Zeeman Effect
Zeeman Effect
Principle:
The “Zeeman effect” is the splitting
of the spectral lines of atoms within
a magnetic field. The simplest is the
splitting up of one spectral line into
three components called “normal
Zeeman effect”. Usualy the phe-
nomenon is more complex and the
central line splits into many more
components. This is the “anomalous
Zeeman effect”. Both effects can be
studied using a cadmium lamp as a
specimen. The cadmium lamp is sub-
mitted to different magnetic flux
densities and the splitting of the red
cadmium line (normal Zeeman effect)
and that of a green cadmium line
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5.1.10 Normal and anomalous Zeeman effect
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(80) CDC-Camera
(73) L3 = +50 mm
(68) Screen with scale (only in classical version)
(45) Analyser
(39) L2 = +300 mm
(33) Fabry-Perot Étalon
(25) L1 = +50 mm
(20) Iris diaphragm
(20) Drilled pole-pieces
(0) Cd-spectral lamp on rotating table Fig.1b: Set-up for the classical version of the experiment.
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Initial adjustment: The rotating table is adjusted so that the Remark: For later evaluations the calibration curve of the mag-
centres of the holes in the pole-pieces lie about 28 cm above netic flux density versus the coil current has to be recorded
the table. The optical bench with all elements (except iris previously. This can be done if a teslameter is available.
diaphragm and CCD-camera) mounted, is then moved closer Otherwise the results of Fig. 3 can be used. The curve of Fig. 3
to the electromagnet so that one of the outlet holes of the was recorded by measuring the flux density in the centre of
pole-pieces coincides with the previous position of the iris the gap in the absence of the Cd-lamp. For the evaluations
diaphragm. L1 is then adjusted so that the outlet hole is with- these centre-values were increased by 3.5 % to account for
in its focal plane. All other optical elements of Fig.2. are sub- the non-uniform flux distribution within the gap.
sequently readjusted with respect to their height.
The current of the coils is set to 5 A (increase in light intensity Theory
of the Cd-lamp!) and the ring interference pattern in axial
As early as 1862, Faraday investigated whether the spectrum
direction is observed through L3 by the eye. The splitting of
of coloured flames changes under the influence of a magnet-
the line should be well visible. The pattern must be centered
ic field, but without success. It was not until 1885 that Fievez
and sharp which is eventually achieved by a last, slight move-
from Belgium was able to demonstrate an effect, but it was
ment of the étalon (to the right or to the left) and by displace-
forgotten and only rediscovered 11 years later by the
ment of L2 (vertically and horizontally) and of L3.
Dutchman Zeeman, who studied it together with Lorentz.
Finally the CCD-camera is focussed so that far away things
Here the effect is demonstrated with the light of a Cadmium
are clear and mounted to the optical bench and adjusted in
lamp and the help of a Fabry-Perot interferometer for resolv-
horizontal and vertical position as well as in tilt until a clear
ing a small part of the spectrum preselected by a color filter or
picture of the ring pattern is visible on the computer screen.
an interference filter so only the light of a single atomic transi-
For installation and use of the camera and software please
tion line is observed. Without field the magnetic sub-levels
refer to the manual supplied with the camera.
have the same energy but with field the degeneration of the
In the classical version the screen with scale is shifted in a way
levels with different mJ is cancelled and the line is split.
that the slash representing the „0“ of the scale is clearly seen
Cadmium has the electron structure (Kr) 4d10 5s2, i.e. the outer
coinciding, for instance, with the centre of the fairly bright
shell taking part in optical transitions is composed by the two
inner ring. The scale itself must be able to move horizontally
5s2 electrons that represent a completed electron shell. ((Kr) =
along the diameter of the ring pattern. (Set-up see Fig. 1b.)
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6.) This is similar to the outer
Hint: best results are achieved when the experiment is carried
electron structure of Helium but also of Mercury. A scheme of
out in a darkened room.
the energy levels of Cd is shown in Fig.4. In a completed shell
The electromagnet is now turned by 90° and the iris dia-
in it's ground state the electron spins always compensate
phragm is inserted for transversal observation.
each other – they are anti-parallel. If the total electron spin is
zero, also the magnetic moment connected to electron spin is
zero. Atomic states with zero total spin are called singulett
states. So in transitions between different singulett states the
magnetic moment of spin does not play a role, as is the case
with the normal Zeeman effect. Electric dipole radiation as in
common optical transitions does not change the electron spin
except in heavy atoms with jj-coupling, so transitions are nor-
mally between different states in the same multiplicity system.
But Fig. 4 shows there is some jj-coupling in Cadmium.
The transition used to demonstrate the normal Zeeman effect
is 3 1D2 S 2 1P1 with 643.847 nm and the transition used to
demonstrate the anomalous Zeeman effect is 2 3S1 S 2 3P2
with 508.588 nm.
In a term like 2 3S1 the first number "2" denotes the main
quantum number of the radiating electron with respect to the
atom's ground state (that is counted as "1"), here this is real-
ly the 6th s-shell since 5s2 is the ground state. (This is why the
2 P – states are below the 2 S – states, 2 3P2 denotes the 5th
p-shell since Krypton has 4p6.) The upper "3" denotes the
multiplicity, that is 2s+1 with s here the spin quantum number.
The lower "1" denotes the quantum number j of the total
angular momentum, i.e. j = l+s, l+s-1, … , l-s with l the quan-
tum number of the angular momentum of the orbit. "S", "P",
"D", "F" denote the actual value of l, i.e. "S" means l = 0, "P"
means l = 1, …
3 1D2 S 2 1P1 is a transition within the singulett system so the
spin magnetic moments have no effect. But in the transition
2 3S1 S 2 3P2 triplett states are involved and the spin magnetic
moment does not vanish in all sub-states.
The selection rule for optical transitions is ∆mJ = 0, ±1 and the
radiation belonging to transitions with ∆mJ = 0 are called
Fig. 3: Magnetic flux density B in the centre of gap without the p-lines and the ones with ∆mJ = ±1 are called s-lines. With the
Cd-lamp (gap width: 9 mm) as a function of the coil magnetic field turned on in the absence of the analyser three
current. lines can be seen simultaneously in the normal Zeeman effect
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5.1.10 Normal and anomalous Zeeman effect
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S
e S l
ml
S l gl mB (*)
2me U
eU
mB 9.274 · 10 24 Am2
2me
0 l 0 U 2l 1l 12 , is: ml mB 2l 1l 12
S
0 J 0 0 L S 0 U2J1J 12 with S a S
S S S S
si
So 0 J 0 0 L 0 U2L1L 12 .
S S
Fig. 4: The atomic states of Cadmium, wavelength in
Å = 0.1 nm
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Normal and anomalous Zeeman effect 5.1.10
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m J2J 0 0S
0 1S m L 0 cos 1 L , J 2 0 S
m S 0 cos 1 S , J 2
SS SS
g Jm B 2J1J1
with
J1J12 S1S12 L1L12
g1 1 .
2J1J12
Fig. 6: Energy shift of the atomic states
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and
BC · cos u = t
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2f2
r2p1 r2p (6)
n0
For u fulfilling equation (1) bright rings will appear in the focal where ka and kb are the corresponding wave numbers and
plane with the radius n1,a, n1,b is the interference order of the first ring. Hence, if the
rings do not overlap by a whole order so n1,a = n1,b and the dif-
rn = f tan un ≈ fun (2) ference in wave numbers between the two components is
for small values un, e.g. rays nearly parallel to the optical axis. ea eb
∆k ka kb (7)
Since 2m · t
with r2p1,a
pe (8)
2m · t r2p1 r2p
n0
l
Applying equation (8) to the components a and b, yields
we finally obtain
r2p1,a
u2n p ea
n n0 a1 b r2p1,a r2p,a
2
or
and
21n0 n2 r2p1,b
un (3) p eb
B n0 r2p1,b r2p,b
If un corresponds to a bright fringe, n is an integer. However is By substituting these fractional orders into equation (7), we
n0 the interference condition for the center (for u = 0) general- get for the difference of the wave numbers:
ly not an integer.
If n1 is the interference order of the first ring, it is n1 < n0 since r2p1,a r2p1,b
a 2 b
1
n1 = n0 cos un. We then let ∆k (9)
2m · t rp1,b r2p r2p1,b r2p,b
n1 = n 0 - e ; 0 < e < 1
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From equation (6) we get the difference between the squares must be equal, regardless of p (the order of interference) and
of the radii of component a: their average may be taken as may be done for the different
2f2 ∆-values. With d (the difference of squares of radii of different
∆p1,p
a r2p1,a r2p,a lines of the same order of interference) and ∆ (difference of
n0,a squares of radii of different orders) as average values we get
for the difference of the wave numbers of the components a
this is equal to (within a very small part) the same difference and b:
for component b
1 d
2f2 ∆k · (10)
∆p1,p
b r2p1,b r2p,b 2m · t ∆
n0,b
Hence we assume Note: Equation (10) shows that ∆k does not depend on the
dimensions used in measuring the radii of the ring system.
∆p1,p
a ∆p1,p
b
Fig.10: Normal Zeeman effect: Interference pattern without polarization filter for no coil current and for 5 A coil current. On the
left there is one ring per order of interference, on the right there are three rings per order of interference
Fig.11: Anomalous Zeeman effect: Interference pattern without polarisation filter and magnified cut-out of the first completely
visible two orders of interference
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