Trends in ionization energy
Down the group
Number of protons increase which means nuclear charge increases.
Number of shielding increases.
Electron is removed from a higher energy quantum shell.
Atomic radius increases
Increase in shielding is more significant than increase in protons.
Weaker attraction between nucleus and electrons
Less energy to remove one electron from the outermost shell
First ionization energy decreases down the group.
Across the group
Number of protons increases which means nuclear charge increases.
Number of shielding remains same across the group.
Electron is removed from the same quantum shell.
Atomic radius decreases
Increase in proton number is more significant than increase in shielding.
Stronger attraction between nucleus and electrons from the outermost shell.
More energy is required to remove electron
First ionization energy increases across the group