ENVIROMATE® 2000

Drew Marine Chemwatch Hazard Alert Code: 2

Chemwatch: 24-0192 Issue Date: 30/11/2023
Version No: 10.1 Print Date: 03/04/2025
Safety Data Sheet according to OSHA HazCom Standard (2024) requirements S.GHS.USA.EN

SECTION 1 Identification

Product Identifier
Product name ENVIROMATE® 2000

Chemical Name Not Applicable

Chemical formula Not Applicable

Other means of
UFI: 7KGS-VSX8-JG04-M60W
identification

Recommended use of the chemical and restrictions on use

Relevant identified uses Use according to manufacturer's directions.

Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Registered company name Drew Marine
Address 400 Captain Neville Drive, Waterbury CT 06705 United States
Telephone +1-973-526-5700

Fax Not Available

Website www.drew-marine.com

Email info@drew-marine.com

Emergency phone number

Association / Organisation Drew Marine CHEMWATCH EMERGENCY RESPONSE (24/7)
Emergency telephone The numbers below are for EMERGENCY USE ONLY. Use
+1 855-237-5573
number(s) the corporate number above for all other calls.

Other emergency
CHEMWATCH: +613 9573 3188 +61 3 9573 3188
telephone number(s)

SECTION 2 Hazard(s) identification

Classification of the substance or mixture

Classification Sensitisation (Skin) Category 1, Serious Eye Damage/Eye Irritation Category 2A

Label elements

Hazard pictogram(s)

Signal word Warning

Hazard statement(s)

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ENVIROMATE® 2000

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

Hazard(s) not otherwise classified

Not Applicable

Supplementary statement(s)
Not Applicable

Precautionary statement(s) Prevention

P280 Wear protective gloves, protective clothing, eye protection and face protection.
P261 Avoid breathing mist/vapours/spray.
P264 Wash all exposed external body areas thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of the workplace.

Precautionary statement(s) Response

P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.

Precautionary statement(s) Storage

Not Applicable

Precautionary statement(s) Disposal

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

SECTION 3 Composition / information on ingredients

Substances
See section below for composition of Mixtures

Mixtures
CAS No %[weight] Name
68131-39-5 1-10 alcohols C12-15 ethoxylated
7758-29-4 1-5 sodium tripolyphosphate
532-32-1 <1 sodium benzoate
Not Available >60 Ingredients determined not to be hazardous

The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret.

SECTION 4 First-aid measures

Description of first aid measures

If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally
Eye Contact
lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Inhalation
Other measures are usually unnecessary.
Immediately give a glass of water.
Ingestion
First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

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ENVIROMATE® 2000

Most important symptoms and effects, both acute and delayed

See Section 11

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5 Fire-fighting measures

Extinguishing media
The product contains a substantial proportion of water, therefore there are no restrictions on the type of extinguishing media which may be used. Choice of
extinguishing media should take into account surrounding areas.
Though the material is non-combustible, evaporation of water from the mixture, caused by the heat of nearby fire, may produce floating layers of combustible
substances.
In such an event consider:
foam.
dry chemical powder.
carbon dioxide.

Special hazards arising from the substrate or mixture

Fire Incompatibility None known.

Special protective equipment and precautions for fire-fighters

Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Fire Fighting
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Equipment should be thoroughly decontaminated after use.
The material is not readily combustible under normal conditions.
However, it will break down under fire conditions and the organic component may burn.
Not considered to be a significant fire risk.
Heat may cause expansion or decomposition with violent rupture of containers.
Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
May emit acrid smoke.
Fire/Explosion Hazard
Decomposes on heating and produces toxic fumes of:
carbon dioxide (CO2)
nitrogen oxides (NOx)
other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions
See section 12

Methods and material for containment and cleaning up

Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Minor Spills
Contain and absorb spill with sand, earth, inert material or vermiculite.
Wipe up.
Place in a suitable, labelled container for waste disposal.

Major Spills Moderate hazard.

Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
Stop leak if safe to do so.
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.
Neutralise/decontaminate residue (see Section 13 for specific agent).

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ENVIROMATE® 2000

Collect solid residues and seal in labelled drums for disposal.

Wash area and prevent runoff into drains.
After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using.
If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

Precautions for safe handling

DO NOT allow clothing wet with material to stay in contact with skin
Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
DO NOT enter confined spaces until atmosphere has been checked.
DO NOT allow material to contact humans, exposed food or food utensils.
Avoid contact with incompatible materials.
Safe handling When handling, DO NOT eat, drink or smoke.
Keep containers securely sealed when not in use.
Avoid physical damage to containers.
Always wash hands with soap and water after handling.
Work clothes should be laundered separately. Launder contaminated clothing before re-use.
Use good occupational work practice.
Observe manufacturer's storage and handling recommendations contained within this SDS.
Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are
maintained.
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Other information
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storage and handling recommendations contained within this SDS.

Conditions for safe storage, including any incompatibilities

Polyethylene or polypropylene container.
Suitable container Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.

Storage incompatibility None known

SECTION 8 Exposure controls / personal protection

Control parameters

Occupational Exposure Limits (OEL)

INGREDIENT DATA
Not Available

Emergency Limits

Ingredient TEEL-1 TEEL-2 TEEL-3

sodium tripolyphosphate 0.61 mg/m3 6.8 mg/m3 620 mg/m3

sodium benzoate 61 mg/m3 680 mg/m3 810 mg/m3

Ingredient Original IDLH Revised IDLH

alcohols C12-15 ethoxylated Not Available Not Available

sodium tripolyphosphate Not Available Not Available

sodium benzoate Not Available Not Available

Exposure controls
Appropriate engineering Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
controls engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation
that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if
designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use.
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ENVIROMATE® 2000

Employers may need to use multiple types of controls to prevent employee overexposure.

General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific
circumstances. If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate protection.
Provide adequate ventilation in warehouse or closed storage areas. Air contaminants generated in the workplace possess
varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove
the contaminant.

Type of Contaminant: Air Speed:

0.25-0.5 m/s (50-
solvent, vapours, degreasing etc., evaporating from tank (in still air).
100 f/min)
aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, 0.5-1 m/s (100-
welding, spray drift, plating acid fumes, pickling (released at low velocity into zone of active generation) 200 f/min.)

direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas 1-2.5 m/s (200-
discharge (active generation into zone of rapid air motion) 500 f/min.)

grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial velocity 2.5-10 m/s (500-
into zone of very high rapid air motion). 2000 f/min.)

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range

1: Room air currents minimal or favourable to capture 1: Disturbing room air currents
2: Contaminants of low toxicity or of nuisance value only. 2: Contaminants of high toxicity

3: Intermittent, low production. 3: High production, heavy use

4: Large hood or large air mass in motion 4: Small hood-local control only

Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity
generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the
extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) for extraction of solvents generated in a tank 2
meters distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction
apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are
installed or used.

Individual protection
measures, such as
personal protective
equipment

Safety glasses with side shields.

Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy
document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should
Eye and face protection include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience.
Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the
event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should
be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers
have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
Skin protection See Hand protection below

Hands/feet protection Wear chemical protective gloves, e.g. PVC.

Wear safety footwear or safety gumboots, e.g. Rubber
NOTE:
The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and
other protective equipment, to avoid all possible skin contact.
Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from
manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material
can not be calculated in advance and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be
observed when making a final choice.
Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands
should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:
· frequency and duration of contact,
· chemical resistance of glove material,
· glove thickness and
· dexterity
Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent).
· When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time
greater than 240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.
· When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes
according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.
· Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for
long-term use.
· Contaminated gloves should be replaced.
As defined in ASTM F-739-96 in any application, gloves are rated as:
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ENVIROMATE® 2000

· Excellent when breakthrough time > 480 min

· Good when breakthrough time > 20 min
· Fair when breakthrough time < 20 min
· Poor when glove material degrades
For general applications, gloves with a thickness typically greater than 0.35 mm, are recommended.
It should be emphasised that glove thickness is not necessarily a good predictor of glove resistance to a specific chemical, as the
permeation efficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection
should also be based on consideration of the task requirements and knowledge of breakthrough times.
Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the
manufacturers technical data should always be taken into account to ensure selection of the most appropriate glove for the task.
Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example:
· Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these
gloves are only likely to give short duration protection and would normally be just for single use applications, then disposed of.
· Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there
is abrasion or puncture potential
Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a
non-perfumed moisturiser is recommended.
Body protection See Other protection below

Overalls.
P.V.C apron.
Other protection Barrier cream.
Skin cleansing cream.
Eye wash unit.

Recommended material(s) Respiratory protection

GLOVE SELECTION INDEX Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 &
Glove selection is based on a modified presentation of the: 149:2001, ANSI Z88 or national equivalent)
"Forsberg Clothing Performance Index". Selection of the Class and Type of respirator will depend upon the level of
The effect(s) of the following substance(s) are taken into account in the breathing zone contaminant and the chemical nature of the contaminant.
computer-generated selection: Protection Factors (defined as the ratio of contaminant outside and inside the
ENVIROMATE® 2000 mask) may also be important.

Material CPI Required

Maximum gas/vapour
BUTYL A minimum Half-face Full-Face
concentration present in
protection Respirator Respirator
NEOPRENE A air p.p.m. (by volume)
factor
VITON A
A-AUS /
up to 10 1000 -
NATURAL RUBBER C Class1 P2
PVA C A-AUS /
up to 50 1000 -
Class 1 P2
* CPI - Chemwatch Performance Index
up to 50 5000 Airline * -
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion up to 100 5000 - A-2 P2
C: Poor to Dangerous Choice for other than short term immersion up to 100 10000 - A-3 P2
NOTE: As a series of factors will influence the actual performance of the glove,
100+ Airline**
a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis,
* - Continuous Flow ** - Continuous-flow or positive pressure demand
factors such as "feel" or convenience (e.g. disposability), may dictate a choice
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or
of gloves which might otherwise be unsuitable following long-term or frequent
hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
use. A qualified practitioner should be consulted.
dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury,
NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic
Ansell Glove Selection compounds(below 65 degC)

Glove — In order of recommendation Cartridge respirators should never be used for emergency ingress or in
AlphaTec® 15-554 areas of unknown vapour concentrations or oxygen content.
The wearer must be warned to leave the contaminated area immediately
AlphaTec® Solvex® 37-185
on detecting any odours through the respirator. The odour may indicate that
AlphaTec® 38-612 the mask is not functioning properly, that the vapour concentration is too
AlphaTec® 58-008 high, or that the mask is not properly fitted. Because of these limitations,
only restricted use of cartridge respirators is considered appropriate.
AlphaTec® 58-530B
Cartridge performance is affected by humidity. Cartridges should be
AlphaTec® 58-530W changed after 2 hr of continuous use unless it is determined that the
AlphaTec® 58-735 humidity is less than 75%, in which case, cartridges can be used for 4 hr.
Used cartridges should be discarded daily, regardless of the length of time
AlphaTec® 79-700
used
AlphaTec® Solvex® 37-675

DermaShield™ 73-711

The suggested gloves for use should be confirmed with the glove supplier.

SECTION 9 Physical and chemical properties

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ENVIROMATE® 2000

Information on basic physical and chemical properties

Appearance Blue colour liquid; mixes with water.

Relative density (Water =

Physical state Liquid 1.033
1)

Partition coefficient n-
Odour Not Available Not Available
octanol / water

Auto-ignition temperature
Odour threshold Not Available Not Available
(°C)

Decomposition
pH (as supplied) 8.6 Not Available
temperature (°C)

Melting point / freezing

-5 Viscosity (cSt) Not Available
point (°C)
Initial boiling point and
100 Molecular weight (g/mol) Not Applicable
boiling range (°C)
Flash point (°C) Not Available Taste Not Available

Evaporation rate >1 Ether = 1 Explosive properties Not Available

Flammability Not Applicable Oxidising properties Not Available

Surface Tension (dyn/cm

Upper Explosive Limit (%) Not Available Not Available
or mN/m)

Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) 2.3 Gas group Not Available

Solubility in water Miscible pH as a solution (1%) Not Available

Vapour density (Air = 1) >1 VOC g/L Not Available

Heat of Combustion (kJ/g) Not Available Ignition Distance (cm) Not Available
Flame Height (cm) Not Available Flame Duration (s) Not Available

Enclosed Space Ignition

Enclosed Space Ignition
Not Available Deflagration Density Not Available
Time Equivalent (s/m3)
(g/m3)

Nanoform Particle
Nanoform Solubility Not Available Not Available
Characteristics

Particle Size Not Available

SECTION 10 Stability and reactivity

Reactivity See section 7

Unstable in the presence of incompatible materials.

Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.

Possibility of hazardous
See section 7
reactions

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardous decomposition
See section 5
products

SECTION 11 Toxicological information

Information on toxicological effects

a) Acute Toxicity Based on available data, the classification criteria are not met.

b) Skin Irritation/Corrosion Based on available data, the classification criteria are not met.
c) Serious Eye
There is sufficient evidence to classify this material as eye damaging or irritating
Damage/Irritation
d) Respiratory or Skin
There is sufficient evidence to classify this material as sensitising to skin or the respiratory system
sensitisation
e) Mutagenicity Based on available data, the classification criteria are not met.

f) Carcinogenicity Based on available data, the classification criteria are not met.

g) Reproductivity Based on available data, the classification criteria are not met.

h) STOT - Single Exposure Based on available data, the classification criteria are not met.
i) STOT - Repeated Based on available data, the classification criteria are not met.

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ENVIROMATE® 2000

Exposure
j) Aspiration Hazard Based on available data, the classification criteria are not met.

The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives
using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable
Inhaled
control measures be used in an occupational setting.
Not normally a hazard due to non-volatile nature of product

The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because
Ingestion
of the lack of corroborating animal or human evidence.

There is some evidence to suggest that this material can cause inflammation of the skin on contact in some persons.
Open cuts, abraded or irritated skin should not be exposed to this material
Skin Contact
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.
Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Eye This material can cause eye irritation and damage in some persons.

Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general
Chronic
population.

TOXICITY IRRITATION
ENVIROMATE® 2000
Not Available Not Available

TOXICITY IRRITATION
alcohols C12-15 [2]
Dermal (rabbit) LD50: >2000 mg/kg Eye: no adverse effect observed (not irritating)[1]
ethoxylated
Oral (Rat) LD50: 1600 mg/kg[2] Skin: no adverse effect observed (not irritating)[1]

TOXICITY IRRITATION

Dermal (rabbit) LD50: >3160 mg/kg[2] Eye: no adverse effect observed (not irritating)[1]
sodium tripolyphosphate
Inhalation (Rat) LC50: >0.39 mg/l4h[1] Skin (Rodent - rabbit): 500mg/24H - Moderate

Oral (Rat) LD50: >2000 mg/kg[1] Skin: no adverse effect observed (not irritating)[1]

TOXICITY IRRITATION
[1]
Dermal (rabbit) LD50: >2000 mg/kg Eye: adverse effect observed (irritating)[1]

sodium benzoate Inhalation (Rat) LC50: >12.2 mg/L4h[1] Skin (Human): 0.5%/20M

Oral (Rat) LD50: 4070 mg/kg[2] Skin (Human): 10%/1H

Skin: no adverse effect observed (not irritating)[1]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

for Tergitol 25-L-9: Neodol 25-9 Neodol 25-7 *Shell Canada ** Huntsman (for Teric 12A9)
Polyethers (such as ethoxylated surfactants and polyethylene glycols) are highly susceptible to being oxidized in the air. They
then form complex mixtures of oxidation products.
Animal testing reveals that whole the pure, non-oxidised surfactant is non-sensitizing, many of the oxidation products are
sensitisers. The oxidization products also cause irritation.
Humans have regular contact with alcohol ethoxylates through a variety of industrial and consumer products such as soaps,
detergents and other cleaning products. Exposure to these chemicals can occur through swallowing, inhalation, or contact with
the skin or eyes. Studies of acute toxicity show that relatively high volumes would have to occur to produce any toxic response.
No death due to poisoning with alcohol ethoxylates has ever been reported. Studies show that alcohol ethoxylates have low
toxicity through swallowing and skin contact.
Animal studies show these chemicals may produce gastrointestinal irritation, stomach ulcers, hair standing up, diarrhea and
lethargy. Slight to severe irritation occurred when undiluted alcohol ethyoxylates were applied to the skin and eyes of animals.
ALCOHOLS C12-15 These chemicals show no indication of genetic toxicity or potential to cause mutations and cancers. Toxicity is thought to be
ETHOXYLATED substantially lower than that of nonylphenol ethoxylates.
Some of the oxidation products of this group of substances may have sensitizing properties.
As they cause less irritation, nonionic surfactants are often preferred to ionic surfactants in topical products. However, their
tendency to auto-oxidise also increases their irritation. Due to their irritating effect it is difficult to diagnose allergic contact
dermatitis (ACD) by patch testing.
Both laboratory and animal testing has shown that there is no evidence for alcohol ethoxylates (AEs) causing genetic damage,
mutations or cancer. No adverse reproductive or developmental effects were observed.
Tri-ethylene glycol ethers undergo enzymatic oxidation to toxic alkoxy acids. They may irritate the skin and the eyes. At high oral
doses, they may cause depressed reflexes, flaccid muscle tone, breathing difficulty and coma. Death may result in experimental
animal. However, repeated exposure may cause dose dependent damage to the kidneys as well as reproductive and
developmental defects.
The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to
irritants may produce conjunctivitis.

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ENVIROMATE® 2000

Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-
allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of
highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic
individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the
SODIUM irritant. Other criteria for diagnosis of RADS include a reversible airflow pattern on lung function tests, moderate to severe
TRIPOLYPHOSPHATE bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal lymphocytic inflammation, without
eosinophilia. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related to the concentration of
and duration of exposure to the irritating substance. On the other hand, industrial bronchitis is a disorder that occurs as a result
of exposure due to high concentrations of irritating substance (often particles) and is completely reversible after exposure
ceases. The disorder is characterized by difficulty breathing, cough and mucus production.

NOTE: Oral doses of 8-10g may cause nausea and vomiting, though tolerance in human is 50 g/day. Use in food limited to 0.1%.
[ICI]
The following information refers to contact allergens as a group and may not be specific to this product.
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The
pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic
skin reactions, e.g. contact urticaria, involve antibody-mediated immune reactions. The significance of the contact allergen is not
simply determined by its sensitisation potential: the distribution of the substance and the opportunities for contact with it are
equally important. A weakly sensitising substance which is widely distributed can be a more important allergen than one with
SODIUM BENZOATE stronger sensitising potential with which few individuals come into contact. From a clinical point of view, substances are
noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.
For benzoates:
Benzyl alcohol, benzoic acid and its sodium and potassium salt have a common metabolic and excretion pathway. All but benzyl
alcohol are considered to be unharmful and of low acute toxicity. They may cause slight irritation by oral, dermal or inhalation
exposure except sodium benzoate which doesn't irritate the skin. Studies showed increased mortality, reduced weight gain, liver
and kidney effects at higher doses, also, lesions of the brains, thymus and skeletal muscles may occur with benzyl alcohol.
However, they do not cause cancer, genetic or reproductive toxicity. Developmental toxicity may occur but only at maternal toxic
level.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye
STOT - Single Exposure
Damage/Irritation

Respiratory or Skin
STOT - Repeated Exposure
sensitisation

Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

SECTION 12 Ecological information

Toxicity

Endpoint Test Duration (hr) Species Value Source

ENVIROMATE® 2000 Not Not Not
Not Available Not Available
Available Available Available

Endpoint Test Duration (hr) Species Value Source

EC50 48h Crustacea 0.143mg/l 2

alcohols C12-15 EC50 72h Algae or other aquatic plants 0.031mg/l 2

ethoxylated LC50 96h Fish >=0.423<=8.211mg/l 2

EC50 96h Algae or other aquatic plants 0.7mg/l 4

NOEC(ECx) 72h Algae or other aquatic plants 0.013mg/l 2

Endpoint Test Duration (hr) Species Value Source

EC50 48h Crustacea >70.7<101.3mg/l 2
sodium tripolyphosphate
EC50(ECx) Not Reportedh Algae or other aquatic plants 25-60mg/L 4

EC50 96h Algae or other aquatic plants 69.2mg/l 2

Endpoint Test Duration (hr) Species Value Source

LC50 96h Fish >100mg/l 2

sodium benzoate EC50 48h Crustacea <650mg/l 1

EC50 72h Algae or other aquatic plants >30.5mg/l 2

NOEC(ECx) 72h Algae or other aquatic plants 0.09mg/l 2

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

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ENVIROMATE® 2000

Toxic to aquatic organisms.

Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning
equipment or disposing of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air

No Data available for all ingredients No Data available for all ingredients

Bioaccumulative potential
Ingredient Bioaccumulation

alcohols C12-15 ethoxylated LOW (LogKOW = 3.4)

sodium tripolyphosphate LOW (LogKOW = -7.74)

Mobility in soil
Ingredient Mobility

No Data available for all ingredients

Other adverse effects

No evidence of ozone depleting properties were found in the current literature.

SECTION 13 Disposal considerations

Waste treatment methods

Containers may still present a chemical hazard/ danger when empty.
Return to supplier for reuse/ recycling if possible.
Otherwise:
If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to
store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
Where possible retain label warnings and SDS and observe all notices pertaining to the product.
Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws
operating in their area. In some areas, certain wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
Reduction
Reuse
Recycling
Disposal (if all else fails)
Product / Packaging
This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it
disposal
has been contaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf life
considerations should also be applied in making decisions of this type. Note that properties of a material may change in use, and
recycling or reuse may not always be appropriate.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Where in doubt contact the responsible authority.
Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable
treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or incineration in a
licensed apparatus (after admixture with suitable combustible material).
Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

SECTION 14 Transport information

Labels Required

Marine Pollutant NO

Land transport (DOT): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

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ENVIROMATE® 2000

14.7. Maritime transport in bulk according to IMO instruments

14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable

14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group

alcohols C12-15 ethoxylated Not Available

sodium tripolyphosphate Not Available

sodium benzoate Not Available

14.7.3. Transport in bulk in accordance with the IGC Code

Product name Ship Type
alcohols C12-15 ethoxylated Not Available

sodium tripolyphosphate Not Available

sodium benzoate Not Available

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture

alcohols C12-15 ethoxylated is found on the following regulatory lists

US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory

sodium tripolyphosphate is found on the following regulatory lists

US - Massachusetts - Right To Know Listed Chemicals

US - Pennsylvania - Hazardous Substance List
US DOE Temporary Emergency Exposure Limits (TEELs)
US New York City Community Right-to-Know: List of Hazardous Substances
US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory

sodium benzoate is found on the following regulatory lists

US DOE Temporary Emergency Exposure Limits (TEELs)

US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory

Additional Regulatory Information

Not Applicable

Federal Regulations

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Section 311/312 hazard categories

Flammable (Gases, Aerosols, Liquids, or Solids) No

Gas under pressure No

Explosive No

Self-heating No
Pyrophoric (Liquid or Solid) No

Pyrophoric Gas No

Corrosive to metal No

Oxidizer (Liquid, Solid or Gas) No

Organic Peroxide No
Self-reactive No

In contact with water emits flammable gas No

Combustible Dust No

Carcinogenicity No
Acute toxicity (any route of exposure) No

Reproductive toxicity No

Skin Corrosion or Irritation No

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ENVIROMATE® 2000

Respiratory or Skin Sensitization Yes

Serious eye damage or eye irritation Yes

Specific target organ toxicity (single or repeated exposure) No

Aspiration Hazard No

Germ cell mutagenicity No

Simple Asphyxiant No

Hazards Not Otherwise Classified No

US. EPA CERCLA Hazardous Substances and Reportable Quantities (40 CFR 302.4)
None Reported

US. EPCRA Section 313 Toxic Release Inventory (TRI) (40 CFR 372)
None Reported

Additional Federal Regulatory Information

Not Applicable

State Regulations

US. California Proposition 65

None Reported

Additional State Regulatory Information

Not Applicable

National Inventory Status

National Inventory Status

Australia - AIIC / Australia

Yes
Non-Industrial Use

Canada - DSL Yes

Canada - NDSL No (alcohols C12-15 ethoxylated; sodium tripolyphosphate; sodium benzoate)

China - IECSC Yes

Europe - EINEC / ELINCS /

Yes
NLP
Japan - ENCS Yes

Korea - KECI Yes

New Zealand - NZIoC Yes

Philippines - PICCS Yes

USA - TSCA All chemical substances in this product have been designated as TSCA Inventory ‘Active'

Taiwan - TCSI Yes

Mexico - INSQ Yes

Vietnam - NCI Yes

Russia - FBEPH Yes

Yes = All CAS declared ingredients are on the inventory

Legend: No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require
registration.

SECTION 16 Other information

Revision Date 30/11/2023

Initial Date 22/07/2010

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available
engineering controls must be considered.

Definitions and abbreviations

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ENVIROMATE® 2000

PC TWA: Permissible Concentration-Time Weighted Average

PC STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit
IDLH: Immediately Dangerous to Life or Health Concentrations
ES: Exposure Standard
OSF: Odour Safety Factor
NOAEL: No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index
DNEL: Derived No-Effect Level
PNEC: Predicted no-effect concentration
MARPOL: International Convention for the Prevention of Pollution from Ships
IMSBC: International Maritime Solid Bulk Cargoes Code
IGC: International Gas Carrier Code
IBC: International Bulk Chemical Code

AIIC: Australian Inventory of Industrial Chemicals

DSL: Domestic Substances List
NDSL: Non-Domestic Substances List
IECSC: Inventory of Existing Chemical Substance in China
EINECS: European INventory of Existing Commercial chemical Substances
ELINCS: European List of Notified Chemical Substances
NLP: No-Longer Polymers
ENCS: Existing and New Chemical Substances Inventory
KECI: Korea Existing Chemicals Inventory
NZIoC: New Zealand Inventory of Chemicals
PICCS: Philippine Inventory of Chemicals and Chemical Substances
TSCA: Toxic Substances Control Act
TCSI: Taiwan Chemical Substance Inventory
INSQ: Inventario Nacional de Sustancias Químicas
NCI: National Chemical Inventory
FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances

end of SDS