2019 Chem 2
2019 Chem 2
CHEMISTRY
8462/2H
Paper 2 Higher Tier
Mark scheme
June 2019
Version: 1.0 Final
*196G8462/2H/MS*
                                                         MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Mark schemes are prepared by the Lead Assessment Writer and considered, together with the relevant
questions, by a panel of subject teachers. This mark scheme includes any amendments made at the
standardisation events which all associates participate in and is the scheme which was used by them in
this examination. The standardisation process ensures that the mark scheme covers the students’
responses to questions and that every associate understands and applies it in the same correct way.
As preparation for standardisation each associate analyses a number of students’ scripts. Alternative
answers not already covered by the mark scheme are discussed and legislated for. If, after the
standardisation process, associates encounter unusual answers which have not been raised they are
required to refer these to the Lead Examiner.
It must be stressed that a mark scheme is a working document, in many cases further developed and
expanded on the basis of students’ reactions to a particular paper. Assumptions about future mark
schemes on the basis of one year’s document should be avoided; whilst the guiding principles of
assessment remain constant, details will change, depending on the content of a particular examination
paper.
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                                            MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Before you apply the mark scheme to a student’s answer read through the answer and annotate it (as
instructed) to show the qualities that are being looked for. You can then apply the mark scheme.
When assigning a level you should look at the overall quality of the answer and not look to pick holes in
small and specific parts of the answer where the student has not performed quite as well as the rest. If
the answer covers different aspects of different levels of the mark scheme you should use a best fit
approach for defining the level and then use the variability of the response to help decide the mark within
the level, ie if the response is predominantly level 3 with a small amount of level 4 material it would be
placed in level 3 but be awarded a mark near the top of the level because of the level 4 content.
You may well need to read back through the answer as you apply the mark scheme to clarify points and
assure yourself that the level and the mark are appropriate.
Indicative content in the mark scheme is provided as a guide for examiners. It is not intended to be
exhaustive and you must credit other valid points. Students do not have to cover all of the points
mentioned in the Indicative content to reach the highest level of the mark scheme.
An answer which contains nothing of relevance to the question must be awarded no marks.
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                                         MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Information to Examiners
1. General
The extra information is aligned to the appropriate answer in the left-hand part of the mark scheme and
should only be applied to that item in the mark scheme.
At the beginning of a part of a question a reminder may be given, for example: where consequential
marking needs to be considered in a calculation; or the answer may be on the diagram or at a different
place on the script.
In general the right-hand side of the mark scheme is there to provide those extra details which confuse
the main part of the mark scheme yet may be helpful in ensuring that marking is straightforward and
consistent.
2.2 A bold and is used to indicate that both parts of the answer are required to award the mark.
2.3   Alternative answers acceptable for a mark are indicated by the use of or. Different terms in the
      mark scheme are shown by a / ; eg allow smooth / free movement.
2.4 Any wording that is underlined is essential for the marking point to be awarded.
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                                            MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
3. Marking points
3.1   Marking of lists
      This applies to questions requiring a set number of responses, but for which students have
      provided extra responses. The general principle to be followed in such a situation is that ‘right +
      wrong = wrong’.
      Each error / contradiction negates each correct response. So, if the number of error /
      contradictions equals or exceeds the number of marks available for the question, no marks can be
      awarded.
      If a student writes a chemical symbol / formula instead of a required chemical name, full credit can
      be given if the symbol / formula is correct and if, in the context of the question, such action is
      appropriate.
      Marks should be awarded for each stage of the calculation completed correctly, as students are
      instructed to show their working. Full marks can, however, be given for a correct numerical
      answer, without any working shown.
      Answers using the word ‘it’ should be given credit only if it is clear that the ‘it’ refers to the correct
      subject.
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                                             MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Any error in the answers to a structured question should be penalised once only.
       Papers should be constructed in such a way that the number of times errors can be carried forward
       is kept to a minimum. Allowances for errors carried forward are most likely to be restricted to
       calculation questions and should be shown by the abbreviation ecf in the marking scheme.
       The phonetic spelling of correct scientific terminology should be credited unless there is a possible
       confusion with another technical term.
3.7 Brackets
       (…..) are used to indicate information which is not essential for the mark to be awarded but is
       included to help the examiner identify the sense of the answer required.
3.8 Allow
3.9 Ignore
       Ignore is used when the information given is irrelevant to the question or not enough to gain the
       marking point. Any further correct amplification could gain the marking point.
       Do not accept means that this is a wrong answer which, even if the correct answer is given as
       well, will still mean that the mark is not awarded.
      Before you apply the mark scheme to a student’s answer, read through the answer and annotate it
      (as instructed) to show the qualities that are being looked for. You can then apply the mark scheme.
      Start at the lowest level of the mark scheme and use it as a ladder to see whether the answer meets
      the descriptor for that level. The descriptor for the level indicates the different qualities that might be
      seen in the student’s answer for that level. If it meets the lowest level then go to the next one and
      decide if it meets this level, and so on, until you have a match between the level descriptor and the
      answer.
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                                      MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
When assigning a level you should look at the overall quality of the answer. Do not look to penalise
small and specific parts of the answer where the student has not performed quite as well as the rest.
If the answer covers different aspects of different levels of the mark scheme you should use a best
fit approach for defining the level.
Use the variability of the response to help decide the mark within the level, ie if the response is
predominantly level 2 with a small amount of level 3 material it would be placed in level 2 but be
awarded a mark near the top of the level because of the level 3 content.
Once you have assigned a level you need to decide on the mark. The descriptors on how to
allocate marks can help with this.
The exemplar materials used during standardisation will help. There will be an answer in the
standardising materials which will correspond with each level of the mark scheme. This answer will
have been awarded a mark by the Lead Examiner. You can compare the student’s answer with the
example to determine if it is the same standard, better or worse than the example. You can then
use this to allocate a mark for the answer based on the Lead Examiner’s mark on the example.
You may well need to read back through the answer as you apply the mark scheme to clarify points
and assure yourself that the level and the mark are appropriate.
Indicative content in the mark scheme is provided as a guide for examiners. It is not intended to be
exhaustive and you must credit other valid points. Students do not have to cover all of the points
mentioned in the indicative content to reach the highest level of the mark scheme.
You should ignore any irrelevant points made. However, full marks can be awarded only if there are
no incorrect statements that contradict a correct response.
An answer which contains nothing of relevance to the question must be awarded no marks.
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                                               MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Question 1
                                                                                                  AO /
    Question               Answers                         Extra information             Mark
                                                                                                Spec. Ref.
                                                    ignore references to
                                                    intermolecular forces or chain
                                                    length
                                                    allow temperature of
                                                    vaporisation / condensation for
    01.2
                                                    boiling points throughout
               (diesel oil has a) lower boiling                                           1
               point / range than heavy fuel oil
               C6H14                                                                      1       AO2
    01.4
                                                                                                 4.7.1.1
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                                  MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
ignore plastics
        C3H6                                                              1     AO2
01.7                                                                           4.1.1.1
                                                                               4.7.1.4
Total 11
                                                                                         9
                                          MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Question 2
                                                                                                AO/
 Question                                  Answers                                     Mark
                                                                                              Spec. Ref
                                                                                                AO1
             Level 3: The design/plan would lead to the production of a valid                  4.8.2.3
 02.1                                                                                  5–6
             outcome. All key steps are identified and logically sequenced.                    4.8.3.1
                                                                                               4.8.3.3
No relevant content 0
Indicative content
             lithium:
             • crush tablets or dissolve tablet (in water or acid)
             • clean wire
             • place on wire
             • place in (roaring / blue / non-luminous) flame
             • observe flame colour
             • crimson flame
             carbonate:
             • add hydrochloric acid
             • effervescence / fizzing
             • bubble gas through limewater
             • limewater becomes cloudy
                                                                                                AO1
 02.2        formulation(s)                                                             1
                                                                                               4.8.1.2
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                                          MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
        1.20 g = 1200 mg                                                           1
        or
        700 mg = 0.700 g
02.3
Total 10
                                                                                                  11
                                            MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Question 3
                                                                                               AO /
 Question                  Answers                      Extra information             Mark
                                                                                             Spec. Ref.
Total 11
12
                                            MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Question 4
                                                                                            AO /
Question                 Answers                         Extra information         Mark
                                                                                          Spec. Ref.
             Tube 2: (nail) does not rust         allow Tube 2: (nail) does not     1       AO1
             because no water                     rust because only air / oxygen
             Tube 3: (nail) does not rust         allow Tube 3: (nail) does not     1       AO1
             because no air / oxygen              rust because only water
             Tube 4: (nail) does not rust         allow Tube 4: (nail) does not     1       AO1
             because paint is a barrier (to       rust because paint is a
             water / air / oxygen)                protective layer / coating
                                                  (against water / air / oxygen)
                                                  or                                        AO2
04.1
                                                  allow Tube 4: (nail) does not            4.10.3.1
                                                  rust because paint protects it           4.10.3.2
                                                  from water / air / oxygen
                                                                                    1
             Tube 5: (nail) does not rust         allow Tube 5: (nail) does not
             because stainless steel resistant    rust because stainless steel
             to corrosion                         does not corrode
                                                  allow Tube 5: (nail) does not
                                                  rust because stainless steel
                                                  contains nickel / chromium
                                                                                                      13
                                     MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Total 9
14
                                          MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Question 5
                                                                                               AO /
Question                  Answers                      Extra information              Mark
                                                                                             Spec. Ref.
                                                                                                         15
                                            MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
         (oxygen needed =
                             3.60 × 5
                                        )        allow correct calculation using
                                3                an incorrectly determined mole
         = 6.0 (dm3)                             ratio                              1
Total 9
16
                                         MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Question 6
                                                                                         AO /
Question                Answers                      Extra information          Mark
                                                                                       Spec. Ref.
06.1
                                              an answer of
scores 2 marks
                                                                                                   17
                                         MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
                                                                                         AO3
                          hydrocarbon                                                  4.10.3.3
monomer
           polyester       polypeptide                                            1
                          reinforcement
                                              allow for 1 mark:
 06.5
                                                                  hydrocarbon
monomer
polyester polypeptide
reinforcement
• waterproof
Total 10
18
                                          MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Question 7
                                                                                              AO /
Question                 Answers                         Extra information           Mark
                                                                                            Spec. Ref.
No relevant content 0
Indicative content
Total 9
                                                                                                        19
                                              MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Question 8
                                                                                               AO /
 Question                Answers                          Extra information           Mark
                                                                                             Spec. Ref.
                                                                                               AO3
             (Titan has) little / no oxygen        ignore references to respiration    1      4.9.1.3
             (which is) re-emitted from the        allow (which is) re-emitted from    1
             surface as long(er) wavelength        the surface as ir / infra-red
             radiation                             radiation
 08.2
             (which is) absorbed (by               allow (which is) trapped (by        1
             methane in the atmosphere)            methane in the atmosphere)
ignore clear
Total 8
20
                                            MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Question 9
                                                                                               AO /
Question                 Answers                         Extra information            Mark
                                                                                             Spec. Ref.
09.1
             (which) relights                     dependent on correct test in         1
                                                  MP1
                                                  ignore with a pop
09.3
             11 (cm3) and 120 (seconds)                                                1
                                                                                                        21
                                          MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
                                                                                        AO2
                                                                                       4.6.1.2
         (because) surface area (of fine       allow converse for coarse lumps    1    4.6.1.3
         manganese dioxide powder)
         greater
 09.5
         (so) more collisions (with            do not accept references to        1
         hydrogen peroxide molecules /         changes in kinetic energy or
         particles) per unit time              speed (of molecules / particles)
                                               ignore references to activation
                                               energy.
Total 11
22
                                           MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Question 10
                                                                                              AO /
Question                   Answers                      Extra information            Mark
                                                                                            Spec. Ref.
                                                                                                       23
                                    MARK SCHEME – GCSE CHEMISTRY – 8462/2H – JUNE 2019
Total 12
24