PT PUPUK SRIWIDJAJA PALEMBANG
SAFETY DATA SHEET DEPARTEMEN
4 SMK3 046 K3 & LH
No. Dokumen Terkait : 3 SMK3 006
UREA
1. Product Identification
Product Name : Urea
CAS Number : 57-13-6
Product Use : Fertilizer, agricultural and Industrial Uses
Manufacturer : PT Pupuk Sriwidjaja Palembang
Adress : Jl. Mayor Zen, Palembang 30118
Emergency Number : Phone : (0711) 712 222 / 712 111 ext. 45 / 7945
Email : k3@pusri.co.id
Date of issue / revision : May 29, 2020
Date of previous issue : November 11, 2019
2. Hazard Identification
GHS Classification : Hazardous incase of skin contact, eye contact, ingestion and
ihalation - irritant
Hazard Pictograms :
Signal Word : Warning.
Hazard Statements : Irritant
3. Composition
Ingredient Name % CAS Number
Urea 99.54 57-13-6
Imidodicarbonic diamide (biuret) 0.46 108-19-0
Analysis Result
No. Parameter Method Unit Result
1. Total Nitrogen SNI 02-2801:2010 %wt 46.44
2. Biuret SNI 02-2801:2010 %wt 0.46
3. Moisture SNI 02-2801:2010 %wt 0.40
4. Free Ammonia DL-Pusri-041.01 ppm 91.68
5. Iron DL-Pusri-051.01 ppm 0.36
6. Crushing strength DL-Pusri-030.01 kg/cm2 14.85
7. Oil content DL-Pusri-069.02 ppm 30.49
8. Size distribution
(US std. sieve) + No. 6 SNI 02-2801:2010 %wt 0.63
No. -6 + 18 SNI 02-2801:2010 %wt 99.18
No. -18 + 25 SNI 02-2801:2010 %wt 0.17
Pan SNI 02-2801:2010 %wt 0.02
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PT PUPUK SRIWIDJAJA PALEMBANG
SAFETY DATA SHEET DEPARTEMEN
4 SMK3 046 K3 & LH
No. Dokumen Terkait : 3 SMK3 006
4. First Aid Measures
Eye Contact : Check for and remove any contact lenses. Flush eyes with
plenty of water at least 15 minutes. Seek medical attention
immediately.
Ingestion : Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, wristband
or belt.Get medical attention if symptoms appear.
Inhalation : Remove person to fresh air. If not breathing, administer
artificial respiration. If breathing is difficult, administer
oxygen. Obtain prompt medical attention.
Skin Contact : Flush affected area with plenty of water at list 15 minutes.
Cover the irritated skin with an emollient. Remove
contaminated clothing and shoes. Seek medical attention
immediately.
5. Fire Fighting Measures
Potential of fire : This product is non-flammable.
Extinguishing Media : Material will not burn. Undergoes thermal decomposition at
elevated temperatures to produce solid cyanuric acid and
release toxic and combustible gases (ammonia carbon
dioxide, and oxides of nitrogen). If fumes or gases are
present, fire fighters should wear self contained breathing
apparatus. Use extinguishing media suitable for surrounding.
Special Remarks on Fire : Flammable / toxic gases will form at elevated temperatures
Hazard by thermal decomposition. When exposed to heat,
ammonia is released.
Unsual Fire and Explosion : May be explosive on contact halogens such as chlorine.
Hazards Non-explosive from open flame and sparks, shocks, heat,
oxidizing materials, combustible materials, organic
materials, metals, acids, alkalis, or moisture.
Special Remarks on Explosion : May be explosive when mixed with hypochlorites due to
Hazard the formation of nitrogen triclhoride which explode
spontaneously in air.
Hazardous Combustion : Undergoes thermal decomposition at elevated temperatures
Products to produce solid cyanuric acid and release toxic and
combustible gases (ammonia carbon dioxide, and oxides of
nitrogen).
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PT PUPUK SRIWIDJAJA PALEMBANG
SAFETY DATA SHEET DEPARTEMEN
4 SMK3 046 K3 & LH
No. Dokumen Terkait : 3 SMK3 006
6. Accidental Release Measures
Steps to be taken if material : Use appropriate tools to put the spilled solid in a suitable
is released or spilled container for intended use or disposal. Prevent additional
discharge of material, if possible to do so without hazard.
Prevent spills from entering sewers, watercourses, wells,
etc. product will promote algae growth which may
degrade water quality and taste. Notify downstream water
users. Recover and place material in suitable container for
reuse, recycle or disposal.
7. Handling & Storage
Precaution : If user operations generate dust, fume, or mist, use
ventilation to keep exposure to airborne contaminants below
the exposure limit. Keep out of reach of children.
Storage : Store in dry, cool and well ventilated area. Keep away from
incompatible materials such as reducing agents. Do not blend
or store in contact with ammonium nitrate.
8. Exposure and Personal Protective Equipment
Engineering Control : Use process enclosures, local exhaust ventilation, or other
engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate
dust, fume, or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit. Keep out of
reach of children.
Personal Protection : The selection of personal protective equipment varies,
depending upon conditions of use. Under well controlled
conditions where contact with the substance is limited
and exposures are below the occupational exposure limit,
normal work clothing may suffice. Where skin and eye contact
may occur as a result of brief periodic exposures, wear long
sleeved clothing or coveralls and safety glasses with side
shields.
Wear appropriate respirator when ventilation is inadequate. A
filtering facepiece dust mask is adequate for most
applications. A NIOSH approved full facepiece or half
mask dust respirator with N-100 or P-100 filters should
be used under conditions where airborne concentrations
may exceed occupational exposure limits. For U.S
facilities, a respiratory protection program that meets
OSHA 29 CFR 1910.134 requirements must be followed
whenever workplace conditions warrant a respirator's use.
Exposure Limits : AIHA Workplace Environmental Exposure Limits: 10
mg/m3 TWA for Urea as inhalable dust. OSHA PEL: 15 mg/m3
for Particulates Not Otherwise Regulated.
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PT PUPUK SRIWIDJAJA PALEMBANG
SAFETY DATA SHEET DEPARTEMEN
4 SMK3 046 K3 & LH
No. Dokumen Terkait : 3 SMK3 006
9. Physical & Chemical Properties
Appearance, odor : White, odorless to slightly ammoniacal.
State : Granular solid.
Molecular weight : 60.06
Boiling point : Decomposes at 135 ℃ (at 1 atm)
Melting point : 132 ℃ (at 1 atm)
Specific gravity : 0.74 g/ml (at -33.4 ℃)
Vapor pressure : 0.08 kPa
Bulk Density : Loose : 721 – 770 kg/m3 ; 45 - 48 lbs/ft3
Tapped : 800-809 kg/m3 ; 49 – 51 lbs/ft3
Solubility : easily soluble in hot water. Soluble in cold water. Partially
soluble in methanol, diethyl.
pH (10% Soln/Water) : 8
10. Stability & Reactivity
Chemical stability : Stable
Materials to avoid : Halogens, oxidizing agents, reducing agents, acids, alkalis,
moisture.
Special Remarks on : Absorb moisture from the air. Hygroscopic; keep container
Reactivity tightly closed.
Special Remarks on : Avoid contact with moisture. Slow hydrolysis may produce
Corrosivity acids corrosive to metals.
11. Toxicological Information
Significant Routes Of : Ingestion, inhalation.
Exposure
Toxicity to Animals : See Section II. Under controlled feeding conditions, urea is
used as a nutritional supplement in cattle and other animals.
The toxic dose in cattle given urea for the first time is
considered to be 0.45 g/kg or a total of 100-200 g. Mature
bulls can digest as much as 400 g a day without ill effect. As
little as 50 g may cause adverse effects in cattle not
accustomed to it.
12. Ecological Information
Ecotoxicity : Will slowly release ammonia and degrade to nitrate.
Ammonia is a toxic hazard to fish. However, ammonia
release is slow making urea much less toxic than ammonium
salts. Aquatic toxicity tests indicate 24 Hr exposure at 16,000
mg/L of urea did not kill Creek Chubs. Urea is added in
small quantities as a feed suppliment for cattle. Urea
ingestion may be harmful to mammals and birds at body
burdens of several thousands of mg/kg. Ensure that
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PT PUPUK SRIWIDJAJA PALEMBANG
SAFETY DATA SHEET DEPARTEMEN
4 SMK3 046 K3 & LH
No. Dokumen Terkait : 3 SMK3 006
livestock and wildlife do not ingest urea unless
adequately mixed with feed rations. Nonpersistent. Non-
cumulative when applied using normal agricultural practises.
The product itself and its products of degradation are not
harmful under normal conditions of careful and responsible
use. U.S. D.O.T.: This material is NOT listed as a Marine
pollutant.
BOD & COD : Not Available
Product of Degradation : Ammonia, carbon dioxide and water.
13. Disposal Consideration
Waste Disposal Or Recycling : Recover and place material in a suitable container for
intended use or disposal. Ensure disposal complies with
government requirements and local regulations.
14. Transport Information
DOT / TDG Classification : Not controlled under DOT (US) or TDG (Canada)
PIN and Shipping Name : Not applicable
Special Provisions For Transport : Not applicable
Non-Hazardous Material under RID / ADR, GGVS / GGVE, ADNR, IMDG, ICAO – TI / IATA –
DCR DGR
15. Regulatory Information
Other Regulations : The Domestic Substances List (DSL) and acceptable for use under the
provisions of CEPA. EINECS: This product is on the European Inventory of Existing Commercial
Chemical Substances. CERCLA/SUPERFUND, 40 CFR 117,302: This product contains no Reportable
Quantity (RQ) Substances. This product is not considered as a priority pollutant as regulated
under the Clean Water Act. TSCA (Toxic Substance Control Act): This product and all its
components are listed on the TSCA Inventory. CALIFORNIA PROPOSITION 65: This product contains
no chemicals known to the State of California to cause cancer, birth defects, or other reproductive
harm.This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and is not subject to control under WHMIS (Canada), or the Hazcom
Standard (US).
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PT PUPUK SRIWIDJAJA PALEMBANG
SAFETY DATA SHEET DEPARTEMEN
4 SMK3 046 K3 & LH
No. Dokumen Terkait : 3 SMK3 006
16. Other Information
Issued by : HSE Department
PT Pupuk Sriwidjaja Palembang
Telp. (+62711) 712 222 / 712 111 ext. 7952 / 7953
Notice to : To the best of our knowledge, the information contained herein is accurate.
consumer However, neither the above-named supplier, nor any of its subsidiaries, assumes
any liability whatsoever for the accuracy or completeness of the information
contained herein. Final determination of suitability of any material is the sole
responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
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