LPB 296
LPB 296
process safety
leadership site visits
Managing the risks
of stored energy
Updated history of a
solvent recovery plant
site after an explosion
and fire
Three Mile Island –
Can we learn from a
nuclear accident that
occurred 45 years ago?
Book Review:
Flixborough ‘I Was
There’
Five commonly missed
hazards in Process
Hazard Analysis or
Hazard Identification
and Risk Analysis
Understanding hazards
■ Advanced Process Safety Considerations for
Hydrogen Projects
■ Pressure Systems
■ What Engineers Need to Know About
Hydrogen Safety
Human factors
■ Human Factors in the Chemical and Process Industries
IN-COMPANY
on-site or online.
www.icheme.org/process-safety-training
Contents
2 Managing the risks of discussions, incident reviews, and
Loss Prevention Bulletin stored energy – always process plant task audits. These
activities aim to engage with
Articles and case studies expect the unexpected. staff, identify process safety risks,
This article highlights the and demonstrate the leader’s
from around the world importance of managing the risks commitment to safety.
associated with stored energy.
Issue 296, April 2024
It discusses common accidents 18 Three Mile Island – Can
Editors: Tracey Donaldson that can occur due to releases
of stored energy and provides
we learn from a nuclear
& Charlotte Wessels
Publications Director: good practices for ensuring accident that occurred 45
Claudia Flavell-While safety. The article also presents years ago?
Subscriptions: Hannah Rourke a case study of an accident at a This article highlights the main
Designer: Alex Revell power station, emphasizing the events leading to the accident
consequences and investigation and the lessons that can still be
Copyright: The Institution of Chemical findings. The article emphasizes applied today. It discusses failures
Engineers 2024. A Registered Charity in the need for proper procedures in design, control room layout,
England and Wales and a charity registered and communication to effectively alarms, operator skills, and the
in Scotland (SCO39661) manage the hazards of stored normalization of deviance. The
ISSN 0260-9576/24 energy. aim is to emphasize the importance
of learning from past accidents to
The information included in lpb is given in 4 Updated history of a improve safety in all industries.
good faith but without any liability on the
part of IChemE
solvent recovery plant site
after an explosion and fire 22 Book Review: Flixborough
Photocopying This article provides an updated ‘I Was There’: The story
lpb and the individual articles are protected history of a solvent recovery plant of the 1974 Flixborough
by copyright. Users are permitted to site in Cheshire, UK, after an
make single photocopies of single articles disaster
explosion and fire in 1981. The site Rick Loudon’s book, marking
for personal use as allowed by national
copyright laws. For all other photocopying was initially considered suitable 50 years since the Flixborough
permission must be obtained and a fee for housing development, but disaster, intertwines personal
paid. Permissions may be sought directly subsequent sampling and analysis stories with the event’s impact
from the Institution of Chemical Engineers, revealed extensive contamination. on chemical safety. Highlighting
or users may clear permissions and make The contamination posed health
payments through their local Reproduction
survivor accounts and emergency
hazards to animals, leading to the responses, it stresses the
Rights Organisation. In the UK apply
remediation and landscaping of importance of prevention and
to the Copyright Licensing agency
Rapid Clearance Service (CLARCS), 90 the site to form a country park. The ongoing safety lessons.
Tottenham Court Road, London, W1P article highlights the hazardous
0LP (Phone: 020 7631 5500). In the USA nature of the plant’s design and 23 Five commonly missed
apply to the Copyright Clearance Center operation and the failures to
(CCC), 222 Rosewood Drive, Danvers, MA address safety concerns.
hazards in Process
01923 (Phone: (978) 7508400, Fax: (978) Hazard Analysis or
7504744). 8 A toolkit for successful Hazard Identification
Multiple copying of the contents of process safety leadership and Risk Analysis
this publication without permission is
always illegal.
site visits This article discusses often missed
This article presents a toolkit for hazards that are not picked up
Institution of Chemical Engineers leaders to conduct impactful during PHAs and HIRAs. It
Davis Building, Railway Terrace, process safety themed site visits. emphasizes the importance of
Rugby, Warks, CV21 3HQ, UK It emphasizes the importance of diversifying analysis methods,
process safety leadership in setting conducting site visits, and
Tel: +44 (0) 1788 578214 challenging existing practices to
Fax: +44 (0) 1788 560833 the culture of an organization
and reducing the risk of major avoid overlooking these hazards.
Email: tdonaldson@icheme.org accidents. The toolkit includes
or journals@icheme.org eight activities that leaders can
www.icheme.org choose from, such as small group
Incident
maintenance. Information was provided to them in shift were called. A paramedic was on site within 20 minutes
instructions and a detailed drainage schedule. followed by the first ambulance a few minutes later.
• 2:30 a.m.: It became clear that the pressure was not The more seriously injured man had to be rescued from the
decaying quickly enough for preparation work to be scaffold using a mobile elevated working platform. All three
completed by the end of the night shift. Consequently, the men were taken to hospital. The man who had been trapped
system would be handed over in a partially isolated and on the scaffold received 60% burns and spent several days in
drained state. a critical condition on a high dependency ward. Thankfully
he pulled through, but he spent six weeks in hospital. His
• 6:00 a.m.: The day shift arrives to receive a handover. At
colleague who had been working with him on the scaffold
this time the system pressure was 3 barg.
received 26% burns and was hospitalised for two weeks. The
The drainage schedule was referred to during the
third man who went to the rescue of his colleague was allowed
handover. It had been marked up with a highlighter pen
home after treatment that night.
and some handwritten notes. Two sets of valves remained
to be open. The first was the group of drainage valves that Investigation
the night shift had been unable to operate. The second
was a pair of ‘tell-tale’ valves that would provide visual An internal inquiry found the cause of the incident was a failure
confirmation that the system had been fully drained. The to drain the discharge side of the high-pressure recirculating
shift instruction stated that these could be opened when pump where the non-return valve was situated. This occurred
the boiler pressure had fallen to 2 barg. due to communication errors from night to day shift that meant
the status of the system’s drains valves was misunderstood.
• 7:10 a.m.: The pressure had fallen below 2 barg. This was
Whilst the status was indicated on the drainage schedule,
taken as a cue to open the tell-tale valves.
use of a highlighter pen and hand-written notes may have
When the tell-tale valves were opened a small amount
contributed to the error.
of steam was observed to flow to drain, which quickly
Inexperience of the maintenance personnel also contributed.
stopped. This created a strong-but-wrong indication that
They interpreted the small steam flow from the tell-tale valves
the whole system had been drained and depressured
as a positive sign that the stored energy in the system (hot
successfully. However, this was not the case because the
condensate) had been removed. However, they should have
group of drainage valves were still closed, which meant the
first seen a quite significant flow that subsided as the residual 2
tell-tales were isolated from the main system.
barg pressure decayed.
The day shift team leader visited the site and inspected
the telltale valves. Seeing no steam or water he assumed
Conclusions
that the system was in a safe state for maintenance to
commence. The hazards of stored energy can be easily be overlooked.
• 9:40 a.m. A permit for work was issued to the maintenance Even when recognised, the indications used to verify system
team member for the valve repairs. safety can be unreliable or prone to misinterpretation. It
is always inherently much safer to work on systems after
• 3.40 p.m. Two contractors, working from the scaffold,
eliminating all potential hazards, including stored energy. If
started to break the pressure seal on the non-return valve.
this is not considered at the design phase it may be difficult to
Suddenly hot condensate escaped from the seal and
achieve or confirm reliably.
engulfed both men.
Good procedures for removal of energy and personnel
Consequences who understand the hazards and how they are controlled are
essential for managing residual risks. Communication errors
One man was able to escape from the scaffold, but his can significantly contribute to these risks, as common place
systems and
procedures
colleague was not. Another contractor from the same company administrative controls such as permit to work and lock-out
witnessed the incident and went to rescue his trapped tag-out may inadvertently reinforce errors due to the high
colleague. regard in which people hold them, making individuals less
First aiders rushed to the scene and emergency services inclined to question or challenge their effectiveness.
Incident
engineering
and design
company owner/directors; one of these was a chemist and one was adjusted manually so that the rate of vapour generation
an electrical engineer. There was also a works director who was did not exceed the condenser cooling capability. Control thus
an industrial chemist. All three had worked previously in the relied totally on the process operator observing by sight and/or
chemical industry. smell that distillate vapour was emerging from the condenser
There were no manuals describing the plant operation. and then reducing the steam supply to the still. He did this
Operators were trained by verbal instruction from one of the by regulating a manual valve in the steam supply line until the
directors. Day-to-day operations were decided usually by the distillate vapour emission stopped. To enable this practice a
vapour vent pipe from the condenser outlet end was located
alongside the batch stills at about 1.5 m above floor level
where the operator could easily see vapour being emitted from
it. This primitive control method obviously required operator
vigilance to avoid distillate vapour emissions. It was similar in
principle to that used in the 19th century for batch nitration of
glycerine where the operator controlled the hazardous process
while sitting on a one-legged stool to ensure his constant
attention11.
It has been suggested that locating the condenser vent
inside the building (Figure 3) was a process design feature
intended to prevent distillate vapour emission to the external
environment and consequent air pollution12. This suggestion
is incorrect and should not be read as a justification for the
hazardous process control practice. The reality is that having
the condenser vent location inside the building and thus
Figure 2 – Chemstar site readily visible was the essential feature of the process that
enabled the operator to control the distillation. Glass had been of steel drums filled with flammable liquids prompted a study13
removed from the windows in the ground floor close to the by the Health and Safety Executive Laboratories in which 200
stills and replaced by wire mesh panels to allow vapours to litre closed steel drums of acetone were exposed to a shallow
disperse outside the building (Figure 4). Each of these three pool fire. They flew vertically up to 130 m and their contents
mesh panels was 2 m high and 1 m wide. formed a fireball in the drum trajectory. Images captured from
After the later (1988-89) analysis of around 500 samples film of this behaviour are shown in reference 14 along with a
of site soil, and discussion of the results with local residents comprehensive discussion of the mechanisms that can produce
in relation to health risks, a site remediation scheme was missiles when steel drums of flammable liquids are exposed
agreed between the local council and the Department of the to fire.
Environment. A grant of £1.3 million was given to the local The Chemstar solvent recovery operation is an example of
council to enable the site to be modified for use as a park. an economically beneficial recycling activity that avoidably
This scheme involved extensive civil engineering work. Land
where benzene concentration exceeded 5 mg/kg or where
total solvent concentration exceeded 500 mg/kg would be
removed. This required excavation and then burial in an
appropriately licensed landfill of 10,000 m3 of soil. 80 m3 of
soil contaminated by polychlorinated biphenyls (PCBs) and
dioxins was to be excavated, drummed and incinerated in
an appropriate high-temperature facility. To intercept water
leaching from the site towards the houses, a vertical barrier of
bentonite (600 mm thick and 2000 mm deep) and polyethylene
was to be installed in the ground along a 21 m stretch of the
land where the site bordered the village. These planned
actions would be followed by the importation of clean soil,
landscaping and tree planting.
During the fire at Chemstar several 200 litre steel drums of
flammable liquids became missiles as a result of fire exposure,
causing their contents to produce boiling liquid expanding
vapour explosions (BLEVEs). Some of the drums flew up to
300 m beyond the site boundaries. This hazardous behaviour Figure 4: Former Chemstar Site (Drum stacks in areas A, B, C)
created an environmental and social disaster. The hazards and was used solely to remove asbestos from fire-damaged
risks of fire and explosion associated with the plant’s clearly buildings near the site, and to reinforce a dam. The grant
sub-optimal design and operation were not identified and recipients (the local council) assumed that the chemical
appropriately addressed in the context of duties set out by UK contamination identified by the first survey of the site
health and safety laws. would dissipate naturally.
Following its failures after the fire to foresee the persistent 9. Dr. M. Nevell et al. Carrbrook: A textile village and its
and hazardous nature of the site contamination after the fire, valley. A study in the industrialisation of the Pennine
the local authority eventually acted commendably in obtaining uplands. University of Manchester Archaeological Unit
derelict land grants to remediate the Chemstar site and and Tameside MBC (2006). This book contains an aerial
landscape it to form part of the adjacent country park.
photograph showing the Chemstar site lying derelict in
1981 after the wrecked plant and buildings had been
Notes and references removed. The book’s authors wrongly attribute the
1. The explosion and fire at Chemstar Limited 6 September Chemstar explosion to a runaway reaction.
1981. Health and Safety Executive 1982. This report 10. David Kilpatrick. The Sunday Times, June 11 1978. “Where
contains an aerial photograph of the site immediately after there’s chemical muck…”.
the fire.
11. Alfred Nobel batch process for nitroglycerine manufacture.
2. Tom Craig and Roman Grzonka. A case study of land A process description and illustration showing the reactor
contamination by solvents, polychlorinated biphenyls and operator in position on a one-legged stool to ensure his
dioxins. . Land Contamination and Reclamation 2 no 1 attention to temperature control of a batch nitration reactor
(1994) 19-25 are at http://lateralscience.blogspot.com
3. T.O. Craig and R.B. Grzonka. Persistent land contamination
12. T.A. Kletz. What went wrong? Case histories of process
from the operation and subsequent fire destruction of a
plant disasters and how they could have been avoided.
solvent recovery plant. Environmental Protection Bulletin
Elsevier 1985. The invalid explanation in this book that
018 (IChemE 1992) 12-18
Chemstar located the condenser vent inside the process
4. B.J. Alloway and D.C. Ayres. Chemical Principles of building to avoid air pollution remains uncorrected in
Environmental Pollution. (Second Edition) 371-2 Blackie 1997
subsequent editions published through 2009.
5. R.D. Kimbrough et al. Health implications of
13. Dr. Graham Atkinson. Private communication to the author
2,3,7,8-tetrachlorodibenzodioxin contamination of
(1993).
residential soil. J. Toxicology and Environmental
Health 14 47-93 (1984). This paper by workers at the 14. Dr Tom Craig. Storing steel drums of flammable liquids
US Environmental Protection Agency mentions the – regulations and reality. Loss Prevention Bulletin 252
use of guinea pigs as sentinel animals on contaminated December 2016 7-12.
sites to indicate the possible presence of dioxin and its 15. Greater Manchester Fire Service: Chemstar Fire Report
bioavailability. Guinea pigs kept on soils contaminated with FP//F/44/11 (1981). Photographs taken at the Chemstar
dioxin develop a characteristic wasting disorder and have site at the end of the firefighting operation are at www.
an abnormally short lifespan. They are more sensitive than facebook.com/manchesterfire
other animal species to dioxin poisoning. 16. The Control of Pollution Act (1974) defined special waste
6. S.A. Skene et al. Polychlorinated dibenzo-p-dioxins and as waste which is dangerous to life. The legal definition
polychlorinated dibenzofurans: the risks to human health. of this property according to the act is that a single dose
A review. Human Toxicology (1989) 8 173-203 of not more than 5 cm3 would be likely to cause death or
7. Ronald A. Hites. Dioxin: an overview and history. serious damage to human tissue if ingested by a a child of
Environmental Science and Technology (2011) 45 1 16-20 20 kg body weight, or if up to fifteen minutes exposure
8. The first derelict land grant (£500,000) had been would be likely to cause serious damage to human tissue
obtained in 1983 (after the first soil analysis results). It by inhalation, skin or eye contact.
Safety Practice
Leadership site visits & supporting tools best possible light during leadership visits, and this may lead to
intensive efforts to make improvements in the days/weeks prior
In support of adherence to the PSLPs, and the requirements for to them such as housekeeping tours and clean-ups, updating
board level visibility, promotion of process safety management, of records, and organising presentations. From the leaders’
and engaging and involving the workforce in managing safety, perspective, an effective visit will also require planning and
a variety of practices have been adopted. Many organisations discussions with site management to get the best out of it. To this
encourage regular visits to their sites by senior leaders to meet end, it makes sense to ensure that an appropriate programme of
staff and see the facilities first hand5. visits and activities is scheduled in advance, such that the site is
In recognising that some leaders may not have the not inundated with short term or multiple requests for visits, and
competence or confidence to address process safety topics, and the engagements are planned. The plan should capture:
with a view to standardising and improving the approach taken,
several companies have developed leadership engagement visit • all planned leadership visits over the course of the coming
tools and guidance for senior staff, based around key process year.
safety management themes. The frequency of visits to each site • the planned content and timing of each visit.
by each leader may also be mandated. • the ground rules and expectations for the visits in terms of
The tools typically require leaders to look at site conditions and duration, who will be engaged with, expected behaviours
work practices first-hand, often in conjunction with a local leader and outcomes.
who is familiar with the area. They encourage leaders to discuss
their observations with a cross section of staff at the site, and to Conduct of leadership site visits
solicit their opinions on how well work is organised, and where
the process safety risks lie. They also provide a good opportunity Hopkins’ analysis of a trip to the Deepwater Horizon rig by BP
for leaders to share their expectations and values. Importantly & Transocean executives, immediately prior to the blowout
they typically require leaders to provide feedback to the site and in 2010, is particularly helpful in terms of identifying the key
wider organisation on what they have seen, and any actions they factors necessary to deliver an effective leadership site visit6. He
intend to progress as a result. concludes that the visit was particularly ineffective because it:
• had an exclusive focus on personal rather than process
Senior leader site visit toolkit safety;
Scope and purpose • targeted assessment of conditions (e.g. housekeeping)
rather than individuals’ behaviours (actions and decisions)
This paper presents a ‘toolkit’ (or set) of activities that leaders can such as adherence to procedures;
choose from to support them in conducting site visits which have • avoided spending time in areas where there was intense
a positive impact on an organisation’s process safety culture. activity, to avoid interference or disruption;
Each activity is described in terms of its purpose, methodology,
• avoided directly engaging with staff at more junior levels, out
expected benefits and outcomes, time and necessary resources
of a concern not to undermine site leadership or be seen as
to deliver it, target audience, and appropriate suggested follow-
challenging individuals’ competence.
up actions.
The toolkit is based upon the author’s own observations of Hopkins suggests several actions that could have been taken to
senior leader site visits and associated visit protocols made whilst make the visit more effective including:
working in major hazard sectors as a site manager, regulatory
• being aware of the major accident events that could occur on
inspector and safety engineering consultant.
the installation, prior to attendance;
Target audience • understanding the controls that should be in place to prevent
such events, with a view to verifying that they are in place
The toolkit will potentially be of benefit to all companies with
and working as intended whilst on site;
major accident hazard risks. It is designed to be suitable for
use by leaders at all levels and in all functions, including board • being aware of any recent significant process safety incidents
members, directors, middle management and supervisors, and that have occurred on other sites which may have relevance
those in HR, finance, procurement, logistics and others as well as to the current site;
assurance
engineering and operations roles (such as production managers, • dedicating time to check processes which may be of
technical experts, HSE managers, and safety representatives). fundamental importance to process safety;
Many of the activities will however require a baseline level of • being aware of any current operations at the site which might
understanding of operations and major hazards, and so are likely present an opportunity for closer attention, and potentially
to be of greater use to those in such functions. relate to the higher risk issues identified above.
Site leadership visit plan Further guidance that can help senior leaders prepare for and
deliver effective site visits7 includes the following suggestions:
Leadership visits are critically important, in terms of the positive
impact that they can have on the process safety culture of a site, • Finding out when key regular operational meetings occur
and the enhanced awareness of a site risk profile that they can and deciding which ones to attend. Discussion with local
culture
bring to leaders. It is important to recognise however that they management to agree the role the leader will play in these
can also be disruptive to day-to-day operations. meetings.
Site managers will typically want to present their site in the • Preparing a list of topics or questions to ask when meeting
with individuals or work groups. For example, asking people concerns that they express. Site staff will know far more
what the key risks are in their work, what dangers they face about the risks of the activities that they perform than many
and how these are controlled. What activities make the team visiting leaders will, and it is important for leaders to show their
feel uneasy? What key health and safety issues are not being interest, competence, and curiosity in such matters. The latter
addressed? What safety-related equipment is not operational is particularly important for those leaders who do not have a
– and why? How can safety critical activities be improved? background in operations or high hazard risk management.
Being visible to the workforce – speak to as many individuals Similarly, it is important for leaders to take any opportunities
and shake as many hands as possible. Do not be restricted just to that present themselves to set a vision for the standards
meetings with site management. that they expect, and to sensitively challenge any expressed
behaviours or actions which do not meet the requirements.
Notification of the visit This may require explanation or reinforcement of such
In advance of the visit, it can be helpful for the visiting leaders standards and the reasons for them.
to explain to site teams who they are in terms of their current
role and professional background, why they are coming, and Engagement with safety representatives
what their expectations are. This may typically be achieved via Engagement with safety representatives and committees can
an email to all site staff, and possibly in online meetings with be a powerful mechanism for influencing behaviour at a site
site management who can cascade the messages. Done well, and obtaining a ‘warts and all’ perspective on how process
a short video message (vlog) can also be particularly effective safety is really being managed.
in reaching a wider audience and increasing engagement. This Scheduling a meeting with safety representatives at an
upfront messaging sets the scene for the visit, gives the leader early point within the visit agenda will clearly demonstrate to
an opportunity to demonstrate their commitment to safety and the representatives and others that their status and opinions
the wellbeing of their staff, and ideally shows their willingness to are valued. It is important also that any feedback from the
listen, learn, and support the team. In so doing, any barriers to visit is shared with safety representatives at the end of the
starting meaningful safety conversations on site should hopefully
engagement.
be lowered.
Follow-up of issues arising
Prioritisation of visit time on safety matters
It is important that the leader provides feedback to the site
Once on site, it is essential that a key focus of the visit is on
on any observations that they make (both positive/negative).
safety, with other topics playing only a minor role in terms of the
Ideally this should be in the form of an immediate debrief
time spent on them. To do otherwise risks site staff having the
perception that safety is of lesser interest to the leader. before they leave the site, and then some more considered
written feedback once they have been able to consult with
Listening and challenging colleagues and have been able to agree any appropriate follow-
In accordance with the positive leadership traits of being up actions. It is particularly powerful for the leader to be seen
trustworthy, serving others, being empathetic, and being to be acting on any process safety issues that they identify, and
humble, it is important that leaders ask open questions of site they should follow these through with personal interest until
staff, and actively listen and acknowledge the thoughts and they are successfully completed.
Walk the talk representative of the site workforce, to increase the impact of
It is important for leaders to be consistent in their approach and the interaction. The activity will likely take up to 60 minutes.
to lead by example, modelling the behaviours that they expect Purpose
of their teams. If a leader does not adhere to the rules, then
• To obtain an independent and/or alternative view on what
trust and engagement will be reduced.
is really going on at the site, and any issues of concern
In the field of personal safety, leaders should take extra effort
relating to process safety.
to ensure that they follow all site safety policies, including
wearing of PPE, following designated pathways, holding • To demonstrate to staff the importance that the leadership
handrails, etc. It can be helpful for leaders to ask for support/ place on process safety management.
reminders to do so, and to explain that they would welcome Methodology
challenge from people on site, as this can help demonstrate
humility and respect for the rules. • A key part of the session is to establish trust and
engagement with the leader, such that the conversation
In terms of process safety, they should similarly be seen to
can be open and honest. If the leader is not well known
follow site safety policies, but this can be extended to include
to the group, they should spend the first few minutes
other desirable traits, such as demonstrating to staff the
describing their background, before then asking for
following attributes and behaviours:
everyone else to do the same.
Visit activities • The leader should:
The table below describes the eight activities, along with an – Explain the purpose of the session, give an overview of
anticipated duration, and a suggested required level of process what process safety is, and how they are keen to hear
safety competence for them to be delivered effectively. honest opinions of how well process safety is managed
Competence levels are as described by the IChemE Safety within the work area, such that they can provide any
Centre8. necessary support.
– Describe why they feel process safety is important to
Required them, with use of any personal experiences to support
Duration/ this wherever possible.
Activity process safety
minutes
competence – Share details of any occasions where they feel they
1 Small group discussion Awareness 60 may have made a poor decision or error of judgement
2 Incident review – what can we Awareness 30
as a leader, which may have impacted on safety. It can
learn? be helpful to share these to demonstrate humility and
3 A-day-in-the-life Awareness 180 willingness to learn.
– Share a copy of any dashboard or PSPI report or
4 Improvement planning Basic 60
assessment similar that the leader receives and explain that this
5 Control room visit Basic 60
is a key means by which they obtain feedback on the
site’s performance, but they are keen to obtain a fuller
6 Degraded major accident barrier Basic 90
assessment
picture.
7 Process plant task audit Skilled 90 • Ask questions of the group. Examples which may be
8 Safety system audit Skilled 90
effective include:
– If there was going to be a major incident at this site in
Table 2 – Visit activities the coming years, what would it be and why?
– What improvements in process safety have there been
It is important that leaders choose activities that they are at the site in recent years?
confident in delivering, have sufficient time to complete fully, – What is on the improvement plan for process safety this
and are likely to align well with the current risk profile and year?
challenges that the site is experiencing. A poorly delivered – Are any of you involved in any process safety
activity may have a negative impact on the perception of a improvement projects?
senior leader’s commitment to process safety by site staff,
– What would have the biggest impact in terms of
and/or miss an opportunity to identify and challenge poor
reducing the risk of a major incident?
behaviours or practices, both of which ultimately could
– If you had (say) £50k, £500K, or £5M to improve
increase the risk of a major accident occurring in the future.
process safety at the site, what would you spend it on?
– What frustrates you about your job, and getting work
Small group discussion
done?
Activity – What aspects of your role impact on process safety?
Lead a discussion with a small group (4-6) of site staff from – Have you ever reported a near miss relating to process
a variety of different roles/backgrounds, to elicit opinions safety? What was it and what was done about it?
on a range of process safety topics, and how well these are – Have you ever taken part in an audit of a safety system,
managed within the company. Individuals can either volunteer or an investigation of an incident?
to take part or be nominated by site management. It can be – If you had a new task or procedure to follow, and you
helpful if the persons involved are seen to be influential and/or were not sure what to do, what would you do?
– If the plant was running unusually, and the team were incident. These can be captured on a flipchart, word-
unsure what to do, and you couldn’t get any external cloud app or similar. Explore with contributors what they
help or advice, what would you do? mean by the stated causes and encourage them to explain
– Have you seen process safety managed better further/dig deeper, for the benefit of the whole audience.
elsewhere? Summarise any key themes arising.
Overall, it is important that the group feels that the leader is • Display a pre-prepared slide of the key themes and causes
in ‘listening mode’. If appropriate, it can be helpful for the of the incident from the ‘official’ incident investigation
leader to explain that any feedback will be anonymous and report. Add to this with any insights from the previous
aggregated with that from the rest of the visit. audience discussion.
• Invite the audience to think individually for two minutes,
Follow-up activity and to identify any parallels that they can see with current
Thank those taking part for their insights and candour. This operations at their site. They might recognise similar
should be in person, but also ideally publicly in front of any hazards, weaknesses, gaps in control, or other specific
local management/peers, and potentially with a follow- concerns. Then invite the audience to share these with the
up email. Make a note of any observations, concerns or group, and again capture these on a flipchart, word-cloud
suggestions made arising from the discussion, and discuss app or similar. If appropriate, the feedback can also be
these with local management/appropriate technical experts to given anonymously via a piece of paper.
validate them. Agree a set of improvement actions to be taken • Discuss the issues as a group and look for any consensus/
(some may include/require action at a senior level). common themes or agreement. Explore any issues where
there is a strong feeling.
Incident review – what can we learn?
• Thank the group for their participation and insights and
Activity explain that you will reflect on what you have heard.
Lead a discussion centred on a major safety incident, where If there is any obvious follow-up activity required,
there is potentially transferable learning. The incident can be acknowledge what you will do next to address it.
from within the leader’s current organisation, their previous
Follow-up activity
experience, or from information available in the public domain.
It is best if there is clear process safety content, but often Review the observations made at the session with local
incidents from within different sectors and with different risks management/appropriate technical experts. Agree a set of
can be valuable where they relate to organisational failings improvement actions to be taken (some may include/require
(e.g. RAF Nimrod, Herald of Free Enterprise etc). The activity action at a senior level).
can engage a room full of people and will likely take up to 30
minutes. A day-in-the-life
Activity
Purpose
Spend a work period (e.g morning/afternoon) shadowing a
• To raise awareness of key process safety principles, hazards
person in a front-line management role with a direct impact
and controls.
on process safety, learning about the tasks that they perform,
• To encourage participants to reflect on operations at their interactions they have with others, and challenges they face.
own site and to look for parallels/transferable learning. This activity will likely take 2-3 hours.
• To demonstrate to staff the importance that the leadership
place on process safety management. Purpose
This activity can be particularly effective if the leader talks The activity provides an opportunity for the leader to better
about an incident they have first-hand knowledge of, as understand the challenges and decisions that front-line staff
audiences will typically be more engaged. are required to manage on a day-to-day basis, and the impact
that decisions made at a senior level are having. By carefully
Methodology observing and listening and asking questions, leaders will also
• Identify a safety incident to base the discussion around, demonstrate the issues that they care about.
and research what happened and why. Good sources of Methodology
incidents investigation reports include the US Chemical
Safety Board9, Health & Safety Executive10 and the Energy • In conjunction with local site management, identify a job
Institute11. role and individual to work shadow. Ideal roles include
shift team supervisors, maintenance team leaders, plant
• Introduce the incident:
managers etc.
– Give a brief description of the site, company, and history
• Contact the individual in advance of the session to explain
leading up to the incident;
the purpose of the visit, establish any ground rules,
– Show pictures of the site before the incident; and allay any concerns that they may have. As with the
– Ask audience to guess what happened next; ‘Leadership-led small group discussion’, a key initial task for
– Show pictures of the site after the incident, and describe the leader is to introduce themselves and establish trust. It
what took place, the scale of the release, who/what was is also important to stress to the individual that it is the role
harmed, and the consequences. and systems that are being observed, and not the person.
• Invite the audience to suggest possible causes of the An individual’s performance should be seen as likely to
reflect the local culture and norms, rather than just the To demonstrate to staff the importance that the leadership
individual. place on continuous improvement of process safety
• The purpose of the session is to observe the individual go management.
about their normal role, so a specific agenda or activities
Methodology
need not be planned. The individual should be asked to
share their expected itinerary for the session (including • In advance of the visit, obtain a copy of the site’s most recent
people to see, meetings to attend, tasks to perform etc), annual performance review and improvement plan.
and where possible to explain what they are doing as they • Review the content of the performance review and assess
do it (or in advance if possible). With consent, the leader whether it adequately takes into account relevant sources of
should tag along to all activities. Topics for the leader to intelligence on the current level of process safety risk,
consider are shown in Table 3. such as:
– Near miss and incident reports and investigations.
Topic Considerations – Safety Management System audit reports and
Priorities How much time is spent by the individual; performing recommendations.
administrative tasks; on plant vs in office; coaching
staff; managing safety systems (e.g. permit to work, – Process Hazard Analysis (revalidation/reHAZOP studies).
task risk assessments). Is the balance appropriate? – Degraded equipment or safety systems (e.g. referenced
Are they accessible to their team? Are they ‘seen’ as a
safety leader?
by temporary operating procedures, operating risk
assessments).
Standards Are high standards expected by the individual of their
team members? – Current asset condition reports and progress with
Does the leader role model good standards improvement initiatives.
themselves?
Does the individual feel they have clear direction from – Staff training and competency assurance systems, and
above? any organisational changes.
Risk management Does the individual focus their time/attention on – Progress with current process safety improvement plans.
the highest risk areas (e.g. due to nature of a task,
competence of team members etc)? – Recent enforcement action by health and safety regulator.
Does the individual have a good understanding of the – Changing legislation and emergent good practice.
local hazards and controls? How do they know that
they are in good health? – Views of staff and safety representatives.
Does the individual feel they have sufficient access to
• Review the content of the improvement plan and assess
support and advice from technical experts and their
line management? whether it adequately addresses the challenges identified by
Safety authority Does the individual feel they have the authority to stop
the performance review above:
a job or task, without reference to others first, if safety – Are the improvement plans SMART (specific, measurable,
is threatened? achievable, relevant, time-bound)?
Barriers to success What are the blockers to the individual delivering – Are the improvement areas prioritised appropriately?
effective process safety management?
– Is there sufficient resource locally to implement the
Table 3 – Work shadowing topics to consider improvements?
Follow-up activity – Is there appropriate resource from outside of the site
(within the company or external) to support the plans?
Thank the individual for taking time to explain the work that
they do and for performing the activities diligently and with – How is progress being measured, and how visible are the
care (where appropriate). This should be in person, but also plans to all?
ideally publicly in front of any local management/peers, • Discuss the above with staff to obtain their perspective on
and potentially with a follow-up email. Make a note of any the matters. Are plans credible? Are the significant threats
observations, concerns or suggestions made arising from the being addressed? Where should resources and attention be
visit, and discuss these with local management/appropriate focussed?
technical experts. Agree a set of improvement actions to be
taken (some may include/require action at a senior level).
Follow-up activity
Make a note of any observations, concerns or suggestions
Improvement planning assessment made arising from the discussion, and discuss these with local
management/appropriate technical experts. Agree a set of
Activity
improvement actions to be taken (some may include/require
Carry out a review of the suitability of the site’s process safety action at a senior level).
improvement plans and initiatives, through discussion with
the site manager, discipline engineers, and worker safety Control room visit
representatives. The activity will likely take up to 60 minutes.
Activity
Purpose Spend time in the control room in discussion with operators,
To assess whether the site has a good understanding of its reviewing paperwork records, and inspecting equipment and
current process safety challenges and has sufficient resources systems. The activity should be limited to a maximum of 60
and capability to deliver any necessary improvements. minutes and be sensitive to the needs of their role.
Access to If you have a plant problem, how do you Supervisors and technical staff are readily contactable. Operating manuals and drawings are available
support get help when you need it? and up-to-date.
Major accident
What emergency situations could occur? A good understanding of credible scenarios (small to big) from the installation safety case/
hazard
report. Written plans which are readily accessible and clearly tell the team what they need to do.
awareness and
Do you have written emergency response Regular exercises (desktop discussions and simulated drills) to refresh understanding and test
emergency
plans and do you practice them? effectiveness of response.
response plans
Topic Considerations
Identification of degraded Have all degraded situations been recognised, and has an assessment of the risk been made? Are there any degraded system
barriers seen on site or discussed which are not assessed within a management system?
Is the assessment suitable and Has the assessment involved the right people with the relevant technical expertise? Has the risk been escalated to an appropriate
sufficient? level within the organisation?
Has the assessment been recorded in writing, authorised by an appropriate person, and communicated to those who need to
Approval and communication
know?
Has an appropriate duration been set for rectification of the fault? If the date has been exceeded, has it had appropriate
Duration
re-assessment and re-authorisation?
Are any mitigation actions identified by the assessment likely to be effective, and are they actually happening? Is there evidence
Mitigation actions
to support this?
Is the residual risk acceptable? Do local leaders feel comfortable that they are managing their degraded barriers? Are cumulative
Residual risk
risks arising from multiple coincident degraded barriers taken account of effectively?
– Please give an overview of the task and the key steps. reviewing a sample of records, discussions with users of the system,
– What could go wrong, and what are the important systems and visits to worksites. It is ideal if the system is actively in use at the
or controls that make it safe? site, with multiple records available for checking, and where a failure
to adhere to it could lead to a risk of a major incident. The activity
– Have there been any near misses or incidents on this
will likely take up to 90 minutes.
system in the past? Has anything changed since then to
deal with the problem? Do you have any concerns with Purpose
the operation or task? • To obtain an independent and/or alternative view on what is
• Walk around the equipment with the operator and get them really going on at the site, and any issues of concern relating to
to explain what each item is and note its condition. process safety.
• Witness the task being performed (ask operator to describe • To demonstrate to staff the importance that the leadership
each step and the purpose before they do it). place on process safety management.
• Ask questions: This activity can be particularly effective if it is targeted at a risk
– Why is this step important? What could go wrong? control system with known weaknesses.
– How would you know if there was a problem? How Methodology
would you deal with each problem?
• Choose a safety system to be checked. Good examples include
Look out for the following sorts of deficiencies listed in Table 6: energy isolations, permit to work, inhibits/ overrides
of instrumented protective systems, Operational Risk
Deficiencies Examples
Assessments (ORAs), asset integrity management, etc.
Plant equipment Pressure gauge not working, interlock system defeated,
defects leaks, drips, spills, valves stiff or missing handles, loose
• In advance of the visit, obtain a copy of the company/site
bolting, open ends on pipework (not capped or blanked). procedure relating to the system being looked at, and with a
relevant expert identify the key controls that need to be in
Workplace Poor housekeeping, inadequate labelling or signage,
conditions defective or insufficient lighting, difficult access, escape place, questions to ask, and evidence to look for.
issues routes blocked, safety equipment not accessible, means • Look at the records (paper or electronic) which relate to the
of communication with control room not functioning well,
noisy environment, extremes of temperature.
system being checked. With the help of a local contact/user
of the system, pick out three examples for further scrutiny
Operating Procedural steps not followed or omitted, steps followed
which appear likely to be a combination of:
procedure non- in a different sequence from procedure, procedure does
compliance not reflect installed equipment or task to be performed. – current (active i.e. the risk is present and controls are in place).
Operator Operator demonstrates lack of understanding of task/ – higher inherent risk (i.e. relate to systems containing high
competence procedure, operator does not have necessary skills pressure, high or low temperature, flammable or toxic
and supervision or experience to perform task successfully, operator
does not have sufficient support or involvement from
materials).
supervision or colleagues. – more unusual or less frequent.
Table 6 – Process plant task deficiencies • Carry out a check of the records against the requirements of
the procedure and the identified key elements of control.
If the leader is not confident in being able to identify deficiencies • Visit the worksite (where appropriate) to check that the
by themselves, it can be helpful to ask the operator to identify controls or systems are in place as expected.
them directly through questioning. For example, the leader can
• Discuss with the users of the system how well they feel the
ask questions such as, ‘is there any of this equipment which is
system is working locally and ask them to suggest any potential
broken?’ or ‘are there any steps in this procedure which don’t make
improvements.
sense?’ In addition, or alternatively, the leader can ask a technical
person to join the walkaround. It is ideal however if that person is An example of the key principles that should be in place, questions
independent of the site, such that they do not risk influencing the to ask, and evidence to look for is shown in Table 7 and 8 for the
behaviour of the operator in the way that they perform the task, or topic of asset integrity management of pressurised equipment.
report on any issues.
Asset integrity management – pressurised equipment
Follow-up activity • There must be an up-to-date register of all pressurised equipment at the
Thank the technician for supporting the audit, taking time to site (pressure vessels, pressure relief devices etc).
explain the work that they do, and performing the activity diligently • All pressure containing equipment must be risk assessed to identify
probable degradation threats and hazards. Written schemes of
and with care (where appropriate). This should be in person, but examination (WSE) and maintenance plans must be defined in
also ideally publicly in front of any local management/peers, and accordance with the assessments.
potentially with a follow-up email. Make a note of any observations, • Inspection and testing of pressure containing equipment must be
concerns or suggestions made arising from the visit, and discuss performed in accordance with the WSE and maintenance schedule.
these with local management/appropriate technical experts. Agree • Leadership must be informed (and have sight) of missed, failed and
overdue inspection, testing, maintenance and remedial repairs to
a set of improvement actions to be taken (some may include/
pressurised equipment.
require action at a senior level). • Equipment should not be operated outside of its safe operating
conditions envelope, or if it has not been inspected and maintained in
Safety system audit accordance with the WSE and maintenance schedule, unless this has
been risk assessed as safe to do so by a suitably competent person.
Activity
Carry out a check on the health of a procedural safety system by Table 7 – Pressure equipment key requirements for safety
How are equipment degradation risks identified A written assessment must have been completed, led by a competent Engineering authority/
and managed? engineer, and with input from relevant functions (materials engineering, responsible person
operations etc).
How are equipment inspection requirements Inspection programme which is based on the equipment degradation Engineering authority/
identified? Who carries out inspections, and assessment (risk-based inspection – RBI). Competent inspector responsible person
who reviews the results? undertakes the inspections, and competent engineer reviews the findings.
How do you know that pressure containing Inspections and maintenance activities are being completed in line with Engineering authority/
equipment is in a safe condition? schedule requirements. Remedial actions identified through inspection are responsible person
being completed in a timely manner.
What do you do if you find a problem with Take plant to a safe state. Stabilise operations and shut down if unsure if Engineering authority/
pressure containing equipment, or it has required. Inform operations leadership. responsible person /operations
operated outside of its safe limits? team
Follow-up activity 5. Hynds, A., Chambers, C., & Prout, K., Leadership matters
Make a note of any observations, concerns or suggestions - examples of process safety leadership good practice,
made arising from the discussion, and discuss these with local IChemE, Hazards 31: Symposium Series No. 168, 46, 2021.
management/appropriate technical experts. Agree a set of 6. Hopkins, A., Management Walk-arounds: Lessons from
improvement actions to be taken (some may include/require the Gulf of Mexico oil well blowout, Safety Science, Vol 49,
action at a senior level). 1421-1425, 2011.
7. Anderson, M., Leadership Site Visits, accessed at https://
References humanfactors101.com/topics/safety-leadership/ on
1. Cooper, D., Improving Safety Culture – a practical guide, John 8/9/2023.
Wiley & Sons Ltd, London, 1998. 8. IChemE, ISC Process Safety Competency Guidance, 2019,
2. Kerin, T., The importance of (process safety) leadership, accessed at https://www.icheme.org/media/12909/isc-
Journal of Loss Prevention in the Process Industries, Vol 66, competency-document-december-2019.pdf on 8/9/2023
104220, July 2020. 9. US Chemicals Safety Board, Completed Investigations,
3. Process Safety Leadership Group, PSLG Principles of Process 2023 accessed at https://www.csb.gov/investigations/
Safety Leadership, 2009 accessed at http://www.p-s-f2.org. completed-investigations/ on 8/9/2023.
uk/wp-content/uploads/PSLG-Principles.pdf on 8/9/2023. 10. Health & Safety Executive, Investigation Reports, accessed
4. Offshore Energies UK, Principles of Process Safety Leadership at https://www.hse.gov.uk/comah/investigation-reports.
for the offshore UKCS Energy Industry, accessed at https:// htm on 8/9/2023.
oeuk.org.uk/wp-content/uploads/2023/03/Principles-of- 11. Energy Institute, Toolbox, https://toolbox.energyinst.org/
Process-Safety-Leadership-1.pdf on 8/9/2023. home on 8/9/2023.
Incident
Summary
This article is written on the 45th anniversary of the Three
Mile Island accident of March 28, 1979. It was the most
serious accident in U.S. commercial nuclear power plant
operating history, although its small radioactive release
had no detectable health effects on plant workers or the
public. Its aftermath brought about extensive changes
involving emergency response planning, reactor operator
training, human factors engineering, radiation protection,
and many other areas of nuclear power plant operations.
It also caused the U.S. Nuclear Regulatory Regime
(NRC) to strengthen its regulatory oversight. This paper
highlights the main events leading to the accidents and
the learnings that could still be valid almost half a century
later. The paper does not intend to cover all failures and
findings from the event, but it highlights tragic events
from other industries which have common features with
this nuclear accident.
Keywords: Nuclear, design, control room, alarms,
normalisation of deviance, operator skills, learning from
past events
Figure 1 – The INES scale (Source: NRC.gov)
Sequence of events series of actions that made the situation worse. The stuck
valve reduced the pressure in the primary system to a level
Figure 2 shows a schematic diagram of the plant to explain the where the reactor coolant pumps started to vibrate and were
series of events on 28 March 1979. turned off. The emergency cooling water being pumped
The event started with either a mechanical or electrical into the primary system threatened to fill up the pressurizer
failure in the secondary, non-nuclear system of the plant. completely—an undesirable condition—to prevent this,
From the investigation report, a resin plug probably prevented operators decided to override the automatic system and
the main feedwater pumps from sending water to the steam cut back on the flow of water. Without the reactor coolant
generators that remove heat from the reactor core. This caused pumps circulating water and with the primary system lacking
the plant’s turbine-generator and then the reactor itself to emergency cooling water, the water level in the pressure vessel
automatically shut down, immediately causing the pressure dropped and the core overheated. As the primary coolant
in the primary system to increase. To control that pressure, drained away that the residual decay heat in the reactor core
the PORV opened. It was located at the top of the pressuriser. was not removed. The core suffered severe damage as a result.
The valve should have closed when the pressure fell to normal
levels, but it became stuck open. Instruments in the control Health effects
room, however, indicated to the plant staff that the valve was
Given the nature of the plant, this nuclear accident caused
closed. As a result, the operators were unaware that cooling
concerns about the possibility of radiation-induced health
water in the form of steam was pouring out of the stuck-open effects, principally cancer, in the area surrounding the plant.
valve. As alarms rang and warning lights flashed, the operators Therefore, the Pennsylvania Department of Health maintained
did not realise that the plant was already experiencing a LOCA. a registry for 18 years monitoring more than 30,000 people
Other instruments available to plant staff provided who lived within five miles of Three Mile Island at the time of
inadequate or misleading information. During normal the accident. The state’s registry was finished in mid 1997,
operations, the large pressure vessel that held the reactor without any evidence of unusual health trends in the area.
core was always filled to the top with water — according to In addition, a number of independent health studies of the
the design at the time “there was no need for a water-level event showed no evidence of any abnormal number of cancers
instrument to show whether water in the vessel covered the around TMI years after the accident. The only detectable
core”. Consequently, operators assumed that if instruments effect was psychological stress during and shortly after the
showed that the pressuriser water level was high enough, it accident, not helped by the China Syndrome movie or the
meant that the core was properly covered with water, but that fact that residents around the plant had never been informed
was not the case. of potential accident scenarios or health effects before the
Unaware of the stuck-open relief valve and unable to tell accident. Media has its acceleration effect in case of tragic or
if the core was covered with cooling water, the staff took a frightening events. People perceive nuclear power energy
systems and
procedures
PORV Control Transformator
rods
Turbine
Generator
Pressurized Condensor
relief tank
Circulating
Reactor Condensate water
core pump pump
Main
feedwater
pump
Primary Secondary
(non-nuclear)
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nuclear plants assumed that the operators were only a backup
to the automatic control.
TMI-2 accident without detailing all the failures revealed by
the investigation. The aim of this paper is to highlight the fact
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that most findings from a nuclear accident that occurred 45
Lack of learning from past events years ago are still valid today and the investigation report is
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As the investigation revealed, there were a lot of so-called worth revisiting for experts not only from the nuclear but all
“precursor events” that would have served as learning points other industries, too. The examples of past accidents which
but not considered by the management of the TMI plant. showed similarities in one way, or another serve as a reminder
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For example, one of the most significant events similar to the to demonstrate how important it is to keep the memory of
TMI-2 accident occurred on 24 September, 1977 at the Davis- past accidents alive and think beyond the fence of our own
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Besse nuclear power station in Ohio, where the relief valve operations to learn and improve.
for the reactor pressurizer failed to close when the reactor,
running at only 9% power, shut down because of a disruption References
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in the feedwater system.
The failure to learn lessons from previous accidents lead 1. “Three Mile Island; A Report to the Commissioners and to
to repeat disasters, for example ammonium-nitrate fertiliser the Public,” by Mitchell Rogovin and George T. Frampton,
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explosions starting with Oppau in 1921, then Texas City NUREG/CR-1250, 1980 (Vol. I, Vol. II Pt. 1, Vol. II Pt.
disaster in 1947, the Toulouse accident in 2001, West Texas 2, Vol. II Pt. 3)
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explosion in 2013, Tianjin explosion in 2015 until the most 2. Three Mile Island Accident, accessed at https://world-
recent accident in Beirut in 2020. nuclear.org/information-library/safety-and-security/safety-
This paper discusses only a few learning points from the of-plants/three-mile-island-accident.aspx
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Hazards34 C nt p
al e en
co w o
no
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or
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IChemE’s Hazards conference is one of the world’s leading process safety conferences. Following a successful event in 2023,
Hazards 34 will continue its tradition of sharing knowledge across every major aspect of process safety.
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Share your insight and experience
Our call for content is open, inviting contributions to the technical programme. We welcome submissions from anyone with
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Sponsoring or exhibiting at Hazards 34 is an excellent opportunity to raise your profile within the international process safety
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296 Gyenes.indd 21 02/04/2024 16:51:58
22 | Loss Prevention Bulletin 296 April 2024
Book review
culture
Safety practice
knowledge and
traps and error-inducing situations); the hazard of workshop.
competence
pyrophoric material; and nitrogen. Vents terminating in congested areas are also dangerous. On 7
February 2010, six workers were killed, and fifty others were injured
Keywords: Process Hazard Analysis, Hazard by a natural gas explosion during the construction of a power plant.
Identification and Risk Analysis, Risk Management At the time of the incident, fuel gas was being vented between
two large structures of heat recovery steam generators (HRSGs).
engineering
and design
The location, while outdoors, was congested by the surrounding
Primary grade source of releases power generation equipment. This arrangement affected the safe
A primary grade source of release is a source of release that is dispersion of the gas and resulted in an accumulation. The gas then
likely to occur periodically or occasionally in normal operations2. found an ignition source, resulting in a vapor cloud explosion3.
In other words, these sources release flammable vapour or gas Pump seals are another primary grade source of release with
during normal operations where it is anticipated to occur during unique hazards. Single or dual pump seals without barrier fluid or
the execution of normal operating procedures. Examples are interspace leak detection are typically considered primary grade
sampling points and drains, process vents, pressure relief valve sources of release2. A packed gland pump seal which requires
tailpipes (terminating to atmosphere), tank vents, breather valves, lubrication from the process media will also be a primary grade
oily water sewers and sumps, pump seals, and pig barrel doors. source of release. Unfortunately, it is not uncommon for process
If the sampling point is frequently used and located in an area pumps to be located inside a pit, below grade level, to provide Net
with adequate ventilation, the source of release will result in Positive Suction Head (NPSH) at the pump inlet. In one of the PHAs
Zone 1 (an area in which an explosive gas atmosphere is likely for an onshore gas receiving facility, a flare knock out vessel also
to occur in normal operation) in the hazardous area classification served as the closed drain vessel. As a drain vessel, it should be
drawing. Most of the time, when designed correctly there will be located at the lowest point of the facility.
human factors
no major concern from these sources. However, during periodic The vessel and the pump used to pump back separated liquid to
plant Hazard Identification and Risk Analysis (HIRA), we found the process was then designed to be located inside the closed drain
specific hazards are missed when the organisation focuses only vessel pit area. The vessel was located approximately 2 m from
on conducting HAZOPs, without site visits, and strengthening the grade on top of a platform inside the pit. The pump was located at
Process Hazard Analysis (PHA) with another method like HAZID the bottom of the pit (about 4.5 m from the grade). Figure 1. Close
(Hazard Identification). drain drum and pump inside a pit shows a simple illustration of the
Firstly, in many facilities’ risk assessment site visits, we found system.
that manual sampling points are located in congested areas. Most The gas received was initially sweet, which indicates that no
of the time this happens when the sampling point is added during hydrogen sulphide (H2S) is present.. However, as production
Flare KO Drum/Closed
Drain Drum
matured, the reservoir became sour and H2S was observed. gas detection and means to provide adequate ventilation need to
Personnel started to smell the rotten eggs-like odour indicating be considered in the design.
the presence of an H2S leak. The team suspected that this came
from the pump seal. During the PHA, it was known that liquid Dissolved toxic gas
inside the vessel (mainly water) contained 5-10 ppm by weight Some toxic gases like H2S can dissolve in water, liquid
of H2S. As will be discussed in the second part of this paper, hydrocarbons, and even liquid sulphur. When these liquids
this concentration may still lead to a high H2S concentration if are routed to equipment open to the atmosphere, H2S will be
flashed to atmospheric conditions. A recommendation was raised released. It is well known that H2S is slightly heavier than air,
to study the feasibility of relocating the system, providing better therefore escaped gas/released H2S may accumulate in low-lying
ventilation, or treating the H2S with chemicals to avoid toxic areas, increasing the risk in case of a leak.
vapour accumulation inside the pit. Another hazard that is commonly missed during PHA is
It is always better to avoid locating a pump with flammable or dissolved H2S in waste streams such as produced water treatment
toxic service inside a pit or any shelter with inadequate ventilation equipment. Produced water is water that comes out from the well
in the first place. The hazardous gas or vapour will accumulate with the crude oil during crude oil production. After the treatment
inside the pit without being effectively dispersed, creating to separate the oil from the water, it is common for produced
significant risk to personnel. If for any technical reason, (e.g. noise, water to be routed to atmospheric tanks, before being re-injected
weather, etc.) the pump needs to be sheltered, toxic/flammable into the reservoir.
To Flare Header
Water from High 3000 ppmv
Pressure Separator H2S in vapour
space Back to HP Separator
Produced
Water Skimmer
To produced
10 ppmw H2S Water Injection
In Water Surge Tank
Crude Oil
Return Pump
Produced
Water Filter
Produced Water
Figure 2 – Produced water skimmer vessel containing H2S Booster Pump
Figure 3 –Two parallel reactors with the same tag number of steam heater actuated valve
REACTOR A REACTOR B
Reactants/Feed Reactants/Feed
Relief Header Relief Header
N2 Sparger N2 Sparger
Water Water
Condensate Condensate
The vapour space between the produced water surface and Error-inducing situation
the top of the tank may be rich in H2S, with a concentration much
With the maturity of plant designs and management system
higher than the liquid itself. For example, in one HAZOP, the
implementation, the industry has now has shifted a significant
process engineer noted that in one produced water skimmer the
portion of its focus to implementing best practices in human
H2S concentration is around 10 ppm (weight based) (Figure 2).
factors. Eliminating error-inducing situations is one of the key
The skimmer experienced accelerated thinning due to focus areas because even the most skillful and experienced
corrosion. Initially the team concluded that the risk was low as the personnel can make errors and mistakes due to error traps.
concentration of H2S was below its IDLH (Immediately Dangerous In one of the HAZOPs of a batch plant, two parallel reactors
to Life and Health) of 100 ppm. However, we suggested the team (Reactor A & B) were heated by steam coils. During the HAZOP,
conduct an isenthalpic flash simulation of produced water from the team identified that one of the overpressure scenarios will
the pressure of the vessel upstream of the skimmer to the skimmer happen if the vent valve of the reactor was accidentally closed
pressure (near atmospheric). This was to understand better the while heating continued (due to accumulation of pressure from
vapour space concentration in case of a skimmer vessel leak. evaporation). The operator was required to close the actuated
The process engineer did a quick simulation and came out with valve for the steam coil using a soft button at the control panel
the result of an H2S concentration of more than 3000 ppm (mole (not automatic) in case of high pressure in the reactor. The
based). This was much higher than the IDLH and could have recommendation was raised to automatically close the actuated
resulted in a fatality following a very short exposure to personnel valve. When formulating the recommendation, the facilitator
in case of a leak. The simulation calibrated the risk perception found that the actuated valve on Reactor A’s tag number was the
of the team, and the risk of produced water skimmer vessel leak same as that of Reactor B. The reactors were located side by side
became a high-priority risk to be mitigated. on the panel display and the actual site. Figure 3 gives a simple
illustration of the setup.
We should never assume that risk is low if the concentration of
Although no incident had happened so far, the team considered
H2S in the liquid phase is low. The vapour space may, and most
how significant the potential for error was. In the case of a high-
of the time will, still represent a serious hazard to personnel. This
pressure alarm, where the operator would be required to take
is true not only for produced water but also for other liquids like
quick action, there are two valves with the same tag number and
crude, condensate (or other hydrocarbon liquids), and liquid
the correct one needs to be quickly closed. The recommendation
sulphur. On 26 October 2019, a release of H2S led to the death was raised with higher priority to close this gap.
of one worker and one member of the public in Odessa Texas. In another HAZOP, an old Sulfamic Acid plant was constructed
This happened inside a pump house of produced water repeated in a three-storey manufacturing building. A significant error-
waterflooding the (injection) facilities. The pump inside the pump inducing situation was identified when the PHA team conducted
house had a broken plunger from which the water containing H2S the site visit. The facilitator noticed a field operator rushing up
was released. A worker attending an alarm was fatally injured from the stairs (unsafely) from the second floor to the third. At the
the exposure to released H2S. Subsequently, the spouse of the end of the site visit, the facilitator asked the operator why he was
injured person gained access to the station and searched for her rushing on the stairs. The operator explained that he was trying to
husband before being exposed to the H2S and succumbing to her close the inlet feed valve to a tank where a high-level alarm was
injuries4. annunciated. The feed came from a neutralisation vessel on
Solution Header
Expansion
Tank 1
Dome Fire Detection
Tank 2
Tank 3
Concentrate Tank 4
Pump
Concentrate Tank 5
Pump
From Firewater
Pump Tank 6
Proportioner
Responder needs to
open the correct value
going to the tank on fire
Figure 4– Centralised foam system for six flammable fluid tanks
the third floor, where sulfamic acid is gravity-fed to the product The foam system was designed to handle a single worst-
atmospheric tank on the second floor. Again, a similar issue case surface tank fire. If the wrong valve was opened in case
was identified. In the case of an alarm, the operator needed to of emergency, there wouldn’t be adequate foam concentrate
quickly close the correct valve. However, the valve was on a left to mitigate the fire. A recommendation was raised to
different floor. The operator needed to rush to climb the stairs, provide adequate labelling and a schematic visible at the
identify the correct valve and then close it. A recommendation solution header to guide the responder in opening the correct
to provide an overflow line was raised to have more passive valve. Another recommendation was to study the feasibility
and inherently safer overflow protection. of modifying the system so that fire detection would open an
In the final example, storage tank facilities were protected actuated valve to the correct tank.
by a centralised foam system. In case of fire, the concentrate The three examples above show how important it is to fight
pump would push the correct amount of foam to the status quo bias in a PHA when eliminating risk from error
proportioner where water was also pumped by the firewater traps and error-inducing situations. The three situations were
pump. The solution produced was then routed to the solution not raised to management before the PHA, as the plant team
header where the responder needed to open one of six valves had grown accustomed to the situation. Only when a more
going to the tank on fire. There were six tanks containing independent facilitator came and pointed out the significance
flammable fluid that depended on the solution of the system in of the risk, was the recommendation raised. In these cases,
PHA site visits also helped raise the independent team to gain a
case of a surface tank fire (Figure 4). During the site visit, the
better understanding of the facility and its concerns.
PHA facilitator noticed that there were no labels or schematics
available on-site to guide the responder to open the correct
valve. As can be seen in the photo, the operator could not see
Pyrophoric hazard
to which tank each of the valves would route the solution. Pyrophoric materials are those that can spontaneously ignite in
the air. They are unique because they do not need an ignition deposits submerged under the water surface during temporary
source to start burning. Some pyrophoric materials also react storage). Lastly, avoid the accumulation of pyrophoric material
violently with water or high humidity. Under some conditions, and immediately remove any solid material removed during
pyrophoric materials deposited inside equipment will smolder for cleaning from the site. Contaminated waste, such as filter
days before spontaneous combustion occurs during equipment elements and waste from fouled equipment cleaning (separation
maintenance or inspection. Pyrophoric ignition is unpredictable tower packing, reboilers, etc.) should be assumed to contain
and thus requires special care. pyrophoric material, unless positively confirmed otherwise.
Iron sulphide (FeS) is the most common pyrophoric material Special care should be given to locating temporary storage of
found in refining and upstream facilities. As its ignition requires the waste from cleaning operations before authorized hazardous
oxygen, there is a higher potential for pyrophoric fires during waste handlers remove them from the site.
shutdowns when equipment and piping are opened to The two examples above show how important it is not to
atmosphere for inspection or maintenance. assume that solid deposits or waste from internal process
At an onshore gas plant, due to reservoir souring, H2S equipment cleaning are free from pyrophoric material if the
started to be observed with a 1-5 ppm concentration in gas. fluid contains H2S. FeS can still form under very low H2S
As the concentration was low, the team considered that concentrations. PHA revalidation should evaluate changes in
no modification was required to the existing process and operating and fluid conditions, including reservoir souring for
procedure. During the PHA, the facilitator raised the concern upstream facilities.
that based on experience, FeS could form even at very low Hazards during activities such as maintenance are rarely
H2S concentrations (below 1 ppm) provided that the partial discussed in periodic plant PHA. A PHA team typically assumes
pressure of H2S exceeded the partial pressure of oxygen in the that a comprehensive Job Hazard Analysis will be done before
environment. A recommendation was raised to review existing the maintenance activities. However, as can be seen in the two
maintenance pigging and equipment maintenance procedures. examples, it is beneficial if the PHA team identifies the hazard
One attendee from the pipeline maintenance team supported the and the need to revisit maintenance procedures during periodic
recommendation and stated that they recently found the deposit PHA upon noticing the change in fluid composition, because
that was cleaned during pigging was smoldering with minor during a PHA, a more complete and independent team is
smoke generated on the pig tray after pigging operations. This working together to identify and assess the risks.
was an indication that some FeS had formed inside the pipeline.
In a similar case at an onshore gas receiving facility, a flash fire Oxygen depletion
occurred during a vessel gas testing for confined space entry The last hazard that is commonly missed during PHA is the use
procedure. During turnaround a horizontal separator needed to of nitrogen (N2) gas in an in adequately ventilated area. In one
be cleaned. Two gas tests were conducted after depressurization upstream facility PHA, the safety function of the wells were
and purging. However, the flammable gas reading after purging managed by wellhead control panels (WHCP). The WHCP
was still high. The team decided to proceed with filling the monitored the downhole safety valves, surface safety valves
vessel with water. The configuration of the nozzles of the vessel (SSV), and other wellhead safety valves for the safety of the
prevented the vessel from being filled with water as the team well and flowlines. The WHCP mainly used pneumatic control
decided to pump the water from the side inlet nozzle instead because the well location is remote from the processing facilities.
of the top. Some portions of the top of the vessel remained In this example, the WHCP pneumatic control used nitrogen
unwetted. When the vessel was emptied and a third gas test was supplied by several 140 barg N2 cylinders connected by hose
conducted, a minor flash fire occurred, injuring the hand of the and tubing to the WHCP. To protect it from the weather and
gas tester (minor burn injury). animals, the WHCP was located inside a house along with the
Upon investigation, it was concluded that after the water filling N2 cylinder (see Figure 5). Periodically, the operations and
or third purging, some of the sludge layers on top of FeS deposits maintenance team would enter the housing to conduct well
were scraped, exposing them to oxygen. As the vessel was surveillance, maintenance, and inspection of the equipment
opened again for the third gas test, FeS ignited upon exposure to inside.
oxygen, and residual vapour at the top portion of the vessel was The system was protected from overpressure by the N2
also ignited. The investigation team also found that the hazard of cylinder by a relief valve discharging directly to atmosphere,
pyrophoric FeS was never identified in the facility’s PHA, as the inside the housing. The facilitator guided the discussion on what
team assumed that the gas was sweet and free of H2S. However, would happen if the relief valve popped or a leak occurred on the
as the reservoir matured some traces of H2S were produced and fitting of the N2 cylinders. To the team’s surprise, the hazard of
this assumption became invalid at the time of the incident. oxygen depletion was not identified in any of the previous PHAs.
Special handling and precautions are required to avoid The WHCP is shown only as a simplified schematic or the P&ID
pyrophoric material hazards. Handling and precautions are based and the fact that it was housed couldn’t be seen in the P&ID. A
on (as a minimum) four strategies explained herewith. First, recommendation was raised to relocate the cylinders, most of the
reduce the concentration of pyrophoric material by periodic valve and fittings, and to relieve the valve outside the housing.
cleaning of internal surfaces. Second, maintain the separation As per one publication, looking into incidents related to N2
of air (oxygen) from pyrophoric material by effective wetting asphyxiation between 1992-2002, failure to detect an oxygen-
of any deposited solid or material as well as inert gas purging deficient atmosphere (due to N2 accumulation) was a significant
(maintaining a continuous barrier of liquid or inert gas between factor that needed to be considered. In the data evaluated
the air and the pyrophoric material). Third, as much as possible, in the study, 78% of incidents involved circumstances where
reduce the temperature of pyrophoric material (keep solid personnel were in or around a confined area where the gas was
Wing valves
accumulating, and personnel failed to detect the increased level system, some risks may be underestimated or overlooked1.
of N2 inside the space5. If a hard-piped fixed N2 system is used A combination of HAZOP and HAZID (e.g., What-If, etc.) is
inside an enclosed building and this cannot be avoided, the advisable. The second best practice is that the PHA should
building should be properly ventilated, and an oxygen-meter also be strengthened by team site visits, not only to gain an
should be installed with an alarm to notify personnel in the case understanding of the process and facilities but also to allow
of an N2 leak. Upon oxygen depletion, a visual indication should intentional hazard inspection of the area by a competent team.
also be provided outside the building or space to warn personnel The third best practice is that the PHA team should act as an
not to enter. independent “hazard hunter” by paying attention to fighting
Auxiliaries and supporting equipment such as WHCP, analyzer status quo bias during the session. Often, a hazard is overlooked
system with its housing, and other similar equipment are often when the team grows accustomed to the site condition, is
missed during plant PHA. The team often focuses only on the weak in process and design, and refuses to challenge existing
main process equipment and thus these pieces of equipment questionable practices and situations.
are often overlooked. But as shown in this example the risk of
oxygen depletion inside the WHCP housing is significant as N2 References
will not be dispersed inside the building. Personnel entering
1. Center for Chemical Process Safety. Guideline for Risk Based
the building may collapse under oxygen depletion resulting in
Process Safety. Hoboken, New Jersey : John Wiley & Sons,
serious injury or even fatality. Storing bottles of compressed N2,
Inc, 2007.
or any other gas, in confined or unventilated areas should always
be avoided. The use of compressed air instead of N2 gas in a 2. Energy Institute. EI15 Model Code of Safe Practice - Area
confined space is inherently safer. Classification Code for Installations. 2015.
3. Chemical Safety and Hazard Investigation Board. Kleen
Conclusions Energy Natural Gas Explosion. [Online] U.S. Chemical Safety
Board, June 28, 2010. [Cited: December 27, 2023.] https://
This paper discusses five (among many) commonly missed
www.csb.gov/kleen-energy-natural-gas-explosion/.
hazards in PHA/HIRA. This includes unsafe designs of primary
grade sources of releases, dissolved toxic gas in the liquid, 4. U.S. Chemical Safety and Hazard Investigation Board.
human factor issues (error-inducing situations), the hazards of Hydrogen Sulfide Release at Aghorn Operating Waterflood
pyrophoric material, and nitrogen. The paper shows that there Station. Washington DC : U.S. Chemical Safety and Hazard
are at least three best practices that we can implement to avoid Investigation Board, 2021. 2020-01-I-TX.
overlooking similar hazards. First, typically, it is advisable to 5. HAZARDS OF NITROGEN ASPHYXIATION. Washington,
diversify the method as each method has unique strengths and DC : U.S. Chemical Safety and Hazard Investigation Board,
weaknesses. If only one method is used to analyze a complex 2003. No. 2003-10-B.
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