WC88033
WC88033
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I                                    BR IT ISH GEOI..OG ICAL SURVEY
                                     Overseas Directorate
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                                     Report WC/88/33
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 I                                   Summary of trials of an integrated gold
                                     exploration system at Chakari, Zimbabwe.
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                                     A   repor~     prepared     ~or    ~
 I     Geographical index
       Zimbabwe, Chakari.
  I    Subject index
       Gold exploration,
  I    Bibliographic reference
       CROW, M.J. and I..AFFOl..EY. N. d'A.
       Tr ials of an In tegra ted Go ld Exp lora t ion
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This report has been generated from a scanned image of the document with any blank
pages removed at the scanning stage.
Please be aware that the pagination and scales of diagrams or maps in the resulting report
may not appear as in the original
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I       CONTENTS
                                                                           Page
I       ABSTRACT                                                                 1
I 1.0
        2.0
              INTRODUCT ION
I 7.0
        8.0
              ACKNOWLEDGEMENTS
              REFERENCES
                                                                            15
15
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  I     FIGURES
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              The Orsat gas analyser.
              The "Gold Genie" spiral concentrator.
              Location map showing Dalny mine and a photogeological
                                                                            3
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I     ABSfRACT
I     the concentrate obtained being passed over a spiral concentrator to extract the
      gold. The gold particles are counted on a gridded pan.
      The shear zones at Chakari have no topographic expression but are readily
I     identified on aerial photographs as they form distinct lineaments. In an
      orientation study high CO 2 values were obtained over the Arlandzer shear zone
      and a small footwall shear zone. These high CO 2 values are associated with high
I     gold particle counts, which form a zone of elevated values extending for about
      60m on either side of the peak gold particle counts directly over the mineralised
      shear zone. The footwall shear zone is associated with high radon and thoron
I     values, probably indicating the presence of water in it. High CO2 values near the
      old Bonzo 2 shaft are related to sulphides only, the gold particle counts being
      low.
I      minera lisa t ion was es tab I ished by so 11 loam ing. Th is exp lora t ion exerc ise was
     - performed with minimal interruption to -farm work.
      The integrated exploration system was shown to work in the semi-arid conditions
I     at Chakari. The uses of aerial photographic interpretation and vapour
      geochemistry will be of more interest to exploration companies than the soil
      loaming since they can afford to use the geochemical laboratories in Zimbabwe.
I     The soil loaming will be of more interest to the prospectors and small-scale
      miners in the exploration of their claims. Prospectors and small-scale miners
      form an important grouping in the rural economy in Zimbabwe and improvements in
 I    their expertise will also benefit the exploration companies who often develop
      mineral occurrences flrst found by prospectors.
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I   1 .0    INTROOUCT ION
    The purpose of testing the integrated system of gold exploration in Zimbabwe was
I   to see if it would work in the sem-arid, single wet season, low-bush grasslands
    of central Africa. The evaluation fieldwork was carried out in the Chakari area
    during July and August 1987 at the kind invitation of Falcon Mines Ltd .. The
I   Chakari area "around Oalny mine was very suitable for the tests, as gold-sulphide
    shear-zone- controlled mineralisation is present, somewhat similar to that at
    Ashanti mine in Ghana where the writers had previously worked (Crow and Laffoley
I 1988).
I   This method works because elevated gold values in shallow soil samples extend
    for several ten's of metres on either side of the anomalous linear zone overlying
    the gold mineralisation (Viewing 1987). This wide dispersion of gold in residual
    soils is likely related to the prolonged period of weathering and topographic
I   planation which has formed the ancient landsurfaces of Zimbabwe (Lister 1979).
    This type of gold dispersion does not occur so markedly when the gold deposit is
    low-grade, or with high-grade deposits when the landsurface is youthful. In such
I   circumstances the initial exploration grids have to be very much smaller and very
    many more samples are generated for analysis.
I   Early in 1987 the writers tested simple gold exploration methods over narrow
    zones of gold-sulphide mineralisation in youthful soil profiles at the Ashanti
    mine, Ghana (Crow and La ff 0 ley, 1988). From the lessons learned in th is
    orientation study an integrated gold exploration system was proposed. The system
I   uses simple and relatively inexpensive apparatus, and laboratory facilities are
    not required, at least in the early stages of exploration.
I   In th is proposed sys tem of exp lora t ion for go ld-su lph ide minera lisa t ion, ins tead
    of samp ling gr ids to find e leva ted go ld values in sha llow so i I samp les
    exploration is focussed on finding promising sections of sulphide mineralisation
    in the host shear zones. Aerial photographs are examined for shear zone
I   lineaments, which are located on the ground by making vapour geochemistry
    traverses across their strike. The sulphide-mineralised portions are precisely
    located by high values of carbon dioxide and low values of oxygen in the soil
I   gases. Shallow soil samples are then loamed to see if gold particles are present
    in the soils." The source of the gold mineralisation lies at depth beneath the
    residual soils with the highest particle counts. When the soil cover is of
I   transported origin, the samples to be processed should be taken from beneath the
    cover
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I·      STOPCOCK
        M ANI FO LD --i1-if::Jt!F==W~;=::::=I~
1 BURETTE
1     BELLOWS                                        BURETTE
                                                      WATER
                                                     JACKET
1 ABSORPTION
1 CHAMBERS
I.    BRASS
                                                    LEVELLING
                                                    BOTTLE
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      CONNECTING
      PIECE                           ((       J)
                Top of mild It •• 1   _~
               SOIL   GAS PROBE            .
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 I   located a shear zone in a promising geological setting for gold mineralisation,
     such as in basaltic greenstones, the shear zone is next located on the ground.
     Vapour geochemical traverses were made to test whether mineralised shear zones
 I   could be located on the ground using this technique. Though the use of vapour
     geochemistry to assist gold exploration has been advocated, to our knowledge it
     has not been widely utilised in Zimbabwe.
I
     The sulphuric acid reacts with the gangue carbonates to give carbonic acid which
I    dissociates to liberate carbon dioxide:
I H2 C0 3 = C02 fl + H2 0
A tubular steel probe was hammered into the ground and soil gas pumped into the
I    Orsat apparatus using a rubber bellows. A volume of 100ml of soil gas was
     analysed firstly for carbon dioxide content by absorption in 40 percent potassium
     hydroxide solution and secondly for oxygen content through absorption in
     sa tura ted ammon ium ch lor ide and ammon ia so lu t ion react ing with co i led copper
I    wire. The reagents are in the absorption chambers and the soil gas is moved
     around the apparatus by using the levelling bottle and stopcocks. The gas
     contents are measured in the burette and the results are available in 8-10
I    minutes. Once it had been established at Dalny that carbon dioxide and oxygen had
     an inverse relationship, carbon dioxide only was determined in several traverses,
     with considerable savings in time.
     Radon and thoron determinations were made during certain traverses. It has been
I    suggested that gold mineralisation in the Chakari shear zones is derived from
     geological plumbing systems connected at depth to plutonic source rocks (Foster
     et al 1979). The Whitewaters tonalite has been identified as a probable plutonic
I £our-ce of the gold. Tonalites contain accessory uranium minerals, and the
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I                      CONCENTRATING BOWL WITH
                       2- LEAD SPIRAL RIFFLES
                               /
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                                                12 V ELECTRIC MOTOR
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I    APRON
I BOX
I LEGS OF FFiAME
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                 THE GOLD GENIE
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I   Fig. 2   The "Gold Genie" spiral concentrator.
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I     mineralised shear zones, if rooted in such radioactive source rocks, might have
      had uranium minerals transported along them. Such uranium minerals could be the
      source of radon, the liberation of which would be enhanced if the shear zone is
I     Radon and thoron in soil gases were determined using an EDA RD-200 Radon
      detector connected to a soil gas probe. The total radon and thoron present was
      measured using a counting period of three consecutive one-minute intervals. A
I     background readin8' of radon and thoron in atmospheric air was taken at each
      station and the amounts of radon and thoron in the soil gas calculated following
      the procedure described in the RD-200 manual.
      In Zimbabwe loaming of soils in gold exploration has been used in the recent
I     past (Morrison 1974) but has been superceded by direct chemical analysis for
      gold. Soil loaming gives a quick indication of the presence of gold, and 'has the
      advantage over chemical gold analysis that large samples can be handled,
 I    e lim ina t ing spur ious resu lts and fa Ise anoma lies resu It ing from the 'nugget
      effect' (Clifton et al 1969).
      The soil loaming method used in these trials was tested in Ghana earlier in 1987
 I    by Crow and Laffoley (1988). It is described in more detail by Laffoley and Crow
      (1988). 15 litre soil samples were taken from 50cm deep pits in the consolidated
      B zone of the soil profile. This depth was chosen so as to be beneath the
 I    disturbed root zone and below any surface contamination. The soil samples were
      taken to Chakari Dam where they were wet-sieved through a 2 mm plastic sieve
      cloth held in a wooden frame. The -2 mm fraction was carefully washed clean of
 I    the clay and silt contents and the sample volume generally reduced by 70 - 90
      percent. The heavy mineral concentrate obtained from this fraction was panned
      down to a volume of 150ml, thus achieving a xlOO reduction in sample size. The
      heavy mineral concentrate was next washed onto a Gold Genie Spiral Concentrator
 I    (Fig. 2), which mechanically separated the gold particles from the less dense
      fractions. Finally the gold particles were counted on a black pan with a grid. The
      complete loaming process took about one hour for each sample.
 I    Care has to be taken in the counting as with large numbers'of gold particles
      there will be a tendency to underestimate the gold content.
 I    Selected pan concentrates have been analysed for gold to find the detection limit
      of the method (Laffoley and Crow 1988). It was found that the analytical value
      below which particles of gold may not be found in a concentrate is 0.5ppm gold.
  I   Above this value gold particles are always present, while below it gold particles
      may not always be found.
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                                              -        o
                                                       -'  --~
                                                                       --
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              '~ _.
             CHAI(AR~
             ZIMBABWE
                           HARARE
                                        f
                                             ---            SHEI\R   ZONE
                                                            LITHOLO G I(;AL
                                                            BOUNOARY
                         MA;VINGO
                                    f         -- ---
                                                  II
                                                            JOINT ZONE
MINE/SHAFT
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I   Fig. 3    Location map showing Dalny Mine and a
              photogeological interpretation of part
              of the Falcon Mines Ltd mining lease
              area.
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I   4..0    OUTLINE OF THE GEOLOGY OF DALNY MINE
    Dalny mine is the largest of the gold mines operated by Falcon Mines Ltd in
I   their Chakari mining lease.- Other deposits, worked at various times, are
    Chadshunt, Pixy, Turkois and Arlandzer. All the major gold deposits in the Chakari
    area are situated on shear zones (Fig. 3) which cut Archaean greenstones and
I   metasediments of the Middle Bulawayan (Wilson 1979). The Bulawayan rocks are
    intruded by the large Whitewaters tonalite pluton to the southeast of Chakari
    (Bliss 1970),
I   The Dalny gold deposit is described by Foster et al (1979). The shear zone
    controlled ore bodies occur within massive and pillowed lavas of basaltic to
    andesitic composition and date from very early in the deformation sequence. The
I   ore bodies are tabular lode-type deposits 0.1-10m in size dipping 70-80° to the
    north. The ore zones are composed of quartz and carbonate stringers associated
    with pyrite, arsenopyrite and other minor sulphides in strongly sheared and
I   propylitised greenstones. Scheelite is present in small quantities throughout the
    ore body. The greenstone wall rocks of the shear zones have sericite-carbonate
    followed by chlorite alteration zones up to 7m wide. Pyrite and minor
    arsenopyrite occur close to the ore zone.
I   The topography of the Chakari area is subdued,with seasonally-dry streams
    cutting shallow valleys into the Post-African landsurface, dating from the
I   Miocene (Lister 1979). Compared to the conical hills forming the "shear zone"
    topography around the Ashanti mine in Ghana (Crow and Laffoley 1988), the shear
    zones at Chakari have no distinct surface expression.
I   Chakar i area is shown in Fig. 3. In th is in terpre ta t ion some "I i tho log ica 1
    boundaries" are taken to be tectonic on the grounds that they truncate other
    shear zones. Several tight folds of lithological boundaries are either sandwiched
    between, or are truncated against shear zones. Late northerly to north-westerly
I   fractures or zones of close jointing form low topographic depressions which do
    not displace the shear zones.
    Several orientation traverses were made over shear zones obscured by soils
    covered with grasses and low-bush. Soil types varied between residual sandy
I   clays and seasonally waterlogged vlei-type soils. The soils were generally
    undisturbed but two traverses were made over hand dug small-holdings. The
    longes t -and mos t in forma t i ve traverse known as Ar landzer # 1 (F ig. 4), over
I   undisturbed soils, is discussed in this summary.
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                                                                      N
PEG B I
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                                               )( PEG 0
                                  ~
                 WEST ~           IN
                  I~ -
                 SHAFT.                        '~................ : ... .
                                               1II.. !-1 N[ O.F (JPE NWClRI( S
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                           PEG A
                                           I
                                       fPEG C
                                       1
                                                           roo
                                                                 Arlandzer
                                                                  ahoft
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                                                                       o
I                                                                BONZO 2
                                                           WORKINGS
",eryapproJ:imofe scale
I                                                      P
                                                       L..._ _ _ _    ----'¥l m
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I   Fig. 4   Sketch plan showing the location
             of the Arlandzer traverses.
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I    5.2.1 Vapour geochemistry: radon and thoron
I    Radon and thoron were determined in soil gases and the atmosphere at 3m spaced
     probe sites between Pegs C and 0 (Fig. 5). The results are typical of the
     radioactive gas traverses and show considerable local variation giving dentate
     graphical plots. The main Arlandzer shear zone at 99m was not detected, though
I    the footwall reef between 129 and 150m appears to be defined by both thoron and
     radon peaks. It is suggested that this is caused by this reef being "wetter" than
     the main Arlandzer shear zone. The presence of water in the reef-zone would
     As the radon and thoron peaks are coincident it is probable that the parent
     radioactive source is very close to the surface. This is because the very short
I    life of thoron (52 seconds) means that it cannot travel far from its parent
     source.
Carbon dioxide contents of soil gases are available· for the entire traverse
I    whilst oxygen was determined only between Pegs C and 0 <Fig. 5). The carbon
     dioxide data picked up the Arlandzer shear zone (at 99m) as a broad anomaly
     between 93 - 108m, and small hanging wall anomalies between 81 - 93m and 60 -
     69m. A separate hanging wall anomaly was found between 9 - 21m. The footwall
I    anomaly between 129 - 150m was also recognised in the Arlandzer #2 traverse.
The carbon dioxide anomalies are well-defined and rise from a background of zero.
I    Although readings were taken on three days over a period of three weeks there
     was no variation in carbon dioxide duplicates and the soil gas atmosphere
     appeared to be stable, pOSSibly due to the dry weather conditions.
I    The carbon dioxide anomaly over the Arlandzer shear zone is low, rising only to
     0.4ml. It is likely that the size of the carbon dioxide anomaly is related to the
     amount of sulphides present in the shear zone and pOSSibly its degree of
I    wetness. The largest carbon dioxide anomaly of 0.8ml is present between 204 -
     238m and is spatially associated with the Bonzo 2 shaft and· surface workings.
     This anomaly is thought to be caused by sulphide mineralisation associated with
 I   very minor gold values since the anomaly is accompanied by a very low
     particulate gold count (Fig. 5).
     5 .2 .3   Go Id loam ing
I    The soil samples for gold loaming were collected in shallow (50cm deep) pits dug
     at 3m intervals between Pegs C and D. The traverse extensions to the east and
 I   west of the pegs were sampled at 6m and 9m intervals <Fig. 5). The traverse was
     extended with the intention of reaching a background of zero gold particles in
     soils. This objective was not achieved.
 I   The highest particle gold count was obtained at 99m coinciding with the
     Arlandzer shear zone. Smaller gold particle peaks at 72m and 84 - 87m define
     hanging wall reef zones. The foot-wall reef at 135m, also defined by carbon
 I   dioxide and radioactive gas anomalies, had only been noted previously as minor
     gold values in exploratory drill core drilled underground.
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I                                          Peg D                       Peg (
             rOOj                            l                           I
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             c
             0
~200J 100
I                100                                                                       80
                                                                                           60 g
                                                                                                     ::0
                                                                                                     Q.t
                                                                                                     Cl.
                                                                                           50~
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                                                                                                     3
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      -"20-8
                                                                                               0
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                 206                                                                           0-8
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                                                                                                     r-.
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                                                                                               O· 2.::
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                                                                                               0
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    z
     0
I                      I
                       0              60                    120
                                                   Distance (Metres)
                                                                               180      21.0
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I                          Fig. 5   The Arlandzer 1 traverse showing values for
                                    thoron,_rado~,       oxygen and carbon dioxide in
I                                   the soil gas atmosphere and counts of gold
                                    particles.
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I   The association of the Arlandzer shear zone and this footwall reef with the high
    gold particle contents in the soils strongly suggests that the gold particles in
    the soils are derived from the gold mineralisation in the rocks from which the
I   soils are derived. The fact that the zero gold particle background was not found
    may be due to the widespread distribution of gold at parts per billion level in
    the soils, perhaps related to the long-duration weathering effects. Whatever the
I   reason for this phenomenon it provides wide exploration targe~s for major gold
    mineralised shear zones. For wxample at the Arlandzer shear zone, the zones of
    elevated gold values extend for 60m on either side of the mineralisation.
I 5 .2 .4 Discuss ion
    With three exceptions the peaks of carbon dioxide anomalies and gold particle
I   counts correspond . The carbon dioxide peak at 66m is displaced 6m from the gold
    particle peak at 72m and the carbon dioxide anomaly between 204 - 238m is not
    associated with enhanced gold particle counts, possibly because the
The orientation exercises over undisturbed and disturbed soils overlying blind
I   mineralised shear zones demonstrated that the Integrated Gold Exploration system
    was working successfully. It was decided next to tackle an actual exploration
    problem. Accordingly, Mr 5 Twemlow, Chief Geologist of Falcon Mines Ltd.
    suggested that the southwest extension of the Chadshunt shear zone (Fig. 6) be
I   explored; it has no surface expression as it lies beneath a ploughed field. As
    Chadshunt Farm is owned by Falcon Mines Ltd. there was no objection to the
    exp lorat ion exerc ise tak ing p lace though it was unders tood tha t the work wou Id
I   be conducted quickly and with minimum disturbance to farm work.
    The first traverse, K - L (Fig. 6), was an orientation traverse close to the
    Chadshunt Inclined Shaft. Two strong carbon dioxide anomalies at 18m and 27m
I   were found to be associated with elevated gold particle counts in soils collected
    from 50cm deep pits. As this was an exploration exercise the background values
    for gold were not determined.
I   The second traverse (M - N) in the ploughed field also showed strong carbon
    dioxide anomalies associated with gold particle values. The third traverse
I   (0 - P), some 50m southwest of M - N, gave only zero carbon dioxide values.
    suggesting that no mineralisation was present at depth. In order to locate the
    mineralisation, which might have been displaced by a fault, two infilling
    traverses were made. In the fourth traverse (Q - R) ragged carbon dioxide values
I   rising to 0.4ml were recorded which in the fifth traverse (5 - T) had coalesced
    in to a sing Ie peak of 0.2 m1. Th is migh t be taken to ind ica te tha t the
    mineralisation decreased in sulphide content southwest of traverse Q - Rand
I   died out in a space of 12m. Alternatively a fault may be present between
    traverses 5 - T and 0 - P, possibly a south-west dipping normal fault with a
    sinistral displacement component (S Twemlow, pers. com.).
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I                                                                                __ ~N
                                                                       Mi< ---           ~hadshunt
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                                                         r
                                                                                         ... ~   Vertical
                                                                                                 Shaft
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        0.4
        g2~
        0.4
        0.2
                 j
           PEG 3 6 9 12
                 S
                                    15 1132",2'4 Zr 'PEGU\       T
                                                                          K e,res Chadshunt
                                                                               ~~
                                                                                     Inclined Shaft
I       o PEG
              Q
                     3 6                                                   metres
                                                                              Number of
I                                                                          r
                                                                             30 Gold
                                                                           ~ 20
                                                                                Particles
                                                                           I
I      0.8
                                                                           i
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                                            A
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       0.6
I      0.4
       0.2
                            /
                                /                           \
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                                         N
                                           20
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                                                 /~
       0.6
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                                                                         L
                                                                                  metres
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    Fig. 6       Location of traverses at Chadshunt farm and results
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I   The soils loamed from Chadshunt were different to those encountered previously
    in the Chakari area. The Chadshunt soils were dark brown clays with deep surface
I   cracks. The 50cm deep samples were collected from beneath the ploughed zone and
    it did not appear that the ploughing, if deeper, had affected the gold particle
    distribution above the shear zone. It is of interest that the soils in traverse M
I   - N produced much coarser, well-rounded gold particles than had been recovered
    previously in either Zimbabwe, Ghana or the UK (Leake et al 1988) .. The largest
    particle was approximately 2.5mm in size, compared to the average of O.2mm. There
    would appear to be a relationship to the soil type; the Chadshunt soils resemble
I   vlei-type soils and it is likely that the area is subject to seasonal
    waterlogging, perhaps explaining the local growth of atypical, larger gold
    particles.
I out by loaming.
    It was confirmed that shear zones with high-grade gold mineralisation have
    extensive "shoulder zones" of elevated gold values on either side of the
I   anomalous central zone which could be confidently recognised using the soil
    loaming technique.
I   Finally in the exploration exercise, a mineralised shear zone was traced into a
    ploughed field with the minimum of disturbance to farm work. This demonstrates
    that soil gas geochemistry is a useful method for exploring ground, such as farm
    land, which the owner does not want disturbed.
I   The vapour geochemistry, in particular the CO2 gave satisfactory results at
    Chakari. However the generation of CO2 in the zone of oxidation is very dependent
I   upon the amount and activity of the groundwaters. It is possible that later on in
    the dry season the CO 2 results would become meaningless. This was found at the
    close of the dry season in Ghana in early 1988 by Crow and Piper (1988).
I   However, as soon as the rains started, the CO 2 results were again strongly
    controlled by the oxidation of sulphides.
    The control of climatic factors on vapour geochemistry may discourage its use in
I   exploration. However when the soil gas atmosphere is influenced by the
    decomposition of sulphides, as is easily verified, it is a fast geochemical method
    giving immediate results.
I   The use of airphoto interpretation and soil gas geochemistry will be of most
    interest to exploration companies who have ready access to the commercial
I   geochemical laboratories and so have no requirement for soil loaming. The gold-
    loaming technique will be of most interest to the prospectors and sma~l-scale
    miners in their exploration for gold and evaluation of claims. It is a well-known
    technique in Zimbabwe, used more in the past than in the present. The
I   improvements due to large sample size and use of a spiral concentrator make it a
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I     powerful exploration method capable of detecting gold values in soils, even over
      low-grade deposits (1-5g/tonne), with a very high degree of certainty. However
      its lower detection limit of about O.5ppm gold means that the background gold
I     values will not always be picked out. This emphasises the need to focus this-
      method as far as possible on the target and reinforces the advisability of prior
      aerial photographic interpretation and soil gas traversing.
I     grade deposits, new techniques of gold recovery like heap leaching now make low-
      grade gold deposits of the type sometimes found by prospectors economic to
      develop if they are large enough.
I 7.0 ACKNOWLEDGEMENTS
I     We thank Mrs J Laurance of the Aid Section of the British High Commission;
      Harare, for assistance in clearing equipment imported into Zimbabwe and the
      Director of the Geological Survey, Mr E R Morrison, for the loan of an office and
I aerial photographs.
 I    This work at Chakari formed a part of the field investigations of the Archaean
      Goldfields of Africa Project, a British Geological Survey Research and Development
      Project funded by the Overseas Development Administration.
 I
      8.0    REFERENCES
BATEMAN, A.M. 1959. Economic geology (2rd edition). New York: Wiley & Sons.
 I    CLIFTON, H.E., HUNTER, R.E., SWANSON, F.J. and PHILLIPS, R.L. 1969.
          sample size and meaningful gold analysis.
          United states Geological Survey Professional Paper, No.625-C.
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I    CROW, M.J. and LAFFOLEY, N.d'A. 1988. Orientation studies of gold exploration
        methods at the Ashanti mine, Ghana. Technical Report British Geological
        Survey, WC/88/25.
I    CROW, M.J. and PIPER, D.P. 1988. Gold exploration trials at the Ashanti mine,
        Ghana. Technical report of the British Geological Survey, WC/88/23.
I    FOSTER, R.P., MANN, A.G., MILLER, R.G., and SMITH, P.J.R. 1979.
        Genesis of Archaean gold mineralisation with reference to three deposits
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