Safety data sheet

according to 1907/2006/EC, Article 31

Printing date 18.05.2020 Version number 1 Revision: 22.04.2020

SECTION 1: Identification of the substance/mixture and of the company/ undertaking

· 1.1 Product identifier

TRADE NAME : BIOPROTECT NEW
· 1.2 Relevant identified uses of the substance or mixture and uses advised against No further
relevant information available.
· Application of the substance / the mixture
Antibacterial and antiviral formulation Factory
treatment for textiles
· Uses advised against Not for consumer use
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
BT BIOTEX SDN BHD.
Lot 71, Jalan P10/21 Selaman Industrial Park,
43650 Bandar Baru Bangi,
Selangor Malaysia
Tel: +603- 8922 3633
Fax: +603- 8920 2100

· Further information obtainable from: Product Safety Department

· 1.4 Emergency telephone number: +603 8922 3633

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
·
· Hazard pictograms Void
· Signal word Void
·
· Hazard statements
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P273 Avoid release to the environment.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
·
· Additional information:
Contains biocidal products: Reaction mass of silver chloride and titanium dioxide
·
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
 Safety data sheet
according to 1907/2006/EC, Article 31

Printing date 18.05.2020 Version number 1 Revision: 22.04.2020

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Description: Mixture of substances listed below with nonhazardous additions.

Dangerous components:
CAS: 9004-95-9 Polyoxyethylene (2) cetyl ether 1.0 - 5.0%
NLP: 500-014-1 Aquatic Chronic 2, H411; Skin Irrit. 2, H315

CAS: 112-02-7 cetrimonium chloride 0.1 - 0.5%

EINECS: 203-928-6 Acute Tox. 3, H311; Skin Corr. 1B, H314; Acute Tox.4, H302

Reaction mass of silver chloride and titanium dioxide ≤ 0.13%

Aquatic Acute 1, H400; Aquatic Chronic 1, H410
· SVHC This product contains no SVHC listed substances at levels of ≥ 0.1%.
· Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures

· General information: If medical advice is needed, have product container or label at hand.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
If symptoms persist, seek medical advice.
· After swallowing:

Rinse out mouth and then drink plenty of water.

If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed No
further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed No
further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media

· Suitable extinguishing agents:

CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet

· 5.2 Special hazards arising from the substance or mixture In

case of fire, the following can be released:
carbon dioxide (CO2)
Carbon monoxide (CO)
Silicon dioxide (SiO₂)
 Safety data sheet
according to 1907/2006/EC, Article 31

Printing date 18.05.2020 Version number 1 Revision: 22.04.2020

· 5.3 Advice for firefighters

· Protective equipment: Wear self-contained respiratory protective device.

· Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures Wear
protective clothing.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.

· 6.3 Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Send for recovery or disposal in suitable receptacles.

· 6.4 Reference to other sections

See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
Always stir well before use Prevent
formation of aerosols.

· Information about fire - and explosion protection: No special measures required.

· 7.2 Conditions for safe storage, including any incompatibilities

· Storage:
· Requirements to be met by storerooms and receptacles:
Store only in unopened original receptacles.
Non-transparent receptacles suitable for light sensitive materials.

· Information about storage in one common storage facility:

Store away from oxidising agents.
Store away from foodstuffs.

· Further information about storage conditions:

Protect from frost.
Protect from heat and direct sunlight.

· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
 Safety data sheet
according to 1907/2006/EC, Article 31

Printing date 18.05.2020 Version number 1 Revision: 22.04.2020

· Additional information: The lists valid during the making were used as basis.

· 8.2 Exposure controls

· Personal protective equipment:

· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Avoid contact with the eyes and skin.
Do not eat or drink while working.
Do not inhale gases / fumes / aerosols.
Wash hands before breaks and at the end of work.

· Respiratory protection:
Use suitable respiratory protective device only when aerosol or mist is formed.

· Protection of hands: Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation

· Material of gloves Butyl rubber, BR Nitrile rubber, NBR

The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has
therefore to be checked prior to the application.

· Penetration time of glove material

The exact break through time has to be found out by the manufacturer of the protective gloves and
has to be observed.

· Eye protection: Safety glasses

·
· Body protection: Protective work clothing

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Colour: Cream coloured
· Odour: Weak, characteristic
 Safety data sheet
according to 1907/2006/EC, Article 31

Printing date 18.05.2020 Version number 1 Revision: 22.04.2020

· Odour threshold: Not determined.

· pH-value at 20 °C: 7.0 ± 0.5
· Change in condition
Melting point/freezing point: Undetermined.
Initial boiling point and boiling range: Undetermined.
· Flash point: Not applicable.
· Flammability (solid, gas): Not applicable.
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not determined.
· Density at 20 °C: 0.8 - 1.0 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Fully miscible.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
Dynamic at 20 °C: 1000 - 1500 mPas (Brookfield, 20RPM)
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.

· 10.2 Chemical stability

· Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.

· 10.3 Possibility of hazardous reactions

No hazardous reactions when stored and handled according to prescribed instructions

· 10.4 Conditions to avoid Extremes of temperature and direct sunlight.

· 10.5 Incompatible materials: No further relevant information available.

· 10.6 Hazardous decomposition products: No dangerous decomposition products known.
·
· Additional information: No further relevant information available.
 Safety data sheet
according to 1907/2006/EC, Article 31

Printing date 18.05.2020 Version number 1 Revision: 22.04.2020

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
Reaction mass of silver chloride and titanium dioxide
Oral Acute Toxicity LD50 >5,000 mg/kg (rat)
Dermal Acute toxicity LD50 >2,000 mg/kg (rat)
Inhalative Acute toxicity LC50 4h >2.07 mg/l (rat)
Irritation of skin Dermal Irritation No skin irritation (rabbit) (Acute dermal irritation/
corrosion)
Irritation of eyes Eye Irrititation Slight irritant effect (rabbit) (Acute Eye Irritation/
Corrosion)

· Primary irritant effect:

· Skin corrosion/irritation No further information available.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Additional toxicological information:
The product itself has not been
tested
The classification is derived from the properties of the individual components
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1 Toxicity

Aquatic toxicity:

Acute toxicity LC50 48h 88 mg/l (Daphnia magna) (Based on toxicity of the constituent
substances)
Acute toxicity LC50 96hr 59 mg/l (aquatic vertibrate, not specified) (Based on toxicity of the
constituent substances)
ErC50 72hr 13 mg/ml (Algae) (Based on toxicity of the constituent substances)

Reaction mass of silver chloride and titanium dioxide

Acute toxicity LC50 48h 0.074 mg/l (Daphnia magna)

Acute toxicity LC50 96hr 0.5 mg/l (aquatic vertibrate, not specified)

ErC50 72hr 0.3 mg/ml (Pseudokirchneriella subcapitata)

 Safety data sheet
according to 1907/2006/EC, Article 31

Printing date 18.05.2020 Version number 1 Revision: 22.04.2020

12.2 Persistence and degradability No further relevant information available.

12.3 Bioaccumulative potential No further relevant information available.

· 12.4 Mobility in soil No further relevant information available.

· Additional ecological information:

· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
· 12.5 Results of PBT and vPvB assessment

· PBT: Not applicable.

· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage
system.
Dispose of in accordance with Federal/State and Local regulations.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, IMDG, IATA Void
· 14.2 UN proper shipping name

ADR, IMDG, IATA Void

· 14.3 Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class Void
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II
of Marpol and the IBC Code Not applicable.
· UN "Model Regulation": Void
 Safety data sheet
according to 1907/2006/EC, Article 31

Printing date 18.05.2020 Version number 1 Revision: 22.04.2020

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms Void
· Signal word Void
· Hazard statements
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P273 Avoid release to the environment.

P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3

· National regulations:
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57 The
product does not contain any listed substances in concentrations > 0.1%
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
· Department issuing SDS: Product safety department
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
 Safety data sheet
according to 1907/2006/EC, Article 31

Printing date 18.05.2020 Version number 1 Revision: 22.04.2020

PBT: Persistent, Bioaccumulative and Toxic

SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Acute Tox. 4: Acute toxicity - oral – Category 4
Acute Tox. 3: Acute toxicity - dermal – Category 3
Skin Corr. 1B: Skin corrosion/irritation – Category 1B
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
* Data compared to the previous version altered