Spill Response USCG
Spill Response USCG
1. INTRODUCTION 1-1
The Oil Pollution Act of 1990 (OPA) amended the Federal Water Pollution Control Act
(FWPCA) to require tank vessel and facility response plans. The plans are intended to
prepare the owner of a vessel or facility to respond to an oil or hazardous substance
discharge. Response plans must describe the training of persons on a tank vessel
which carries oil or hazardous substances in bulk as cargo or cargo residue, at an
offshore facility, or at an onshore facility where its location could reasonably be
expected to cause substantial harm to the environment by discharging oil or hazardous
substances into the navigable waters, adjoining shoreline, or exclusive economic zone.
The training is required to ensure the safety of the vessel or facility and to mitigate or
prevent a discharge of oil or a hazardous substance. The definition of a facility is very
broad under OPA and includes any offshore facility, onshore facility, motor vehicle,
rolling stock, or pipeline used for oil exploration, production, storing, handling,
transferring, processing, or transporting oil.
In addition to OPA-required response training, there are other federal and state
response training requirements. Vessel and facility owners or operators are responsible
for ensuring that all private response personnel which they employ are trained to meet
the Occupational Safety and Health Administration (OSHA) Hazardous Waste
Operations Standard (29 CFR 1910.120.) These requirements, commonly referred to as
the HAZWOPER regulations, were established to ensure the health and safety of
personnel employed in hazardous substance response and clean-up operations.
Personnel employed at facilities which transfer or store products in bulk, classified as
hazardous substances by OSHA, must also comply with HAZWOPER regulations.
Crude oil, petroleum oil, and petroleum distillates are considered hazardous substances
by OSHA. In addition to the HAZWOPER regulations, employers must comply with
federal requirements contained in 49 CFR Parts 172 and 176 to train employees
handling hazardous materials.
There are four federal agencies with responsibilities under OPA to require vessel and
facility response plans: the U.S. Coast Guard (USCG), the U.S. Environmental
Protection Agency (EPA), the Department of Transportation's Research and Special
Programs Administration (RSPA), and the Minerals Management Service (MMS). These
agencies recognize that pollution response training should be directly related to the
duties and responsibilities of the workers in the response organization. Workers with a
limited role in a response need to be trained to protect their health and to perform their
normal duties in a safe manner. They must also be trained to conduct the proper
notifications to the National Response Center and to immediately intervene to mitigate a
spill once it has occurred. Workers with spill clean-up responsibilities will need to be
trained to deploy and operate the equipment they will actually use in the response.
Other personnel with a more active role in the response organization or w"ith supervisory
responsibilities may need additional training in such subjects as response or clean-up
technology, spill trajectory forecasting or response management strategies.
                                            1-1
     " Qualified Individual (Section 3)
The International Maritime Organization (IMO), based in London, England, has been
developing training courses for oil spill response. Resolution seven of the International
Convention on Oil Pollution Preparedness, Response and Cooperation, 1990 (OPRC),
committed IMO to the "development and implementation of a training program for oil
pollution preparedness and response." After analyzing responses to major oil spills,
IMO recognized that the capability of a nation to respond to an oil spill is dependent on
both the availability of adequate equipment and trained response personnel to operate
the equipment. A special need was identified to assist developing countries by
providing training to their response personnel. As a result, IMO invited interested
member governments to help develop training programs in preparedness and
response. IMO working groups then identified three levels of training for oil spill
response:
The Canadian Coast Guard agreed to act as lead country of a correspondence group in
the design work for these IMO courses. Drawing upon its own expertise and that of
member nations, the Canadian Coast Guard has actively pursued course development.
                                              1-2
    Design work on the first two courses has been completed. The subsequent stages of
    course development, testing, implementation, and evaluation are expected to follow.
    The course design material for the first two IMO courses has been modified slightly to
    make it more relevant to the oil spill training needs of the United States. The design
    material, presented in the form of a job task analysis, is included in the appendix
    sections of this document for your information only. The IMO courses were never
    intended to be promulgated as standards or regulations and should not be used as
    such. Please consider the material as a menu of training elements from which to select
    relevant material that may be incorporated into your own training program on an as
    needed basis .•
                                              1-3
On February 5, 1993, the USCG published interim final rules requiring vessel and facility
owners to identify the training to be provided to each individual who has responsibilities
as described in company response plans [58 FR 7424 (vessels); and 58 FR 7352
(facilities)]. The USCG regulates and is required to review and approve all deepwater
port, vessel, and marine transportation-related facility response plans. Rather than
develop highly prescriptive regulatory requirements, the USCG has allowed vessel and
marine transportation-related facility owners and operators the flexibility to choose the
manner in which they describe training in their response plans. USCG regulations are
found in 33 CFR parts 150, 154 and 155.
EPA regulates non-transportation related onshore facilities and certain offshore facilities
located landward of the coastline under the oil pollution prevention regulations (40 CFR
part 112). EPA published a final rule in the Federal Register on July 1, 1994. to amend
these regulations to include response plan requirements under OPA [50 FR 34097).
The final rule requires the owner or operator of a substantial harm facility to develop and
implement a facility response plan, which includes a training program for those
personnel involved in oil spill response activities. The rule recommends that the training
program be based on this reference manual. as applicable to facility operations. An
alternative training program can also be acceptable, subject to approval by the Regional
Administrator.
Under OPA, the MMS regulates offshore facilities, including associated pipelines, other
than deepwater ports subject to the Deepwater Port Act. Under a Memorandum of
Understanding among the Department of the Interior, the Department of Transportation,
and the EPA, MMS only regulates those offshore facilities located seaward of the
coastline. The MMS published an interim final rule (IFR) on February 8, 1993, requiring
spill response plans from offshore facilities [58 FR 7490). The IFR will expire on February
18, 1995, or when superseded by a final rule. The MMS is currently preparing a notice
of proposed rulemaking (NPRM) for the final rule on spill response plans.
                                             2-1
Industry response plan holders must identify a qualified individual who will act as the
point of contact between the federal government and the owner or Operator of the
vessel or facility. This individual is also referred to as the emergency response
coordinator by EPA regulations. The responsibilities of the qualified individual go far
beyond that of a mere intermediary. As defined in OPA, the qualified individual is that
person identified in a response plan having "full authority to implement removal actions"
on behalf of the plan holder. The qualified individual must have the authority to commit
the financial resources of the company to prevent or clean up a spill.
One of the primary responsibilities of the qualified Individual is, upon learning of a spill or
potential spill of an oil or hazardous substance, to immediately communicate with the
appropriate federal official and the persons providing personnel and equipment for the
spill response. This procedure will ensure timely notification of federal officials so that
they may activate Area Contingency Plans notify other federal, state, and local agencies
ensure adequate measures are taken by the responsible party and activate
governmental response resources when necessary. It also ensures that response
resources identified by the plan holder will commence appropriate response actions in a
timely manner.
Federal regulations require response plan holders to identify the type of training the
qualified individual will receive. The goal is to ensure that the qualified individual is fully
capable to perform his or her duties. Although the qualified individual is not expected to
be a technical expert in vessel salvage, clean-up technology, or pipeline repair, the
qualified individual must be familiar enough with the company's response plan to know
what measures must be taken under the circumstances. The qualified individual must
ensure adequate steps.are taken to mitigate the situation and should know the
capabilities of any oi! spill removal organization (OSRO) which is contracted to respond
on behalf of the company. The qualified individual should be thoroughly familiar with
procedures to activate and contract with the company's OSRO.
The following TAB provides suggested elements which could be incorporated into the
training program for a qualified individual. The material should not be considered as
mandatory training nor should it be considered all-inclusive. A training program which
provided all of the suggested training elements would certainly be very comprehensive.
An individual receiving this training would have an excellent educational foundation to
help him or her play a highly pro active role in the plan holder's response organization.
 Plan holders must decide the actual role of the qualified individual in their organizations
 and customize their training programs accordingly.
                                               3-1
                                            TABA
Suggested training elements for qualified individuals:
Demonstrate knowledge ofthe following:
  • Procedures the crew or facility personnel may use to mitigate or prevent any
  discharge or a substantial threat of a discharge of oil resulting from shipboard or facility
· operational activities associated with internal or external cargo transfers, storage, or
 .use.
• Procedures the vessel's crew may use to mitigate or prevent any discharge or a
substantial threat of a discharge of oil in the event of --
        • Grounding or stranding;
         • Collision;
          • Explosion or fire;
           • Hull failure;
            • Excessive list; or
              • Equipment failure.
• Procedures for both the Internal and ship-to-ship transfers of car99 in an emergency.
 • Procedures and arrangements for emergency towing, including the rigging and
 operation of any emergency towing equipment aboard the vessel.
 • Vessel crew or facility personnel responsibilities, and procedures to, use of shipboard
 or facility equipment which may be carried to mitigate an oil discharge.
 • The vessel crew's responsibilities, if any, to initiate a response and supervise shore
 based response resources.
                                               3-2
• Responsibilities and authorities of the qualified individual as described In the vessel or
facility response plan and company response organization.
• The organizational structure that will be used to manage the response actions,
including --
                      Planning;
                        0
° Finance.
• The responsibilities and duties of each oil spill management team member within the
organizational structure.
• The drill and exercise program to meet federal and state regulations as required
underOPA.
• The role of the qualified individual in the post discharge review of the plan to evaluate
and validate its effectiveness.
• Area Contingency Plans (ACPs) for the areas in which the vessel operates or the
facility is located.
• Public affairs.
• Crisis management.
• Procedures for obtaining approval for dispersant use or in-situ burnin~ of the spill.
                                               3-3
A spill management team is also required to be designated by USCG regulations. The
function of the team is to assist or relieve the companys qualified individual in the actual
response to an oil or hazardous substance spill. The team staffs the organizational
structure the company has identified to manage response plan implementation. The
team may also provide the operational oversight of field response personnel.
Although the size and qualifications of the spill management team have not been
federally mandated, the team must be adequately staffed to ensure a credible response
depending on the size of the spill. The number of members will be expected to grow if
the situation warrants 24 hour per day operations and a cast of several thousand clean
up personnel. A well-structured response organization will be able to accommodate
changes in the size of the spill management team and rapidly integrate additional
members.
Many private companies have chosen response organizations based on the Incident
Command System (!CS) model which was developed in the early 1970's in California by
federal, state, and local officials to fight major forest fires. There are many systems that
are used throughout the United States for the direction and control of resources in
emergencies. The National Fire Academy and the National lnteragency Incident
Management System have both developed popular models for !CS-based response
organizations. However, regardless of the specifics of the systems, all !CS systems are
based on the same basic business management principles. In a business or
government environment, managers and leaders perform the basic daily tasks of
planning, directing, organizing, coordinating, communicating, delegating, and
evaluating. The same is true for emergency response management.
    ):( Command;
       " Operations;
        " Planning;
         " Logistics; and
          ):( Administration and Finance.
OPA requires the On-Scene Coordinator (OSC) to work with state and local officials in
the development of ACPs, to ensure pre-planning of joint response efforts, and to
expedite decisions for the use of dispersants and other mitigating substances. The
Federal Government, through its NCP, uses a Unified Command Structure (UCS). This
structure is intended to bring the OSC, state official, and the responsible party together
to facilitate the decision making processes and optimize the combined response efforts
of all participants. The UCS structure can easily integrate members of the spill
management team who will be most likely invited to participate.
The key to training spill management team members is to train them according to their
functional role within the response organization. Members staffing an operations center
need to be trained differently from members whose primary function is logistics. Many
of the company's personnel will be able to draw upon skills they use and training they
                                             4-1
have obtained in the company's everyday activities of running the facility or vessel
operation. Personnel designated to administer the financial duties of spill response and
cost documentation are especially likely to have such experience. Other personnel will
be asked to fill roles which they may only perform in a crisis situation: therefore, due to
the infrequency of an actual crisis, these personnel would need extra periodic training to
perform crisis functions.
If the individual will always fill the same spill management team function, training
requirements will be narrowed in scope. If a company desires greater flexibility in use of
their personnel and redundancy in available knowledge in case key personnel are
unavailable, it may choose to add to the curricula presented to team members. The
goal is to train these personnel so that the team can function as a coordinated unit and
direct the clean-up activities or preventative measures in an efficient and timely manner.
4-A provides suggested elements which could be incorporated Into the training program
for the spill manageITlent team. The material should not be considered as mandatory
training nor should it be considered all-inclusive. A training program which provided all
of the suggested training elements would certainly be very comprehensive. Team
members receiving this training would have an excellent educational foundation to help
them play a highly pro active role in the plan holder's response organization. Plan
holders must decide the actual role of their spill management team members in their
organizations and customize their training programs accordingly.
4.A. Suggested training elements for Spill Management Team members:
• Procedures the vessel's crew may use to mitigate or prevent any discharge or a
substantial threat of a discharge of oil in the event of --
       • Grounding or stranding;
        ° Collision;
         • Explosion or fire;
          • Hull failure;
           • Excessive list; or
             • Equipment failure.
• Vessel crew or facility personnel responsibilities, and procedures for use of shipboard
or facility equipment which may be carried to mitigate an oil discharge.
                                             4-2
• The operational capabilities of the contracted oil spill removal organizations (OSROs)
to respond to the --
+ The organizational structure that will be used to manage the response actions,
including --
                      Planning;
                           0
° Finance.
• The responsibilities and duties of the oil spill management team member within the
organizational structure, in accordance with designated job responsibilities.
+ The training procedures as described in the response plan for members of the spill
management team.
+ The drill and exercise program to meet the federal and state regulations as required
byOPA.
• Procedures for the post discharge review of the plan to evaluate and validate its
effectiveness.
+ The Area Contingency Plans (ACPs) for the areas in which the vessel operates or the
facility is located.
• Basic information on spill operations and oil spill clean-up technology including --
       0       Oil containment;
           0
                Oil recovery methods and devices;
               0
                       Equipmsi1t limitations and uses;
                                                     4-3
           • Shoreline clean-up and protection;
            • Spill trajectory analysis;
             • Use of dispersants, in-situ burning, bioremediation; and
              • Waste storage and disposal considerations.
• OSHA requirements for worker health and safety (29 CFR 1910.120).
• Ship salvage procedures, vessel damage stability and hull stress considerations
when perfonming shipboard mitigation procedures, as applicable to designated job
responsibilities.
• Procedures for both the internal and ship-to-ship transfers of cargo in an emergency,
as applicable to designated job responsibilities.
• Procedures and arrangements for emergency towing, including the rigging and
operation of any emergency towing equipment aboard the vessel, as applicable to
designated job responsibilities.
• Procedures for directing the deployment and use of spill response equipment, as
applicable to designated job responsibilities.
                                             4-4
~ I A : 031 ~60 ~ ~
The USCG has worked closely with IMO and the Canadian Coast Guard in the
development of course curricula for oil spill response. In August 1993, the USCG
distributed two sets cf draft voluntary training guidelines for oil pollution response. The
guidelines were modifications of training material which IMO will be using to train
members of the international community. The guidelines provided industry with an
outline of recommended subject areas in which personnel involved in oil spill response
and clean-up could be trained in. They were presented in the form of a job task analysis
for two separate training courses. One course was designed for non-supervisory
operational personnel, while the other course was designed for supervisory operational
personnel. The guidelines were intended to assist owners and operators of vessels,
marine transportation-related (MTR) facilities, and deepwater ports in developing or
choosing training programs for oil spill response for their operational personnel.
A job task analysis (JTA) can be considered a job performance outline. Job
requirements are broken into specific performance elements referred to as tasks and
sub-tasks. For instance, task number 13, "Transfer oily wastes,• is subdivided into three
sub-tasks:
The knowledge which must be communicated to teach each sub-task and the resulting
skills which the student must demonstrate after training is completed are also provided.
Because of the different job responsibilities of each employee and their intended role in
the vessel or facility plan, the JTA should be customized by the trainer. Trainers may
use the guidelines as a menu of subject areas from which to select relevant topics
depending on the duties and responsibilities of the individual employee. This procedure
ensures a direct correlation between the job which is performed and the training which
is provided to perform that job. Specific lesson plans must be developed by the
instructor to actually deliver the subject material to the student .•
                                            A-1
OPA clearly requires vessel response plans include information on training and
response actions of vessel crews to ensure the safety of their vessel and to mitigate or
prevent an oil or haz:,rdous substance discharge. Therefore, the basic training
elements which should be addressed include both --
    a.  Prevention training to prevent a spill from occurring and the tank ship or tank
    barge from endangering its cargo, and
    b. Response training so that each crew member knows what his or her role is in
    a marine emergency, and how to respond if the crew has failed in its effonts to
    prevent a discharge of cargo onto the deck or into the surrounding water.
Prevention training is used to hone the normal operational skills of the mariner. It
ensures the safe operation of the vessel during transit and during cargo transfer
operations. Theoretically, if a comprehensive prevention training program is
implemented by the vessel owners and employees, it will substantially reduce the
number and severity of oil and hazardous substance spills. Unfortunately, many factors
combine to cause pollution incidents: these factors include but are not limited to minor
errors in judgment, equipment failure, crew fatigue, and severe weather conditions.
Response training will ensure the preparedness of the vessel's crew to respond if
prevention training has failed. A response plan training program which does not include
elements of both prevention and response is not a complete program.
The USCG has issued interim final rules in codified at 33 CFR part 155 which require
tank vessels and offshore tank barges to carry appropriate equipment and supplies for
the containment and removal of on-deck oil cargo spills. The amount of oil which the
vessel's crew must be able to contain Is dependent upon the size of the vessel. Inland
oil barges must have appropriate equipment and supplies ready for immediate use to
control and remove on-deck oil spills of at least one barrel. The Coast Guard
recognizes that the use of vessel crews in the control and clean-up of oil spills, once the
spill hits the surrounding water, is inefficient given the present state of technology and
endangers the vessel, crew, and the remainder of the cargo on board. Control and
clean-up of oil on the water is more appropriately handled by shore-based response
resources. Owners or operators of tank vessels or facilities must ensure the availability
of, through contract or other approved means, the resources to respond to an oil
discharge from a tank vessel or facility.
5-A provides suggested elements which could be incorporated into the training program
for vessel personnel. The material should not be considered as mandatory training nor
should it be considered all-inclusive. A training program which provided all of the
suggested training elements would certainly be very comprehensive. Vessel crews
receiving this training would have an excellent educational foundation to help them play
a highly proactive role in the plan holder's response organization. Plan holders must
decide the actual role of their vessel crews in their organizations and customize their
training programs accordingly.
                                            5-1
5.A. Suggested training requirements for vessel response plans to comply with
33 CFR 155.1035, 155.1040, and 155.1055 {Vessels carrying oil as primary cargo:
unmanned tank barges).
• A vessel owner or operator may identify equivalent work experience which fulfills
specific training requirements.
• The training program for manned vessels and unmanned tankbarges carrying oil as a
primary cargo should include participation in periodic announced and unannounced
drills or exercises conducted in compliance of 33 CFR 155.1060. Participation in drills or
exercises should approximate the actual roles and responsibilities of individuals as
specified in the vessel response plan.
• Training should be conducted periodically to reinforce the required knowledge and to
ensure an adequate degree of preparedness by individuals with responsibilities under
the vessel response plan.
• Training may be delivered via classroom sessions, group discussions, videotapes,
self-study workbooks, resident training courses, on-the-job training, or other means as
deemed appropriate to ensure proper instruction.
• New employees should complete the training program prior to being assigned job
responsibilities which require participation in emergency response situations.
5.B. Suggested training reguirements for vessel response plans to comply with
33 CFR 155.1045 (Oil carried as secondary cargo).
• A response plan submitted to meet the requirements of33 CFR 155.1045 (vessels
carrying oil as a secondary cargo) must identify the training to be provided to all
personnel with responsibilities under the plan.
 • The alternate qualified individual, designated to meet the requirements of 33 CFR
 155.1026, should complete the same training program as the primary qualified
 individual.
                                            5-2
• A vessel owner or operator may identify equivalent work experience which fulfills
specific training requirements.
♦ The training program for vessels carrying oil as a secondary cargo should include
participation in periodic drills or exercises conducted in compliance of 33 CFR
155.1045(h). Participation in drills or exercises should approximate the actual roles and
responsibilities of individuals as specified In the vess_el response plan.
♦ New employees should complete the training program prior to being assigned job
responsibilities which require participation in emergency response situations.
                                            5-3
5.C. Suggested training elements for members of the vessel crew having
responsibilities under the plan:
• The Captain of the Port (COTP) Zones in which the vessel will operate.
• Primary and secondary (if applicable) communication systems used for the
notifications.
• Information on the cargoes carried by the vessel, including familiarity with the cargo
material safety data sheets, chemical characteristics, special handling procedures,
health and safety hazards, and spill and firefighting procedures.
• Procedures the craw may use to mitigate or prevent any discharge or a substantial
threat of a discharge of oil resulting from shipboard operational activities associated with
internal or external cargo transfers.
• Personnel actions to take in the event of a transfer system leak, tank overflow, or
suspected cargo tank or hull leak.
• Procedures the crew may use to mitigate or prevent any discharge or a substantial
threat of a discharge of oil in the event of --
       0       Grounding or stranding;
           ° Collision;
               0
                       Explosion or fire;
                   0
                        Hull failure;
                       0
                         Excessive list; or
                           Equipment failure.
                           0
• Ship salvage procedures, damage stability, and hull stress considerations when
performing shipboard mitigation measures.
• Procedures for both the internal and ship-to-ship transfers of cargo in an emergency.
                                                   5-4
        ° Fendering equipment;
            0
                    Transfer hoses and connection equipment;
                0
                     Portable pumps and ancillary equipment;
                    0
                       Lightering and mooring masters; and
                        Vessel and barge brokers.
                        0
• Procedures and arrangements for emergency towing, including the rigging and
operation of any emergency towing equipment aboard the vessel.
• Crew's responsibilities, and procedures for use of shipboard equipment which may
be carried to mitigate an oil discharge.
+ Training procedures as described in the vessel response plan for members of the
vessel's crew.
• Drill and exercise program to meet the requirements of 33 CFR 155.1060.
• The role of the vessel's crew in the post discharge review of the plan to evaluate and
validate its effectiveness.
• OSHA requirements for worker health and safety (29 CFR 1910.120).
                                                 5-5
2) Training elements for ship's crew members with responsibilities under the plan.
Demonstrate knowledge o f -
• Information on the cargos carried by the vessel, including familiarity with the cargo
material safety data sheets, special handling procedures, health and safety hazards,
spill and fire fighting procedures.
       0       Grounding or stranding;
           ° Collision;
               0
                       Explosion or fire;
                   0
                        Hull failure;
                       0
                         Excessive list; or
                           Equipment failure.
                           0
+ Procedures, in accordance with designated job responsibilities, for both the internal
and ship-to-ship transfers of cargo in an emergency.
       0       Fendering equipment;
           0
                Transfer hoses and connection equipment; and
               0
                 Portable pumps and ancillary equipment.
+ OSHA requirements for worker health and safety (29 CFR 1910.120).
+ Primary and secondary (if applicable) communication systems used for the
notifications.
                                                5-6
5.D Suggested training elements for other personnel as described In 33 CFR
155.1040 (unmanned tank barges) with specific responsibilities under the plan:
Demonstrate knowledge o f -
+ Information on the cargoes carried by the barge including familiarity with the cargo
material safety data sheets, special handling procedures, health and safety hazards,
and spill and firefighting procedures.
+ Damage stability and hull stress considerations when performing shipboard mitigation
measures in accordance with designated job responsibilities.
+ Procedures, in accordance with designated job responsibilities, for both the internal
and barge-to-barge transfers of cargo in an emergency.
+ OSHA requirements for worker health and safety (29 CFR 1910.120).
+ Name of the qualified individual and how to contact him or her.
                                             5-7
• Primary and secondary (if applicable) communication system used for the
notifications.
+ The Captain of the Port Zones (COTP) in which the tank barges covered by the
response plan will operate.
+ Procedures for the post discharge review of the plan to evaluate and validate its
effectiveness.•
                                           5-8
Facility owners and operators are required to explain in detail how to implement the
facility's emergency response plan by describing response actions to be carried out
under the plan to ensure the safety of the facility and to mitigate or prevent discharges.
They must identify the response resources for worst case discharges and identify facility
personnel responsible for performing specific procedures to mitigate or prevent a
discharge or potential discharge.
EPA has proposed, but not finalized, several additional prevention training requirements
as follows: (1) the training previously described is proposed as a requirement, and (2)
personnel involved in oil-handling activities at facilities with certain operations are
proposed to receive at least 8 hours of training initially and at least 4 hours of refresher
training per year.
MMS regulations require that personnel who respond to spills through deployment and
operation of oil spill response equipment be provided with hands-on training classes at
least annually [30 CFR 250.43]. In addition, future MMS regulations may require a
description of the training to be carried out under the plan.
If the individual will always fill the same function in the facility response plan, training
requirements will be narrowed in scope. If a company desires greater flexibility in use of
Its personnel and redundancy in available knowledge in case key personnel are
unavailable, it may_ choose to add to the curricu_la presented_to facility op~rators. Th_e.
following 6-A provides suggested elements which could be incorporated into the training
program for facility personnel. The material should not be considered as mandatory
training nor should it be considered all-inclusive. A training program which provided all
                                             6-1
of the suggested training elements would certainly be very comprehensive. Facility
personnel receiving t~is training would have an excellent educational foundation to help
them play a highly proactive role in the plan holder's response organization. Plan
holders must decide the actual role of their facility personnel in their organizations and
customize their training programs accordingly.
• The Captain of the Port (COTP) Zone or EPA Region in which the facility is located.
• Facility personnel responsibilities, and procedures for use of facility equipment which
may be available to mitigate or prevent an oil discharge.
• The organizational structure that will be used to manage the response actions,
including --
                                               6-2
        • Public information;
         • Safety;
          • Liaison with government agencies;
           • Spill response operations;
            • Planning;
              • Logistics support; and
                • Finance.
• The Area Contingency Plan for the area in which the facility is located.
• OSHA requirements for worker heallh and safety (29 CFR 1910.120) ..
                                            6-3
Federal regulations require owners and operators of tank vessels and facilities to
ensure, through contracts or other approved means, sufficient private resources to
remove specific volumes of oil. A USCG-classified oil spill removal organization (OSRO)
may be identified in the response plan instead of providing a detailed list of equipment
and personnel resources. USCG regulations require marine transportation-related
(MTR) facility or vessel owners or operators to ensure that an OSRO identified in the
facility or vessel response plan maintains records to document training of the OSRO's
personnel. These training records must be available for inspection by the vessel or
facility management personnel, qualified individual, or federal inspectors. OSRO
personnel must also be trained to meet OSHA regulations in 29 CFR 1910.120.
OSROs may provide the contracted resources for oil and hazardous substance
response and clean-up. In some response plans, the OSRO may be contracted to
provide the spill management team, all of the response equipment, and the operational
personnel needed to deploy, operate and maintain the equipment. In other response
plans, the OSRO is merely contracted to provide the bulk of the response equipment
on- scene. The equipment may then be deployed and operated by responsible party
personnel. As an alternative to contracting with an OSRO, facilities are allowed to own,
operate, or have under their direct control the personnel and equipment necessary for
timely response. Active membership in a local or regional OSRO commonly referred to
as a cooperative is another means of compliance.
OSRO personnel are involved in the direct operational functions of oil spill clean-up.
Personnel should be trained in hazard recognition, worker health and safety issues, oil
containment, oil recovery methods and devices, equipment operation, shoreline clean
up, and waste storage and disposal considerations. Specialized training may involve
such topics as the use of dispersants, slick trajectory forecasting, in-situ burning,
bioremediation, or ship salvage. Training methods may include a variety of techniques
but an emphasis should .be placed on hands-on equipment deployment and operations.
Because of the large number of OSRO personnel involved in major pollution incidents
and the fact that many of these people are hired as temporary employees, it is expected
that only senior supervisory personnel will receive broad-based training or experience in
oil spill removal technology. The majority of the OSRO's personnel may, as appropriate,
receive training to enable them to safely and efficiently perform the specific duties
assigned to them within the organization. For example, someone who will only perform
beach clean-up operations should not be expected to know how to operate, repair, or
maintain a weir skimmer.
The Level 1 and Level 2 courses for oil spill response described in Appendix A to this
document provide suggested training elements in the form of tasks and sub-tasks.
Some of these elements could be incorporated into the training program for personnel
employed by an OSRO. The material should not be considered as mandatory training
nor should it be considered all-inclusive. A training program which provided all of the
suggested training elements would certainly be very comprehensive. Personnel
employed by an OSRO receiving this training would have an excellent educational
foundation to help them play a highly proactive role in all aspects of the organization's
clean-up efforts. Each OSRO must decide the actual role of its personnel in their own
organization and customize its company's training program accordingly.•
                                            7-1
Vessel and facility owners or operators must ensure that all private response personnel,
volunteers, or casual laborers, which they employ are trained to meet the OSHA
standards for emergency response operations promulgated in 29 CFR 1910.120. These
requirements, commonly referred to as the HAZWOPER regulations, were established
to ensure the health and safety of personnel employed in hazardous substance
response and cleanup operations. OSHA has defined hazardous substances as any
substance "exposure to which results or may result in adverse affects on health or
safety of employees."[29 CFR 1919.120] This includes substances defined under
101(14) of the Comp•ehensive Environmental Response, Compensation and Liability
Act (CERCLA), as amended, those listed by the Department of Transporation (DOT) as
designated hazardous substances under 49 CFR Part 172.101, hazardous wastes, end
biological agents. DOT regulations designate petroleum crude oil, petroleum distillates,
end petroleum oil (DOT hazard class 3, flammable liquids) as hazardous substances.
Responding to oil spills is typically different from other hazardous material emergencies
in that worker safety issues are often a more significent concern than is protection from
toxic chemicals. This focus on worker safety does not mean that we are not concerned
with the potential affects of toxic chemicals to the worker. The danger to the responder,
however, from a large variety of oils is more probable to occur from common hazards
such as slipping or tripping while trying to cleen up a highly slippery substance.
Relatively minor health problems such as dermatitis can be prevented by wearing
proper gloves, boots and protective clothing. However, there are also oils, such as high
sulfur crude oils or oils with a high benzene content, which may cause life threatening
health concerns. Proper personal protective equipment, including respiratory
protection, must be worn by the responder when responding to incidents involving
these oils or other hazardous substances with a respiratory hazard.
In general, personnel must be provided with adequate training to do their jobs safely.
This includes the fundamentals of site safety which apply generally to personnel working
at hazardous waste sites. It further includes safety conscious operational training for the
particular job (e.g., methods of deploying boom safely by boat). An ongoing training
program to reinforce and build upon previous training is also required (i.e., annual
refresher training). It is not necessary to conduct all training in one block of time, or
restrict it to a single training event.
OSHA's Hazardous Waste Operations Standard (29 CFR 1910.120) sets basic
requirements for training of personnel. These requirements are dependent on the
operations (e.g., general site operations, emergency response operations, and post
emergency response operations); on the individual's duties (e.g., first responders,
general site workers, supervisors, special short term operations, technicians, etc.); and
on the degree of exposure (e.g., minimal exposure, unknown exposures, etc.). It Is
important to recognize that these requirements may change as the operations progress
from emergency phase to post-emergency phase. At the same time, the degree of
exposure risk is also changing with time. For example, as high vapor pressure products
which might pose an inhalation hazard evaporate from the weathering oil, or as the
hazards become better characterized the amount of potential danger is also altered.
6-A and 6-B provide more specific information on OSHA requirements and training
qualifications.
                                            8-1
8.A. Outline of General Requirements for Emergency Phase and
Post-emergency Response Operations.
  1.-General requirements for emergency phase response operations (e.g., spill control
  measures conducted prior to recovery). Specific competencies are listed in 29 CFR
  1910.120(q)(6).
                                              8-2
             This level is for personnel that may be called upon to assume supervisory
             (incident command) responsibilities on-scene.
             (7) The contents of site specific safety and health plans (e.g.,
             decontamination procedures, emergency procedures, confined space
             entry procedures, and spill containment program in particular).
             (1) General site workers. General site workers (e.g., general laborers or
             equipment operators) must have the following:
             (2) Minimal hazard workers. Routine site workers who work in areas
             that have been monitored and fully characterized such that exposures are
             within permissible limits (and published limits or other hazards),
OR ............. .
                                              8-3
        non-routine site employees who are on site only occasionally for a specific
        limited task, and who are unlikely to be exposed over permissible
        exposure limits (or published limits) may be trained as follows:
                                       8-4
6.B.       Decision Guide for On-site Training Requirements.
       I
 ______v____ _
 Supervisor in ~he           yes     Must be fully qualified in
 operational chain           -->     accordance with A.l.e. (Inci
 of command?                         dent Commander) and/or A.2.b
                                     (Management and Supervisory).
                                     EXAMPLE: Operations control
             no                               team leaders
 ______v_____
  May be expected to          yes     Awareness level training
  perform emergency           -->     per A.l.a. and
  phase operations?                   annual refresher training.
                                     EXAMPLE: Local police and fire
                                              smallboat stations
no
                                                  I(continue)
                                     --~---~v_________
                               Performs advanced emergency
               Go to next      response operations such as:
               page [POST no containment from safe distance,
         (1)<- EMERGENCY   <-- entering hot zones, or
               OPERATIONS]     supporting hot zone entrants.
                                              I yes
                                     _________v_________
  V
                  Go to next         Further training in accordance
                  page [POST- no     with -
         (l)<-    EMERGENCY   <-.   A.l.b:     operations level
                  OPERATIONS]        A.l.c:     technician level
                                     A.l.d:     specialist level
     I
     v__________
 Performs unexpected, yes Site safety and ha~ard
 special limited risk --> awareness briefing per A.l.f.
 operations support      EXAMPLES: Crane operators
 ing emergency phase                Longshoremen
 response operations?               Buoy tender for VOSS
                                         8-5
(continued):
               ( 2)                              (1)
                I                                 I
     ._____v_____              ~ - - - - - - - - - v_ _ _ _ _ _ _ __
     POST-EMERGENCY            Emergency response personnel that
       OPERATIONS              also perform post-emergency ops may
                           <-- require both A.l & A.2. or hybrid
                               training that is consistent with
                               both requirements.
     ____v______ .
     Performs minimal        yes 4 hours of training in accordance
     exposure risk ops       --> with A.2.c. Must be supervised
     for post-emergency          by a qualified supervisor.
     response to oil             EXAMPLE: (a) Temporary hire for
     spills ONLY?                              a large oil spill
                                           (b) Bird rehab volunteer
                                 May be combined with A.l.a
                                 training.
                                   --------~_v________
                                                       I
                                   For prolonged operations
                                   continue training to meet the
                                   minimal risk requirements.
    ______v_______
    Performs minimal          yes 24-hour training in accordance
    exposure risk ops         --> with A.2.a.(2)
    for post-e111ergency          EXAMPLE: Ground water monitors
    response to HAZMAT                     Geophysical surveyist
    incidents?
                                   May be combined with A.1.
                                   training.
    ______v_______
    Regular response pers yes 40-hour training in accordance
    and/or site workers   --> with A.2.a.(1).
    for post-emergency        EXAMPLE:
    operations at HAZMAT       Cleanup contractor personnel
    oil spills?                Gov't pollution response pers
                               May be combined with A.l.
                               training.
    _____v__________
     For special cases contact
     the site safety and health
     officer for a specific
     determination.
                                   8-6
The USCG has worked closely with IMO and the Canadian Coast Guard in the
development of course curricula for oil spill response. In August 1993, the USCG
distributed two sets of draft voluntary training guidelines for oil pollution response. The
guidelines were modifications of training material which IMO will be using to train
members of the international community. The guidelines provided industry with an
outline of recommended subject areas in which personnel involved in oil spill response
and clean-up could be trained in. They were presented in the form of a job task analysis
for two separate training courses. One course was designed for non-supervisory
operational personnel, while the other course was designed for supervisory operational
personnel. The guidelines were intended to assist owners and operators of vessels,
marine transportation-related (MTR) facilities, and deepwater ports in developing or
choosing training programs for oil spill response for their operational personnel.
A job task analysis (JTA) can be considered a job performance outline. Job
requirements are broken into specific performance elements referred to as tasks and
sub-tasks. For instance, task number 13, "Transfer oily wastes," is subdivided into three
sub-tasks:
     " 13.1 Categorize and quantify collected materials;
The knowledge which must be communicated to teach each sub-task and the resulting
skills which the student must demonstrate after training is completed are also provided.
Because of the different job responsibilities of each employee and their intended role in
the vessel or facility plan, the JTA should be customized by the trainer. Trainers may
use the guidelines as a menu of subject areas from which to select relevant topics
depending on the duties and responsibilities of the individual employee. This procedure
ensures a direct correlation between the job which is performed and the training which
is provided to perform that job. Specific lesson plans must be developed by the
instructor to actually deliver the subject material to the student.■
                                            A-1
                            LEVEL 1 COURSE FOR OIL SPILL RESPONSE
----------------------------------------------------------------------------------------------------------]
[----------------------------------------------------------------------------------------------------------
  TASK 1: ASSESS SPILL AND RESPONSE OPERATION.
1.1   Assist tn initial            · Type and volume of spill            Recognize oil type, behavior and properties.
assessment of spill source         sources: e.g., tankers,               Detennine slick trajectory.
and potential impacts.             barges, pipelines, etc.               Predict fate and consequences.
                                   · General description of
                                   causes of spills: e.g.,
                                   collisions; breakups;
                                   groundings; mechanical,
                                   human, and environmental
                                   factors.
                                   · S~ill volume
                                   · Oi.1 types: e.g., crude,
                                   bunker fuels, gasoline,
                                   diesel, and non-petroleum.
                                   • Proximity to shoreline.
                                   · Potential impacts on
                                   resources and amenities.
                                   · Effects on flora and
                                   fauna.
                                   · Persistence of oil on
                                   shorelines.
1.2   Hazard recognition.          · Awareness of physical             · Identify hazards associated with spilled oil
                                   chemistry of oil and                or product.
                                   product.
                                   · Awareness of oil
                                   toxicology.
                                   · Material safety data
                                   sheet.
                                   • Fire and explosion
                                   hazards.
                                   · Potential hazards to
                                   human health.
                                                            A· I
1.3 Assess water and         · Influence of water and        Recognize limitations of response equipment.
weather conditions.          weather conditions on oil       Use data to predict speed and direction of
                             properties and slick          slick transport, fate, and behavior.
                             behavior.
                             • Boating safety
                             · Implications of water
                             conditions and wind speed
                             on response operations.
1.4 Identify and stop          Causes of spills.           · Assist in selecting control measures.
pollution source, if           Options tor.top oil flow.
continuing.
1.5 Identify response        · Description of clean-up     • Prioritize sensitivity, identify protection
priorities and select        phases and hardware           zones.
countermeasures.             alternatives.                 · Review merits and disadvantages of spill
                             · Response steps: stopping,   control alternatives.
                             monitoring, containment,      · Assist in determining best response
                             deflection, removal,          methodology.
                             storage, disposal.
                             · Planning and logistics:
                             timing, resource
                             utilization, safety,
                             incident command structure.
                               Protection priorities.
                               Spill control o~tions.
                               Deployment requirements.
1.6 Reassess cleanu~           Operational efficiency of   • Apply changing data to the selection of
requirements on ongoing      equipment and alternative     cleanup gear and to the choice of response
basis.                       resources.                    effort locations to optimize operations
                             · Changing oil properties
                             and environmental factors.
                               New information.
1.7 Perform administrative     Accounting of personnel,    · Reep records and conduct assigned tasks.
duties.                      expenditures, and
                             equipment.
                             · Recording of impacts,
                             response actions and
                             locations.
                             · Recording of sampling,
                             legal statements and/or
                             discussions.
                             • Organization of personnel
                             and task assignments,
                                                   A-2
                                                                        -
1.8   Take sam~les from             · Legal sampling methods.           • Take samples from water and source admissible
source and slicks.                  · Storage and chain of              as court evidence.
                                    custody requirements.               · Process samples so that the accuracy of test
                                                                        results is ensured.
[----------------------------------------------------------------------------------------------------------
  TASK 2: ASSESS THE EFFECTS OF OIL MOVEMENT AND WEATHERING ON RESPONSE OPERATIONS
 ----------------------------------------------------------------------------------------------------------
                                                                                                            l
[ _________ SUB·TASK ---- ·___   I__________   KNOWLEDGE___________   I___________________   SKILL________________________ ]
2.1 Identify oil types              · Types of oil: crude,                Demonstrate general knowledge of oil types,
and their properties.               gasoline, diesel, bunker,           grades, physical, and chemical properties.
                                    non-petroleum.
                                    · Properties: e.g.,
                                    specific gravity,
                                    viscosity, pour point,
                                    flash point, and
                                    solubility.
2.2 Forecast slick                  · Effect of oil properties,         · Estimate spill volume and direction of
transport and spreading.            sea state, and water and            movement.
                                    weather conditions on
                                    spread rate and transport.
                                    · Spill volume as a
                                    function of slick area,
                                    thickness and appearance.
                                    · Trajectory modeling.
                                    · Interaction with ice
                                    (where appropriate).
2.3 Identify the effect of          · Weathering processes:            · Assess effect of environmental conditions on
weathering on response              e.$., evaporation,                 oil and product.
operations, hazards and             oxidation, dissolution,
impacts.                            sinking, emulsification,
                                    biodegradation, and
                                    sedimentation.
                                    • Effect of weather, sea
                                    state and oil type on
                                    weathering.
                                    · Fire hazards
                                    · Implications to
                                    countermeasures operations.
                                                             A-3
 ----------------------------------------------------------------------------------------------------------]
[----------------------------------------------------------------------------------------------------------
      TASK 3: DETERMINE AND IMPLEMENT SAFETY PROCEDURES
 --------- SUE-TASK --------r----------KNoWLEDGE___________I___________________ SKILL________________________ l
[
    -------------------------- ------------------------------ ------------------------------------------------
3.1     Ensure provision of      · Safety risks of petroleum     Attend or facilitate attendance to injured.
first aid and access to          and non-petroleum oils:         Prevent self·injury.
medical facilities.              e.g., fire, and explosion.
                                 · Effects of exposure:
                                 e.g., inhalation, dermal,
                                 and ingestion.
                                 · Safety risks and handling
                                 guidance of mechanical, and
                                 electrical equipment.
                                 · Safe boating practices
                                 and guidelines.
                                 · First aid.
                                 · Marine safety data
                                 sheets.
3,2     Implement safety         · Safety checklist for        • Recognize need for and properly use personal
procedures.                      response operations.          protective clothing and equipment.
                                 · Safe work practices:        • Use safety equipment.
                                 e.g., clean-up equipment,     · Prevent unsafe worker performance,
                                 petroleum products, and
                                 site.
                                 · Personal protective
                                 clothin~ and equipment.
                                 • Capability of personnel:
                                 e.g., length of shift, and
                                 level of training,
                                 · Decontamination
                                 procedures.
3.3 Take appropriate             · Site security and access    · Ensure security of work site.
site security measures.          procedures,
                                                       A-4
[----------------------------------------------------------------------------------------------------------
 __________________________________________________________________________________________________________
  TASK 4: SELECT AND OPERATE MEANS OF TRANSPORT                                                             ]
 ---------SUB•TASK --------1----------KNOWLEDGE-----------1-------------------SKILL________________________l
[__________________________ ------------------------------ ------------------------------------------------
4.1   Assess transport needs. · Ongoing transportation needs · Determine transportation requirements.
                              of ALL cleanup phases.
4.2 Choose appropriate         • Capabilities of available       Select appropriate means of trans~ort.
response vessels or mobile     small boats.                      Operate vessels safety and effectively.
response equipmen'.:.          · Safe deployment and
                               operation of boats.
                               · Navigation: aids, areas
                               of operation.
                               · Effects of environmental
                               factors an operation of
                               vessels or mobile response
                               equipment.
 ----------------------------------------------------------------------------------------------------------      ]
[__________________________________________________________________________________________________________
  TASK 5: ESTABLISH AND MAINTAIN COMMUNICATIONS
                                                      A· 5
[----------------------------------------------------------------------------------------------------------
  TAS~ 6: CONTAIN SPILLED OIL
 ----------------------------------------------------------------------------------------------------------
                                                                                                            ]
 ---------su»:rAsi---------r----------;;owtEDGi-----------r-------------------;iiii________________________ l
[
 -------------------------- ------------------------------ ------------------------------------------------
6.1 Select appropriate        · Main uses of boom:           · Select boom upon consideration of location,
boom.                         e.g., containment,             oil type, and environmental factors.
                              deflection, and protection.
                              • Boom components and
                              structure.
                              • Types of commercial and
                              improvised booms: skirt,
                              fence, sorbent, others.
                              • Selection criteria for
                              offshore, near-shore use.
                              • Boom failure mechanisms
                              and solutions: entrainment,
                              drainage, splashover, boom
                              submergence and planning.
                              · Response time.
                              · Safety warning for spills
                              of gasoline or other
                              explosive products.
                              · ~ i te specific
                              considerations: wetland
                              damage at low tide, mooring
                              to existing structure,,
                              location of nearby
                              amenities or sensitive
                              areas.
6.2 Deploy b~oms.             • Deployment equipment and     • Deploy and moor booms to safely and
                              safety requirements.           effectively concentrate oil for recovery,
                                Slick behavior.              to protect resources, and to deflect slicks.
                              · Selecting booms·for
                              response, which would
                              depend upon sea state and
                              application.
                              • Typical deployment
                              configurations for
                              contairunent and deflection.
                              • Determination of boom
                              angle.
                                                      A·6
                              • Vessel or deployment
                              vehicle selection.
                              • Preparation and
                              inspection.
                              • Towing: e.g., tow line
                              length attachment to tow
                              post.
                              · Mooring: e.g., anchor
                              size and number, length of
                              mooring line, and mooring
                              arrangement.
                              · Safety checklist for
                              operations.
6.3 Assess water and          · Influence of water, wind,   · Monitor and assess boom performance.
weather conditions.           and currents on ability to    • Redeploy booms as tides, currents, and oil
                              contain oil.                  volumes dictate.
                              · Safety implications.
6 .4   Retrieve booms         • Recovery, cleaning,         · Safely recover booms without damage, clean and
                              disassembly, and storage of   store.
                              equipment.
 ----------------------------------------------------------------------------------------------------------]
[----------------------------------------------------------------------------------------------------------
  TASK 7: OPERATE OIL RECOVERY EQUIPMENT
 --------------------------r-----------------------------·r--·---------------------------------------------1
[_________ SUB·TASK ________ ----------~OWLED:E______________________________ SKILL-----------------------
7.1 Select appropriate        • Skimming principles and     · Select appropriate skimmer for intended
skimmer,                      types: i.e.,weir,             application.
                              oleophilic,suction and
                              other.
                              · Common nomenclature of
                              skimmers and hardware.
7.2    Operate skimmers.      • Basic engine types; fuel    • Start, operate and shut down skimmer.
                              needs; control, lube and      · Monitor for optimum performance and reselect
                              hydraulic srstems; fittings   skimmer, if needed.
                              and connect1ons.              • Troubleshoot minor problems.
                              · Operational difficulties:
                              e.g., breakdown and debris.
                              · Safety considerations.
                                                    A· 7
7.3   Equipment maintenance.   • Cleaning, disassembly,          Remove oil and debris, repair broken or worn
                               and storage.                   parts and store skimmer in ready to use
                               · Check and repair             condition.
                               equipment.
[----------------------------------------------------------------------------------------------------------]
  TASK 9; ASSIST IN APPLICATION OF RIOREKEDIATION PROCESS/SYSTEMS
 ----------------------------------------------------------------------------------------------------------
[:::::::::su»•TASK :::::_::r::::::::::KNOWLEDG~ ::::::::::1:::::::::::::::::::SKILL::::::::::::::_::_______)
9.1 Identify appropriate       · Principle of ~recess,        • Determine applicability of bioremediation to
conditions for conducting      agents and application         oil clean·up.
bioremediation.                methods.
                               • Limitations and
                               advanta$es:          .
                               · Restrictions governing
                               application and pre·
                               approval.
                                                       A-8
[ TASK 10:   ASSIST IN APPLICATION OF-CHEMICAL DISPERSION SYSTEMS        ---------------------------------11
 ---------------------------------------------------------------------------------------------------------J
 --------------------------1------------------------------r-----------------------------------------------
[--------~~~~~~~~~--------- ----------~~~=~~:~----------- -------------------~~~::_______________________]
10. l Identify aJ?propriate    · Action of dis'persant:      · Determine whether or not dispersants are
conditions for dispersing      e.g., surface tension,        potentially applicable,
oil.                           emulsion formation, and
                               water column distribution.
                               · Effective application
                               conditions: e.g., oil type,
                               slick thickness, mixing
                               energy, and water
                               temJ?e:atu:e,
                                · L1.m1tat1on: e.g.,
                                ineffective(calm)
                               conditions, interference
                               with mechanical
                               countermeasures, and
                               overall effectiveness.
                               · Toxicity of chemical and
                               dispersed hydrocarbon
                               in water column.
                               • Advantages: i.e., oil
                               degradation rate, tar
                               residue formation,
                               hydrocarbon flammability,
                               and reduction in impacts to
                               shoreline and water fowl.
                               · Restrictions governing
                               application and pre·
                               approval.
10.2   Assist in chemical     • Choice and effectiveness      Assist in the safe use and monitoring
dispersion of oil.            of a$ents, and dosage,          dispersants.
                              application equipment and
                              methods.
                              · Safety considerations.
                                                     A·9
 ------------------------------------------------------ --------------------------------------------------1 I
[ TASK II: ASSIST IN CONDUCTING IN-SITU BURNING
 ---------------------------------------------------------------------------------------------------------J
[ _________ SUB-TASK ________   I__________   ~?~LEDGE__- ________   I___________________   SKILL_______________ - _______ ]
11.l    Identify appropriate       · Conditions conducive to             Determine whether or not combustion will be
conditions for conducting          combustion: e.g., slick                successful and appropriate.
in-situ buring.                    thickness, oil type and
                                   weathering, weather and sea
                                   state and pro~er timing.
                                   · Safety considerations:
                                   e.g., highly trained
                                   personnel, air quality,
                                   fire hazard to nearby
                                   facilities, ecological and
                                   wildlife, and nearby
                                   populations.
                                   · Advantages: e.g., removal
                                   rates, shoreline impacts,
                                   storage, and disposal.
                                   · Restrictions governing
                                   use and pre-approval.
[
    TASK 12:   CLEANUP SHORELINE                                                 - -              -        -         --   11
  ---------------------------------------------------------------------------------------------------------J
[ _________ SUB-TASK_________  !__________
                                       KNOWLEDGE _- ________ I____________:_____ :~i1tL ----------------------J l
12.1    Assist in selection        • Methods and required             • Assess factors dictating shoreline response.
of approprl•t• toohniqY••·         tqYipment; @,g,, nitural1          · Aa&i&t in selection of appropriate cleanup
                                   mechanical, manual, and            methods.
                                   flushing.
                                                           A•IO
                                   Clean-up alternatives vs.
                                 environmental sensitivities.
                                 · Habitat disturbance from
                                 clean -ue ope.rations.
                                 · Changing conditions:
                                 e.g., seasonal, diurnal
                                 and tidal.
                                 · Practical considerations:
                                 e.g., access and disposal.
12.2     Clean up shoreline.     · Safety considerations:        · Safely conduct and organize shoreline
                                 tides, equipment, animals,      cleanup activities.
                                 o Careful and efficient           Minimize disturbance to shoreline.
                                 execution of response.          · Minimize amount of non-oily wastes-collected.
[---------------------------------------------------------------------------------------------------------
  TASK 13: TRANSFER OIL WATERS
 ---------------------------------------------------------------------------------------------------------J
                                                                                                           l I
[
    --------------------------r------------------------------1-----------------------------------------------
             SUB·TASK                    KNOWLEDGE                               SKILL
    -------------------------- ------------------------------ -----------------------------------------------
                                                                                                              l
13.1 Categorize and              · Oily liquids and solids       · Determine factors affecting operation of
quantify collected               generated during clean-up.      transfer equipment.
materials.
13.2 Select pumps,               · Transfer options and          · Determine suitable means to transfer
conveyors and other              mechanical principles:          materials.
equipment.                       e.g., pumps (centrifu$al,
                                 lobe, gear, intermesh1ng
                                 screw vane, flexible
                                 impeller, screw auger,
                                 progressing cavity, piston,
                                 and diaphragm).
                                 Other: aire conveyor,
                                 vacuum truck, portable
                                 vacuum unit.
                                 · Capabilities of transfer
                                 equipm~nt: e.g., o~l
                                 v1scos1ty, pour point,
                                 debris, abrasives,
                                 portability,
                                 emulsification, cold
                                 weather operation and ease
                                 of repair and handling.
                                 · Lightering operations
                                                          A·ll
13.3 Safely operate                    Pre~aration, operation              Safely operate pumps, conveyors, and other
transfer equipment.                  and disconnection of                equipment.
                                     equipment.                          • Troubleshoot minor problems.
                                     · Use of controls.
                                     · Safety considerations.
[----------------------------------------------------------------------------------------------------------
 __________________________________________________________________________________________________________
  TASK 14 STORE AND DISPOSE OF OILY WASTES                                                                  ]
( _________ sUR·TASK __ - _____   r__________   KNOWLEDGE___________   r___________________   SKILL_____________ - __ -- __   ---:1
14.1 Store materials by              · Land-based and-water·             · Assist in the selection of storage sites
cleanup.                             based storage options:              and options.
                                     e.g., pit; prefabricated            · Set up and use storage facilities.
                                     kit; towable tank; drum;
                                     trucks (tank, vacuum, dump,
                                     pickup), barges
                                     (tank, deck, and hooper);
                                     vessels (workboat, skimmer,
                                     supply boat, and tanker),
                                     plastic bag and tubing; and
                                     spent boom.
                                     · Factors re: selection of
                                     storage sites(envirorunental
                                     regulatory).
                                       Permit requirements.
14.2 Segregate and                   · Segregation of materials.         · Sort materials to facilitate storage and
minimize waste.                      · Waste reduction,                  disposal.
                                     practices: e.g., re·                · Separate and recycle waste.
                                     use; oiland water
                                     separation; minimal
                                     collection of non-oiled
                                     material; and minimal
                                     formation of waste water,
14.3 Facilitate disposal             · Disposal options:                · Assist in the selection of disposal sites and
of collected materials.              e.g., reprocessing,                options.
                                     recycling, landfilling,              Operate on-site disposal methods.
                                     stabilization, burning,              Provide feedstock for disposal units.
                                     incineration,
                                     bioremediation, and
                                     landfarming.
                                     · Capabilities of equipment
                                     and techniques.
                                                              A·l2
                                    · Factors re: selection of
                                    dis~osal options: e.g.,
                                    environmental, re~ulatory,
                                    access, and security
                                    factors.
                                    · On·site disposal for
                                    remote locations.
                                    · Safety: e.g., fire
                                    control equipment.
                                    · Permit requirements.
[---------------------------------------------------------------------------------------------------------
  TASK 15: PERFORM POST-SPILL ACTIVITIES
 ---------------------------------------------------------------------------------------------------------J
                                                                                                           l [
[_: _______ SUB-TASK _- ______   I__________   KNOWLEDGE __________   I___________________   SKILL __________________ - __ -)
15.1 Ensure                         · Health and safety                 · Set u~ and use personnel decontamination
decontamination of                  guidelines.                         facilities.
personnel.                          · Facility set·up.
15.2 Restore equipment              · Equipment decontamination         · Perform equipment restoration
to pre·spill condition.             procedures.                         activities.
                                    · Cleaning requirements and
                                    method,
                                    • Waste water collection.
                                    · Equipment maintenance and
                                    storage.
                                                             A-13
                             Ll;VEL__2___COURSE FOR OIL SPILL RESPONSE
[----------------------------------------------------------------------------------------------------------
  TASK 1: ASSESS SITUATION
 ----------------------------------------------------------------------------------------------------------
                                                                                                            ]
                                                                A· 14
                                 · Awareness of oil and
                                 product toxicology.
                                 · Fire and explosion
                                 hazards.
                                 · Potential hazards to
                                 human health,
                                 · Recovery capabilities of
                                 coastal and inland areas.
                                 · Effects on flora and
                                 faWla.
                                   Sensitivity mapp~_ng.
1.5   Hazard evaluation          · Sampling techniques         • Prevent accidental injury to personnel.
                                 · Sampling instruments
                                 (e.g., CG/02 meter,
                                 Draeger, etc,),
                                 ' Monitoring techniques.
                                 · Site characterization and
                                 analysis.
[----------------------------------------------------------------------------------------------------------]
  TASK 2: ACTIVATE RESPONSE PLAN
 ----------------------------------------------------------------------------------------------------------
[---------suB:TASi_________   I__________ KNOWLED~~--:--------I-------------------siiLL::---------:------------J
2.1 Notify appropriate           · Vessel and facility         · Demonstrate practical activation of plan
authorities and alert key        plans.                        through drills and exercises.
personnel according to           · Notification of
plan.                             authorities.
                                 • Clean-up resources.
                                 · How and when to mobilize
                                 resources.
2.2   Initiate response.         • Base line survey            · Identify and coordinate immediate response
                                 techniques and                activities.
                                 requirements.
                                 · Contracting procedures.
                                   Salvage/mitigation.
                                 • Liability issues.
                                 · Equipment uses and
                                 limitations.
                                 · Funding sources.
                                                       A•l5
                              • Natural resource damage
                              assessment, including
                              assaessement of statutory
                              and regulatory
                              requirements.
[----------------------------------------------------------------------------------------------------------
 __________________________________________________________________________________________________________
  TASK 3: PREPAKE A RESPONSE ACTION PLAN (STRATEGY)                                                         ]
 --------------------------1------------------------------i------------------------------------------------i
[_________ su»-TAsx_________ ----------~OWL~DGE ---------- ___________________ s~IL: -----------------------
3.1 Identify and              • Shoreline and inland          Identify protection J?riorities.
prioritize resources at       types.                          Identify clean-up priorities.
risk.                         · ielative sensitivity of
                              coastal ty1;>es,
                              · Sensitiv1ty mapping.
                                Local geography.
                                Local oceano~raphy.
                                Critical hab1tats. ·
                                Use of tide and tidal
                              current tables.
3.2 Spill trajectory          · Influence of water and      • Use data to predict speed and direction of oil
forecasting.                  weather conditions on oil     movement.
                              properties and slick
                              behavior and spread rate.
                                Estimating spill size.
                                Trajectory modeling.
3.3 Identify resources          Use and limitations of      • Selection of proper equipment for the given
required.                         dispersants;              circumstance.
                                  tracking systems;           Determine personnel requirements.
                                  booms;                    · Determine surveillance requirements.
                                  skimmers;                 • Determine fWldin~ required,
                                  pumps;                    • Determine logistical needs; i.e., food,
                                  portable storage;         shelter, hygiene.
                                  chemical barriers;
                                  sorbents;
                                  bioremediation;
                                  communication
                              equipment;
                                · shoreline cleanup;
A· 16
                                                                                                        ~
                              equiJ?ment; and
                              in·situ burning.
                            Logistics
                            FW1ding sources
                            Permits and other
                          approvals required.
3.4 Identify addit+onal   · Location of additional       · Locat,e and acquire additional resources.
resources,                resources.
                          · Means to obtain
                          resources.
                            Regional agreements.
                            International agreements.
                            Negotiations.
                            Contract procedures.
3.5 Maintain records as     Contract agreements,         · Establish log keeping procedures for the
required.                   Market rates.                following:
                            Purchase order systems.           contractors.
                            Change order agreements.          subcontractors.
                            Accounting procedures.            hired equipment.
                                                              consumables used.
                                                              personnel hired.
3.6 Prepare response      • Elements of a viable           Prepare and brief appropriate members of
action plan.              response plan including        response community.
                            · time available;
                              resources available;
                              containment plan;
                              protection/deflection
                              plan;
                              oil recovery plan;
                              temporary storage and
                              disposal plan;
                              application of
                              chemicals, etc. ;
                              method of deployment of
                              e9-uipment;
                              site safety plan;
                              personnel protective
                              equipment;
                              plan adjustment
                              mechanisms; and
                              permits and other
                          Federal and state approval~
                          required.                  ·
                                                 A•l7
 ----------------------------------------------------------------------------------------------------------
[----------------------------------------------------------------------------------------------------------
  TASK 4i ACTIVATE ORGARIZATIONAL RESPONSE                                                                  ]
[
 --------------------------1------------------------------i------------------------------------------------
          SUB·TASK                    KNOWLEDGE                               SKILL
 -------------------------- ------------------------------ ------------------------------------------------
                                                                                                            l
4.1 Define operation team      · Typical spill response       Organize response structure.
command structure.             organization which would       Delegate responsibilities.
                               depend on scale of the
                               spill (e.g., minor, medium,
                               or major).
                               · Typ1cal spill response
                               command structure.
                               · Roles   and
                               responsibilities of team
                               members.
                               · Incident Command System
                               and Unified Command System.
                                 Tiered response methods.
4.2 Establish internal and     · Log-keeping requirements.    Control information flow as follows:
external communication         · Standardized report            Downwards to operations level; and
procedures.                    forms.                         · Upwards to supervisors.
                               · Common communication
                               problems.
                               · Reporting schedules.
4.3   Establish command post   • Site selection               Select appropriate command post site.
                               consideration:                 Provide for logistics.
                                   infrastructure.
                                 · logistics concerns.
                                 · future expansion.
4.4 Implement safety and         Reasons for                  Organize safety/security operations structure.
security procedures.           security and safety.           Delegate responsibilities.
                               • Potential problems with
                               securityand safety.
                               · Local resources.
                               · Training requirements and
                               skill level of personnel.
                               · Occupational safety and
                               health requirements.
                                                     A-18
                       · Environmental monitoring
                       requirements (e.g., l~wer
                       explosive limit and
                       toxicity).
4.5 Establish claims    Claims procedures.            Organize claims office.
office.                 Regulatory requirements.      Delegate responsibilities.
4.6 Coordinate sub·      Contracting procedures.      Assess need for subcontracted services.
contracted services.     Basic ordering               Execute contracts.
                       agreements.                    Define role of subcontractors in overall
                         Market rates.              response organization.
                       · Daily work sheets.         • Monitor work.
                                            A•l9
----------------------------------------------------------------------------------------------------------]
[----------------------------------------------------------------------------------------------------------
  TASK 5: MANAGE ONGOING OPERATIONAL RESPONSE
[:::::::::suB~TASK ::::::::1::::::::::KNOWLEDGE:::::::::::1___::::::::::::::::sKILL::::::::::::::::::::::::J
5.1 Management of             · Use and limitations of          Direct & supervise
operational response          pollution control.                  secure source;
activities.                   equipment and techniques            chemical/biological treatment methods;
                              · Logistics concerns, such          containment methods;
                              as personnel and equipment,         protection & deflection procedures; and
                                                                  recoveryand clean-up procedures.
                                                                Monitor adherence to site safety and security
                                                              plans.
                                                              · Coordinate disposal of pollutants.
                                                                Direct and supervise logistical support.
5.2   Conducting briefings.   · Briefing techniques.            Conduct briefings for --
                                                                  supervisors;
                                                                  subordinates;
                                                                  media;
                                                                  community; and
                                                                  public officials.
5.3 Adjusting operations      · Methods for changing            Revise operation.
or organization as needed.    response priorities.              Revise organization.
                              · Methods for monitoring        Evaluate changing conditions to modify and
                              information flow.               adjust response considering the following
                              · Methods for progress          factors:
                              measurement.                        Safety.
                              • Methods for monitoring            Strategy.
                              contracted services.                Tactics.
5.4   Personnel management.     Team leadership.                Identify, define and assign tasks and
                                Time management.              expectations.
                                Stress management,            · Monitor results.
                                Delegation methods.
5.5 Assisting in                Methods scientists use to     · Assist in sampling for later scientific
scientific monitoring of      collect data and document       analysis.
affected area.                harm to the environment           Describe environmental monitoring program.
                              (e.g., sampling, storage,         Describe aerial surveillance.
                              custody, documentation).
                                                       A-20
[----------------------------------------------------------------------------------------------------------]
  TASK 6: DEACTIVATE RESPONSE
 ----------------------------------------------------------------------------------------------------------
[ _________ SUB·TASK _____ - __   l__________   KNOWLEDGE ______--__   1-________-_________   SKILL ____________ - __________ ]
6.1 Conduct analysis to              · Effort and benefit                  Rank the different criteria.
determine if response                 analysis as follows:                 Use effort and benefit analysis method.
should be continued,                   Effort: manpower, equip
suspended or terminated              ment and time requirements,
with appr~priate agencies.           environmental damage, anJ
                                     area use interference
                                       Benefits: aesthetic
                                     benefits, environmental,
                                     economical, and social
                                     water use benefits; and
                                     addressing public pressure.
6.2   Ass~ss eotential for           • Location of remainin$ oil         · Use spill projection models.
recontam1na ti.on.                   in the environment or 1n            · Determine whether cleanup should be continued
                                     the source.                         or terminated.
                                       Trajectory modelin~.
                                       Final survey techn1ques.
6.3   Shut ~own field                  Updated inventory and             · Describe how the operations should be
operations,                          location of equipment and           terminated in an orderly manner.
                                     personnel.
                                     · Procedures to terminate
                                     operations.
                                                             A.·21
 ----------------------------------------------------------------------------------------------------------]
[_________________________________________________________________________________________________________
  TASX 7: CONSOLIDATE COSTS                                                                                _
 ---------su;:TASi_________I__________ iiOWLEiGE___________ I___________________ Siiii________________________ l
[-------------------------- ------------------------------ ------------------------------------------------
7. l Verify and certify        · Reasons for cost             • Present a plan for filing and record
costs.                         documentation.                 maintenance.
                               · Liability, and cost          · Consolidate records and produce reports of
                               recovery,                      expenditures by category.
                                 Daily log procedures.
                                 Equipment cost report.
                               • Manpower forms.
                               · Invoices for contract
                               services.
                               · Personnel activity
                               sheets.
                                 Daily work sheets.
                                 Travel claims.
7.2 Provide final cost           Cost\ documentation          · Construct a simple coding structure for the
documentation report,          procedures                     response.
                               and report writing             • Produce final cost report.
                               techniques.
                               · Coding structure.
                                                       A·22
 ----------------------------------------------------------------------------------------------------------1
[----------------------------------------------------------------------------------------------------------
  TASK 8: DEBRIEF AlfD REPORT
 --------------------------i------------------------------r------------------------------------------------1
[_________ SUB·TASK __________________ KNOWLEDGE______________________________ SKILL-----------------------
B.l Conduct operational         Daily report.                · Conduct an effective and productive team
review of the response.         Purpose of review.           review of response.
8.2 Provide information,        Daily report   and           • Consolidate information to produce operations
documentation and evidence    chronological report.          report.
to final operations           · Maps, charts, or
report.                       diagrams.
                              • Message traffic, telex,
                              radio, and fax.
                              · Shoreline survey
                              evaluation form.
                              • Photographic
                              documentation.
8.3 Make recommendations      • Familiarity with existing    · Demonstrate the ability to make pertinent
for improved preparedness.    contingency plan.              recommendations for improvements to the
                                                             contingency plan.
                                                             demonstrate analytical skills.
                                                      A-23
The federal government encourages private industry and training institutions to develop
and further refine courses available for oil and hazardous substance spill prevention and
response. While training for pollution response is important, emphasis should be given
to improving the training available for the prevention of all spills. This goal would be best
accomplished by existing in-house training programs developed by companies which
are more familiar with the operational job requirements of their own employees.
Private sources have developed a large number of training courses for the oil and
chemical industries. The International Tanker Owners Pollution Federation, Limited has
published a manual for oil spill response titled Response to Marine Oil Spills and has
also produced accompanying training video tapes. The Texas A & M University offers a
wide variety of courses on oil and hazardous substance prevention and response at its
National Spill Control School in Corpus Christi, Texas, at the Texas Engineering
Extension Service, and at the Center for Marine Training and Safety in Galveston, Texas.
The Paul Hall Training Center in Piney Point, Maryland offers courses in hazardous
materials and oil spill response as well as a wide variety of courses for the professional
mariner. The Massachusetts Maritime Academy has also developed courses for
qualified individuals and supervisory personnel. Other maritime academies either have
existing courses or are in the process of developing courses to better serve the
changing needs of the maritime industry.
                                             B-1
     Training Registrar
     U.S. EPA Environmental Response Training Program
     3280 River Road
     Cincinnati, OH 45204
     Tel: (513) 251-7776;FAX: (513) 251-4137.
FEMA also operates the National Emergency Training Center in Emmitsburg, Maryland.
The Center houses the U. S. Fire Administration, the National Fire Academy, and the
Emergency Management Institute. The Center offers a wide variety of resident and
nonresident courses in emergency preparedness and several courses on hazardous
substances. Interested individuals may correspond to the following:
                                           B-2
Sample Lesson Plans
TAB A OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
                     ♦ Purpose of containment
                     ♦ Reference  material
                     ♦ Boom Selection
                     ♦ Commercial Floating Boom
                     ♦ Improvised Boom
                     ♦ Sorbent Boom
                     ♦ Air or Water Streams
                     ♦ Bubble Barriers
                     ♦ Chemical Barriers
                     ♦   Boom Failures
                          o Sheet Breakaway [Entrainment]
                          o Droplet Breakaway [Drainage]
                          o Splash-over [Submergence/Planing]
                          a Wave Induced Failure
                     ♦ Recovery
                     ♦ Skimmers
                         oWe\r
                         o Suction
                         o Centrifugal
                         o Submersion
                         o Sorbent Surface
                     ♦ Sorbents
                          o Classes
                          o Uses
                      ♦ Manual Recovery
                      ♦ Solidifying Agents
                      ♦ Chemical Agents
                          o Collecting Agents
                          o Dispersing Agents
                          o Sinking Agents
                          o Burning Agents
                          o Biological Agents
                          o Gelling Agents
                          o Neutralizing Agents
                                      C-1
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
                                           C-2
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
                         of manpower.
                      o Its compatibility with other types of booms.
                      o The location of access points for recovery equipment.
                      o Deployment areas must have good anchoring locations
                         for shoreside and waterside ends of the boom.
                      o Its buoyancy.
                      o Its roll response in currents.
                      o Its heave response in waves.
                      o Does it have adequate freeboard height and skirt depth.
                      o Is it easily visible in daylight: yellow or international
                         orange is good.
                      o Can it be packaged for ease of transportation.
                      o Is it easy to assemble, deploy and retrieve.
                      o Are there anchor points at about 50 foot (15m) intervals.
                      o Are the surfaces smooth to permit laminar (layered) fluid
                         flow & prevent the collection of debris.
                      o Is it easy to assemble, deploy and retrieve.
                       o Ballast System
                   Weight applied to the skirt to improve performance. Ballast may
                   be a series of weights attached to the skirt along the entire
                   length, a chain, or metaj rods supported along the bottom of
                   the skirt.
                                    C-3
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
                       o Anchor points
                       o End connectors
                       o Handholds
                       o Hinge
                       o Lifting Points
                       o Stiffeners
                       o Quick
                       o Universal slide
                       oSlide
                       o Slotted tube
                       o Raised Channel
                       o Bolt
                       o Hinged Plate and Pin
                       o Hinge and Pin
                  ♦ There are two types of booms in general use today: FENCE and
                  CURTAIN booms.
                  Fence booms have a rigid or semi-solid material as a vertical
                  screen against oil floating on the water. Curtain booms have a
                  flexible skirt that is held down by ballasting weights or separate
                  tension lines.
                  Fence booms can be classified according to the type of flotation
                  used:
                       o Centerline flotation,
                       o Outboard flotation, and
                       o One-sided outboard flotation.
                                     C-4
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
IMPROVISED BOOM        Can be used to contain relatively small spills which occur in
                       sheltered waters or as a temporary measure until more suitable
                       boom is brought on-site.
                      ♦ EXAMPLES:
                          o inflated fire hose
                          o telephone poles
                          ologs
                          o linked railroad ties
                          o earthen dams
                      ♦ USES:
                          o As diversion boom to divert oil to area where commercial
                             boom is already deployed.
                          o Collection point for river debris to protect main containment
                             boom.
                          o GOOD in streams or ditches which are too shallow for
                             conventional boom.
                      A major problem with this system is that the oil can readily spill
                      over the top or in-between sections.
· SORBENT BOOMS AND   Specialized containment devices that absorb oil in porous
  BARRIERS            materials such as straw or synthetic materials [This will be covered
                      in more detail in the RECOVERY portion of the lesson].
                      Used when the oil slick is relatively thin because efficiency rapidly
                      decreases once the porous surface is saturated with oil.
                      ♦ DRAWBACKS:
                          o Requires considerable additional support to avoid breakage
                            under the force of wind/current.
                          o Often requires some method of additional flotation to
                             prevent sinking when saturated with oil & water.
                          o A great deal of caution must be used to prevent the
                            contaminated side of the boom from turning over and
                             recontaminating the water.
AIR OR WATER          Under some circumstances, the force of a water stream from a fire
STREAMS               hose or pump can be used to contain or divert an oil slick. A high
                      pressure airflow will produce the same results.
                      ♦ USES:
                           o Keep oil out of a gap between conventional floating booms.
                           o Temporary containment measure wjllle a boom is being
                             deployed.
                           o Direct oil towards a recovery sight.
                           o Flush oil from beneath a dock.
                           o Adjust booms that have already been deployed.
                                        C-5
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
                    ♦ DRAWBACKS:
                         o ONLY effective when current Is less than .5 knots.                 \
                         o If current exceeds 1 knot this systems adds to the problem
                            by causing the oil to form emulsions hindering cleanup.
                         o Requires continuous use.
                         o Requires considerable skill to use effectively.
                         o Requires close coordination between operators and
                            recovery personnel.
BUBBLE BARRIERS     A rising curtain of bubbles can be produced when air is pumped
                    into a perforated pipe located below the water's surface. This
                    rising curtain causes the surface water to spread horizontally in
                    two directions perpendicular to the submerged pipe, thereby
                    forming a natural barrier.
♦ BASIC PRINCIPLE:
♦ USE/ADVANTAGES:
♦ DISADVANTAGES:
CHEMICAL BARRIERS   Certain chemicals act as surface tension modifiers and inhibit the
                    spread of oil. These are known as "herders". When relatively
                    small quantities of these chemicals are placed on the water 1s
                    surface next to the floating oil, the oil is pushed away as a result of
                    the stronger spreading force (low surface tension) of the chemical.
♦ HOW DISPERSED:
                                      C-6
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
♦ DRAWBACKS:
                    Primarily used when currents are less then .7 knots and breaking
                    waves are negligible.
                                     C-7
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
♦ HOW DEPLOYED:
SORBENT BOOMING    Boom composed of sorbent material. This type of boom is usually
                   deployed along a shoreline to protect sensitive areas or keep
                   heavier, emulsified oils from spreading.
SORBENT BARRIERS   A sorbent barrier is usually constructed of wire mesh, stakes and
                   loose sorbent materials. It is often deployed across a waterway or
                   outfall. It allows water to flow through it but retains and absorbs oil
                   on the water's surface. Primarily used in small, low-velocity
                   streams, tidal inlets or channels.
                                      C-8
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
                              •
BOOM FAILURES     Oil loss resulting from boom failure may be attributed to one or
                  more of the following causes:
                                    C-9
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
                    to occur first in that part of the boom curving to cross the direction
                    of flow ..
                    When booms fail in fast currents, oil escaping under the boom
                    tends to collect in the water flowing along the backside of the
                    boom. This provides a spill response crew with another
                    opportunity for containment. A second boom can be deployed just
                    downstream from the boom that is showing failure.
DROPLET BREAKAWAY   High velocity currents cause another type of failure (oil loss)
                    known as DROPLET BREAKAWAY [DRAINAGE) because:
                         1. Oil mass forms a headwave, and
                        2. The rear of the headwave becomes unstable, so•..
                        3. Oil droplets are tom off and entrained in water flow, flowing
                           under the skirt.
                    If the boom is not securely anchored on both sides and the wind is
                    blowing opposite the current, the boom will move back and forth
                    causing "SPLASH OVER".
WAVE INDUCED        ♦ Waves   affect the efficiency of booms. Typical failures are:
FAILURE
                         o Submergence
                         o Roll over [Planing]
                                     C-10
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
RECOVERY          After the oil is contained, the next step in the response op.eration is
                  to recover it from the water. In most instances the containment
                  and recovery phases proceed simultaneously.
                                   C-11
OIL SPILL CONTAINMENT & nECOVERY EQUIPMENT
                  Disc, Drum, Rope mop, Floating head belt, Sorbent lifting belt,
                  Sorbent submersion belt, Submersion belt, Drum brush, Chain
                  brush, submersion planes, boom-skimmer, Vortex.
                  Paddle belt, Sorbent lifting belt, Rope Mop, Drum brush, chain
                  brush, Oil head weir.
                      oWeir,
                      o Suction,
                      o Centrifugal,
                      o Submersion, and
                      o Sorbent surface.
WEIR              This type of skimmer takes advantage of gravity to drain the oil off
                  the water's surface. It consists of a weir or dam, a holding tank
                  and an attachment which is connected to external pumping
                  equipment.
♦ OPERATION:
                                    C-12
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
♦ ADVANTAGES:
♦ ADVANTAGES:
                      o Simple to operate.
                      o Have a shallow draft.
                      o Can be used nearly everywhere, even under piers.
                      o Require little or no adjustment.
                      o Efficiently recovers a wide range of different viscosity oils.
                  ♦ DISADVANTAGES:
                      o Susceptible to clogging.
                      o Doesn't work well in choppy waves.
                      o Loses suction (planing) if current exceeds .6 knots.
                      o Must be tended with lines from ashore or a boat.
                      o Susceptible to clogging.
                                  C-13
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
CENTRIFUGAL
                  ♦ ADVANTAGE:
                      o Not susceptible to clogging with debris (debris screen).
                  ♦ DISADVANTAGES:
                      o Currents and waves limit its effectiveness.
                      o Does not work well when current exceeds .6 knots.
                  1. Solid belt,
                  2. Sorbent belt.
♦ ADVANTAGES:
♦ DISADVANTAGES:
                                     C-14
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
SORBENT SURFACE   This type t>f skimmer incorporates a surface to which oil can
(OLEOPHILIC)      adhere in order to facilitate its recovery from the water. The
                  sorbent, or Holeophilic", surface can be in the form of a drum, disc,
                  belt or rope which is continuously moved through the oil film. The
                  collected oil is removed by a wiper blade or pressure roller and is
                  then deposited in an onboard container or pumped to a storage
                  facility.
                  1. Rope mop,
                  2. Disc,
                  3. Drum.
                  4. Paddle belt,
                  5. Sorbent lifting belt, and
                  6. Brush (drum or chain).
                  ♦ ADVANTAGES:
♦ DISADVANTAGES:
                                     C-15
     OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
                           o Natural organic:
'                            - peat moss,
I                            - straw,
                             -hay,
I,                           - sawdust,
                             - ground corn cobs,
                             - chicken feathers,
                             - cork, wool, clay.
                             - snow.
                           o Inorganic/Mineral Based:
                             - vermiculite (silicates),
                             - perlite (natural volcanic glass),
                             - volcanic ash,
                             - glass wool,
                             - volcanic ash/rock.
                       They usually sorb about four to eight times their weight in oil.
                       Some of these are difficult to apply because they blow in the wind.
                       Others are hazardous and require operators to wear breathing
                       apparatus (respirators).
                           o Synthetic Organic:
                             - rubber,
                             - polyester foam,
                             - polyurethane,
                             - polystyrene,
                             - nylon fibers.
                       These are highly oleophilic and hydrophobic and are ideal for
                       recovering oil floating on water. They are generally strong enough
                       to be used several times.
                                         C-16
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
MANUAL RECOVERY      -Where access is difficult, oil may have to be removed using a
                      bucket.
                     Manual recovery can be manpower intensive and expensive.
SOLIDIFYING AGENTS   Although not an oil recovery technique in its own right, chemicals
                     have been developed that convert liquid oil into solid mats, thereby
                     facilitating recovery by manual means or nets. While such
                     chemicals have been demonstrated successfully in the laboratory,
                     difficulties in achieving the required intensive mixing into the oil
                     and their high cost are likely to preclude their use except for small
                     pockets of oil in restricted locations.
                          o Collecting,
                          o Dispersing,
                          o Sinking,
                          o Burning,
                          o Biological,
                          o Gelling,
                          o Neutralizing.
COLLECTING AGENTS     ♦ Cause the oil to herd to a collection point. Works by affecting the
                      surface tension of the oil.
DISPERSING AGENTS     ♦ Dispersants contain chemicals which reduce the surface tension
                      between oil and water and therefore result in the breakup and
                      dispersal of the slick throughout the water column in the form of an
                                       C-17
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
♦ Advantages:
♦ Disadvantages:
                                    C-18
    OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
    SINKING AGENTS    ♦ Special  materials can be applied to the oil slick which adsorb the
                       oil to their surface. The combination of the oil and the sinking
                       agent is heavier than water, therefore it sinks.
'
                                      C-19
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
                          o treated sand
                          o brick dust
                          a cement
                          o silicone-treated materials
                          o chalk
                        ♦ Sinking agents are not particularly effective with low viscosity oils
                        or when the oil slick is relatively thick.
BURNING AGENTS          ♦ A substance that will make it possible to ignite the oil on the
                        surface of the water or upon a shoreline. It creates a buffer
Facilitates "In-Situ"   between the oil and the water's surface, which allows for ignition.
burning.                Most oils will burn on water or land provided that the oil is thick,
                        sufficiently emulsified and heated to its ignition temperature.
                          a Gasoline.
                          o Light crude oils.
GELLING AGENTS          ♦ Gelling agents are chemicals which increase the viscosity of the
                        oil slick and thereby reduce its rate of spread over the water's
                        surface. Some gelling agents change the oil into cellular-like
                        foam, while others actually coat the oil with a material having the
                        consistency of plastic thread.
                                          C-20
OIL SPILL CONTAINMENT & RECOVERY EQUIPMENT
                   Gelling agents are used as a first step for other cleanup methods
                   (i.e. gelling agent is used on a light oil to thicken it so a skimmer
                   can remove it from the water's surface).
APPROVAL FOR USE   ♦ The OSC has the authority to deploy chemical agents only under
                   the following circumstances:
                                    C-21
TABB OVERVIEW
                                       C-22
OVERVIEW (cont)
                                  C-23
OVERVIEW (cont)
                                     C-24
     TYPES OF SHORELINES
     Introduction   Before cleanup operations may begin, the area to be cleaned must
                    be evaluated. This is done by determining:
                    ♦     the type of shoreline,
                    ♦     the degree of exposure to waves and currents,
                    ♦     the associated biological sensitivity, and
                    ♦     the ease of cleanup.
                    All of these factors are used to determine an Environmental
                    Sensitivity Index (ESI), which ranks shoreline environments on a
                    scale of 1 to 10. Generally speaking, areas exposed to high levels
                    of physical energy such as wave action and tidal currents and have
                    low biological activity rank low on the scale (1 ); while sheltered
                    areas associated with high b"1ological activity have the highest
                    ranking (10). The shoreline ranking system provides a useful first
                    step in the evaluation process because it identifies the priority
                    areas that require maximum effort for protection and cleanup. The
                    ESl is prioritized as follows with 1 being the lowest concern and 10
                    being the highest concern:
                    1.        Seawalls and piers,
                    2.        Exposed wave-cut platforms,
                    3.        Fine-grained sand beaches,
                    4.        Coarse-grained sand beaches,
                    5.        Mixed sand and gravel (or shell) beaches,
                    6.        Gravel beaches and riprap structures,
                    7.        Exposed tidal flats,
                    8.        Sheltered rocky shores,
                    9.        Sheltered tidal flats,
                    10.       Fringing and extensive slat marshes.
,I
                                             C-25
TYPES OF SHORELINES (cont)
Fine-       ♦         These beaches are generally flat, wide and hard packed.
Grained
Sand        ♦         They are commonly backed by dunes or seawalls along
Beaches               exposed outer coasts.
            ♦         Along sheltered bays, they are narrower, often fronted by tidal
                      flats.
                                        C-26
; TYPES OF SHORELINES (cont)
                                    C-27
TYPES OF SHORELINES (cont)
            ♦   The wider shores may have some surface sediment, but the
                bedrock is the dominant substrate type.
                                  C-26
TYPES OF SHORELINES (cont)
                                   C-29
ENVIRONMENTAL CONCERNS
Human Life     Human life concerns can be broken down into two categories:
               general population and on-site workers.
               ♦   General population concerns are factors which will affect the
                   population in the immediate vicinity of the spill. These factors
                   include:
                   " Inhalation hazard, i.e. the pollutant is emitting a toxic plume.
                     You need to know how large of an area will be affected by the
                     plume and evaluate the need to evacuate.
                   " Ingestion hazard, i.e. is there a possibility that the pollutant will
                     affect water on food supplies.
                   " Skin contact, i.e. does the pollutant pose a threat of absorption
                     or corrosivity.
                   " Flammability, i.e. is the pollutant emitting flammable vapors
                     which pose a threat of fire.
               ♦   On-site workers concerns are the same factors listed above, but
                   also include:
                   " Threat from wildlife in the area,
                   " Hazards caused by the terrain, such as steep cliffs, and
                   " Heat and cold stress.
                                          C-30
WILDLIFE RESOURCES AND HABITATS (cont)
Exposed     ♦   Oil will not adhere to the rock platform but rather be
Wave-Cut        transported across the platform and accumulate along the high
Platforms       tide line.
            ♦   These habitats can support large populations of encrusting
                animals and plants with rich tidal pool communities.
            ♦   Oil can penetrate and persist in the beach sediments, if
                present.
            ♦   Persistence of oiled sediments is usually short term, except in
                wave shadows or larger sediment accumulations.
Coarse      ♦   Light oil will be deposited primarily as a band along the high-
Grained          tide line.        •
Sand
Beaches      ♦   Under very heavy accumulations, oil may spread across the
                 entire beach face, though the oil will be lifted off the lower
                 beach with the rising tide.
             ♦   Penetration of oil into coarse-grained sand can reach 25
                 centimeters (cm).
             ♦   Burial of oiled layers by clean sands can be rapid, and up to 60
                 cm or more.
             ♦   Burial over one meter deep is possible if the oil comes ashore
                 at the start of a depositional period (the change from low to
                 high tide).
             ♦   Generally, species density and diversity is low.
             ♦   Biological impacts include temporary declines in infaunal
                 (aquatic animals living on the substrate) populations, which can
                 also affect feeding shore birds.
Mixed Sand   ♦   During small spills, oil will be deposited along and above the
and Gravel       high tide swash.
(or Shell)
Beaches      ♦   Large spills will spread across the entire intertidal area.
             ♦   Oil penetration into the beach sediment may be up to 50
                 centimeters (cm); however, the sand fraction can be quite
                 mobile, and oil behavior is much like on a sand beach if the
                 sand fraction exceeds about 40 percent.
             ♦   Burial of oil may be deep at and above the high tide line, where
                 oil tends to persist, particularly where beaches are only
                 intermittently exposed to waves.
             ♦   On sheltered beaches, extensive pavements of asphalted
                 sediments can form if there is no removal of heavy oil
                 accumulations, because most of the oil remains on the surface.
             ♦   Once formed, pavements are very stable and can persist for
                 many years.
             ♦   Oil can be stranded in the coarse sediments on the lower part
                 of the beach, particularly if the oil is weathered or emulsified.
                                   C-33
WILDLIFE RESOURCES AND HABITATS (cont)
Exposed          ♦   Oil does not usually adhere to the surface of exposed tidal flats,
Tidal                 but rather moves across the flat and accumulates at the high
Flats                tide line.
                 ♦   Deposition of oil on the flat may occur on falling tide if
                     concentrations are heavy.
                 ♦   Oil does not penetrate the water saturated sediments.
                                       C-34
WILDLIFE RESOURCES AND HABITATS (cont)
Sheltered      ♦   On rocky shores, oil will adhere readily to the rough rocky
Rocky              surface, particularly along the high tid.e line, forming a distinct
Shores             oil band.
               ♦   Fractures in the bedrock will be sites of pooling and oil
                   persistence.
               ♦   Even on wide ledges, the lower intertidal zone usually stays
                   wet (particularly when algae covered), preventing oil from
                   adhering to the rock surface.
               ♦   Heavy and weathered oils can cover the upper zone with little
                   impacts to the rich biological communities of the lower zone.
               ♦   Where surface sediments are abundant, oil will penetrate into
                   the crevices formed by the surface rubble and pool at the
                   contact of the sediments and the surface.
               ♦   Where the rubble is loosely packed, oil will penetrate deeply,
                   causing long term contamination of the subsurface sediments.
               ♦   Species density and diversity vary greatly, but barnacles,
                   snails, mussels, clams, periwinkles (a small marine snail),
                   amphipods (beach fleas). polychaetes (marine worm),
                   rockweed and crabs are often very abundant.
               ♦    Fresh oil and light refined products have high acute toxicities
                    that can affect attached organisms after even short exposures.
Sheltered      ♦    Oil does not usually adhere to the surface of sheltered tidal
Tidal               flats, but rather moves across the flat and accumulates at the
Flats               high tide line.
               ♦    Deposition of oil on the flat may occur on a falling tide if
                    concentrations are heavy.
                                      C-35
WILDLIFE RESOURCES AND HABITATS (cont)
Sheltered       ♦    Oil will not penetrate the water saturated sediments at all.
Tidal
Flats (cont)    ♦    In areas of high suspended sediments, sorption of oil can result
                     in contaminated sediments that can be deposited on the flats.
                ♦    There are usually large populations of clams, worms and
                     snails.
                ♦    Bird life is seasonally abundant.
                ♦    Biological damage may be severe.
                                       C-36
ECONOMICAL IMPACT
Introduction   Every oil spill has the potential to effect local economies and can
               be categorized into three areas:
               ♦   Public Access
               ♦   Commercial Harvest
               ♦   Other Trades
                                     C-37
COMMONLY USED CLEANUP METHODS
               ♦    Rocks,
               ♦    Cobble Stone,
               ♦    Sand Beaches, and
               ♦    Marshes.
                                      C-38
COMMONLY USED CLEANUP METHODS (cont)
                                 C-39
RECOMMENDED RESPONSE ACTIVITY
Introduction   Once the priorities have been established and all environmental
               concerns have been addressed, shoreline cleanup can start.
               Shoreline cleanup is usually required in three stages:
                                        C-40
RECOMMENDED RESPONSE ACTIVITY (cont)
Fine       ♦   These beaches are among the easiest beach types to clean.
Grained
Sand        ♦   Cleanup should concentrate on the removal of oil from the
Beaches         upper swash zone after all oil has come ashore.
            ♦   Removal of sand from the beach should be minimal to avoid
                erosion problems; special caution is necessary in areas backed
                by seawalls.
            ♦   Activity through both oiled and dune areas should be severely
                limited to prevent contamination of clean areas.
            ♦   Manual cleanup, rather than road graders and front-end
                loaders, is advised to minimize the volume of sand removed
                from the shore and requiring disposal.
            ♦   All efforts should focus on preventing the mixture of oil being
                pushed deeper into the sediments by vehicular and foot traffic.
                                  C-41
RECOMMENDED RESPONSE ACTIVITY (cont)
Mixed Sand   ♦   Remove heavy accumulations of pooled oil from the upper
and Gravel       beach face.
(or Shell)
Beaches      ♦   All oil debris should be removed.
             ♦   Sediment removal should be limited as much as possible.
             ♦   Low pressure flushing can be used to float oil away from the
                 sediment for recovery by skimmers or sorbents.
             ♦   High pressure spraying should be avoided because of potential
                 for transporting the finer sediment (sand) to the lower intertidal
                 or subtidal zones.
             ♦   Mechanical reworking of oiled sediment from the high tide zone
                 to the upper intertidal zone can be effective in areas regularly
                 exposed to wave activity. However, oiled sediment should not
                 be relocated below the mid tide zone.
             ♦   In place tilling may be used to reach deeply buried oil layers in
                 the mid beach on exposed beaches.
                                   C-42
RECOMMENDED RESPONSE ACTIVITY (cont)
Sheltered   ♦   These are high priority areas necessitating the use of spill
Tidal           protection devices to limit oil spill impact; deflection or sorbent
Flats           booms and open water skimmers should be used.
            ♦   Cleanup of the flat surface is very difficult because of the soft
                substrate and many methods may be restricted.
            ♦   Manual operations and deployment of sorbents from shallow
                draft boats may be helpful.
                                  C-43
RECOMMENDED RESPONSE ACTIVITY (cont)
Fringing      ♦   Under light oiling, the best practice is to let the area recover
& Extensive       naturally.
Salt
Marshes       ♦   Heavy accumulations of pooled oil can be removed by vacuum,
                  sorbents or low pressure flushing. During flushing, care must
                  be taken to prevent transporting oil to sensitive areas down
                  slope or along shore.
              ♦   Cleanup activities should be carefully supervised to avoid
                  vegetation damage.
              ♦   Any cleanup activity must not mix the oil deeper into the
                  sediments. Trampling of the roots must be minimized.
              ♦   Cutting of oiled vegetation should be considered when other
                  resources present are at great risk from leaving the oiled
                  vegetation in place.
                                     C-44
RCRA
                                    C-45
RCRA (cont)
                                     C-46
DISPOSAL OF OIL
Background     The disposal of recovered oil and oily debris from spill response
               operations has traditionally been one of the most difficult aspects of
               a response. Disposal options for oil and oily debris should be
               researched for your area during the planning process. Various oil
               disposal options consist of:
               ♦   Recycling
               ♦   In-Situ Burning
               ♦   Incineration
               ♦   Landfills
               ♦   Land Farming
In-Situ        In-Situ burning is the burning of oil and oily debris on-site in lieu of
Burning        attempting recovery. In cases where marshes or other
               environmentally sensitive areas have been impacted, in-situ
               burning may be the only feasible response option. However, before
               in-situ burning can take place, approval, or in some cases even a
               permit, must be obtained from the state.
                                      C-47
DISPOSAL OF OIL       (cont)
Landfills      Although landfills are still a common disposal method, their use is
               becoming increasingly difficult due to many states now regulating
               recovered oil and oily debris as a hazardous waste. In any case,
               recovered oily debris destined for a landfill site must be free of any
               free standing liquids that may separate from the solid debris.
Land Farming   Land farming is the spraying of recovered oil in a fine mist over a
               large area of land and then tilling the oil into the soil. Although it
               may take up to three years for the oil to break down in the soil,
               nutrients such as ammonium phosphate can be app\led to enhance
               this process. The option is only feasible for small :spills as the
               amount of land required is significant. the land should have low
               value, and has to be located away from potable water supplies.
State Law      In selecting any disposal option, it is important to consult with state
               environmental representatives to ensure the disposal option you
               wish to use is acceptable and within state law requirements.
                                     C-48
HAZARDOUS WASTE HANDLERS
Generator      Generators are the first link in the "Cradle to Grave" chain of
Definition     hazardous waste management. A generator is any owner.
               operator, or person who first creates a hazardous waste or the
               person who makes the waste subject to subtitle C regulation.
               There are three categories of generators:
               ♦    Large Quantity - Creates a quantity of waste greater than 1,000
                    kg per month or greater than 1 kg per month of acutely
                    hazardous waste.
               ♦    Small Quantity - Creates a quantity of waste greater than 100
                    kg per month and less than 1 kg per month of acutely
                    hazardous waste.
               ♦    Conditionally Exempt - Creates a quantity of waste less than
                    100 kg per month and less than 1 kg per month of acutely
                    hazardous waste.
Generator      Large and small generators must comply with the regulations found
Requirements   in 40 CFR 262. These regulations require that they:
               ♦    Determine that a solid waste is hazardous;
               ♦    Obtain an EPA Identification Number;
                ♦   Prepare the waste for transportation IAW 49 CFR;
                ♦   Follow accumulation and storage requirements;
                ♦   Meet record-keeping and reporting requirements; and
                ♦   Properly manifest the shipment IAW 40 CFR 262, using a
                    hazardous waste manifest.
                                      C-49
HAZARDOUS WASTE HANDLERS (cont)
                                   C-50
 HAZARDOUS WASTE HANDLERS                      (cont)
                                       C-5
RCRA PENALTIES
                                    C-52
TAB C OVERVIEW
Introduction   You may encounter various types of oils and petroleum products
               during pollution response activities. It is imperative that you
               become familiar with the physical, chemical, and toxic properties of
               oil and how these properties change when oil is released into the
               environment. The physical and biological effects of an oil spill as
               well as the behavior of the slick and the efficiency of various
               cleanup methods are strongly influenced by the type of oil spilled.
               The properties of the oil will help you to determine the oil's potential
               health hazards along with the most practical cleanup techniques in
               order to develop an effective response plan and, more importantly,
               to take the proper safety precautions for yourself and the people
               that work for you.
                                       C-53
SOURCES AND COMPOSITION OF OIL
Crude Oils           Crude oils are the most chemically complex type of petroleum oils.
                     Hundreds of different chemicals are found in any crude oil and each
                     oil well produces its own unique blend of these chemicals. Crude
                     oils are source oils used to produce, through distillation, many other
                     refined oils and petroleum products including:
So in essence        ♦ Gasoline
crude oils contain   ♦ Jet fuel (JP4)
the chemical         ♦ Naphthas
characteristics      ♦ Kerosene
of many oils.        ♦ Diesel fuel oils (#2 fuel oil)
                     ♦ Fuel Oils (Bunker C and #6 fuel oil)
                     ♦ Lubricating oils
                     ♦ Residuum (asphalts, tar)
                                            C-54
SOURCES AND COMPOSITION OF OIL (cont)
                                       C-55
PHYSICAL AND CHEMICAL PROPERTIES OF OIL
Introduction   Crude oils of different origins have a wide range of physical and
               chemica.1 properties, whereas the refined oil products have more
               well-defined properties irrespective of the crude oil from which they
               are derived. Physical and chemical properties of petroleum oil
               defined and discussed below include:
               ♦ Boiling Point
               ♦ Viscosity
               ♦   Specific Gravity
               ♦   Melting Point
Boiling        Boiling Point is the temperature at which a liquid boils. Low boiling
Point          point liquids are more volatile and will evaporate faster. Crude oil
               can be separated into its chemical components (cuts in a fractional
               distillation column based on the boiling points of these
               components). As the temperature of the crude oil is raised,
               different components reach their boiling point and in turn are
               distilled out, with the lower boiling point components rising towards
               the top of the column and the higher boiling point components
               settling towards the bottom of the column.
Note:          The boiling point is what separates the crude into different refined
               oils.
                                      C-56
PHYSICAL AND CHEMICAL PROPERTIES OF OIL (cont)
lllSIGllUM
                                                     <'•UDC   STRll',.NO;
                                                               STUA>I
                                             C-57
PHYSICAL AND CHEMICAL PROPERTIES OF OIL (cont)
Viscosity        Units for viscosity vary based on measurement method, but are
(cont)           commonly reported as centistokes (cS1) at 38° C (100.4° F).
                 Viscosity is an important property for determining appropriate oil
                 recovery techniques.
Example:         What type of sorbent materials would be better to use on a spill?
                 Absorbents distribute the material taken up throughout the body of
                 the absorbing material. They work better on light to medium
                 viscosity oils.
                 Adsorbents distribute the material on the surface of the adsorbing
                 material. It is generally considered that adsorbents work better on
                 high viscosity oils.
Melting          Melting point represents the temperature below which an oil will not
Point            flow due to its paraffin wax content. The greater the wax content,
                 the higher its Melting point. Melting point reveals the physical state
                 of the oil. (liquid or solid)
                 Melting point tells us whether the oil will act as a solid or a liquid.
                  Melting point is one of the most important properties in terms of
                  impact to the shoreline and subsequent cleanup techniques.
Note              II ambient temperature < Melting point, oil will behave as
                  solid/semi - solid. This will prevent an oil such as # 6 heating oil
                  from dispersing and cleanup may consist of using pitchforks and
                  shovels to remove the product from the water.
                                          C-58
TOXIC PROPERTIES OF OIL
Introduction   Petroleum oils may pose health hazards through inhalation or skin
               contact due to the toxicity of any chemical components within the
               oil. This is why we must consider the use of personal protective
               equipment (tyvek suits and respirators) for the safety ofcleanup
               personnel. The most common toxic properties of petroleum oil
               defined and discussed below are:
               ♦   Benzene content
               ♦   Sulfur content
               ♦   Skin hazards
Sulfur         Sulfur content reveals important toxicity hazards about the oil;
Content        specifically, hydrogen sulfide hazards. The amount of sulfur (by
               weight percentage) in a crude oil determines whether it is labeled
               as "sweee or 11sour" crude oil:
               ♦    Sweet crude has a Low sulfur content and
               ♦    Sour crude has a High sulfur content
               Sour crude oils pose a serious health hazard because the High
               sulfur components generate toxic hydrogen sulfide gas which has
               an odor of rotten eggs. A human's nose can become desensitized
               after initial inhalation of hydrogen sulfide, making it extremely
               hazardous. Once we stop smelling it, we do not realize we are still
               being exposed to its toxic effects.
NOTE           Measuring devices like a Draeger Multi Gas Detector and detection
               tubes that determine the presence of hydrogen sulfide gas are
               critically important so we can take the proper safety measures such
               as wearing a respirator or other personal protection.
                                     C-59
TOXIC PROPERTIES OF OIL (CONT)
Skin       Crude oils and certain oils (asphalts and tar) contain
Hazards    several chemical solvents considered to be "defatting agents."
           These chemicals in essence remove the natural oils in our skin and
           cause it to dry out , crack and peel. This is a very painful. When
           these solvents contact the skin they can cause direct skin irritation
           leading to painful damage known as "contact dermatitis." These
           oils also contain chemical compounds of hydrocarbons known to
           cause skin cancer upon prolonged or repeated (chronic) contact
           with the skin. This carcinogenic process may be accelerated
           greatly by exposure to ultraviolet rays from the sun, which
           underscores the need for workers to have adequate skin protection
           on cleanups to prevent exposure to this type of potential cancer
           causing agent. This would include the use of tyvec suits and
           gloves.
WEATHERING PROCESSES OF OIL
EVAPORATION
                                                          •. ~   OISSOUJTION
                                                      ~~:JS ~ A N D 8IOOEGRAOATION
                                                    ;:,;•:'.?! ,,
                                                       ._... :
                                     C-61
WEATHERING PROCESSES OF OIL (CONT)
Spreading·    Spreading is one of the most significant processes during the early
              stages of a spill. It is dependent on the oil's weight, viscosity,
              melting point, as well as the weather and sea state. High viscosity
              oils spread very slowly and those spilled at temperatures below
              their melting point barely spread at all. Low viscosity oils spread
              rapidly. After a few hours, the slick begins to break up and form
              narrow bands parallel to the wind direction. At this stage, the
              fluidity of the oil becomes less important since further spreading is
              primarily due to winds, weather and turbulence at the sea surface. It
              should be appreciated that except in the case of small spills of low
              viscosity oils, spreading is not uniform and large variations of oil
              thickness occur within the slick.
Example:      A large quantity of oil spilled at a fast rate will spread more rapidly
              than a large quantity of oil spilled at a slow rate,
                                       C-62
WEATHERING PROCESSES OF OIL {CONT)
Emulsification Many oils tend to absorb and mix with water to form emulsions
                  which can increase the total amount of pollutant by a factor
                  between 3 and 4. Such emulsions possess a high viscosity and
                  thus retards the other processes which would dissipate the oil.
                  Rough sea conditions increase the emulsification process. This
                  causes a change in the original oil's properties. Absorption of water
                  usually results in black oil changing color to brown, orange or
                  yellow. As the amount of water absorbed increases, the density of
                  the emulsion approaches that of sea water.
Note              This can effect the type of cleanup method used to remove the oil
                  from the water.
Example           Sorbents do not work well on emulsified oil because of the oil water
                  mixture. You would be better off employing skimmers and vacuum
                  trucks to remove the oil water mixture.
Dispersion        Dispersion occurs when waves and turbulence at the sea surface
                  act on the stick to produce oil droplets with a range of sizes. Small
                  droplets remain in suspension while the larger ones rise back to the
                  surface where they reform the stick. Droplets small enough to
                  remain in suspension become mixed in the water column and the
                  increased surface area presented by this dispersed oil can enhance
                  other tong term processes such as biodegradation and
                  sedimentation. Rough sea conditions (breaking waves) increase
                  the rate of natural dispersion. High viscosity oils or those that form
                  stable emulsions tend to form thick tenses on the water surface and
                  show tittle tendency to disperse. They can persist for several
                  weeks. Low viscosity oils which remain fluid and can spread
                  unhindered may disperse completely in moderate sea conditions
                  within a few days.
                   ♦ If we are dealing with a tow viscosity oil and the cleanup effort is
                      not immediate, there will be very tittle if any oil to recover.
                   The end result is that dispersion hinders cleanup efforts and makes
                   time an important factor in cleanup efforts.
                                                               *U.S. G.P.0,:1994-301-717:45
                                         C-63