Suny Chem International Co.
,Ltd
th
E-F,6 Fl,No.155 Shengli Road,Yantai China
Tel: 86-535-6622355 Fax: 86-535-6228696
www.sunychem.com
MATERIAL SAFETY DATA SHEET
AT-1010
1. Identifications of the substance/product and company
Commodity Name of the Chemical : Antioxidant 1010
Chemical Name in English : Tetrakis [methylene-3- (3,5 -di-tert - butyl -4- hydroxyphenyl- propionate) ] methane
Supplier: Yantai Sunychem International Co.Ltd.
E-F.,6th Fl., No.155,Sheng Li Road, Yantai,
China, 264000
Tel: 86-535-6622355
Fax: 86-535-6228696
2. Product Identity
INGREDIENT NAME CAS NO. %
Tetrakis [methylene-3- (3,5 -di-tert - butyl -4- 6683-19-8 94% min.
hydroxyphenyl-propionate) ] methane
*Indented chemicals are components of previous ingredient.
Additional Information
5 mg/m3 Respirable Dust Level (OSHA)
3 mg/m3 Respirable Dust Level (ACGIH)
PNOR = Particulates Not Otherwise Regulated
PNOC = Particulates Not Otherwise Classified
3. Hazard Information
Emergency Overview: White to off-white powder, granules or pellets
No odor
Not expected to be a hazard in normal industrial use.
Dusts can form an explosive mixture with air.
Relevant Routes of Exposure: Inhalation and ingestion.
Signs and Symptoms of
Overexposure: No known signs and symptoms of exposure.
Medical Conditions Generally
Aggravated By Exposure: None reported
Potential Health Effects: See Section 11 for additional information.
Eyes: Not expected to be a hazard in normal industrial use.
As with any dust, mechanical irritation is possible to the eye.
Skin: Not expected to be a hazard in normal industrial use.
As with any dust, mechanical irritation is possible to the skin.
Ingestion: Not expected to be a hazard in normal industrial use.
Inhalation: As with any dust, mechanical irritation is possible to mucous
membranes and the respiratory tract.
Chronic Health Effects: None known
Carcinogenicity:
NTP: No ACGIH: No IARC: No OTHER: No OSHA: No
1
Suny Chem International Co.,Ltd
th
E-F,6 Fl,No.155 Shengli Road,Yantai China
Tel: 86-535-6622355 Fax: 86-535-6228696
www.sunychem.com
4. First Aide Measures
Eyes: Flush with large volumes of water for at least 15 minutes.
Get medical attention.
Skin: Wash with large volumes of soap and water for at least 15
minutes. If irritation develops, get medical attention.
Ingestion: If conscious, give person 1 to 2 glasses of water. Get
medical attention immediately.
Inhalation: Remove person to fresh air. Get medical attention.
Antidotes: No information available
Notes to Physicians and/or
Protection for First-Aiders: No information available
5. Fire Fighting Measures
Flammable Limits in Air (% by Volume): Not available
Flash Point: 298 degrees C (Closed Cup)
Autoignition Temperature: Not available
Extinguishing Media: All conventional media are suitable.
A strong jet stream of water is not suitable.
Fire Fighting Instructions: Wear a self-contained breathing apparatus and protective
clothing to prevent skin and eye contact in fire situations.
Unusual Fire and Explosion Hazards: Under fire conditions, toxic and irritating fumes may be
emitted. Dusts can form an explosive mixture with air.
Flammability Classification: Combustible dust
Known or Anticipated Hazardous Products of
Combustion: Carbon monoxide and carbon dioxide
6. Accidental Release Measures
Accidental Release Measures: Shut off all sources of ignition.
Wearing appropriate personal protective equipment,
carefully sweep up material and place in suitable labeled
containers for disposal. Avoid creating a dusting condition.
Use only non-sparking tools.
Wash spill area after pick-up is complete, collecting all clean
up water for appropriate disposal.
Personal Precautions: See Section 8.
Environmental Precautions: Avoid releasing to the environment.
7.Handling and Storage
Handling: Use appropriate personal protection equipment.
Avoid eye, skin and clothing contact.
Avoid breathing dust.
Avoid repeated and prolonged contact.
Avoid creating a dusting situation.
Prevent buildup of static electricity.
All equipment should be properly grounded.
2
Suny Chem International Co.,Ltd
th
E-F,6 Fl,No.155 Shengli Road,Yantai China
Tel: 86-535-6622355 Fax: 86-535-6228696
www.sunychem.com
Storage: Store in a cool, dry, well-ventilated area away from
incompatible materials.
Keep container tightly closed.
Store away from heat, sparks, and flame.
Protect containers against damage.
Keep material in supplier's packaging.
Other Precautions: Avoid contact of material with open flames.
8. Exposure controls/Personal protection
Engineering Controls: Adequate general ventilation is recommended when
handling to control airborne levels.
Ventilation Requirements: Use local exhaust to minimize dusting.
Use mechanical ventilation for general area control.
Personal Protective Equipment: Chemical safety glasses with side shields or
Eye/Face Protection: chemical safety goggles
Skin Protection: Gloves - PVC
Do not wear textile or leather gloves.
Clothing designed to minimize skin contact
Respiratory Protection: Wear a NIOSH/MSHA approved dust respirator if dusting
occurs, or there is potential for airborne exposures to
exceed established threshold values.
Consult the OSHA respiratory protection information located
at 29CFR 1910.134 and the American National Standard
Institute's Practices of Respiratory Protection Z88.2.
Other Protective
Clothing or Equipment: No information available
Exposure Guidelines: See Section 2.
Work Hygienic Practices: Wash thoroughly after handling.
Wash contaminated clothing before reuse.
Do not eat, drink, chew gum, use tobacco products, or apply
cosmetics in work areas.
9. Physical and Chemical Properties
Appearance: White to off-white powder, granules or pellets Percent Volatile: Not available
Boiling Point: 1130.3 degrees C (calculated) pH Value: Not available
Bulk Density: Not available pH Concentration: Not available
Color: White to off-white Physical State: Solid
Decomposition Temperature: Not available Reactivity in Water: Not water reactive
Evaporation Rate: Not available Saturated Vapor Concentration: Not available
Freezing Point: Not available Softening Point: Not available
Heat Value: Not available Solubility in Water: Insoluble
Melting Point: 110-125 degrees C Specific Gravity or Density (Water=1):
1.15 (d 20/4)
Molecular/Chemical Formula: C73H108O12 Vapor Density: Not available
Molecular Weight: 1176.5 Vapor Pressure: 1 x 10(-12) at 20 degrees C
3
Suny Chem International Co.,Ltd
th
E-F,6 Fl,No.155 Shengli Road,Yantai China
Tel: 86-535-6622355 Fax: 86-535-6228696
www.sunychem.com
Octanol/Water Partition Coefficient: Log Pow = 23 Viscosity: Not available
Odor: No odor Volatile Organic Compounds: Not available
Odor Threshold: Not available Water/Oil Distribution Coefficient: Not available
Particle Size: Not available Weight Per Gallon: Not available
Additional Information
Minimum Ignition Energy: Between 1 mJ and 3 mJ
Minimum Ignition Temperature: 420 degrees C
10. Stability and Reactivity
Stability: Stable under normal conditions of handling and use.
Conditions to Avoid: Ignition sources and dusting
Incompatibility With Other Materials: Strong oxidizers
Hazardous Decomposition Products: Thermal decomposition may produce the following:
Carbon monoxide and carbon dioxide
Hazardous Polymerization: Will not occur
Conditions to Avoid: None
11. Toxicological information
VALUE (LD50 OR LC50) ANIMAL ROUTES COMPONENTS
>46 mg/L/1H Rat Acute Inhalation Tetrakis(methylene(3,5-di-tertbutyl-
4-hydroxyhydrocinnamate))methane
>3,160 mg/kg Rabbit Acute Dermal Tetrakis(methylene(3,5-di-tertbutyl-
4-hydroxyhydrocinnamate))methane
>5,000 mg/kg Rat Acute Oral Tetrakis(methylene(3,5-di-tertbutyl-
4-hydroxyhydrocinnamate))methane
Toxicological Information:
Tetrakis(methylene(3,5-di-tert-butyl-4-hydroxy-hydrocinnamate))methane: This material has been
determined not to be a primary eye or skin irritant in rabbits. Negative results were found in a sensitization
study in guinea pigs. Negative mutagenicity results were obtained in an Ames test, a dominant lethal assay,
a somatic mutation assay, and a reverse mutation assay.
In a 13 week repeated dose study in beagle dogs at doses of 1,000, 3,000, and 10,000 ppm, no adverse effects
could be related to treatment.
In a two generation reproductive study at doses of 1,000, 3,000 and 10,000 ppm, no reproductive effects were
seen.
Teratogenicity studies in rats and mice have shown negative results.
12. Ecological Information
Ecological Information: EC50 in Daphnia magna (24 hour) >86 mg/L
LC50 in Zebra fish (96 hour) >100 mg/L
LC50 in Salmo gairdneri (96 hour) = 49 mg/L
EC50 in Algae (72H) >100 mg/L
EC50 in Escherichia coli (3H) >100 mg/L
A photodegradation half-life has been estimated at 1.2 hours.
4
Suny Chem International Co.,Ltd
th
E-F,6 Fl,No.155 Shengli Road,Yantai China
Tel: 86-535-6622355 Fax: 86-535-6228696
www.sunychem.com
Partially biodegradable
Avoid releasing to the environment.
13. Disposal Consideration
Disposal Considerations: Dispose of waste at an approved chemical disposal facility in
compliance with all current Local, State/Province,
Federal/Canadian laws and regulations.
14. Transport Information
ADR/RID Class: Free
IMO Class: Free
ICAO Class: Free
15. Regulatory Information
U.S. Federal Regulations:
The components of this product are either on the TSCA Inventory or exempt (i.e. impurities, a polymer
complying with the exemption rule at 40 CFR 723.250) from the Inventory.
State Regulations:
No information available
International Regulations:
This material (or each component) is listed on the following inventories:
Canada - DSL
EU - EINECS
Australia - AICS
Japan - ENCS
Korea - ECL
Philippines - PICCS
China - List I
Canadian WHMIS Hazard Class and Division = Not controlled
SARA Hazards:
Acute: No Chronic: No
Reactive: No Fire: No
Pressure: No
Additional Information
The above regulatory information represents only selected regulations and is not meant to be a complete list.
16. Other Information
NFPA Codes:
Health: 0 Flammability: 1
Reactivity: 0 Other: 0
HMIS Codes: * indicates chronic health hazard.
Health: 0 Flammability: 1
Reactivity: 0 Protection: X
Label Statements: Not available
Other Information: Abbreviations:
(L) = Loose bulk density in g/ml
LOEC = Lowest observed effect concentration
MATC = Maximum acceptable toxicant concentration
NA = Not available
N/A = Not applicable
NL = Not limited
5
Suny Chem International Co.,Ltd
th
E-F,6 Fl,No.155 Shengli Road,Yantai China
Tel: 86-535-6622355 Fax: 86-535-6228696
www.sunychem.com
NOAEL = No observable adverse effect level
NOEC = No observed effect concentration
NOEL = No observable effect level
NR = Not rated
(P) = Packed bulk density in g/ml
PNOC = Particulates Not Otherwise Classified
PNOR = Particulates Not Otherwise Regulated
REL = Recommended exposure limit
TS = Trade secret
Additional Information
Information on this form is furnished solely for the purpose of compliance with OSHA's Hazard
Communication Standard, 29CFR 1910.1200 and The Canadian Environmental Protection Act, Canada
Gazette Part II, Vol. 122, No. 2 and shall not be used for any other purpose.
Revision Information:
General review and update
Section 9 - Physical properties
Section 11 - Toxicological information
Section 12 - Ecological Information
Declaration
This information only concerns the above mentioned product and does not need to be valid if used with
other product(s) or any process. The information is to our best present knowledge correct and complete
and is given in good faith but without warranty. It remains the user’s own responsibility to make sure that the
information is appropriate and complete.
