Doğallif 2
Doğallif 2
http://jrp.sagepub.com/
Some natural fibers used in polymer composites and their extraction processes: A review
K Palani Kumar and A Shadrach Jeya Sekaran
Journal of Reinforced Plastics and Composites 2014 33: 1879 originally published online 3 September 2014
DOI: 10.1177/0731684414548612
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What is This?
Abstract
Natural fibers are used as reinforcing materials for more than 2000 years. The need for natural fibers has been emerged
due to its weight saving, cost effective, and environmentally superior alternatives to synthetic fibers in composites. The
interest in natural fiber reinforced polymer composites has been increased rapidly, due to high performance in mech-
anical properties, significant processing advantages, and it also provides a solution to environmental pollution. The main
objective of this paper is to review and discuss the natural fibers like banana, aloe vera, kenaf, and sisal fibers and their
extraction processes.
Keywords
Natural fibers, polymer composites, extraction process, review
than in any other form. The ultimate aim of the natural The incorporation of natural fibers such as sisal (in
fiber composite is to avoid expensive glass fibers and to the form of fibers), ridge gourd (in the form of natural
go for biodegradable materials. The biggest advantages woven mat), and coconut leaf sheath (in the form of
of using natural fibers in composites are the cost of natural woven mat) into the epoxy matrix shows the
materials, their sustainability and density; mainly they moderate improvement in the tensile properties of the
have no health hazard. Natural fiber reinforced com- composites. The hybridization of these natural fibers
posite has a plate material, which uses sisal, banana, has provided considerable improvement of tensile
and roselle for internal and external fixation on human strength when compared to individual reinforcement;
body for fractured bone.6 The benefits of using natural this is due to transfer of loads and sharing of loads
fiber reinforced composites include improvement of among the fibers.11 Natural fibers have a good potential
plastic shrinkage, settlement cracking, low permeabil- in the future. Many types of natural fibers have been
ity, greater impact, abrasion, and shatter resistance of investigated and some are under investigation for repla-
the matrix material. However, it is clear that the prob- cing plastics. This paper reviews the processing meth-
lems of durability are associated with compatibility of ods of selected natural fibers such as banana, aloe vera,
fibers and matrix material and environmental effect on kenaf, and sisal. The natural fibers considered in the
stress corrosion resulting from interfacial debonding.7 present review and their woven fabric form is presented
Analytical hierarchy process method is used to deter- in Figure 1.
mine the most suitable natural fiber composites for
automotive dashboard panel. Analysis reveals that
Banana fiber
kenaf 60% +PP is the most suitable material for auto-
motive dashboard panel, as it has the highest value Banana fiber, a lignocellulosic fiber, obtained from the
(5.2%) among other natural fiber materials.8 Abdul pseudostem of banana plant (Musa sapientum), is a bast
Khalil et al.9 have indicated that the best alternative fiber with relatively good mechanical properties. Plant
for synthetic fiber composites is natural fiber compos- fibers are sclerenchymatous cells with heavily lignified
ites. The natural fiber reinforced composites are typic- cell walls having a narrow lumen in cross section.
ally filled or reinforced with plant fibers, as well as Natural fibers possess several advantages over synthetic
plastics such as polyvinyl chloride or recently, even fibers such as low density, appropriate stiffness, and
bioplastics. Sathiskumar et al.10 have reviewed the mechanical properties and also have high disposability
mechanical properties such as tensile, flexural, impact, and renewability. Also, they are recyclable and bio-
and dynamic properties as well as thermal and machin- degradable. Banana fibers are used for various pur-
ability properties of the composites with and without poses such as in textile, paper, or handicrafts
chemically treated fibers. The water absorption capabil- industry. Banana paper is versatile, as it is waterproof
ity of the composites and its effect on mechanical prop- and stronger than wood-pulp paper, which means it has
erties is also reported. been used in packaging and even as a basis for building
Figure 1. Fibers and woven fabrics of different natural fibers. (a) Banana, (b) aloe vera, (c) kenaf, (d) sisal.
materials.12 Banana is a well-known fruit crop which decrease by increasing the diameter of fibers. The diam-
has been grown extensively in Indian peninsula. The eter variability has a normal distribution. At lower
banana plantation is presented in Figure 2(a). In fact, strain rate, an increase in strain facilitates the amorph-
India is the leading producer of this perennial crop. It is ous to crystalline sharing of load. At higher speed, the
estimated that, after the harvest of fruits, huge quantity faults dominate with catastrophic failure at the highest
of biomass residues (60–80 t/ha) is left over as waste strain rates. Stress–strain curves show strain harden-
that constitutes pseudostem, leaves, sucker, etc. There ing.17 The hybrid composites of equivalent weight
exists a vast potential of extracting fibers from the ratio of jute and banana reinforced epoxy hybrid com-
banana pseudostem. It is estimated that annually posite posses better thermal property and have less
17,000 tons of fibers are extracted from this waste water absorption capacity comparatively. The addition
that has been roughly valued as Rs. 85 crores.13 The of banana fiber in the composites increases the tensile,
fiber volume fraction and fibers aspect ratio are the flexural, and impact strength. Moisture absorption
most significant factors affecting the hardness strength study of hybrid composite of equivalent mixture
of the composites. Although the effect of fiber orienta- shows minimum moisture uptake.18 Tensile properties
tion is significantly less for both pseudostem and empty are predicted to be little higher for banana and sisal
fruit bunch banana fiber as well, it cannot be ignored, natural fiber reinforced composite by using rule of
as it is one of the major load-bearing components in the hybrid mixtures equation.19 Due to low density, high
composites.14 The composites of banana empty fruit tensile strength, high tensile modulus, and low elong-
bunch fiber are stronger in tension than that of pseu- ation at the break of banana fibers, composites based
dostem based on the control factors such as volume on these fibers have very good potential use in various
fraction of fibers, aspect ratio of fibers, and fiber orien- sectors like construction, automotive, machinery, etc.20
tation.15 Silane and alkali treatment on plantain empty
fruit bunch fiber lead to a higher tensile strength than
that of untreated fibers. From the mechanical tests,
Extraction process
plantain empty fruit bunch has a very promising There are two methods for the extraction of banana
future and it is used as a substitute for artificial/glass fiber, namely Bacnis method and Loenit method.
fibers. Hence, it has a good superior interface.16 Banana The extraction of banana fiber is presented in Figure
fibers have shown high variability along the length and 2(a) to (f). In the Bacnis method, banana fiber is pro-
between fibers, which is a characteristic of natural duced from waste stalk of banana plant. The outer
fibers. The standard deviation has been found to sheath is tightly covered by layers of fiber. The fiber
Figure 2. Extraction of banana fiber. (a) Banana plantation,21 (b) banana fiber extraction in field,22 (c) hand stripping of banana fiber,23
(d) Raspador,24 (e) banana fiber extraction,23 and (f) banana fiber.25
is located primarily adjacent to the outer surface of the is blended easily with cotton fiber or other synthetic
sheath and it is peeled off readily in ribbons of strips of fibers to produce blended fabric and textiles. Banana
5–8 cm wide and 2–4 mm thick, from the entire length fiber also finds its use in high quality security/currency
of sheath. The banana fiber extraction in the field is paper, packing cloth for agriculture produce, ships
shown in Figure 2(b). This stripping process is known towing ropes, wet drilling cables, etc.12 The ‘‘pseu-
as tuxying the strips, which is also called as tuxies. Two dostem’’ is a clustered, cylindrical aggregation of leaf
methods of tuxying are employed in Philippines. The stalk bases. Banana fiber, at present is a waste product
first method called Bacnis method, where the trunks are of banana cultivation and it is not properly utilized. The
pulled apart and the sheath is separated according to extraction of fiber from the pseudostem is not a common
their position in stalk. They are then flattened and the practice and much of the stem is not used for the pro-
fiber is stripped from the stem by cutting the pulpy duction of fibers. The buyers of banana fibers are erratic
portion and pulling away the tuxy.12 In Loenit and there is no systematic way to extract the fibers regu-
method, the tuxies have pulled off the stalk from one larly. Useful applications of such fibers would regularize
sheath at a time. In either of these methods, the tuxies the demand, which would be reflected in a fall of the
are tied into bundles of 23–27 kg and they are cleaned prices.12 Bast fibers like banana fibers are complex in
by stripping knife. In this process, tuxies are pulled structure. They are generally lignocellulosic, consisting
under a knife blade, where they are pressed tightly of helically wound cellulose microfibrils in amorphous
against the tuxy in order to scrape away the plant matrix of lignin and hemicellulose. The cellulose content
tissue between the fibers. The clean fiber is then dried serves as a deciding factor for mechanical properties
in air and it is made as bundles for subsequent grading along with microfibril angle. A high cellulose content
and bailing.12 The hand stripping of banana fiber is and low microfibril angle impart desirable mechanical
presented in Figure 2(c). In addition to the hand strip- properties for bast fibers. Lignins are composed of nine
ping, machines are used as trunks from which the dark carbon units derived from substituted cinnamyl alcohol;
outer sheaths have been removed, and they are cut into that is, coumaryl, coniferyl, and syringyl alcohols.
sections of 120–180 cm in length. In this process the Lignins are associated with the hemicelluloses and play
chopped plant is passed through a machine called an important role in the natural decay resistance of the
Raspador which is shown in Figure 2(d). The sections lignocellulosic material.12
are then crushed between rolls and the pulpy tissues are
scraped away, one half the length at a time, by two
Kenaf fiber
large revolving drums, the rim of which are fitted
with scrapping blade which scrape the sheath while it Kenaf or its scientific name Hibiscus cannabinus is a
is pressed against a bed plate as shown in Figure 2(e). warm season annual fiber crop closely related to
The extracted banana fibers are dried by using oven. cotton and jute. Historically, kenaf has been used as a
After the drying, the fibers are graded and bundled for cordage crop to produce twine, rope, and sackcloth.
further use. The extracted banana fiber is shown in Nowadays, there are various new applications for
Figure 2(f). The yield of fiber is almost 10 times more kenaf including paper products, building materials,
by mechanical extraction, however, the quality of the absorbents, and animal feeds. Kenaf has a single,
fiber is inferior. straight, and branchless stalk. Kenaf stalk is made up
Banana fibers are extracted by employing chemical, of an inner woody core and an outer fibrous bark is
mechanical, or biological methods. Chemical method surrounded by the core. The fiber derived from the
causes environmental pollution, and the mechanical outer fibrous bark is also known as bast fiber. The
method fails to remove the gummy material from the kenaf plantation, kenaf leaves, and the kenaf flower
fiber bundle surface. Biological procedures yield more are shown in Figure 3(a) to (c).
fiber bundles than the other two procedures without any Kenaf bast fiber has superior flexural strength com-
harm to the environment. After extracting the fibers, bined with its excellent tensile strength, which makes it
degumming is an essential one prior to the utilization as the material of choice for a wide range of extruded,
of fibers. The removal of heavily coated, noncellulosic molded, and nonwoven products. Kenaf fiber is utilized
gummy material from the cellulosic part of plant fibers is as reinforcement material for polymeric composites,
called degumming.12 Banana fiber is a multiple celled which is an alternative to the glass fiber. It also have
structure. The lumens are large in relation to the wall some advantages over traditional reinforcement
thickness. Cross markings are rare and the fiber tips are materials such as glass fiber in terms of cost, density,
pointed and flat; they have ribbon like individual fiber renewability, recyclability, abrasiveness, and bio-
diameter range from 14 to 50 mm and the length from degradability. The efficiency of the fiber reinforced
0.25 to 1.3 cm, showing the large oval to round lumen. composites depends on the fiber–matrix interface
Banana fiber is a natural fiber with high strength, which which has the ability to transfer stress from the
Figure 3. (a) Kenaf plant. Kenaf plantation,26 (b) kenaf leaves,27 (c) kenaf flower.28
matrix to the fiber. The main obstacles in the use of manufacturing process, which has never been asso-
natural fibers in plastics have been the poor compati- ciated with other natural fibers before, such as pultru-
bility between the fibers and the matrix, since it inher- sion and potentially filament winding.36 The use of
ent high moisture absorption results in dimensional kenaf fiber reinforced composite helps to generate
changes of the fibers. It also leads to microcracking of jobs in both rural and urban areas, in addition by help-
the composite and degradation of mechanical proper- ing to reduce waste and thus contributes to a healthier
ties. Various chemical treatments have been used to environment.37
improve the mechanical performance of the natural Kenaf is primarily grown for its fiber. It has an amaz-
fiber, which include jute and hemp by many researchers ing ability to grow up to 14 ft in one growing season, by
in the past.29 Exposure of the natural fiber (kenaf) com- yielding around 6–10 tons of fiber per acre. Fibers in
posite material to environmental conditions such as dis- kenaf are usually found in the bark, which constitute
tilled water, sea water, and rain water results has 40% of the plant, and at the core which makes 60% of
decreased the fracture toughness. The decrement of the plant. For more than thousands of years Kenaf
the fracture toughness is due to the water absorption fibers are used for making textiles. The Egyptians have
characteristic, which depends on the content of the used these fibers to make boat for sails and other textiles.
fiber, fiber orientation, area of exposed surface, and Fibers made from the outer layer of the plant are used
permeability of fiber, void content, and the hydrophil- for making cords, ropes, and storage bags. Bast fibers
icity of the individual component.30 A cross sectional are simple to process. Blended with cotton, kenaf fibers
area evaluation for natural fiber (kenaf) is treated with are made into yarn and woven into fabrics. These tex-
alkali solution by data-based approximation method, tiles are esthetically pleasing, lightweight, and have a
which increases the tensile strength.31 Twisted kenaf soft feel. Apparels have the appearance of linen. They
hybrid material, fabricated by hot impregnation are the most sustainable fabrics, due to its growth rate
method presents good mechanical properties. It can and ability to replenish. It does not require much water
be utilized in bumper beams of automotive compo- for its cultivation, almost no fertilizer or pesticides, and
nents; moreover, impact properties could be improved grows to its full length, approximately in 150 days.
by optimizing the structural parameter like thick- Kenaf is completely biodegradable, as it does not
ness, beam curvature, and strengthening ribs.32 require many chemicals for its degradation.
Deterioration in tensile modulus of hybrid composites
uses kenaf and fiber glass with polyester due to longer
Separation of kenaf fibers
immersion time in distilled water, sea water, and acidic
solutions at room temperature. The main reason is the The process of separating the long and short fibers
formation of hydrogen bonding between the water mol- depends on the method of harvesting. In frost free
ecules and cellulose fiber.33 Kenaf composites cannot regions, the kenaf stalk is cut with special equipment.
compete with glass composites. The dry specific proper- In cooler regions, the plant is typically frost killed and a
ties are slightly lower for the kenaf composites, where natural drying of the stalk occurs. The separation is
the wet samples are drastically lower.34 The factors done in either whole stalk or chopped.29
which affect the mechanical properties and some chem-
ical modification in woven natural fiber, especially
Mechanical separation method
banana and kenaf increase the scope for better
future.35 Kenaf fiber reinforced composite has utilized There are many methods to separate the kenaf
its availability and readiness with various fibers. Mechanical separation of fiber is a quite
economical way. The kenaf fiber extractor is shown in depends on the availability of water and the cost of
Figure 4. The bast kenaf fibers that separate most of the retting process. To extract fine fibers from kenaf
core materials are fed to the Rando Cleaner, a roller plant, a small stalk is harvested for preretting.
type cleaner equipped with fine saw tooth wire. There Usually, this small stalk is brought before 2 weeks of
are two kinds of Rando cleaner, they are stick machine harvesting time. The fiber is easily removed from the
and trash master. Standard stick machine is equipped kenaf core and tied into bundles and submerged in soft
with three 355.6 mm diameter saws with and without running water. The stalk stays submerged in water for
Pelxiglas. The trash master is a six-cylinder incline clea- 20 days. However, the retting process requires less time,
ner with 12.7 mm space between grid bars and the if the quality of the fiber is better. In most cases, the
degree of incline, which is different, for example, 30 fiber extraction process of bast fibers in water retting is
or 45 . In order to get the cleanest fiber, it is necessary done by the farmers while standing under water. The
to process the bast fibers through both stick machine Kenaf water retting process is shown in Figure 5(a).
and trash master which is equipped with different saws The popular method and process in extracting fine
at inclination. In the procedure of separating kenaf into bast fibers is mechanical retting. The fiber is pulled
its two fractions, moisture content is a significant pre- out from the hurd or core and then it is hit with a
dictor of final fiber content; in this case, moisture con- wooden hammer and washed with water and at last
tent of whole stalk kenaf and humidity of ambient air the water is squeezed out and stocked.29 The Kenaf
need to be tested carefully. The separation efficiency stem showing the fibers is shown in Figure 5(b) and
and processing rate are the two important parameters the produced bundle of fiber is shown in Figure 5(c).
to be considered. By using drying or separation during
periods of low ambient humidity, separation efficiencies
are drastically improved to 99%. Whole stalk kenaf
Sisal fiber (SF)
fiber above the moisture content of about 18–20% is SF is a hard fiber that has been extracted from the
difficult to separate. Separation efficiency is low when leaves of the sisal plant (Agave sisalana). Though it is
the ambient humidity is above 60% and it is accom- the native to tropical and subtropical North and South
plished with the aid of drying. The stick machine is America, sisal plant is now widely grown in tropical
more efficient at fiber and core separation of kenaf countries of Africa, West Indies, and Far East. SFs
stalk than the six-cylinder cleaner. The slower process are extracted from its leaves. SF is one of the most
rate had increased the separation efficiency.29 widely used natural fibers and it is very easily culti-
vated. It has short renewal times and grows wild in
the hedges of fields. Tanzania and Brazil are the two
Water retting method
main producing countries. A sisal plant produces about
It is a wet process by which the bundles of cells in the 200–250 leaves and each leaf contains 1000–1200 fiber
outer layers of the stalk are separated from nonfibrous bundles, which is composed of 4% fiber, 0.75% cuticle,
matter by the removal of pectins and other gummy 8% dry matter, and 87.25% water. So, normally a leaf
substances. The available retting processes are called weighing about 600 g yields about 3% by weight of
mechanical retting which means by hammering, chem- fiber with each leaf containing about 1000 fibers.42
ical retting (boiling and applying chemicals), steam or The sisal plant, fiber extraction, and the extracted
vapor retting, and water or microbial retting. Among fiber are shown in Figure 6(a) to (c).
them, the water or microbial retting is a century old but The incorporation of natural fibers such as sisal (in
it is the most popular process in extracting fine bast the form of fibers), ridge gourd (in the form of natural
fibers. However, selection of these retting processes woven mat, and coconut leaf sheath (in the form of
Figure 5. Kenaf fiber and its processing. (a) Kenaf water retting process,39 (b) kenaf stem showing fibers,40 (c) kenaf fiber.41
Figure 6. (a) Sisal fiber extraction. Sisal plantation,43 (b) sisal fiber extraction,44 and (c) sisal fiber.45
natural woven mat) into the epoxy matrix shows mod- having a lustrous color, while the retting process
erate improvement in the tensile properties of the com- yields a large quantity of poor quality fibers. After
posites, when compared to individual reinforcement; extraction, the fibers are washed thoroughly in plenty
this is due to transfer of loads and sharing of loads of clean water to remove the surplus wastes such as
among the fibers.11 chlorophyll, leaf juices, and adhesive solids.43
The sisal leaf contains three types of fibers: (1) mech- The length of SF is between 1.0 and 1.5 m and the
anical, (2) ribbon, and (3) xylem.43 diameter is about 100–300 mm. The fiber is actually a
bundle of hollow subfibers. Their cell walls are rein-
1. The mechanical fibers are mostly extracted from the forced with spirally oriented cellulose in a hemicellulose
periphery of the leaf. They have a roughly thickened- and lignin matrix. So, the cell wall is a composite struc-
horseshoe shape and seldom divide during the ture of lignocellulosic material reinforced by helical
extraction processes. microfibrillar bands of cellulose. The composition of
2. Ribbon fibers occur in association with the conduct- the external surface of the cell wall is a layer of lignac-
ing tissues in the median line of the leaf. They are the eous material and waxy substances, which bonds the
longest fibers when compared with mechanical fibers cell to its adjacent neighbors. Hence, this surface does
and they are easily split longitudinally during not form a strong bond with a polymer matrix. Also,
processing. cellulose is a hydrophilic glucan polymer consisting of a
3. Xylem fibers have an irregular shape and occur linear chain of 1, 4-b-bonded anhydroglucose units and
opposite to the ribbon fibers through the connection this large amount of hydroxyl groups gives SF the
of vascular bundles. They are composed of thin- hydrophilic properties. This leads to a very poor inter-
walled cells and therefore they are easily broken up face between SF and the hydrophobic matrix and has
and lost during the extraction process. very poor moisture absorption resistance.43 The incorp-
oration of SF with Glass fiber reinforced plastics
The processing methods for extracting SFs include (GFRP) has exhibited superior properties than the
(1) retting followed by scraping and (2) mechanical by jute fiber reinforced GFRP composites in tensile prop-
means of using decorticators. Mechanical process yields erties and jute fiber reinforced GFRP composites have
about 2–4% fiber (15 kg per 8 h) with good quality performed better in flexural properties.46
Figure 7. Sisal fiber processing and fabricated sisal ropes. (a) Sisal fiber extractor,48 (b) drying of sisal fiber,49 and (c) sisal fiber rope.50
thick layer of 15–20 cells called as rind has protective researchers have carried out several studies on natural
function and synthesizes carbohydrates and proteins. fiber composites and their mechanical properties. Table
Inside the rind are vascular bundles responsible for 1 presents the summary of the natural fibers used in this
transportation of substances such as water (xylem) paper such as banana, kenaf, sisal, and aloe vera; the
and starch (phloem). Aloe vera plant has good medic- resin used; the manufacturing process employed for the
inal values and is extensively used in cosmetics and manufacturing of the composites; and its mechanical
medicines. Since yarn prices started soaring up, the properties.
jute weavers started looking for natural fibers to manu- The results from the table indicate that the property
facture saris. After using banana fiber, the (tensile strength and flexural strength) of the natural
Anakaputhur weavers are now using fiber from aloe fiber composites varied depending on the type of
vera plant.51 In the western countries like Germany fibers, type of resin, and the manufacturing process.
and Spain, aloe vera enriched clothing is in the initial The mechanical properties of banana fiber/phenol-
stages of development. It has been claimed that this formaldehyde resin composites fabricated by resin
herb in garments prevents aging of the skin, rejuvenates transfer molding (RTM) and compression molding
skin cells, and keeps skin free from the microbial infec- (CM) techniques are analyzed as a function of fiber
tions. Dermatology tests related to the textile applica- length and fiber loading. Tensile and flexural properties
tions of these fibers are conducted by a research are found to be higher in RTM composites as com-
university in Germany. Presently, these garments are pared to CM composites at all values of fiber loading.
manufactured in Barcelona, Spain. It is mainly used Thus, the mechanical properties of the composites are
for manufacturing inner garments, stockings, etc. due intimately dependent on the fabrication techniques.56
to the claimed additional functions like absorbing bad An alkali-treated banana-coir epoxy hybrid composite
smell and providing antibacterial features. By looking has greater tensile strength and impact strength than an
at the initial stages of development of garments from untreated banana-coir epoxy hybrid composite.
aloe vera, the achievement of Tamil Nadu weavers is However, the alkali-treated banana-coir epoxy hybrid
really commendable, as they are making full fledged composite has less flexural strength than the untreated
embellished sarees with it.52 The aloe vera plant, the banana-coir epoxy hybrid composite. The properties
aloe vera fiber extractor, and the aloe vera fiber are are improved by the alkali treatment process.57 The
shown in Figure 8(a) to (c). tensile strength of abaca composite is relatively more
than abaca and banana composite and much higher
Comparisons of different composites when compared with banana composite. The single
consisting of different fibers with composite withstands more strain before failure in ten-
sile testing than the hybrid fiber composite. The flexural
different resins strength of the composite is in decreasing order from
Natural fiber composites are finding increased applica- banana, abaca and banana hybrid, and abaca compos-
tion in many areas due to their environment friendly ite. Abaca has the highest flexural strength since its
nature. These composites are manufactured either by strength increases with increase in interfacial adhesion.
using synthetic resin or biodegradable resin. Banana composite can be used in applications where
Thermoplastics or thermosetting plastic can be used high impact strength is necessary.58 Chemical treatment
as a matrix material for these composites. The like NaOH increases the flexural strength of the fiber up
Figure 8. Aloe vera fiber extraction. (a) Aloe vera plant,53 (b) aloe vera fiber extractor,54 and (c) aloe vera fiber.55
to 20–30% and removes the moisture content of the characterization of the composites reveals that the
fiber. The tensile strength and flexural strength increase hybridization is having significant effect on the mech-
with increasing fiber volume fraction. Among all the anical properties of composites. Among all the compos-
hybrid fiber composites tested, banana reinforced ites, the composite having outer layer of kenaf and core
epoxy hybrid composites registered the highest mech- of banana had the highest modulus, tensile, and flexural
anical properties. The mechanical properties of the nat- strength and composite having skin of banana and core
ural fiber and synthetic fiber plates composites tested of kenaf shows lowest mechanical properties.65 The
are found to compare favorably with the corresponding results from the research66 indicated that 40%
tensile and flexural properties.59 Tensile tests are car- reinforcement of kenaf gives better tensile strength.
ried out at the strain rates of 0.1 mm/s. The ultimate The results indicated that the fatigue life is affected by
tensile strength is highest for the banana–silica compos- the amount of fiber volume ratio but it may not have
ite though it is still less than that of the epoxy resin. It is shown any significant improvement at very high
seen that addition of silica and fibers significantly number of cycles.67 The kenaf/epoxy composites have
affects the modulus of elasticity. About 12% increase the highest ultimate tensile strength compared to kenaf/
in modulus of elasticity has been seen due to addition of polyester composites and kenaf/vinyl ester composites.
10 wt% of banana fibers.60 Sharma and Kumar61 have The composites strength gradually increased when the
fabricated banana fiber reinforced thermoplastic poly- fiber volume fraction increased.68
urethane (Grade: LPR5725EG) composites. They have The mechanical properties of SF reinforced urea–
used up to 25% banana fibers in variation of 5%. The formaldehyde resin composites with 50 wt% SF have
results from their studies indicated that 15 wt% banana the optimal Charpy impact strength and it reaches
fibers shows an increase of modulus by 359% (max- 9.42 kJ/m2. Whereas the flexural, wear resistance and
imum) and then it decreases as the banana fiber wt% water absorption properties are proved to be excellent
increases. Tensile strength increases continuously up to in the composite with 30 wt% SF.69 A polymer matrix
15%, and the trend is continued in 20% reinforcement composite contains coir, banana, and sisal as the
also, but 25% shows a decrease in tensile strength. The reinforcement phase has been successfully fabricated
tensile strength of kenaf bast fiber is between 400 and by Sakthivel and Ramesh.70 The material properties
550 MPa which is higher than some natural fiber, of fabricated natural fiber reinforced composites are
namely sisal and jute. Therefore, kenaf fiber has the observed. It is found that banana reinforced natural
potential to be used as reinforcement in the polymer composites are the best natural composites among the
composite. For tensile and flexural strength properties various combination. It can be used for manufacturing
of the Kenaf fiber reinforced polymer (KFRP) compos- of automotive seat shells among the other natural fiber
ite, the higher overlapped length resulted in higher ten- combinations.70 SFs have good potential as reinforce-
sile and bending strength. From the results of both ments in polymer (thermoplastics, thermosets, and rub-
tests, the KFRP composites with 40 mm overlapped bers) composites. Due to the low density and high
length have the highest value of tensile and flexural specific properties of SFs, composites based on these
strength.62 The mechanical properties of kenaf fiber fibers may have very good implications in the automo-
reinforced polyester composites made by vacuum infu- tive and transportation industry. Moreover, reduced
sion method are investigated. It has been found that the equipment abrasion and subsequent reduction of
alkalization treatment used has improved the mechan- retooling costs make these composites more attractive.
ical properties of the composites. Kenaf fiber can be a The use of SFs as a source of raw material in plastic
good reinforcement candidate for high performance industry not only provides a renewable resource, but
polymer composites. The kenaf–polyester composite could also generate a nonfood source of economic
manufactured by vacuum infusion process provides development for farming and rural areas. SF polymer
an opportunity of replacing existing materials with a composites with and without hybridization should be
higher strength, low-cost alternative that is environ- developed and characterized so as to arrive at a series of
mentally friendly.63 Short natural fiber composite composites which may find use in several areas such as
laminate is prepared using the Kenaf fiber and polyes- marine, structural, consumer articles, and industrials
ter isopthalic resin. Fiber matrix weight ratio of 1:20 applications.71 Thermal treatment of sisal fabric
has been employed. The fiber treatment has improved reinforcement applied before molding the polyurethane
the tensile properties of composite lamina. But it is composite is suitable when considering its flexural
observed that the flexural strength is decreased by behavior, once the treatment increases notable flexural
4.4% for Kenaf UT-8 mm laminate when compared strength. The best performance in flexural mode to
to resin lamina. Surface treatment of fiber had a signifi- reinforce structures, when considering the flexural
cant effect on fiber/matrix adhesion and due to this strength and its deflection, is the thermally treated
there is an increase in flexural strength.64 The sisal/phenolic followed by untreated sisal/phenolic,
thermally treated sisal/Polyurethane (PU), and treatment. When carefully treated and developed, nat-
untreated sisal/PU composites, respectively.72 The com- ural fiber composites can have comparable properties
posite with 50% sisal–glass fiber and 50% resin com- to the existing synthetic fiber composites.
bination has maximum tensile strength.73 The effect of
moisture absorption on mechanical properties of coco-
Conclusion
nut coir and SF reinforced hybrid epoxy composite is
compared with the composites containing the dried Research on natural fibers composites has created enthu-
fibers. Increasing the fiber content at dry condition, siastic attention due to its marvelous properties and eco-
the tensile and the flexural strength increased. At wet logical considerations. A brief discussion on some of the
condition, the tensile and flexural strength have a high- natural fibers and its extraction is given along with a
level reduction. Exposure to moisture caused a signifi- review. Also the comparison between the different resin
cant drop in the mechanical properties due to the deg- used, manufacturing process employed for the manufac-
radation of the fiber–matrix interface.74 The impact turing of the composites, its mechanical properties are
strength and flexural strength of the composites discussed in brief. The main aim to focus on the attention
increase for randomly taken fiber length and fiber of the researchers is to look at the potential of the natural
weight percentage by the addition of red mud, but ten- fibers as an alternative medium to replace the conven-
sile strength value decreases due to the distribution of tional materials or synthetic fibers as reinforcement in
the particulates along with matrix which results in poor composites. In general, the use of natural fiber reinforced
stress interface between matrix and filler. Impact and composite helps to generate jobs in both rural and urban
flexural for red mud filled sisal polyester composites are areas, and supports for green environment.
more when compared with that of banana fiber com-
posites. The addition of red mud along with sisal and Acknowledgements
banana fiber increases impact and flexural strength. The review is prepared based on the references and web
Due to high impact and flexural strength, red mud resources, for which the authors expresses their sincere
filled polymer matrix composites are suitable for high thanks to them.
load withstanding and load-bearing capacity applica-
tions.75 The resin composites with three different bio- Conflict of interest
polymers (cane chaff, aloe vera, and rice husk) and None declared.
extensive study of its thermal stability, flame retard-
ancy, and thermal degradation mechanism with differ- Funding
ent natural fibers can be successfully incorporated into
This research received no specific grant from any funding
thermosetting resin matrix like phenolics and substi-
agency in the public, commercial, or not-for-profit sectors.
tuted phenolics by condensation method using acid
catalyst as is evident from spectral studies.
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