4,0

Alcohol H,0 Alkene

alayoes cheneso eneat Jhey
H =CH
nnole 2
CH,=CH
-(! CH
nole
HDr
CH
CHy-(H-H,H,
KOH all
PminaHongteh
alkenes +HX CHy-CH,
-X
Renents
HX
NaOHKOH 2)clc
unalkao comot 5Caz
sake Ax-X
ho n?
kX NaX KOH 0
R-OH
giues. hebgn R-X
Remeues
OH and
em
xeact Jhey
R KOH. AlacH ag
Date:
No. Page
 Page No.
Date: I

H, O CH,-CH,-OH
H+

CHCH- CH
CH,-CH=(H, H,te

-ttHts H,0
H,ot CH

Hz0y
vingteteethet
H20
HT

clrshala
- H,0
CH-CH,-OH
oH
tonc H, 504

tent ,set
GHg-O-C,H5

elimtnoten
 Date:

5) KCN
E neact on alhyl haltes bynly
KCN R-CN
CN
KON

Ar/a - CEN 5nCl, Ha /DP0AL-H Prntne

Patol kedm.

Lompl ete Aedn. 2H2,

ArlR-C=N Ht OH
Paxtad Hyekolys

Ht OH
-tmpiete tytbeetyofr

-Pratnealdehyde
Anfne
-CEN Arnele
Leuboyte aeldl.
 Page No.
Date:

R-X Ae CN

1No-CEH
holides only
R- X Na -C=CH,

hlooehcne to Butamont

SE eot omine
A) On Anloe BDC.
NH
NaNO, + H
213 K -218 K
Diuzotzc'or

Con Afphate annfne>

HNO2 1alcohol

C)NH HNO2

y (ta),NH NG, 3° Sot

 Date:

NHA (Aromom Po
alkyl hallde only
Rm is called
NH3
hnmenslysis.
(19 29) (3)

ISult) (Ru)N

Reducng Aqents
A) NPLPA) P LiALH Sn + HU Fet HO Na Ha
cH, CH, OH. B,He

Alkene Alkyne Alkane

- NO, NH
LIAIHH
-(Hy-NH
-(4,-0H

Zr-tHg ttHtet 7CH

) H,N -NH2
i1) CH,-OH
4-OH
 Page No.
Data :

NPPE pd-C NaBHy DiBAH

--H
Pl

-CH= NH

at-C+0-GHg DYDAI -H -C-H +

GHsOH

Oxdatton
KmnOuOH

CH- Ha CH (00H
(DOH

oot

AHkane
1° Acohol 2° A toho)
Ketone
Atdehyde
Hky benzene
Benealdehyele
 Page No.
Date://

B) CrO PCC

AohoS AdenydetKetone
-CH-0H
>CH-OH
No xm.

CHO

CHyO)

CrO

CuG73 K.

Remenes H(Dehycdzclna MoH xn) gie aldehyde.

Alcohots Cu-513K Mdethyte tKeo fetkene
-4,-0H

i2NaoH Cal (sonlalknt ) (DeLaaboxylafon)

Art-tot -Ar tRH

CH, CoGH cHt

 Page No,
Date:|

13) Ozonalysla

kahones.
CH-CH CH, HCHa HCHO
) Zn -H,0

CH-H CH=H, 2H,cHo

2 t--H

2
2,3- diphênyl but-2-ene
HU.
Jaey teact en cmhounds Lentankng cogin and

A , eci, s00,

-CHO

7C=0
 Page No.
Date: I

Red P X2y H
HVZ (oDH

15)Recd hot Fe- tube

3CHEH Recl hot Fe-tuloe

16)KNO, NaNo, Nit te -0-N=0]

R-x KNO, R-0-N=0 + KX

I)Zn -cust
seact
Zn- dust

halide
kümesna haloan
Ag NO R-N

19) HBE (Hydogan Fluouo Bokote)

NO,
ntolenaene
) HBFH
21)H,po,CHa0H

H5PO, Ok GHe O4.

22)Rsn of Armnonfo E, Pts cdes&vcte itth Aldehydes

Orncl Ketones.
H-NH
Ammonta Imine
HN-R
Aky amtne ShYCfs base
HN-OH
Hydexylcrrine
HeN-NH2
Hycaone Hycba 2one
HN-NHN
2,4 -DNP Devave
HN-NH-- NH
Semcoba zBde SemfcaScbazone
Pheng hy ocne
Pheng nyskerz
ESR

OH/x/HalNH, CHOlCODHNO

meta
 Date

HolagnetA
*Anhy. M,Fe clowck,
gH/x/tsNH
Aitcion

CHo/CDOH /No 5dphon cuhen

CHa t Anhy-AtU
Akylaton

-Augtatoa

Sondmeyca
Anflfne eOct NNO, HO CHND,) at 213 k- 2IRK
BDC x ghses haloakenes.

+ N t Cuplt X
273(<

Ho CuCN
KI
 FPn kel Ste Rn
2)
R-X

2)
AaF
Aq, 56,(o
R-X Hgz2plorn
4 ) t z Rxn.

RX 2Na

5) AH Rxn

2 20 + 2NaY

owtz- PH Rxn
alontnch and alkylhafoles eact în patence
R

Rx 2NaX.
e
 Page No.
Date

)Chsfonaucl Recqent
alayllylamiuna baltle
ArR-X
her

Phenydoagmeiurohalile
Benzene Benzyl oleohol

HCHO

CH, CHO (eHhcma)

H
tHtt-et

wth CHy-l=cHy Cpaopernone)

Hgo
Ar/R-C-OH

Pee solPd Co,) Casbaxult attd.

ArJR-c-0-H
i1) H,o
 Paga No,
Data

e) Rxm ufth RCEN (CH,)a

AvtR
i)Ar/ACEN

Rnwlth HON
H
)H-CEN
AclR-y
8)Dow Pxoces
Halon&eneh keact uslth Qg AlaoH kOH t 623K temh. and
ahenol.

)Kolbe'G Ran.
Lphenlxeact Hh NaOH gles Na - hhenoîde wheh

NaoH 9) co

Salicyl'e ad
 Page No.
Date:

10) R?eme- Tornann

Phenel Heacts hCHU KOH

) CHCb t KOH
Salylaldehyde

Supaheais
Akylholides (1 only) entt usih sonlm alkozlode

R-0-R NoX

NOTE The sexn takes lace by N atack of lkoxfade fon

(A-o by S? nechanigm.
hen mcalox pocdutta
kenes deto.

42) Bgpaaon of phenol by (umene

-eH-0-H
H,ot
unene
Iso.popybenzene)
 Date

12)Ro5enmund Rx

aldehales.
Artee PJ- Bo9O H-H

)Stephen R

hudsclystt gius 2H
drhyale
OHArki
Art ArtRtHAH

Joliene hlsene

CHD

) H,ot

Gttemann Koch

cInhg- AC, CHO

1)Clemratnsen Red.

SC=0
>CH
 Page No.
Date

H CHO Zn-Ha

Zn-Hg
HO

Wolf
3)Wolf Klshnex Bed.

Aldehyles bnd Retones hecluced to olkaneh

KOH_A CH-OH
HN -NH H-EN-H, -oH

halatora

J, + NaOH -toONe
NaOI
O
tetow
KOT

CH,-CH

GHG-0H
 Date

20) Aldol Condensatorn

Aletodes oensl hesnchot contoms
tleaat1a-H
the heated

H,CHO H,-H= H- CHO

CH,-C= CH--CH

z) Alcdo.

CHH= CH-CHO

CH-C= CH--Ha
CHa-CH= CH-C- CHa

CH, - = CH--H,
 Page No.
Date

22)Comnlz akO Rxn.

Jhoke cletchycles uhich doehnit Danse oH qt

NeOH
CCHO cacoON
(Chlorod)
CHa CHs
tH,-C-HO -C-CUoNG

HCOONa
HHO

23) HVZ Rxmd- Halonenstfon of Casboxylt acels)

R- CHo-COOH R- CH- COOH.

Bra (od- B0no Coboxylic

24) Kolbe Eleceolyts

Jhalher alkaneh
2R-COra
 Date:

Phholnafde 5ynthesfs
25) hobOt o

halede (he sm takes place b

by
sth alkyl poa nucleophflPc attuelk
S22mechunEn These
PhoclmFole orn prbnny clkyl hoide.
tence
Aae peducks ake only pkemasy emnes nof amlne)

Salt

KOrt
OFo

24 OH

tooK
R-NH, eook

2) Haffnan Bo.Cmamfde
gn aeactHen TDequodotion Ran.
Ann Roles Bn
AHh Br t KOH_NaOH
Naobr ROgr

Br, t KOM
ArlR-NH
 Dae

2)DazoHsoPon Axn.
niline Na No,t HU
DC at 73- 278 K emh

Crermicet
Lucas Test
blw a2| leohels

Znl, t H

a R.
H,-C-CH,

2) To distngutsh Alcohol PhenoL

OH

(whtte ppt).

Phenol E Benzoc ackl Pr, + H,0.

No n.
 ) Date

9To dFsHequfah. ehenol Denzot Actd

NaHCO tofforvences

NuHCO
effevences

NeuH) Fe CJ, Test

FeC) Fe lo-ta
votet otowt

Fel3
No 2m.

SocdalProe Test
NoUH + tat
No n

effovences

Adehydes Ketones.
.Tollen's
 SPlver benzrtehyte
Page
No.
:
Date I
pPt CHED-
locltd
Recdesh
bAoun
ArlR-cOONa sdibad
tastxate
Sod.
Pot
NosXn Salt
Rochell
qet Aretetetehgete
Tollen'g
eagent
aldehydes
CNH),J
CAg Cut2
fealing
engut Cut2 bto
NaOH
+
I,
aCus0 aliplacle Cut
Feh
A
atsrngutsth oco
forn
Test
ArR-cHD
ketomes
Calycu,o)
ArHe
FR=
 ae
j cmines
1°2°&
3°
horl, (39A--KNon
cuu'dc
Page
No. fuchose
Date:
a ArR-
N )
5ulphomilchlo:lode
chegoup.
CH,--H E Test
Test)
omines.
H glucosetest
as (Isocyomfle
SuCAosedoesntgive t29e--R
je of-so, fehlng's disttngush Inolwb
NaoH
sathe Icycntde.
smell
aul KOHtCHO,
IkeTollen'sE Benzene
effect
N
Ew CH-(H,-CHoi
TodofozumTest
Test fosm
Lodo Sugaxs Test
Tst
FehlBag to
Test
Htmsbog
he Test
Tollen's H-H,-CHO Test A)Caxhylamoine Test
NOTE:Reducing Ar[A-
NH,
ot PostHve Chemfcal e)H?nsbtku Soluble
Ca2
-
s)
 Qnilne AN-N-c p-hydoxyezobeunzene. to
neAet
Dye) poH pH
Page
No.
Date:
aonlne COkana t etfecfv
OUp
[OH] -COOH
-I
E
hhensl CH-cH-H,CoOH
pks pha
tb
blw
Br
olitinguh
p-aminoazobenz
ene
Elwb EDU
Tebt
Azo-dye -I 04
bond
polaihy
N0,X fnecses
Acidc.
CMelow
dye)
N=N
to
Debt Alc