2
PVC MANUFACTURE TECHNOLOGY
2.1 MONOMER
Vinyl chloride is the sole monomer used in the production of PVC. Its structure and prop-
erties are given in Table 2.1.1.
Table 2.1.1. Typical properties of vinyl chloride
Property Description
General Vinyl chloride is a flammable, colorless gas with a
sweet odor at room temperature. It is mainly used for
the production of PVC but also as a refrigerant and
comonomer.
Chemical structure
H H
C C
H Cl
Chemical formula C2H3Cl
IUPAC name chloroethene
Alternate names chloroethylene, chloroethene, ethylene monochloride
Identifiers CAS # − 75-01-4; EC # − 200-831-0; ΕΧΗΑ # −
618-338-8; UN # − 1086; RTECS − KU9625000;
NIOSH # − KV0350000; transportation # − 49 057 92
Molecular weight, g/mol 62.5
Odor mild, sweet, ethereal
Color colorless
o
Melting point, C -153.8
Boiling point, oC -13.37
o
Decomposition temperature, C 450
Flash point, oC -78 (closed cup)
Autoignition temperature, oC 472
Explosive limits in air, vol% 3.6 and 33
o
Refractive index at 20 C 1.3700
Density, kg/m3 at 20oC 2.56 (gas); 910.6 (liquid)
Vapor density (air=1) 2.15