Coordinaion
Simple
Com pouuds
(Noo,n9cle) Basic Mixed
Acidic
Coutcuna KNa SO4(koH+Maoso)
(Nensoe )
Complex
(2oruore noru sats
Double
(20ruore Simple
fonised
- not to07.
S04s )
- Sol.d tate Jous
i r e es of aw
- do not
-aires tes for
cl ccel-feCcN),+14KcN
Sous resentint K4lFe
2
A40es o 9on
(GAS (Peso.(rku), So,.6M,6)
k<l.mg Cla.6Hd
Cornelti te
* Alai
M+3
MN (S0u)a-2Heo
(AQ+3,fe+3, crt3 )
M, (Sou),.N2(sou).24Hyo (NOt,Kt,Rb,C+
Suclisize
pphigh
- Coordinaion NwmbeY:
|noof p accepted
.of atous in suroudiug
by P4+2, pd+2,A+,Ag3
+3 ious (fe*,cyt, cots.
42 i0nS -’(Nt2 (H20ta) ) ’ 6
AutAg* ’2
One donor Se mono dented Lisgod
2 door sie
( for 4ueuber ring
foru 3 neuber - monodee aso
bideued
culled fexdeted
Mot
(S a2 -,So
3 memb
Stable
bide ed or didented
S,6,7 member
e§- EAhoe Cue)diaine
(en) NR-e-cH2-NH
NH-cM,-9
Cao?- (ox?-) - Giycinate (g'y )
phenathhroline
(phen)
Pipyridene Coip) -
-
Acety acetonate (acac-) - Dimethy glyoxiae
(dng-)
CH3 o
Mot
- Tridee
(dieu) (diehyenetngueue)
tetraanine)
(4ríQn ) (tehy
Tetrodentate 4 (ríen) (4e4hu
en)(tetroethylenepentaine)
Pentadeute’ ( te4
(eoTA )
+ Hexo dentae Ligamd
CAhee cdiuine 4etra acetohe io u
e-co
CH2
chromim diauine][ethylene bi)
chloride (I)
amine Tetro )
uimida aido M )(W Wtcob
[oNMsd
co
NH2
Nk
plainate
(u Lpt
CO]> CCNH3), ]
plcinu
(u) 1etrowiue
4eirochlo
rido
berallae
(n) tetrahydroxo
chromium chloridoPentauiuQ (om),Ce
7 LerCNHg)s
(a)
C)terate chloride plainum
(D)
rote Hexcqluid Hexaryaido (a) 4ron miBisehylene
ne diau
[feccn),) lrecew),),+ fe, (enl,]ez [o4
cycai
do copperca) ferrate
(a) cqami
co
ik cohaJ
icu) nqorigono
Jicnineichlorido Potassidm
hexca
ordo Gromido Aqua Ammine
(Feccn)o) Ku
xammles: IuAe -
CH3
ppt red rosy
(Ni(OMa),)l bare
weak
for *CT
opA) toace. (idY Suffix
seesi charge -veNOMing
prefix
ligndure
as
donor T-
-for
AC 6e Ac
Ac
erqllian
(I) G Be Be
xidotetra uacetao hexa
Ac
prefix
cMAu 2au more
h toGch
chloride ad lbridge
ig Por -
(nL)) cobcepentanine
anio
(bis
chloride
peutie (D) cohtlt
(D)cobwt pentawue
prefix ligaad
uye bridye for
cin) formi Liqaud
1ypecomplex Ligad
is of
NOe
liqd of
nue preset
in
ore
s,risetrakis
--etc
11 uje ve1etra Anstead
A.. -
Ari,
e). couider
in not 4etra
bu
rei ligamd
se oftype sGune oue hau more4
for -
iustead -ae Suffix o cMIl Sphere
nue coMmon CMIlO m comlex ner Coionic
ox) rwe), eiicd(ALphab Liqaud ’ Speci
es pQx Com
or.ion Caion an,oF mention n@re
-Ianion CCtion
I -
|UPAC *
S4ereoisOmers
[magbs) -- * 5) 9souerijm;
3)Linkage
Ambidende -t (P:f
bridgingfor - lco(ms)
(No3))ca
(Ncs) ) *
Coordin [co
[co(NHs);
knog)}so4 Joni
LSo
Souf(NHg),
S
atig iu tion meri
faciasfad aqS Sou
Sm:
posiion gad phaje Jro34souerisms:
plex
CN
4 9so: Coordinaion
9somenj: )
-
Both
Solrotion
Hydrcuion a)
TH (rcH,o))3 CrC3.
G6H2 0
coion
(Ha0)scaa)(.
cowpoud
newral 2Hyo(Cr
donal
Cmer) b
aion
co
uplex
-
-ve *On -
-On'y Perfet Perfeet complex
PerfecB O complexi
Types of
Bo Ony
one -
On Synergi O
M&
CO Cu
M basis Leptic
Homo
, Naturo of Sout
BL1.doning douate
4
bondig of [cu(cN)«J
BE mperfect kCN 2
boudiwg
tendency
tocMI p
CN
ceN)43
excess
ld
9 nature
6(A patHeru: - SN
1 less 3 Ksp
8) complexron.
foruaion
redox not -
1pof (G): ConC -
aen.CuccN) O -
Bo
=
3 aso redox a
-Bot. More
ismperHetevoleptic
O syuergicone7
Go>, +donate
-accept-n - couplex veg
rBMOJligh+ depens of
-acid
NOn-classica H2S b + fect 1han
Ber CCN)e high,
on
BL this
place
take
bw igamoS Yellocds! foruation complex: one
ou: is k{
BMO no a <io type
cmnt
i
eg no.of- -
) - -Ze
M Zeises
Sat of NO: - M
ndonor Acceptace -c
ligadigeud
Synergic
metalfor 04 1,
0\ Jon
C
X ,ein
gMo ABM0
Aein J
TI (boud cion
bonding
acceptos: eudacy t
Liqcand is
donotes3e’ ng
,
6*(AgMo)
B0l d in Syuergc
of
-dn
trasefec 8o! brdoe cot
not bondi
H (n* [mnccol)19L< (co)](c- BO
s07. 7
BMO A oP
)
co1,8G
)
+
8Lof ‘,L
co
2
stable
42x
Coordinaioo
no, le al
9irection
Non-onisab
(willkinson
catoyt)
’ (Switner
Sat) Ligcud
pair
e gogcomplex 6
(cis
plain) (ferro(ene) *Werners
1heory o 6
3
wPL 38
c3)4c
Red
ds CNH)s
LAnion
liqam
noble 37 CNH
nwmber O
- Xno.
of(oY-$4ate [o
[co
net 36 eg
(Sod
iuam
nitropruide)
of
adomic
no. complex)
ring ecy
Aomic
k3
lcocNOa),]
NOn-directio
-
: (Fischer
Sat) (2iese'!
SaJt) va
donorskfecAive
N,C 34 M primog
le
= ab bu
AN TetrameriJ.
(Bro
n 9onis for
repr.
4 39 M
-
-
+
dp,d'sp3
L dsp?,
oner orbitol compley
Ower
* CN =6:
- wEL
WFL (aunuot pcure
- SFL Ca nair e
do- (d'sp3)
- wfL:
(dspe)
Spectro cheic series:
...>5CN Br I
bond 1.A1trationt, Bll
-Zeff strength of igandi ore sfL)
CMI
Call t f e
ou
- for 4d,s,+4
Cu 2+
Mo 2 Co2+
co3
NfL
(NH3, NCcS,edtae) pre4atin of
titati ve inter
Sonot ’ quau magnetic daa
-)imitaions colour, 0|kinetic stabiliy
Pistinguih aeometry
blwsYLdwfL
Theory:
+ CrystaJ field ercicy
-loss o degen
oc4ahedra:
soli1in9
dye
dex
dz4 dy dix
-Spliating'n
tetrahedral:
Oahed rol
O Square
Nrauidal Squore
plano
linear
dr?y> d2 > d?-y? >dz
- Relaion blw
- Splitting in trigona plamor'
ASp Ao >Ar
Arigona bipyrani da
d22
energY
* factorS offecting spliitirg
Da 2effeyl 3dhd<sd
charge on CMI
Dd tve
ofiigau d
Da strength
pauirs
(o-bbo) -ni
(cose) ne (-o.6a4) + nt (o4 at)
* Stabiity of compleres:
CN >chelaion Streugtho)
-Cfse,spiting 9 stilty
Ocolourless
* Colour of
complex: O Chorge tranfer
LMCT, MLCT,
MMCT
2t
[fef13 :ColoyrlQ3S Lrecscn] Blodred
(highpolaritibiity
ofsCN-)
Aqueouy cons
d- block
Op-block
MO (eJ,J)
2+ ,2+
fe",co ,Ni
T3+ Cr3+
colou red
(viole) qreen) (fellau) (Pine
Cuet
(blu)
-S-block |olock 2n2t ’ colourleS
’9reen Cu2 ,c2t Blue Mn.co Pink
fe' 2edd ishbrosn
- In sq-planGr spi1ing -high,
[cromsol.]
violet
4ranion (eS ) colourles
9Yeen
Sn tetrohedra ’ ntense thanocta he.
[co cHo4) LcocJj'
(Blue )
Co cQ.6H20 1ellow l
(Light pink) - Otohedrol cyauo (ompouds tellow
streugth ofugand ?,
B
Aabr d, Aewit (opps,deb
Aamiors
H
LcoCwHg), CA J* - yetl ou keel
(co (wHs)5 Hzo]* +Gluu green Ltenl(M,o),]" Srawge
)e-yello
tellow
order For colour Complex:
Priorit
Good occentor liGandy
LMCT
MMCT (b0th CMI J-bloc< )
[cu2+ CNH3),J'* ’ Peep blut
(LMCr)
(d-d)
Balroy yellow
keMnOy + reen
cd-d)
K4lfe cCN) ]MM-NICfez+
colouvp coloured
N^=pe2n2t, Agthie p
-russian
blue
blula
1Turnbwls chocolae
brow
riJtion
-fe" pe [fe ccne] hiGh polo
42ed bYo wu Qctahedra complex where
colourai
<8Le
BLa BLegr la
Pistortion :
show sT
+ Jahn Teller
Strong
Unequa ditribion in
fe9 for JFl : d7, d9
foy SFL. d',d,ds
(rou
Cr204
3s
pora pia pia
4etrahedra
(JT-pr)
ianognedC
