Safety Data Sheet

HAPPY COLOR SPECCHIANTE ACCIAIO LUCIDO

Safety Data Sheet dated 21/9/2017, version 3

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Mixture identification:
Trade name: HAPPY COLOR SPECCHIANTE ACCIAIO LUCIDO
Trade code: 88155002
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use:
Spray painting decorative household, industrial and professional

Uses advised against

This product is not recommended for all those industrial, professional or consumer uses not
specifically identified on the label.

1.3. Details of the supplier of the safety data sheet

Company:
SARATOGA INT. SFORZA SPA Via Edison 76 20090 Trezzano s/Naviglio (MI) - ITALY
Tel. +039 02.445731 Fax +039 02.4452742
Competent person responsible for the safety data sheet:
trading@saratogasforza.com
1.4. Emergency telephone number
CAV - Ospedale Pediatrico "Bambino Gesù" - Roma - Tel. +39 06 68593726 (h24)
CAV - Azienda Ospedaliero-Universitaria Foggia - Foggia - Tel. +39 0881 732326 (h24)
CAV - Azienda Ospedaliera "A. Cardarelli" - Napoli - Tel. +39 081 7472870 (h24)
CAV - Policlinico "Umberto I" - Roma - Tel. +39 06 4450618 (h24)
CAV - Policlinico "A. Gemelli" - Roma - Tel. +39 06 3054343 (h24)
CAV - Azienda Ospedaliera "Careggi" U.O. Tossicologia Medica - Firenze - Tel. +39 055 7947819(h24)
CAV - Centro Nazionale di Informazione Tossicologica - Pavia - Tel. +39 0382 24444 (h24)
CAV - Ospedale "Niguarda Ca' Granda" - Milano - Tel. +39 02 66101029 (h24)
CAV - Azienda Ospedaliera "Papa Giovanni XXIII" - Bergamo - Tel. +39 800 883300 (h24)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
EC regulation criteria 1272/2008 (CLP):
Danger, Aerosols 1, Extremely flammable aerosol. Pressurized container: may burst if
heated.

Adverse physicochemical, human health and environmental effects:

No other hazards
2.2. Label elements
Hazard pictograms:

Danger
Hazard statements:
H222+H229 Extremely flammable aerosol. Pressurized container: may burst if heated.
Precautionary statements:
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50 °C/122°F.
P501 Dispose of contents / container to authorized centers.

The formation of explosive mixtures is possible in insufficiently ventiladed environments.

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 Safety Data Sheet
HAPPY COLOR SPECCHIANTE ACCIAIO LUCIDO
Safety Data Sheet dated 21/9/2017, version 3

Special Provisions:
None
Special provisions according to Annex XVII of REACH and subsequent amendments:
None
2.3. Other hazards
vPvB Substances: None - PBT Substances: None
Other Hazards:
No other hazards

SECTION 3: Composition/information on ingredients

3.1. Substances
N.A.
3.2. Mixtures
Hazardous components within the meaning of the CLP regulation and related classification:

Qty Name Ident. Number Classification

>= 25% - dimethyl carbonate Index 607-013-00-6 2.6/2 Flam. Liq. 2 H225
< 30% number:
CAS: 616-38-6
EC: 210-478-4
REACH No.: 01-21195483
99-23-XXXX
>= 20% - propane Index 601-003-00-5 2.2/1 Flam. Gas 1 H220
< 25% number:
CAS: 74-98-6
EC: 200-827-9
>= 10% - butane Index 601-004-00-0 2.3/3 Aerosols 3 H229
< 12.5% number: 2.2/1 Flam. Gas 1 H220
CAS: 106-97-8
EC: 203-448-7
>= 2.5% - and isobutane Index 601-004-00-0 2.2/1 Flam. Gas 1 H220
< 5% number:
CAS: 75-28-5
EC: 200-857-2
>= 1% - acetone; Index 606-001-00-8 2.6/2 Flam. Liq. 2 H225
< 2.5% propan-2-one; number:
propanone CAS: 67-64-1 3.3/2 Eye Irrit. 2 H319
EC: 200-662-2 3.8/3 STOT SE 3 H336
REACH No.: 01-21194724 EUH066
26-35-XXXX

SECTION 4: First aid measures

4.1. Description of first aid measures
In case of skin contact:
Wash with plenty of water and soap.
In case of eyes contact:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
In case of Ingestion:
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION
IMMEDIATELY.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed

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Safety Data Sheet
HAPPY COLOR SPECCHIANTE ACCIAIO LUCIDO

Safety Data Sheet dated 21/9/2017, version 3

Treatment:
None

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media:
CO2 or Dry chemical fire extinguisher.
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for firefighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.
Move undamaged containers from immediate hazard area if it can be done safely.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove all sources of ignition.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible
authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material
residuals in the containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Store at below 20 °C. Keep away from unguarded flame and heat sources. Avoid direct
exposure to sunlight.
Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to
sunlight.
Keep away from food, drink and feed.
Incompatible materials:

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Safety Data Sheet
HAPPY COLOR SPECCHIANTE ACCIAIO LUCIDO

Safety Data Sheet dated 21/9/2017, version 3

None in particular. See also section 10 below.

Instructions as regards storage premises:
Cool and adequately ventilated ones.
7.3. Specific end use(s)
For interior uses

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
propane - CAS: 74-98-6
ACGIH - Note: Asphyxia
VLE short - 1000 ppm
butane - CAS: 106-97-8
ACGIH - STEL: 1000 ppm - Notes: CNS impair
and isobutane - CAS: 75-28-5
ACGIH - STEL: 1000 ppm - Notes: CNS impair
VLE short - 1000 ppm
acetone; propan-2-one; propanone - CAS: 67-64-1
UE - TWA(8h): 1210 mg/m3, 500 ppm
ACGIH - TWA(8h): 250 ppm - STEL: 500 ppm - Note: A4, BEI - URT and eye irr,
CNS impair
DNEL Exposure Limit Values
N.A.
PNEC Exposure Limit Values
N.A.
8.2. Exposure controls
Eye protection:
Not needed for normal use. Anyway, operate according good working practices.
Protection for skin:
No special precaution must be adopted for normal use.
Protection for hands:
Not needed for normal use.
Respiratory protection:
Not needed for normal use.
Thermal Hazards:
None
Environmental exposure controls:
None
Appropriate engineering controls:
None

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Properties Value Method: Notes:

Appearance and colour: Liquid aspect -- --
(under
pressure),
various
colours.

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 Safety Data Sheet
HAPPY COLOR SPECCHIANTE ACCIAIO LUCIDO

Safety Data Sheet dated 21/9/2017, version 3

Odour: Caracteristic -- --
of solvent
Odour threshold: N.A. -- --
pH: N.A. -- --
Melting point / freezing N.A. -- --
point:
Initial boiling point and N.A. -- --
boiling range:
Flash point: Inf. 0 ° C -- --
Evaporation rate: N.A. -- --
Solid/gas flammability: Extremely -- --
flammable
Upper/lower flammability N.A. -- --
or explosive limits:
Vapour pressure: at 20°C - 4,0 bar -- --
at 50°C - 8,0 bar

Vapour density: > of air. -- --

Relative density: 0,75 - 0,80 -- --
g/ml
Solubility in water: NONE -- --
Solubility in oil: YES -- --
Partition coefficient N.A. -- --
(n-octanol/water):
Auto-ignition temperature: N.A. -- --
Decomposition N.A. -- --
temperature:
Viscosity: N.A. -- --
Explosive properties: N.A. -- --
Oxidizing properties: N.A. -- --

9.2. Other information

Properties Value Method: Notes:

Miscibility: N.A. -- --
Fat Solubility: N.A. -- --
Conductivity: N.A. -- --
Substance Groups N.A. -- --
relevant properties

SECTION 10: Stability and reactivity

10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
It may generate toxic gases on contact with powerful oxidising agents, and powerful reducing
agents.
It may catch fire on contact with powerful oxidising agents.

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Safety Data Sheet
HAPPY COLOR SPECCHIANTE ACCIAIO LUCIDO

Safety Data Sheet dated 21/9/2017, version 3

10.4. Conditions to avoid

Stable under normal conditions.
10.5. Incompatible materials
Avoid contact with combustible materials. The product could catch fire.
10.6. Hazardous decomposition products
None.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Toxicological information of the mixture:
N.A.
Toxicological information of the main substances found in the mixture:
acetone; propan-2-one; propanone - CAS: 67-64-1
LD50 (RABBIT) ORAL: 5300 MG/KG

If not differently specified, the information required in Regulation (EU)2015/830 listed below must be
considered as N.A.:
a) acute toxicity;
b) skin corrosion/irritation;
c) serious eye damage/irritation;
d) respiratory or skin sensitisation;
e) germ cell mutagenicity;
f) carcinogenicity;
g) reproductive toxicity;
h) STOT-single exposure;
i) STOT-repeated exposure;
j) aspiration hazard.

SECTION 12: Ecological information

12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.
N.A.
12.2. Persistence and degradability
None
N.A.
12.3. Bioaccumulative potential
N.A.
12.4. Mobility in soil
N.A.
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled
conditions. In so doing, comply with the local and national regulations currently in force.

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Safety Data Sheet
HAPPY COLOR SPECCHIANTE ACCIAIO LUCIDO
Safety Data Sheet dated 21/9/2017, version 3
SECTION 14: Transport information

14.1. UN number
Not classified as dangerous in the meaning of transport regulations.
ADR-UN number: 1950
IATA-Un number: 1950
IMDG-Un number: 1950
14.2. UN proper shipping name
ADR-Shipping Name: AEROSOL
IATA-Technical name: AEROSOL
IMDG-Technical name: AEROSOL
N.A.
14.3. Transport hazard class(es)
ADR-Class: 2 5F
ADR - Hazard identification number: -
IATA-Class: 2.1
IATA-Label: 2.1
IMDG-Class: 2
N.A.
14.4. Packing group
ADR-Packing Group: -
IATA-Packing group: -
IMDG-Packing group: -
N.A.
14.5. Environmental hazards
Marine pollutant: Marine pollutant
N.A.
14.6. Special precautions for user
IATA-Passenger Aircraft: ---
IATA-Cargo Aircraft: 203
IMDG-Technical name: AEROSOL
IMDG-Page: F-D, S-U
N.A.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
N.A.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
D.Lgs. 9/4/2008 n. 81
D.M. Work 26/02/2004 (Occupational Exposure Limit Values)
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) 2015/830
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Regulation (EU) n. 487/2013 (ATP 4 CLP)
Regulation (EU) n. 944/2013 (ATP 5 CLP)
Regulation (EU) n. 605/2014 (ATP 6 CLP)
Regulation (EU) n. 2015/1221 (ATP 7 CLP)
Restrictions related to the product or the substances contained according to Annex XVII Regulation
(EC) 1907/2006 (REACH) and subsequent modifications:
None
Volatile Organic compounds - VOCs = 565.95 g/l
Volatile CMR substances = 0.00 %

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Safety Data Sheet
HAPPY COLOR SPECCHIANTE ACCIAIO LUCIDO
Safety Data Sheet dated 21/9/2017, version 3

Halogenated VOCs which are assigned the risk phrase R40 = 0.00 %
Organic Carbon - C = 0.00
Where applicable, refer to the following regulatory provisions :
Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent
amendments.
Regulation (EC) nr 648/2004 (detergents).
1999/13/EC (VOC directive)

Provisions related to directive EU 2012/18 (Seveso III):

N.A.
15.2. Chemical safety assessment
No chemical safety assessment has been carried out for the mixture.

SECTION 16: Other information

Remove dried varnish with acetone or nitre diluent.

Text of phrases referred to under heading 3:

H220 Extremely flammable gas.
H229 Pressurized container: may burst if heated.
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
EUH066 Repeated exposure may cause skin dryness or cracking.
Changes to previous review:
The following sections were modified:
SECTION1: 1.2 Uses advised against
SECTION 3:
Qty Name Ident. Number Classification
>= 25% - dimethyl carbonate Index 607-01 3-00-6
2.6/2 Flam. Liq. 2 H225
< 30% number:
CAS: 616-38-6
EC: 21 0-478 -4
REACH No.: 01-21195483
99 -23-XXXX
SECTION 16: Other information

Classification and procedure used to result it according to Regulation (EC)1272/2008 [CLP]

related to mixtures:
Classification according to Regulation (EC) n. 1272/2008 Classification procedure
Aerosols 1, H222+H229 Based on experimental tests

This safety data sheet has been completely updated in compliance to Regulation 2015/830.
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
Nostrand Reinold

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 Safety Data Sheet
HAPPY COLOR SPECCHIANTE ACCIAIO LUCIDO

Safety Data Sheet dated 21/9/2017, version 3

The information contained herein is based on our state of knowledge at the above-specified date.
It refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to
the specific use intended.
This MSDS cancels and replaces any preceding release.

ADR: European Agreement concerning the International Carriage of

Dangerous Goods by Road.
CAS: Chemical Abstracts Service (division of the American Chemical
Society).
CLP: Classification, Labeling, Packaging.
DNEL: Derived No Effect Level.
EINECS: European Inventory of Existing Commercial Chemical Substances.
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of
Chemicals.
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport
Association" (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization"
(ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.

KSt: Explosion coefficient.

LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LTE: Long-term exposure.
PNEC: Predicted No Effect Concentration.
RID: Regulation Concerning the International Transport of Dangerous Goods
by Rail.
STE: Short-term exposure.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day.
(ACGIH Standard).
WGK: German Water Hazard Class.

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