Process Safety LL
Process Safety LL
Process Safety-II
CONTENT
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The areas outside those classified as hazardous are referred to as "safe areas".
The MSDS is a detail information bulletin prepared by the manufacturer or importer of a chemical that
describe the physical and chemical properties, physical health hazard, routes of exposure, precaution for
safe handling and use, emergency and first-aid procedures, and control measures.
Employer must have an MSDS for each hazardous chemical, which they use.
In order to have a successful program, it will be necessary to assign responsibility for both the initial and
ongoing activities that have to be undertaken.
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The list will eventually serve as an inventory of everything for which an MSDS must be maintained.
Once you have complied as complete a list as possible of the potential hazardous chemicals in the work
place, the next step is to determine if you have received material safety datasheet for all of them.
The written program must be describe how the requirements for levels and other forms of warning,
material safety data sheet, and employee information and training , are going to be met in your facility.
In plant containers of hazardous chemical must be leveled, tagged, or marked with the identity of the
material and appropriate hazard warning. Chemical manufacturers, importer, and distributor are required
to ensure that every container of hazard chemicals they ship is appropriate labeled with such information
and with the name and address of the producer or other responsible party.
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The effect of chemical substances on the body depends not only on the individual chemical but
also on the dose and susceptibility of the individual.
In general no chemical can be considered non toxic; there are only differences in degree or effect.
Absence of any immediate effect is not an indication that a substance is harmless. Precaution
measure should be taken therefore and protective equipment supplied where chemicals can effect
persons.
By which routes will the contaminant gain entry to the human body?
Toxic effects:
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Most substances have a safe level of exposure below, which there are no significant
adverse effects. This level is the Threshold Limit Value (TLV)
The best protection is not to have any hazardous substances or if possible substitute it for something not
hazardous. Unfortunately this can not be always achieved.
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Flammable Liquids
Flammable liquid means any liquid having a flashpoint below 100 deg. F. (37.8 deg. C.), except any
mixture having components with flashpoints of 100 deg. F. (37.8 deg. C.) or higher, the total of which make
up 99 percent or more of the total volume of the mixture.
Flammable liquids shall be known as Class I ,II,III liquids. Class I liquids are divided into three classes
as follows:
• Class IA shall include liquids having flashpoints below 73 deg. F. (22.8 deg. C.) and having a boiling
point below 100 deg. F. (37.8 deg. C.).
• Class IB shall include liquids having flashpoints below 73 deg. F. (22.8 deg. C.) and having a boiling
point at or above 100 deg. F. (37.8 deg. C.).
• Class IC shall include liquids having flashpoints at or above 73 deg. F. (22.8 deg. C.) and below 100 deg.
F. (37.8 deg. C.).
Class II Liquids
• Class II liquids shall include those with flashpoints at or above 100 deg. F. (37.8 deg. C.) and below 140
deg. F. (60 deg. C)
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Class III liquids shall include those with flashpoints at or above 140 deg. F. (60 deg. C.) Class III liquids are
subdivided into two subclasses:
Class IIIA liquids shall include those with flashpoints at or above 140 deg. F. (60 deg. C.) and below 200
deg. F. (93.3 deg. C)
Class IIIB liquids shall include those with flashpoints at or above 200 deg. F. (93.3 deg. C)
Flammable limits apply generally to vapors and are defined as the concentration range in
which a flammable substance can produce a fire or explosion when an ignition source
(such as a spark or open flame) is present. The concentration is generally expressed as
percent fuel by volume.
• UEL/UFL
Above the upper flammable limit (UFL) the mixture of substance and air is too
rich in fuel (deficient in oxygen) to burn. This is sometimes called the upper
explosive limit (UEL).
• LEL
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Hazard Communication
Most of the chemicals produced, handled in OQ plants are hazardous in nature such as flammable, toxic,
irritant, corrosive etc. Therefore it is essential for all employees and contractors to be aware of the hazards and
risk of those chemicals.
OQ ensures that hazards of all chemicals are properly identified and information concerning those hazards
is transmitted to all employees and contractors handling them. The classification used in OQ is consistent
with United Nations Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
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Hydrogen Sulfide (H S) 2
Extremely toxic and extremely flammable gas (flammable range: 4.3–46%). It can be fatal
at higher concentrations. Being heavier than air it tends to accumulate at the bottom of poorly
ventilated spaces, in lower concentrations it has a distinct smell of rotten eggs which
disappear rapidly at dangerous concentrations above 50 ppm which can kill sense of smell, so
victims may be unaware of its presence until it is too late.
Prevention
Keep away from heat, spark and flame. Do not breath gas.
Response
If inhaled, remove person to fresh air. Leaking gas fire: do not extinguish unless leak can be stopped
safely.
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One of the refinery products and present in several process streams, used as fuel in heating appliances,
cooking equipment and vehicles. Extremely flammable gas (flammable range:
2.2 – 9.5%). Highly volatile, vapors are heavier than air.
Prevention
Keep away from heat, spark and flame. Do not breath gas
Response
If inhaled, remove person to fresh air. Leaking gas fire: do not extinguish unless
leak can be stopped safely.
Naphtha
Produced by the process units as a petroleum distillate and used in the plant as raw material to produce
motor gasoline. Highly flammable liquid (flammable range: 1.1 –5.9%). vapors are heavier than air.
If released may spread around the ground, accumulate in low points and may form flammable and
asphyxiate atmosphere in confined spaces. It may contain toxic substances like H2S & Benzene. It is
irritant to the skin and flow causes static charges.
Prevention
Keep away from heat, spark and flame. Do not breath gas
Response
If inhaled, remove person to fresh air
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Benzene
A natural part of crude oil and produced by the Aromatic process units as a product. Benzene is a
colorless and highly flammable liquid (1.2– 7.8% )with a sweet smell, and is responsible for the aroma
smelt around petrol stations. It Increases risk of illnesses, as per OSHA, the maximum allowed
amount of benzene during an 8-hour workday, 40- hour work week is 1ppm. Avoid high temperatures,
open flames, sparks, welding, smoking and other ignition sources. Flow cause static charge.
Prevention
Keep away from heat, spark and flame. Do not breath gas
Response
If inhaled, remove person to fresh air
Sulfur
Produced as elemental sulfur one of the refinery byproducts as a result of removing sulfur-containing
contaminants from crude oil. Mainly used for the production of sulfuric acid for sulfate fertilizers.
Combustible liquid. Vapors are heavier than air.
Prevention
Keep away from heat, spark and flame. Do not breath gas
Response
If inhaled, remove person to fresh air
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Noise
Vibration
Temperature
Radiation
Illumination
Ergonomics
Slips
Noise
Noise is unwanted sound. Continuous noise tires the person. Excessive noise can cause damage to the eardrums
and increase the possibility of accidents because of the difficulty of hearing warning or instructions.
Noise levels (the pressure created by sound waves) is measured in Decibels-dB
There are instruments, which measure sound levels.
If people appear not to be bothered by level of noise this does not mean there is no problem. People do not get
used to noise they get deaf.
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Where the noise level is above 90dB the condition for the 85dB are applicable plus
The area must be restricted and marked with appropriate sign
Hearing protection becomes mandatory
Noise control
Machinery maintenance
Machinery insulation.
Noise wall barrier
PPE
Quite rooms for rest away from noise
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Vibration
Vibration often originates from the same source as noise. There are two types of vibration.
Whole body vibration
Segmental vibration
Whole body vibration such as that from sitting on a tractor leads to an increased oxygen
consumption, increased respiratory rate, increase cardiac output.
Segmental vibration usually results from the use of certain hand tools. These can cause constriction
of blood vessels leading to white finger. It can also lead to degeneration of nerves causing paralysis
and decrease sensitivity to touch and temperature as well as deformation of the bones of the wrist.
Temperature extremes
Extreme cold can cause tissue damage from hypothermia and frostbite with little discomfort or warning.
Extended exposure to low temperature may cause death.
High temperature is also problematic. Heat stress strains the cardiovascular system, causes cramps, heat
stroke and even death.
Illumination
Poor illumination can lead to both tiredness and mistake. Many workplaces have inadequate
illumination or poorly maintained illumination.
Dirty light covers
No emergency lights
Dirty windows
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Any purging and venting must be stopped for at least 10 minutes prior
to conducting the gas test, with the exception of maintaining a slight
positive pressure if required.
The Permit Issuer may increase the stoppage time if necessary for
larger vessels or equipment
Do not place gas detectors for measuring flammable gases directly into
the steam vapors while steaming out.
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1 Hour Rule
If more than an hour passes from the initial gas test and the work is not started the gas
test shall be conducted again prior starting of the job.
Work stoppage for any reason for more than one hour requires that revalidation by permit
issuer and permit receiver shall be done
To make sure there is sufficient Oxygen in the air to support the life.
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Poor or missing isolation has been the cause of many serious accidents. Do not rely on valves
except for quick jobs; use blinds or disconnection and blanking unless the job is so quick that
blinding (or disconnection) would take as long and be as hazardous as the main job. Valves used for
isolation (including isolation while fitting blinds or disconnecting) should be locked shut (for
example, by a padlock and chain). Blinds should be made to the same standard (pressure rating and
material of construction) as the plant. Plants should be designed so that blinds can be inserted without
difficulty; that is, there should be sufficient flexibility in the pipe work or a slip ring or figure-eight
plate should be used.
Electricity should be isolated by locking off or removal of fuses. Do not leave them lying around for
anyone to replace. Always try out electrical equipment after defusing to check that the correct fuses
have been withdrawn.
Many accidents have occurred because maintenance workers opened up the wrong equipment.
Equipment which is under repair should be numbered or labeled unambiguously. Temporary labels
should be used if there are no permanent ones. Pointing out the correct equipment is not sufficient. “The
pump you repaired last week is leaking again” is a recipe for an accident.
Equipment which is to be repaired should be freed as far as possible from hazardous materials. Gases
can be removed by sweeping out with nitrogen (if the gases are flammable) or air, water-soluble liquids
by washing with water, and oils by steaming. Some materials, such as heavy oils and materials that
polymerize are very difficult or impossible to remove completely. Tests should be carried out to make
sure that the concentration of any hazardous material remaining is below an agreed level. Machinery
should be in the lowest energy state. Thus the forks of forklift trucks should be lowered and springs
should not be compressed or extended. For some machinery, the lowest energy state is less obvious. Do
not work under heavy suspended loads.
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a) Physical Hazards
a) Chemical hazards
Fire
Burn injuries
Toxic gas release. Such as hydrogen sulfide
Spill
Leak
Explosion
Asphyxiation
Deficiency of oxygen
Hot Surface
Accidental discharge of steam, high pressure air
Failures to wear appropriate respiratory protection.
Inadequate working space
Inadequate ventilation
a) Electrical Hazards
Burn injury
Electrical shock
Fires from electrical short circuit.
a) Special Hazards
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Blinding / De-Blinding
Hazards / Consequences Precautions to be Taken
Exposure to hydrocarbons vapors Purge it with steam or nitrogen before opening the equipment if flammable / toxic gas is
while opening the flange. suspected.
Fire Use SCBA (Self-Containing Breathing Apparatus) while opening the flange in case any
Spillage of hydrocarbons after toxic or inert gas is suspected.
placing blind or spacer. Keep the fire water hose ready while opening any toxic gas service especially for H2S gas to
Injury to the personnel while absorb it.
spreading flanges and while opening Poke the drain point using L-shaped brass rod and ensure that it reaches inside the pipeline
the corroded fasteners using before opening the flange.
slugging wrench. Gas cutting. Follow Safe Work Permit Procedure HSE-S 201.Details of the precautions shall be clearly
mentioned in work permit under special precautions column.
Appraise the possible hazards to workmen before starting the job as well as in Tool box talk.
Use appropriate PPE as per the requirement.
Pyrophoric material to be removed by putting steam or super heated steam before opening
the equipment.
Pour water on the pyrophoric material if any after opening the equipment.
Use hydraulic torque wrench / nut splitter to loosen the flange fasteners instead of
hammering / gas cutting.
Keep a drum to collect the hydrocarbons while de-choking and transfer it to OWS system.
Ensure that blind provided in the process line is suitable for the fluid and test pressure.
Ensure the faces of flange and blind / spacer is matching with each other without any gap.
Closely supervise the draining activity.
Ensure that drain point is closed fully after carrying out draining operation.
Use hydraulic torque wrench / nut splitter to loosen the flange fasteners.
Take care to install pipe spreaders snugly to avoid hit and slips injuries.
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Insulation
Material Handling
Hazard/Consequences Precautions to be taken
Strains Manual handling
Sprains Correct positioning of feet
Fractures Knees to be bent.
Bruises Back to be kept straight
Breaking of sling, chains, Arms close to the body.
or ropes. Correct grip.
Falling of lifted loads Head in correct position
Use of body weight.
Mechanical Means
All lifting machines, chains, ropes, hoists and lifts to be thoroughly
examined by competent person. Hoist and lifts are to examined
every six months and other lifting machines are to inspected once in
a year.
Safe working load to be marked on all lifting machines and tackles
and it should not be exceeded except for the purpose of testing.
All lifting machines, chains, ropes and lifting tackles except fibre
rope or fibre sling, which have been lengthened, altered or repaired
by welding or otherwise, shall not be used again, unless it is
adequately tested and examined by competent person and certified
in writing by him to be in order.
Follow safe material handling procedure HSE-S-228
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Thank You
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