Tel 0571 8352 7220 TCH24008747

Fax 0571 8352 7219 No TCH24008747

/ORIGIN
Post code 311215 2024-04-30
Add. 398 Date 2024-04-30

ZAIQ-RF(HH)-01-19

Safety Data Sheet

Applicant name Jiaxing baitao insulation material technology co., ltd.

Product Name: synthetic resin containing flammable solvents

Edit date: 2024-04-30

Edit institution: Technology Center of Hangzhou Customs District

Approver

1. Unless other wise stated, this test report is only responsible for the sample(s).
2. This test report can not be reproduced,except in full,without prior written permission of the lab.
 Tel 0571 8352 7220 TCH24008747
Fax 0571 8352 7219 No TCH24008747
/ORIGIN
Post code 311215 2024-04-30
Add. 398 Date 2024-04-30

ZAIQ-RF(HH)-01-19

DECLARATION

1.

The result in this test report is only valid for the tested samples.
2.

This report is invalid without authorized signature or the stamp of this organization.
3.

If there is any dissidence to the test data, the entrusting party shall apply for retesting within 15 days
upon receiving this report (Some special item can not be retested).The former tested samples will be
used as the retested ones. If the retest results are the same as the former ones, the retest fee will be paid
by the entrusting party.
4.

This report shall be used in integrity. This organization will not be responsible for any misleading caused
by the content of this report.
 Safety Data Sheet Page 1 of 10
synthetic resin containing flammable solvents According to GHS rev 10

1. Identification of substance
Product Name synthetic resin containing flammable solvents
Trade Name None
Chemical Name None
Recommended Use Adhesion between PVC plate and color film, plate adhesion.
Producer Name Jiaxing baitao insulation material technology co., ltd.
Address NO. 198, GAOXIN WEST FIRST ROAD, TONGXIANG ECONOMIC
DEVELOPMENT ZONE, ZHEJIANG PROVINCE / 314500
Phone Number +86-0573-88899102
Fax Number +86-0573-88892926
WEB or E-mail None
Emergency Phone +86-0573-88899102 or call your nearest poison control centre
Number
2. Hazards identification
GHS classification Flammable liquids 2
Acute toxicity-oral 4
Skin corrosion/irritation 2
Serious eye damage/eye irritation 1
Reproductive toxicity 2
Specific target organ toxicity, single exposure 3
Specific target organ toxicity, repeated exposure 2
Aspiration hazard 1
Hazardous to the aquatic environment, acute hazard 2
Hazardous to the aquatic environment, long-term hazard 3
GHS Pictograms

Signal words Danger

Hazard statements H225:Highly flammable liquid and vapour
H302:Harmful if swallowed
H315:Causes skin irritation
H318:Causes serious eye damage
H361:Suspected of damaging fertility or the unborn child
H335:May cause respiratory irritation
H336:May cause drowsiness or dizziness
H373:May cause damage to organs through prolonged or
repeated exposure
H304:May be fatal if swallowed and enters airways
H401:Toxic to aquatic life
H412:Harmful to aquatic life with long lasting effects
 Safety Data Sheet Page 2 of 10
synthetic resin containing flammable solvents According to GHS rev 10

Precautionary Statement P203:Obtain, read and follow all safety instructions before use.
Prevention P210:Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P233:Keep container tightly closed.
P240:Ground and bond container and receiving equipment.
P241:Use explosion-proof

P242:Use non-sparking tools.

P243:Take action to prevent static discharges.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash

not touch eyes.

P270:Do not eat, drink or smoke when using this product.
P271:Use only outdoors or with adequate ventilation.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye

Precautionary Statement P301+P316:IF SWALLOWED: Get emergency medical help

Response immediately.
P301+P317:IF SWALLOWED: Get medical help.
P302+P352:
P303+P361+P353:IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse affected areas with water[or
shower].
P304+P340:IF INHALED: Remove person to fresh air and keep
comfortable for breathing.
P305+P354+P338:IF IN EYES:Immediately rinse with water for
several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P317:Get medical help.
P318:IF exposed or concerned: Get medical advice.
P319:Get medical help if you feel unwell.
P321:Specific treatment (see the supplemental first aid
instruction).
P330:Rinse mouth.
P331:Do NOT induce vomiting.
P332+P317:If skin irritation occurs:Get medical help.
P362+P364:Take off contaminated clothing and wash it before
reuse.
P370+P378:In case of fire, use appropriate media to
extinguish.
Precautionary Statement P403+P233:Store in a well-ventilated place. Keep container
 Safety Data Sheet Page 3 of 10
synthetic resin containing flammable solvents According to GHS rev 10

Storage tightly closed.

P403+P235:Store in a well-ventilated place. Keep cool.
P405:Store locked up.
Precautionary Statement P501:Dispose of contents/container in according with local
Disposal regulation.
Other hazards which do Not available.
not result in classification
3. Composition/information on ingredients
Substances
Mixtures
Component Information
Component CAS number EINECS number Mass(%wt)
Vinisol 9005-09-8 618-409-3 20-30
Toluene 108-88-3 203-625-9 15-25
Divalent acid ester 95481-62-2 619-131-5 15-25
Polyester resin 25135-73-3 15-25
Cyclohexanone 108-94-1 203-631-1 10-20
Solvent oil 64742-94-5 265-198-5 10-20
Ethyl acetate 141-78-6 205-500-4 10-15
Note:1. Unless a component presents a severe hazard, it does not need to be considered in the SDS if the
concentration is less than 1%.
4.First-aid measures
In case of shortness of breath, give oxygen. Keep victim warm.
NOTE TO PHYSICIAN
Keep victim under observation. Symptoms may be delayed.
After inhalation Move to fresh air. Oxygen or artificial respiration if needed. Get
immediate medical attention.
After skin contact Immediately flush skin with plenty of water. Remove and isolate
contaminated clothing and shoes. If irritation persists, get
medical attention immediately. For minor skin contact, avoid
spreading material on unaffected skin. Wash clothing separately
before reuse.
After eye contact First rinse with plenty of water for several minutes (remove
contact lenses if easily possible). Assure adequate flushing of
the eyes by separating the eyelids with fingers. Get medical
attention immediately.
After ingestion Rinse mouth. Do not induce vomiting without medical advice. If
vomiting occurs naturally, have victim lean forward to reduce
risk of aspiration. Loosen tight clothing such as a collar, tie, belt
or waistband. Do not use mouth-to-mouth method if victim
ingested the substance. Seek immediate medical attention.
Most important Harmful if swallowed. Causes skin irritation. Causes serious eye
symptoms/effects, acute damage. Suspected of damaging fertility or the unborn child.
and delayed May cause respiratory irritation. May cause drowsiness or
dizziness. May cause damage to organs through prolonged or
 Safety Data Sheet Page 4 of 10
synthetic resin containing flammable solvents According to GHS rev 10

repeated exposure. May be fatal if swallowed and enters

airways.
5. Fire-fighting measures
Suitable extinguishing Water spray, foam, dry powder, carbon dioxide, Keep container
agents cool with water.
Special hazards caused Its vapor and air can form an explosive mixture, which may
by the material, its cause combustion and explosion in case of open flame, high
products of combustion or heat or contact with oxidants. When burning, carbon oxides,
flue gases hydrogen chloride, irritating and toxic fumes and gases may be
produced.
Protective equipment for Wear respirator and protective gloves. Evacuate non-essential
fire-fighters personnel. Water used for fire fighting must not be discharged
into drains or water sources. Maintain ventilation of the place
after a fire.
6. Accidental release measures
Person-related safety Ensure adequate ventilation. Remove all sources of ignition.
precautions Prevent dust generation. Prevent vapors from accumulating to
explosive concentrations. Do not touch damaged containers or
spilled material unless wearing appropriate protective clothing.
Ventilate closed spaces before entering. Keep unnecessary
personnel away.
Measures for Prevent further leakage or spillage if safe to do so. Do not allow
environmental protection material to be released to the environment without proper
governmental permits.
Measures for Contain spillage, and then collect with non-combustible
cleaning/collecting absorbent material (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in suitable container. Large amount of
leakage: collect to tank car with explosion-proof pump and
transport to professional waste disposal center.
Additional information See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
7. Handling and storage
Handling
Information for safe Airtight operation, strengthen ventilation, no smoking.
handling Avoid contact with skin, eyes, mucous membranes and clothing.
In case of insufficient ventilation, wear suitable respiratory
equipment.
Do not breathe dust/fume/gas/mist/vapours/spray.
Keep out of reach of children.
Information about Highly flammable, easy to cause combustion and explosion in
protection against case of open flame and high heat.
explosions and fires Use only non-sparking mechanical equipment and tools.
Take measures to prevent the build up of electrostatic charge.
 Safety Data Sheet Page 5 of 10
synthetic resin containing flammable solvents According to GHS rev 10

STORAGE
Requirements to be met Store in a cool and well-ventilated warehouse. Fireproof.
by storerooms and Keep away from fire and heat source.
containers Keep tightly closed until used.
Information about Ventilation system. Fireproof.
storage in one common Keep away from incompatible materials: strong oxidant, strong
storage facility reducing agent, strong acid, strong alkali, halogen, etc.
Further information about Equipped with the corresponding variety and quantity of fire
storage conditions fighting equipment and leakage emergency treatment
equipment.
8. Exposure controls/personal protection
Limit Values for Exposure
ACGIH ACGIH NIOSH NIOSH
Component CAS number
TLV-TWA TLV-STEL REL-TWA REL-STEL
Vinisol 9005-09-8 N.E. N.E. N.E. N.E.
Toluene 108-88-3 20 ppm N.E. 100 ppm 150 ppm
Divalent acid ester 95481-62-2 N.E. N.E. N.E. N.E.
Polyester resin 25135-73-3 N.E. N.E. N.E. N.E.
Cyclohexanone 108-94-1 20 ppm 50 ppm 25 ppm N.E.
Solvent oil 64742-94-5 N.E. N.E. N.E. N.E.
Ethyl acetate 141-78-6 400 ppm N.E. 400 ppm N.E.
Appropriate engineering Closed operation. Strengthen ventilation.
controls Make sure safety showers and eyewashes are available near
work and storage.
General protective and Do not get this material in contact with skin. Do not get this
hygienic measures material on clothing. Avoid contact with eyes. Handle in
accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.
Personal protective Self-contained filter gas masks, chemical safety goggles,
equipment impervious work clothes, oil-resistant rubber gloves.
Breathing equipment When workers are facing concentrations above the exposure
limit they must use appropriate certified respirators.
Protection of hands Wear appropriate chemical resistant gloves.
Eye/Face protection Use safety glasses with side shields or safety goggles as
mechanical barrier for prolonged exposure.
Body protection Full set of anti chemical reagent overalls, flame retardant
antistatic protective clothing, choose body protection according
to the amount and concentration of the dangerous substance at
the work place.
Note:1. N.E. not established.
9.Physical and chemical properties
Physical state Transparent liquid
Colour Light yellow
Odour No data available
 Safety Data Sheet Page 6 of 10
synthetic resin containing flammable solvents According to GHS rev 10

Melting point/freezing No data available

point
Boiling point or initial >35
boiling point and boiling
range
Flammability Highly flammable
Lower and upper No data available
explosion limit/
flammability limit
Flash point <23 (Closed cup)
Auto-ignition No data available
temperature
Decomposition No data available
temperature
pH No data available
Kinematic viscosity No data available
Solubility No data available
Partition coefficient: No data available
n-octanol/water(log
value)
Vapour pressure No data available
Density and/or relative No data available
density (water=1)
Relative vapour density No data available
(air=1)
Particle characteristics Not applicable
10. Stability and reactivity
Reactivity No data available.
Chemical stability Stable on storage under specified conditions.
Possibility of hazardous No data available.
reactions
Conditions to avoid (e.g.Heat and flame and spark. Incompatible materials. The extreme
static discharge, shock or
temperatures and direct sunlight. Static discharge. Shock or
vibration) vibration.
Incompatible materials Strong oxidant, strong reducing agent, strong acid, strong
alkali, halogen, etc.
Hazardous decomposition The decomposition products depend on temperature, air supply
products and other substances. Decomposition products may include but
are not limited to: carbon oxides, hydrogen chloride, irritating
and toxic fumes and gases.
11.Toxicological information
This product is a preparation for which no toxicological data exists. When available,

Routes of Entry: Dermal contact, eye contact, inhalation, ingestion.

 Safety Data Sheet Page 7 of 10
synthetic resin containing flammable solvents According to GHS rev 10

Acute Toxicity
Toluene CAS 108-88-3 LD50 (Oral, rat): 5580 mg/kg
LC50 (Inhalation, rat): 25.7 mg/l (4 h)
LD50 (Dermal, rabbit): 12000 mg/kg
Cyclohexanone CAS LD50 (Oral, rat): 1530 mg/kg
108-94-1 LC50 (Inhalation, rat): > 6.2 mg/l (4 h)
LD50 (Dermal, rabbit): 947 mg/kg
Ethyl acetate CAS LD50 (Oral, rat): 5620 mg/kg
141-78-6 LC50 (Inhalation, rat): 58 mg/l (8 h)
LD50 (Dermal, rat): >18000 mg/kg
Skin corrosion/Irritation Causes skin irritation.
Serious eye damage Causes serious eye damage.
/irritation
Respiratory or skin Not classified
sensitization
Germ cell mutagenicity Not classified
Carcinogenicity Not classified
Reproductive toxicity Suspected of damaging fertility or the unborn child.
STOT-single exposure May cause respiratory irritation.
May cause drowsiness or dizziness.
STOT-repeated exposure May cause damage to organs through prolonged or repeated
exposure.
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic Effects Not classified
Further Information None
12. Ecological information
Ecotoxicity
Aquatic Toxicity Toluene CAS 108-88-3
Test & Species
96 Hr LC50 Fish: 5.5 mg/l
48 Hr EC50 Daphnia: 3.78 mg/l
72 Hr EC50 Algae: 12.5 mg/l
Cyclohexanone CAS 108-94-1
Test & Species
96 Hr LC50 Fish: 527-732 mg/l
48 Hr EC50 Daphnia: N/A
72 Hr EC50 Algae: N/A
Ethyl acetate CAS 141-78-6
Test & Species
96 Hr LC50 Fish: 230 mg/l
48 Hr EC50 Daphnia: 717 mg/l
72 Hr EC50 Algae: 3300 mg/l
Persistence and Not available
degradability
 Safety Data Sheet Page 8 of 10
synthetic resin containing flammable solvents According to GHS rev 10

Bioaccumulative potential Not available

Mobility in soil Not available
Additional Information Toxic to aquatic life.
Harmful to aquatic life with long lasting effects.
13. Disposal considerations
WASTE DISPOSAL INSTRUCTIONS
Contact a qualified professional waste disposal service to dispose of this
material.
Dispose of in accordance with local environmental regulations or local
authority requirements.
14. Transport information
The Recommendation of Transport of Dangerous Goods(TDG)
UN Number UN 1866
Proper Shipping Name RESIN SOLUTION, flammable
Class/Division Class 3 Flammable Liquids
Package Group PG II
Subsidiary risk
labelling pictogram

Maritime transport IMDG Being same with TDG

Marine pollutant (Yes/No): No
Air transport ICAO-TI and Being same with TDG
IATA-DGR
15. Regulatory information
European/International Regulations
OSHA: Hazardous by definition of Hazard Communication Standard
(29CFR 1910.1200).
EINECS Status The main components of this product (Except Vinisol, Divalent
acid ester, Polyester resin) are included in EINECS inventory.
EPA TSCA Status The main components of this product(Except Divalent acid
ester) are included in TSCA inventory.
Canadian DSL/NDSL The main components of this product(Except Divalent acid
(Domestic Substances ester) are included in DSL/NDSL.
List/ Non-domestic
Substances List):
 Safety Data Sheet Page 9 of 10
synthetic resin containing flammable solvents According to GHS rev 10

HMIS(Hazardous Health: 3
Material Identification Flammability: 3
System Ratings): Physical hazard:0
Personal protection: J
(4. Severe Hazard; 3. Serious Hazard; 2. Moderate Hazard; 1.
Slight Hazard; 0. Minimal Hazard)
WHMIS (Canadian
Workplace Hazardous B2, D2A(Toluene), B3, D1B, D2B(Cyclohexanone), B2,
Material Identification D2B(Ethyl acetate)
System Ratings):
GB 12268-2012 List of This product is a dangerous goods on the GB 12268-2012 list of
dangerous goods dangerous goods.
16. other information
Employers should use this information only as a supplement to other information
gathered by them, and should make independent judgment of suitability of this information
to ensure proper use and protect the health and safety of employees. This information is
furnished without warranty, and any use of the product not in conformance
with this Material Safety Data Sheet, or in combination with any other product or process, is
the responsibility of the user.
This Material Safety Data Sheet was based on the "Globally Harmonized System of
Classification and Labelling of Chemicals", "Recommendations on the TRANSPORT OF
DANGEROUS GOODS Model Regulations", "INTERNATIONAL MARITIME DANGEROUS
GOODS CODE"," International Air Transport Association Dangerous Goods Regulations", the
National Standards and other related dangerous chemicals management laws, regulations
and standards, which are periodically updated and changed. To make dangerous goods /
hazardous chemicals comply with the relevant requirements of the latest management,
regularly update is recommended.
This Material Safety Data Sheet has been compiled in both English and Chinese. For
any discrepancies, the Chinese version shall prevail.
Abbreviations and ADR: European Agreement concerning the International
acronyms Carriage of Dangerous Goods by Road
RID: Regulations Concerning the International Transport of
Dangerous Goods by Rail
IMDG: International Maritime Code for Dangerous Goods
IATA-DGR: Dangerous Goods Regulations by the "International
Air Transport Association" (IATA)
ICAO-TI: Technical Instructions by the "International Civil
Aviation Organization" (ICAO)
EINECS: European Inventory of Existing Commercial Chemical
Substances
CAS: Chemical Abstracts Service
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
EC50: Effective concentration, 50 percent
 Safety Data Sheet Page 10 of 10
synthetic resin containing flammable solvents According to GHS rev 10

Edit Date 30.04.2024

Update and Revise Third edition
Globally Harmonized System of Classification and Labelling of
Edit Standard
Chemicals Part 1.5
Revised Institution Technology Center of Hangzhou Customs District