 231-555-9 Eye Dam./Irrit. 2A
Aquatic Acute 1
M-factor acute: 1
H272, H319, H301, H400
For the classifications not written out in full in this section the full text can be found in section 16.
4. First-Aid Measures
Description of first aid measures
Immediately remove contaminated clothing. Remove affected person from danger area. Symptoms
of poisoning may occur even after several hours, continue medical observation for at least 48 hours
after the accident. First aid personnel should pay attention to their own safety.
If inhaled:
Remove the affected individual into fresh air and keep the person calm. If symptoms persist, seek
medical advice.
On skin contact:
Flush with copious amounts of water for at least 15 minutes. If symptoms persist, seek medical
advice.
On contact with eyes:
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 08.04.2019 Version: 1.0
Product: GARDOBOND ACCLERATOR 14
(ID no. 30723693/SDS_GEN_00/EN)
Date of print 13.04.2019
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist. Immediate medical attention required.
On ingestion:
Rinse mouth and then drink 200-300 ml of water. Summon medical aid without delay.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11.
Hazards: Danger of methaemoglobin formation.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:
carbon dioxide, dry powder, water spray, alcohol-resistant foam
Unsuitable extinguishing media for safety reasons:
water jet
Special hazards arising from the substance or mixture
nitrogen oxides
When dry, the substance/product is oxidising.
Advice for fire-fighters
Special protective equipment:
Appropriate breathing apparatus may be required.
Further information:
Cool endangered containers with water-spray. Collect contaminated extinguishing water separately,
do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated
extinguishing water in accordance with official regulations.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Advice on product handling can be found in sections 7 and 8 of this
safety data sheet.
Environmental precautions
Do not discharge into drains/surface waters/groundwater. Do not discharge into the subsoil/soil.
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 08.04.2019 Version: 1.0
Product: GARDOBOND ACCLERATOR 14
(ID no. 30723693/SDS_GEN_00/EN)
Date of print 13.04.2019
Methods and material for containment and cleaning up
Ensure adequate ventilation. Take up mechanically and collect in suitable container (adequately
labelled) for disposal. Pick up with inert absorbent material (e.g. sand, earth etc.).
7. Handling and Storage
Precautions for safe handling
To avoid the risk of fire, do not allow this product to dry out. Do not return residues to the storage
containers. Provide good ventilation of working area (local exhaust ventilation if necessary). Avoid
inhalation of vapour and spray mist. The workplace should be equipped with an emergency shower
and eye-rinsing facility. Avoid contact with skin and eyes. Keep away from food, drink and animal
feeding stuffs. Warn users about safety measures and precautions to prevent accidents.
Protection against fire and explosion:
The relevant fire protection measures should be noted. Prevent drying-out. Substance/product in the
dry state promotes fires.
Conditions for safe storage, including any incompatibilities
Segregate from acids. Segregate from oxidizable substances. Segregate from ammonium salts.
Segregate from combustible materials.
Suitable materials for containers: Stainless steel 1.4301 (V2), High density polyethylene (HDPE),
Low density polyethylene (LDPE), Polyethylenetherephtalate (PET), Polypropylene (PP)
Further information on storage conditions: The entrance to storage rooms is to be granted only to
appropriately trained personnel. Keep only in the original container. Keep container tightly closed in a
cool, well-ventilated place. Avoid direct sunlight.
Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.
8. Exposure Controls/Personal Protection
Exposure controls
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. (Gas filter EN 14387 B)
Hand protection:
Chemical resistant protective gloves (EN 374)
Further information on penetration time is available from the manufacturer of the glove.
The gloves should be replaced immediately in case of damage or signs of wear. It is recommended
to use preventative skin protection (skin cream).
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 08.04.2019 Version: 1.0
Product: GARDOBOND ACCLERATOR 14
(ID no. 30723693/SDS_GEN_00/EN)
Date of print 13.04.2019
Use suitable protective gloves made of nitrile rubber or butyl rubber. Please observe the glove
manufacturer's instructions on permeability and ruptur times as well as the specific workplace
conditions.
Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)
Body protection:
Chemical resistant protective clothing according to DIN EN 13034 (Type 6)
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Eye wash fountains and
safety showers must be easily accessible. Contact with eyes and skin must be avoided. Take off
immediately all contaminated clothing. Keep away from food, drink and animal feeding stuffs. Hands
and/or face should be washed before breaks and at the end of the shift.
9. Physical and Chemical Properties
Information on basic physical and chemical properties
Form: liquid
Colour: pale straw yellow
Odour: odourless
pH value: 9,0
(20 °C)
(undiluted)
Melting point:
not determined
Boiling point: 100,00 °C
Flash point: > 99 °C
Flammability: hardly combustible
Lower explosion limit:
not determined
Ignition temperature:
not determined
Vapour pressure:
(20 °C)
not determined
(50 °C)
not determined
Density: 1,290 g/cm3
(20 °C)
Viscosity, kinematic: 9,8 mm2/s
(20 °C)
(40 °C)
not determined
Explosion hazard: not explosive
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 08.04.2019 Version: 1.0
Product: GARDOBOND ACCLERATOR 14
(ID no. 30723693/SDS_GEN_00/EN)
Date of print 13.04.2019
Fire promoting properties: not fire-propagating
Other information
Self heating ability: It is not a substance capable of
spontaneous heating.
Miscibility with water:
miscible
Flow time: 35 s (DIN EN ISO 2431; 3 mm)
10. Stability and Reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
Contact with acids may liberate toxic gas. Dried product promotes spreading of fire.
Conditions to avoid
Avoid drying-out. Avoid prolonged exposure to extreme heat.
Incompatible materials
Substances to avoid:
ammonium salts, organic substances, acids, amines
Hazardous decomposition products
Possible decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
11. Toxicological Information
Information on toxicological effects
Acute toxicity
Assessment of acute toxicity:
Of moderate toxicity after single ingestion.
Information on: Sodium nitrite
Experimental/calculated data:
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 08.04.2019 Version: 1.0
Product: GARDOBOND ACCLERATOR 14
(ID no. 30723693/SDS_GEN_00/EN)
Date of print 13.04.2019
LD50 rat (oral): 180 mg/kg
----------------------------------
Irritation
Assessment of irritating effects:
Eye contact causes irritation.
Respiratory/Skin sensitization
Assessment of sensitization:
Based on available Data, the classification criteria are not met.
Germ cell mutagenicity
Assessment of mutagenicity:
Based on available Data, the classification criteria are not met.
Carcinogenicity
Assessment of carcinogenicity:
Based on available Data, the classification criteria are not met.
Reproductive toxicity
Assessment of reproduction toxicity:
Based on available Data, the classification criteria are not met.
Developmental toxicity
Assessment of teratogenicity:
Based on available Data, the classification criteria are not met.
Specific target organ toxicity (single exposure)
Assessment of STOT single:
Based on available Data, the classification criteria are not met.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity:
Based on available Data, the classification criteria are not met.
Aspiration hazard
No aspiration hazard expected.
Other relevant toxicity information
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 08.04.2019 Version: 1.0
Product: GARDOBOND ACCLERATOR 14
(ID no. 30723693/SDS_GEN_00/EN)
Date of print 13.04.2019
Reversible methaemoglobin formation, lowering of blood pressure, danger of circulatory collapse.
Inhalation of nitrous gas (e.g. after fires) can cause lung oedema.
12. Ecological Information
Toxicity
Assessment of aquatic toxicity:
Very toxic to aquatic life. There are no test results available for this product. Do not allow to enter
drains or waterways.
Persistence and degradability
Assessment biodegradation and elimination (H2O):
Biological degradability of hazardous substances mentioned in section 3:
Information on: Sodium nitrite
Elimination information:
not applicable
----------------------------------
Bioaccumulative potential
Bioaccumulation potential:
No data available.
Mobility in soil
Assessment transport between environmental compartments:
Adsorption in soil: No data available.
Results of PBT and vPvB assessment
According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance
fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very
bioaccumulative) criteria.
Other adverse effects
The product does not contain substances that are listed in Regulation (EC) 1005/2009 on
substances that deplete the ozone layer.
13. Disposal Considerations
Waste treatment methods
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 08.04.2019 Version: 1.0
Product: GARDOBOND ACCLERATOR 14
(ID no. 30723693/SDS_GEN_00/EN)
Date of print 13.04.2019
Observe national and local legal requirements.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in the same manner
as the substance/product.
14. Transport Information
Land transport
ADR
UN number UN3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains SODIUM NITRITE)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for
user:
RID
UN number UN3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains SODIUM NITRITE)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for
user:
Inland waterway transport
ADN
UN number UN3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains SODIUM NITRITE)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for
user:
Transport in inland waterway vessel
Not evaluated
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 08.04.2019 Version: 1.0
Product: GARDOBOND ACCLERATOR 14
(ID no. 30723693/SDS_GEN_00/EN)
Date of print 13.04.2019
Sea transport
IMDG
UN number: UN 3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains SODIUM NITRITE)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Marine pollutant: YES
Special precautions for
user:
Air transport
IATA/ICAO
UN number: UN 3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains SODIUM NITRITE)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for
user:
Transport in bulk according to Annex II of MARPOL and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
15. Regulatory Information
Safety, health and environmental regulations/legislation specific for the substance or
mixture
Not applicable
16. Other Information
Full text of classifications, hazard symbols and hazard statements, if mentioned in section 2 or 3:
Acute Tox. Acute toxicity
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BASF Safety data sheet according to UN GHS 4th rev.
Date / Revised: 08.04.2019 Version: 1.0
Product: GARDOBOND ACCLERATOR 14
(ID no. 30723693/SDS_GEN_00/EN)
Date of print 13.04.2019
Eye Dam./Irrit. Serious eye damage/eye irritation
Aquatic Acute Hazardous to the aquatic environment - acute
Ox. Sol. Oxidising solids
H272 May intensify fire; oxidizer.
H319 Causes serious eye irritation.
H301 Toxic if swallowed.
H400 Very toxic to aquatic life.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.
