increases.
■ The volume of a gas under different conditions of
temperature and pressure can be calculated using
the ideal gas equation pV = nRT.
■ The ideal gas equation can be used to determine the
relative molecular mass of simple molecules.
■ Gases do not obey the ideal gas equation at low
temperatures and high pressures.
■ The kinetic-molecular model can be used to describe
the states of matter in terms of proximity and motion
of the particles, and to describe changes of state and
vapour pressure.
■ Ionic compounds such as sodium chloride and
magnesium oxide form a giant three-dimensional
lattice structure containing ions in a regularly
repeating pattern.
■ The strong ionic forces acting in all directions
between the ions in the lattice cause ionic
substances to have high melting and boiling points.
■ Simple molecular solids with low melting points such
as iodine have a regular arrangement of molecules;
they are crystalline. There are weak intermolecular
forces between the molecules.
■ Giant covalent (giant molecular) structures such as
diamond have a large number of covalent bonds
arranged in a regularly repeating pattern.
■ Fullerenes are allotropes of carbon in the shape
of hollow spheres (buckminsterfullerene) or
tubes (nanotubes).
■ Graphene is composed of a single flat sheet of
hexagonally-arranged carbon atoms.
■ The strong covalent bonds between the atoms in
giant molecular structures cause these substances to
have high melting and boiling points.
■ In metals, the atoms are closely packed in a giant
lattice in which the outer electrons are free to move.
■ Metals such as aluminium and copper and their
alloys have a variety of uses, which can be related to
their physical properties, e.g. density, malleability,
conductivity, hardness.
■ Physical data can be used to suggest the type of
structure and bonding present in a substance.
■ Recycling plays an important part in conserving finite
resources such as metals.
End-of-chapter questions
1 Four types of structure are:
giant molecular
giant ionic
giant metallic
simple molecular
a Give two examples of a giant ionic structure and two examples of a simple molecular structure. [4]
b Explain why substances with giant ionic structures are often brittle but metallic structures are
malleable. [6]
c Explain why giant molecular structures have higher melting points than simple molecular structures.
[6]
d Diamond and graphite are two forms of carbon with giant molecular structure