SAFETY DATA SHEET
Safety Data Sheet according to GB/T 16483-2008 and GB/T 17519-2013
Date of issue/Date of revision 13 December 2024
Version 16.1
Section 1. Chemical product and company identification
Product code : 00153979
Product name : SIGMACOVER 456 BASE GREEN 4199
化學品名稱 : SIGMACOVER 456 BASE GREEN 4199
Product type : Liquid.
Relevant identified uses of the substance or mixture and uses advised against
Product use : Professional applications, Used by spraying.
Use of the substance/ : Coating.
mixture
Uses advised against : Not applicable.
Supplier's details : PPG Coatings (Kunshan) Co., Ltd
53 Jinyang Road, Lujia Town,
215331 Kunshan City, Jiangsu Province, P.R. China
Tel: 86 512 57678859 Fax: 86 512 57678857
Emergency telephone : 00 86 532 83889090
number (with hours of
operation)
Section 2. Hazards identification
Classification of the substance or mixture according to GB 13690-2009 and GB 30000-2013
Emergency overview
Liquid.
Various
Aromatic.
Flammable liquid and vapor.
May be harmful in contact with skin.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful if inhaled.
Suspected of causing cancer.
Toxic to aquatic life.
Harmful to aquatic life with long lasting effects.
Prolonged or repeated contact may dry skin and cause irritation.
IF exposed or concerned: Get medical advice or attention. IF INHALED: Call a POISON CENTER or doctor if you
feel unwell. IF ON SKIN: Call a POISON CENTER or doctor if you feel unwell. If skin irritation or rash occurs: Get
medical advice or attention. If eye irritation persists: Get medical advice or attention.
See Section 12 for environmental precautions.
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Product code 00153979 Date of issue 13 December 2024 Version 16.1
Product name SIGMACOVER 456 BASE GREEN 4199
Section 2. Hazards identification
Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture ACUTE TOXICITY (dermal) - Category 5
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
AQUATIC HAZARD (ACUTE) - Category 2
AQUATIC HAZARD (LONG-TERM) - Category 3
Percentage of the mixture consisting of ingredient(s) of unknown acute dermal
toxicity: 34.5%
Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation
toxicity: 37.7%
Percentage of the mixture consisting of ingredient(s) of unknown hazards to the
aquatic environment: 62.2%
GHS label elements
Hazard pictograms :
Signal word : Warning
Hazard statements : Flammable liquid and vapor.
May be harmful in contact with skin.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful if inhaled.
Suspected of causing cancer.
Toxic to aquatic life.
Harmful to aquatic life with long lasting effects.
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Wear protective gloves, protective clothing and
eye or face protection. Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking. Use explosion-proof electrical, ventilating
or lighting equipment. Use non-sparking tools. Take action to prevent static
discharges. Keep container tightly closed. Use only outdoors or in a well-ventilated
area. Avoid release to the environment. Avoid breathing vapor. Wash thoroughly
after handling. Contaminated work clothing should not be allowed out of the
workplace.
Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. IF ON SKIN: Call a POISON
CENTER or doctor if you feel unwell. If skin irritation or rash occurs: Get medical
advice or attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice or attention.
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
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Product code 00153979 Date of issue 13 December 2024 Version 16.1
Product name SIGMACOVER 456 BASE GREEN 4199
Section 2. Hazards identification
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Physical and chemical : Flammable liquid and vapor.
hazards
Health hazards : Causes skin irritation. May cause an allergic skin reaction. Causes serious eye
irritation. Harmful if inhaled. Suspected of causing cancer. Prolonged or repeated
contact may dry skin and cause irritation.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
dryness
cracking
Ingestion : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Environmental hazards : Toxic to aquatic life. Harmful to aquatic life with long lasting effects.
Other hazards which do not : Prolonged or repeated contact may dry skin and cause irritation.
result in classification
Section 3. Composition/information on ingredients
Substance/mixture : Mixture
CAS number/other identifiers
CAS number : Not applicable.
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Product code 00153979 Date of issue 13 December 2024 Version 16.1
Product name SIGMACOVER 456 BASE GREEN 4199
Section 3. Composition/information on ingredients
Ingredient name % CAS number
Epoxy Resin 10 - <25 SUB110652
xylene isomers mixture 10 - <25 1330-20-7
barium sulfate 10 - <25 7727-43-7
Epoxy resin (MW ≤ 700) 1 - <10 25068-38-6
Talc , not containing asbestiform fibres 1 - <10 14807-96-6
ethylbenzene 1 - <10 100-41-4
2-methylpropan-1-ol 1 - <10 78-83-1
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
SUB codes represent substances without registered CAS Numbers.
Section 4. First aid measures
Description of necessary first aid measures
Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the
eyelids apart for at least 10 minutes and seek immediate medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label.
Keep person warm and at rest. Do NOT induce vomiting.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled.
Skin contact : May be harmful in contact with skin. Causes skin irritation. Defatting to the skin.
May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
dryness
cracking
Ingestion : No specific data.
Indication of immediate medical attention and special treatment needed, if necessary
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Product code 00153979 Date of issue 13 December 2024 Version 16.1
Product name SIGMACOVER 456 BASE GREEN 4199
Section 4. First aid measures
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media
Specific hazards arising : Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
from the chemical In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion. This material is toxic to aquatic life. This
material is harmful to aquatic life with long lasting effects. Fire water contaminated
with this material must be contained and prevented from being discharged to any
waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon oxides
sulfur oxides
halogenated compounds
metal oxide/oxides
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
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Product code 00153979 Date of issue 13 December 2024 Version 16.1
Product name SIGMACOVER 456 BASE GREEN 4199
Section 6. Accidental release measures
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air). Water polluting material.
May be harmful to the environment if released in large quantities.
Methods and materials for containment and cleaning up
Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.
Section 7. Handling and storage
Precautions for safe : Put on appropriate personal protective equipment (see Section 8). Persons with a
handling history of skin sensitization problems should not be employed in any process in
which this product is used. Avoid exposure - obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Do not
get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist.
Avoid release to the environment. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when
not in use. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use only non-sparking tools. Take precautionary measures against
electrostatic discharges. Empty containers retain product residue and can be
hazardous. Do not reuse container.
Conditions for safe storage, : Store between the following temperatures: 0 to 35°C (32 to 95°F). Store in
including any accordance with local regulations. Store in a segregated and approved area. Store
incompatibilities in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not
store in unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
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Product code 00153979 Date of issue 13 December 2024 Version 16.1
Product name SIGMACOVER 456 BASE GREEN 4199
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name Exposure limits
xylene GBZ 2.1 (China, 11/2022) [Xylene]
PC-TWA 8 hours: 50 mg/m³.
PC-STEL 15 minutes: 100 mg/m³.
barium sulfate GBZ 2.1 (China, 11/2022)
PC-TWA 8 hours: 10 mg/m³ (as Ba).
Talc , not containing asbestiform fibres GBZ 2.1 (China, 11/2022)
PC-TWA 8 hours: 3 mg/m³. Form: total
dust.
PC-TWA 8 hours: 1 mg/m³. Form:
respirable dust.
ethylbenzene GBZ 2.1 (China, 11/2022)
PC-TWA 8 hours: 100 mg/m³.
PC-STEL 15 minutes: 150 mg/m³.
2-methylpropan-1-ol ACGIH TLV (United States, 7/2023)
TWA 8 hours: 50 ppm.
TWA 8 hours: 152 mg/m³.
Recommended monitoring : Reference should be made to appropriate monitoring standards. Reference to
procedures national guidance documents for methods for the determination of hazardous
substances will also be required.
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye protection : Chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Gloves : butyl rubber
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Product code 00153979 Date of issue 13 December 2024 Version 16.1
Product name SIGMACOVER 456 BASE GREEN 4199
Section 8. Exposure controls/personal protection
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If
workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed
respirator complying with an approved standard if a risk assessment indicates this is
necessary.
Section 9. Physical and chemical properties
Appearance
Physical state : Liquid.
Color : Various
Odor : Aromatic.
Boiling point : >37.78°C (>100°F)
Flash point : Closed cup: 27°C (80.6°F)
Lower and upper explosive : Not available.
(flammable) limits
Relative density : 1.35
Media Result
Solubility(ies) :
cold water Not soluble
Viscosity : Dynamic (room temperature): Not available.
Kinematic (room temperature): >400 mm2/s
Kinematic (40°C): >21 mm2/s
Viscosity : > 100 s (ISO 6mm)
Section 10. Stability and reactivity
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition
products.
Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.
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Product code 00153979 Date of issue 13 December 2024 Version 16.1
Product name SIGMACOVER 456 BASE GREEN 4199
Section 10. Stability and reactivity
Hazardous decomposition : Depending on conditions, decomposition products may include the following
products materials: carbon oxides sulfur oxides halogenated compounds metal oxide/
oxides
Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
xylene isomers mixture LD50 Dermal Rabbit 1.7 g/kg -
LD50 Oral Rat 4.3 g/kg -
barium sulfate LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
Epoxy resin (MW ≤ 700) LD50 Dermal Rabbit >2 g/kg -
LD50 Oral Rat >2 g/kg -
ethylbenzene LC50 Inhalation Vapor Rat 17.8 mg/l 4 hours
LD50 Dermal Rabbit 17.8 g/kg -
LD50 Oral Rat 3.5 g/kg -
2-methylpropan-1-ol LC50 Inhalation Vapor Rat 24.6 mg/l 4 hours
LD50 Dermal Rabbit 2460 mg/kg -
LD50 Oral Rat 2830 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
xylene isomers mixture Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Epoxy resin (MW ≤ 700) Eyes - Mild irritant Rabbit - - -
Skin - Mild irritant Rabbit - - -
Sensitization
Product/ingredient name Route of Species Result
exposure
Epoxy resin (MW ≤ 700) skin Mouse Sensitizing
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
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Product name SIGMACOVER 456 BASE GREEN 4199
Section 11. Toxicological information
Name Category Route of Target organs
exposure
Talc , not containing asbestiform fibres Category 3 - Respiratory tract
irritation
2-methylpropan-1-ol Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
ethylbenzene Category 2 - -
Aspiration hazard
Name Result
ethylbenzene ASPIRATION HAZARD - Category 1
Information on the likely : Not available.
routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled.
Skin contact : May be harmful in contact with skin. Causes skin irritation. Defatting to the skin.
May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
dryness
cracking
Ingestion : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
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Product name SIGMACOVER 456 BASE GREEN 4199
Section 11. Toxicological information
Potential delayed effects : Not available.
Potential chronic health effects
General : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/
or dermatitis. Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts
(ppm) (mg/l) and mists)
(mg/l)
SIGMACOVER 456 BASE GREEN 4199 8649.5 3361.8 N/A 29.6 3.8
xylene isomers mixture 4300 1700 N/A 11 1.5
barium sulfate N/A 2500 N/A N/A N/A
Epoxy resin (MW ≤ 700) 2500 2500 N/A N/A N/A
ethylbenzene 3500 17800 N/A 17.8 1.5
2-methylpropan-1-ol 2830 2460 N/A 24.6 N/A
Other information :
Prolonged or repeated contact may dry skin and cause irritation. Sanding and grinding dusts may be harmful if inhaled.
Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain
and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits
causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with skin and
clothing.
Section 12. Ecological information
Toxicity
Product/ingredient name Result Species Exposure
Epoxy resin (MW ≤ 700) Acute LC50 1.8 mg/l Daphnia 48 hours
Chronic NOEC 0.3 mg/l Daphnia 21 days
ethylbenzene Acute EC50 1.8 mg/l Fresh water Daphnia 48 hours
Chronic NOEC 1 mg/l Fresh water Daphnia - Ceriodaphnia dubia -
2-methylpropan-1-ol Acute EC50 1100 mg/l Daphnia 48 hours
Persistence/degradability
Product/ingredient name Test Result Dose Inoculum
Epoxy resin (MW ≤ 700) OECD 301F 5 % - 28 days - -
ethylbenzene - 79 % - Readily - 10 days - -
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Section 12. Ecological information
Product/ingredient name Aquatic half-life Photolysis Biodegradability
xylene isomers mixture - - Readily
Epoxy resin (MW ≤ 700) - - Not readily
ethylbenzene - - Readily
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
xylene isomers mixture 3.12 7.4 to 18.5 Low
Epoxy resin (MW ≤ 700) 3 31 Low
ethylbenzene 3.6 79.43 Low
2-methylpropan-1-ol 1 - Low
Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Other adverse effects : No known significant effects or critical hazards.
Section 13. Disposal considerations
Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Care should be taken when handling
emptied containers that have not been cleaned or rinsed out. Empty containers or
liners may retain some product residues. Vapor from product residues may create a
highly flammable or explosive atmosphere inside the container. Do not cut, weld or
grind used containers unless they have been cleaned thoroughly internally. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
Section 14. Transport information
China UN IMDG IATA
UN number UN1263 UN1263 UN1263 UN1263
UN proper PAINT PAINT PAINT PAINT
shipping name
Transport hazard 3 3 3 3
class(es)
Packing group III III III III
Environmental No. No. No. No.
hazards
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Product name SIGMACOVER 456 BASE GREEN 4199
Section 14. Transport information
Marine pollutant Not applicable. Not applicable. Not applicable. Not applicable.
substances
Additional information
CN : None identified.
UN : This class 3 viscous liquid is not subject to regulation in packagings up to 450 L according to
2.3.2.5.1.
IMDG : This class 3 viscous liquid is not subject to regulation in packagings up to 450 L according to
2.3.2.5.
IATA : None identified.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
Transport in bulk according : Not applicable.
to IMO instruments
Section 15. Regulatory information
China inventory (IECSC) : All components are listed or exempted.
References : Production Safety Law of the People's Republic of China
Code of Occupational Disease Prevention of the People's Republic of China
Environmental Protection Law of the People's Republic of China
Fire Control Law of the People's Republic of China
Regulations on the Control over Safety of Dangerous Chemicals
Occupational exposure limits for hazardous agents in the workplace chemical
hazardous agents (GBZ2.1)
General rule for classification and hazard communication of chemicals (GB13690)
Safety data sheet for chemical products - Content and order of sections (GB/
T16483)
Guidance on the compilation of safety data sheet for chemical products (GB/
T17519)
General rule for preparation of precautionary label for chemicals (GB15258)
Safety rules for classification, precautionary labeling and precautionary statements
of chemicals (GB30000.2-29)
Section 16. Other information
History
Date of issue/Date of : 13 December 2024
revision
Date of previous issue : 8/19/2024
Version : 16.1
EHS
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Product name SIGMACOVER 456 BASE GREEN 4199
Section 16. Other information
Key to abbreviations : ADN = European Provisions concerning the International Carriage of Dangerous
Goods by Inland Waterway
ADR = The European Agreement concerning the International Carriage of
Dangerous Goods by Road
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
RID = The Regulations concerning the International Carriage of Dangerous Goods
by Rail
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader
The information contained in this data sheet is based on present scientific and technical knowledge. The
purpose of this information is to draw attention to the health and safety aspects concerning the products
supplied by PPG, and to recommend precautionary measures for the storage and handling of the products.
No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted
for any failure to observe the precautionary measures described in this data sheet or for any misuse of the
products.
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