Introduction To Explosives 3
Introduction To Explosives 3
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Introduction to Explosives:
An explosive (or explosive material) is a reactive substance that contains a great amount
of potential energy that can produce an explosion if released suddenly, usually
accompanied by the production of light, heat, sound, and pressure. An explosive
charge is a measured quantity of explosive material, which may either be composed
solely of one ingredient or be a mixture containing at least two substances.
The potential energy stored in an explosive material may, for example, be
chemical energy, such as nitro-glycerine or grain dust
pressurized gas, such as a gas cylinder, aerosol can, or BLEVE
nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239
Explosive materials may be categorized by the speed at which they expand. Materials
that detonate (the front of the chemical reaction moves faster through the material than
the speed of sound) are said to be "high explosives" and materials that deflagrate are said
to be "low explosives". Explosives may also be categorized by their sensitivity. Sensitive
materials that can be initiated by a relatively small amount of heat or pressure are primary
explosives and materials that are relatively insensitive are secondary or tertiary
explosives.
A wide variety of chemicals can explode; a smaller number are manufactured specifically
for the purpose of being used as explosives. The remainder are too dangerous, sensitive,
toxic, expensive, unstable, or prone to decomposition or degradation over short time
spans.
In contrast, some materials are merely combustible or flammable if they burn without
exploding.
The distinction, however, is not razor-sharp. Certain materials—dusts, powders, gases, or
volatile organic liquids—may be simply combustible or flammable under ordinary
conditions, but become explosive in specific situations or forms, such as dispersed
airborne clouds, or confinement or sudden release.
History:
Early thermal weapons, such as Greek fire, have existed since ancient times. At its roots,
the history of chemical explosives lies in the history of gunpowder.[1][2] During the Tang
dynasty in the 9th century, Taoist Chinese alchemists were eagerly trying to find the elixir
of immortality.[3] In the process, they stumbled upon the explosive invention of black
powder made from coal, saltpetre, and sulphur in 1044. Gunpowder was the first form of
chemical explosives and by 1161, the Chinese were using explosives for the first time in
warfare.[4][5][6] The Chinese would incorporate explosives fired from bamboo or bronze
tubes known as bamboo firecrackers. The Chinese also inserted live rats inside the
bamboo firecrackers; when fired toward the enemy, the flaming rats created great
psychological ramifications—scaring enemy soldiers away and causing cavalry units to
go wild.[7]
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The first useful explosive stronger than black powder was nitro-glycerine, developed in
1847. Since nitro-glycerine is a liquid and highly unstable, it was replaced
by nitrocellulose, trinitrotoluene (TNT) in 1863, smokeless powder, dynamite in 1867
and gelignite (the latter two being sophisticated stabilized preparations of nitro-glycerine
rather than chemical alternatives, both invented by Alfred Nobel). World War I saw the
adoption of TNT in artillery shells. World War II saw extensive use of new explosives
(see List of explosives used during World War II).
In turn, these have largely been replaced by more powerful explosives such as C-
4 and PETN. However, C-4 and PETN react with metal and catch fire easily, yet unlike
TNT, C-4 and PETN are waterproof and malleable.[
GUNPOWDER
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Properties of explosives:
I. Sensitivity:
Sensitivity is a measure of how easily an explosive can be initiated by external
stimuli such as heat, shock, friction, or impact.
Heat Sensitivity:
Describes how likely an explosive is to detonate or deflagrate when exposed to
heat. A low ignition temperature indicates high heat sensitivity.
Shock Sensitivity:
Indicates how susceptible the explosive is to detonating from a sudden
mechanical shock, such as a hammer blow or a blast wave from another
explosion.
Friction Sensitivity:
Refers to the tendency of the explosive to ignite or detonate when subjected to
frictional forces (e.g., rubbing).
Impact Sensitivity:
Concerns how easily the explosive can be detonated by impact, such as being
struck with a hard object.
II. Velocity of Detonation (VoD):
VoD is the speed at which the detonation wave travels through the explosive
material. It is typically measured in meters per second (m/s).
A higher VoD generally indicates a more powerful explosive, capable of
producing a stronger shock wave.
VoD is crucial for evaluating the effectiveness of an explosive in various
applications, such as cutting or shattering materials.
III. Density:
Density is the mass per unit volume of an explosive, typically expressed in grams
per cubic centimetre (g/cm³).
Higher density can result in more compact, powerful explosions with greater
energy release.
Low-density explosives may require larger volumes to achieve similar effects as
higher density explosives.
IV. Energy Content:
Energy content, also known as heat of explosion, refers to the total energy
released when the explosive detonates.
Measured in joules per gram (J/g) or kilojoules per gram (kJ/g), this energy is
released as heat, light, and sound.
The higher the energy content, the greater the explosive force and effectiveness.
V. Stability:
Stability encompasses the ability of an explosive to withstand environmental
factors without decomposing or becoming overly sensitive.
Stability is influenced by factors such as temperature, humidity, aging, and
exposure to sunlight or other radiation.
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Stable explosives can be stored and transported safely without the risk of
unintentional detonation.
VI. Safety:
Safety encompasses how safely an explosive can be handled, stored, and used.
Safety measures include proper storage conditions (e.g., cool, dry places),
handling procedures, and adherence to regulations and safety standards.
Safer explosives are less sensitive and pose a lower risk of accidental ignition
or detonation.
COMPOSITION OF EXPLOSIVES:
Types of Explosives:
1 .Low Explosives: Understanding Their Nature and Example
Low explosives are a class of explosives that undergo rapid combustion rather than
detonation. Unlike high explosives, which produce supersonic shock waves upon
detonation, low explosives deflagrate, meaning they burn rapidly, generating expanding
gases that create pressure. This gradual release of energy makes them suitable for
applications where a controlled release of energy is desired, such as propellants and
pyrotechnics.
Chemical Composition: Low explosives typically contain a fuel component and an
oxidizer, which react together to produce combustion. Common fuel components include
organic compounds such as charcoal, sulphur, and metals like aluminium. The oxidizer
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component is usually a chemical compound containing oxygen, such as nitrates or
perchlorates.
Examples of Low Explosives:
1. Black Powder:
Black powder, also known as gunpowder, is one of the earliest known low
explosives.
It is composed of three main ingredients: potassium nitrate (oxidizer),
charcoal (fuel), and sulphur (stabilizer).
Black powder is commonly used in firearms, fireworks, and traditional
mining applications.
2. Smokeless Powder:
Smokeless powder is a modern low explosive used as a propellant in
firearms and ammunition.
It is typically made from nitrocellulose (a type of nitrate ester) combined
with other additives for stabilizing and shaping.
Smokeless powder produces less smoke and residue compared to black
powder, making it suitable for use in modern firearms.
Characteristics of Low Explosives:
1. Deflagration: Low explosives deflagrate, meaning they burn rapidly and produce
expanding gases without supersonic shock waves.
2. Controlled Release of Energy: Low explosives are suitable for applications
where a controlled release of energy is desired, such as propulsion or
pyrotechnics.
3. Safety: Compared to high explosives, low explosives are generally less sensitive
to initiation stimuli and can be handled with greater safety precautions
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TNT is one of the most well-known and widely used high explosives. It
consists of a toluene molecule with three nitro (-NO2) groups attached to
it.
When initiated, TNT undergoes rapid decomposition, releasing a large
amount of heat, gases (such as nitrogen and carbon dioxide), and pressure.
TNT is commonly used in military munitions, including artillery shells,
bombs, and grenades, as well as in demolition and mining operations.
2.RDX (Royal Demolition explosives):
RDX is another powerful high explosive that is widely used in military
applications. It has a molecular structure consisting of a hexahydro-1,3,5-
trinitro-1,3,5-triazine.
RDX detonates with a high velocity, producing a shock wave that can
shatter metal and concrete structures.
RDX is used in a variety of military munitions, including shells, bombs,
and missiles, as well as in industrial blasting applications.
2-Methyl-1,3,5-trinitrobenzene
Pentaerythritol tetranitrate
RDX
1,3,5,7-Tetranitro-1,3,5,7-tetrazoctane
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Preparation of explosives:
1.PREPARATION OF RDX
2.Preparation of HXM
3.Preparation of TNT
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4.Preparation of PETN
1.Combustion Reaction:
Combustion is a chemical process that involves the rapid combination of a fuel
with oxygen, typically from the atmosphere, resulting in the release of energy in
the form of heat and light. In the case of explosives, the combustion process is
highly exothermic, meaning it releases a large amount of heat energy in a very
short period.
Mechanism: The combustion of explosive compounds typically involves
the oxidation of carbon, hydrogen, and nitrogen atoms present in the
molecular structure of the compound. This oxidation reaction releases
energy, which is then rapidly transferred to the surrounding medium,
leading to gas expansion and pressure increase.
Example Reaction (TNT):
2C7H5N3O6+9O2→14CO2+5H2O+3N22C7H5N3O6+9O2→14CO2
+5H2O+3N2
In this reaction, trinitrotoluene (TNT) reacts with oxygen to produce carbon
dioxide, water, and nitrogen. The release of heat during this reaction contributes to
the explosive force of TNT.
Factors Affecting Combustion: Factors such as the availability of
oxygen, temperature, pressure, and the physical state of the explosive
(solid, liquid, or gas) can influence the combustion process and the rate of
energy release.
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2.Decomposition Reaction:
Decomposition is a chemical reaction in which a compound breaks down into
simpler substances. In the case of explosives, decomposition reactions are
typically initiated by heat, shock, or friction, leading to the rapid release of energy
and gases. This sudden release of energy and gas expansion results in an
explosion.
Mechanism: Decomposition reactions in explosives can involve various
processes such as bond breaking, rearrangement of atoms, and the
formation of new chemical species. These reactions release a significant
amount of energy stored within the molecular structure of the compound.
Example Reaction (Nitro-glycerine):
4C3H5N3O9→6N2+10H2O+12CO2+O24C3H5N3O9→6N2+10H2
O+12CO2+O2
Nitro-glycerine decomposes into nitrogen gas, water, carbon dioxide, and oxygen.
This decomposition reaction is highly exothermic and contributes to the explosive
force of nitro-glycerine.
Factors Affecting Decomposition: The initiation of decomposition
reactions in explosives can be influenced by factors such as temperature,
pressure, chemical composition, and the presence of impurities or
sensitizers
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2.Grenades:
Key Points:
Handheld explosive devices designed for throwing or launching.
Typically contain a fuse mechanism for detonation after a set time
delay or upon impact.
Used by military forces for offensive and defensive purposes.
Can cause casualties and damage in close-quarters combat situations.
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3.Dynamite:
Key Points:
High explosive consisting of nitro-glycerine absorbed onto an inert
material.
Used in construction, mining, and demolition.
Typically packaged in sticks for easy handling and transportation.
Requires careful handling due to its sensitivity to shock and friction.
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Stable and easy to handle, making them preferred choices for combat
engineers and special forces.
Application of Explosives: -
1.Mining and Quarrying:
4.Pyrotechnics:
Fireworks: Explosives are a key component of fireworks, producing colourful
visual displays in the sky. Different chemical compositions of explosives create
various colours and effects.
Theatrical Effects: Pyrotechnics use explosives to create special effects such as
sparks, flames, and loud noises in performances such as concerts, stage shows,
and films.
Safety Considerations: Pyrotechnics must be handled and executed with care,
adhering to safety regulations to prevent accidents and ensure the well-being of
performers and audiences.
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5. Space and Aerospace:
Rocket Propulsion: Explosives are used as propellants in rockets, enabling them
to launch into space. Solid and liquid propellants provide the thrust needed for
liftoff and in-flight manoeuvres.
Separation Systems: Explosives are used in space missions for stage separation,
where different stages of a rocket separate to continue the mission. Explosives
may also be used for fairing separation and other critical events during space
missions.
Reliability and Safety: In space applications, reliability is crucial due to the high
stakes involved. Advanced engineering and rigorous testing are employed to
ensure the safe and successful use of explosives.
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Mechanism of explosives: -
1. Initiation:
Energy Input: The initiation step begins with the application of energy to
the explosive material. This energy can be in the form of heat, shock,
friction, or an electrical spark, depending on the type of explosive and the
initiation method being used.
Decomposition Trigger: The energy input causes the explosive material to
undergo primary decomposition, where chemical bonds in the explosive
molecules break apart. This creates reactive intermediates such as free
radicals or ions.
Chain Reaction Start: These reactive intermediates lead to a chain
reaction, where the explosive material rapidly begins to decompose further,
releasing energy in the form of heat.
2. Propagation:
Rapid Decomposition: The initial decomposition reaction quickly
propagates through the entire explosive material. The speed of this
propagation is typically supersonic, resulting in a detonation wave.
Shock Wave Generation: As the explosive material decomposes, it releases
high-pressure gases and energy. This rapid release of energy creates a shock
wave that travels outward from the point of initiation.
Pressure and Heat: The shock wave is accompanied by a sudden increase in
pressure and heat, which further accelerates the reaction and drives the
detonation wave through the explosive material.
3. Termination:
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Complete Reaction: The termination step occurs when the explosive
material has been entirely consumed in the reaction. This means that the
chemical reaction has reached completion, and all available reactants have
been converted into products.
Formation of Gaseous Products: The products of the reaction are
primarily gases such as nitrogen, carbon dioxide, and water vapor. These
gases rapidly expand, causing a sudden increase in pressure that contributes
to the shock wave.
Energy Dissipation: As the reaction completes and the shock wave travels
through the surrounding environment, the energy of the explosion begins to
dissipate. The heat, light, and sound generated by the explosion eventually
fade as the reaction reaches its end.
Effects of Explosives:
1. Mechanical Damage:
Explosions generate shockwaves and overpressure that can cause significant mechanical
damage to structures and the surrounding environment.
Shockwaves: When an explosive detonates, it releases energy rapidly in the form
of a shockwave, which is a high-pressure wave that travels through the air at
supersonic speeds. This wave can severely damage buildings, vehicles, and other
structures by exerting high pressure on them. The intensity of the shockwave
decreases with distance from the explosion, but close proximity to the blast can
lead to structural collapse and catastrophic damage.
Overpressure: Overpressure is the sudden increase in air pressure caused by the
explosion. It can shatter windows, doors, and walls, and may cause injuries or
fatalities from flying debris. The pressure wave can also cause internal injuries,
such as lung damage, from the rapid compression of air in the body.
2. Thermal Effect:
Explosions release intense heat, which can cause various forms of thermal damage:
Burns: The high temperatures generated by the explosion can cause severe burns
to individuals nearby, leading to immediate pain and potential long-term health
issues.
Fires: The heat from explosions can ignite fires in nearby materials, leading to
further destruction and danger. This secondary hazard can spread quickly and
cause additional property damage and injuries.
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Material Melting and Vaporization: Intense heat can cause nearby materials,
such as metal, to melt or vaporize. This can further weaken structures and increase
the risk of collapse.
3. Acoustic Effect:
The loud noise generated by explosions can have significant impacts on both individuals
and the surrounding environment:
Hearing Damage: The high decibel levels from explosions can cause temporary
or permanent hearing loss. Individuals close to the explosion may experience
immediate, intense pain and long-term damage to their hearing.
Barotrauma: The rapid change in pressure can also cause barotrauma, leading to
damage in the ears, sinuses, and other parts of the body due to pressure changes.
4.Environmental Effect:
Explosives can have negative impacts on the environment due to the release of toxic
substances:
Toxic Gases: Explosives often contain nitrogen compounds that release harmful
gases such as nitrogen oxides, which contribute to air pollution and can have
adverse effects on human health.
Particulate Matter: Explosions release fine particulate matter into the air, which
can settle on surfaces, contaminate water sources, and pose health risks when
inhaled.
Soil and Water Contamination: The release of toxic substances can contaminate
soil and water sources, impacting local ecosystems and potentially entering the
food chain.
4. Humanitarian Impact:
Explosions can have significant humanitarian impacts, affecting both individuals and
communities:
Loss of Life: Explosions can result in immediate fatalities, particularly in densely
populated areas or confined spaces where the impact of the explosion is
concentrated.
Injuries and Displacement: In addition to causing physical injuries, explosions
can displace populations when homes and infrastructure are damaged beyond
repair.
Psychological Trauma: Survivors and witnesses of explosions may experience
long-term psychological effects, such as post-traumatic stress disorder (PTSD),
anxiety, and depression.
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Safety and Regulation:
Safety and regulation are crucial aspects of working with explosives in any industry or
application. Strict adherence to safety protocols and compliance with regulations are
necessary to protect workers, the public, and the environment. Below are key points to
include when discussing safety and regulation in relation to explosives:
1. Legal Compliance:
Permits and Licenses: Individuals and organizations must obtain the necessary
permits and licenses to handle, transport, and use explosives.
Regulatory Agencies: Compliance with regulations set by agencies such as the
Bureau of Alcohol, Tobacco, Firearms, and Explosives (ATF) in the U.S. or
similar agencies in other countries.
2. Training and Certification:
Professional Training: Proper training is essential for anyone working with
explosives to ensure safe handling and operation.
Certification Requirements: Workers may need specific certifications to handle
explosives, depending on the industry and country.
3. Storage and Transport:
Secure Storage: Explosives must be stored in secure, locked facilities designed to
prevent unauthorized access and accidental ignition.
Transportation Safety: Explosives must be transported according to strict safety
guidelines, including proper labelling, packaging, and vehicle security.
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4. Handling and Usage:
Standard Operating Procedures (SOPs): Establish and follow SOPs for
handling and using explosives, including proper use of protective gear.
Risk Assessment: Conduct risk assessments to identify potential hazards and
implement measures to mitigate risks.
5. Emergency Response:
Preparedness Plans: Develop and maintain emergency response plans in case of
accidents involving explosives.
Evacuation Procedures: Establish clear evacuation routes and procedures for
workers and the public in case of an explosion.
6. Inspections and Audits:
Regular Inspections: Perform regular safety inspections and audits to ensure
compliance with safety standards and regulations.
Documentation and Record-Keeping: Maintain accurate records of explosive
handling, storage, and usage for regulatory compliance.
7. Disposal and Environmental Considerations:
Safe Disposal: Follow established procedures for the safe disposal of unused or
expired explosives.
Environmental Impact: Monitor and manage the impact of explosives on the
environment, including air, water, and soil pollution.
8. Public Awareness and Education:
Community Engagement: Inform the public about potential risks and safety
measures related to explosives.
Report Suspicious Activity: Encourage community members to report any
suspicious activities involving explosives.
9. Technological Advances:
Safety Innovations: Implement new technologies and safety measures that
improve the safety of explosive handling and usage.
Monitoring Systems: Utilize advanced monitoring systems for real-time tracking
of explosive storage and usage.
10. International Standards:
Global Compliance: Adhere to international standards and agreements on the
handling and transport of explosives, such as those set by the International Civil
Aviation Organization (ICAO) and the International Maritime Organization
(IMO).
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References:
2. Davis, T. L. (1942). The chemistry of powder and explosives. John Wiley & Son
3. https://www.slideshare.net/abhijitcool18/explossives
4.
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